检索结果-南通市图书馆

Mechanistic insight into the synergy between nickel single atoms and nanoparticles on N-doped carbon for electroreduction of CO2

引用

Journal of Energy Chemistry 2025年第1期100卷 327-336页

作者： Mingdong Sun Wenwen Guan Cailing Chen Chao Wu Xiaoling Liu Biao Meng Tao Chen Yu Han Jun Wang Shibo Xi Yu Zhou State Key Laboratory of Materials-Oriented Chemical Engineering College of Chemical Engineering Nanjing Tech University Advanced Membranes and Porous Materials Center Physical Sciences and Engineering Division King Abdullah University of Science and Technology Institute of Sustainability for Chemicals Energy and Environment A*STAR (Agency for Science Technology and Research) College of Materials Science and Engineering Sichuan University

The synergy of single atoms （SAs） and nanoparticles （NPs） has demonstrated great potential in promoting the electrocatalytic carbon dioxide reduction reaction （CO2RR）;however,the rationalization of the SAs/NPs proportion remains one challenge for the catalyst ***,a Ni2+-loaded porous poly（ionic liquids）(PIL) precursor synthesized through the free radical self-polymerization of the ionic liquid monomer,1-allyl-3-vinylimidazolium chloride,was pyrolyzed to prepare the Ni,N co-doped carbon materials,in which the proportion of Ni SAs and NPs could be facilely modulated by controlling the annealing *** catalyst Ni-NC-1000 with a moderate proportion of Ni SAs and NPs exhibited high efficiency in the electrocatalytic conversion of CO2into *** Ni K-edge X-ray absorption near-edge structure （XANES） spectra and theoretical calculations were conducted to gain insight into the synergy of Ni SAs and *** charge transfer from Ni NPs to the surrounding carbon layer and then to the Ni SAs resulted in the electron-enriched Ni SAs active *** the electroreduction of CO2,the coexistence of Ni SAs and NPs strengthened the CO2activation and the affinity towards the key intermediate of*COOH,lowering the free energy for the potential-determining*CO2→*COOH step,and therefore promoted the catalysis efficiency.

关键词： Single atom catalyst Synergy effect carbon catalyst Electrocatalysis

来源：

同方期刊数据库评论

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

Filling the in situ-generated vacancies with metal cations captured by C-N bonds of defect-rich 3D carbon nanosheet for bifunctional oxygen electrocatalysis

引用

Journal of Energy Chemistry 2021年第8期30卷 47-54,I0002页

作者： Dawei Chen Wei Cao Jing Liu Jie Wang Xiaoke Li Luhua Jiang Nanomaterial&Electrocatalysis Laboratory College of Materials Science and EngineeringQingdao University of Science and TechnologyQingdao 266042China

Nitrogen-doped carbon materials with vacancies/defects have been developed as highly efficient ORR electrocatalysts but with poor activity for OER,which limits their application in rechargeable metal-air *** the vacancies/defects with heteroatoms is expected to be an effective strategy to obtain surprising catalytic activities and improve their stability especially under the strongly oxidizing conditions during the OER ***,we successfully transformed the defect-rich 3 D carbon nanosheets(DCN)into a bifunctional ORR/OER electrocatalyst(DCN-M)by utilizing the in-situ generated vacancies to capture metal cations via a modified salt-sealed *** varying the metal(Fe,Ni)content,the captured metal cations in DCN-M existed in different chemical states,i.e.,metal atoms were stabilized by CàN bonds at low metal contents,while at high metal contents,bimetal particles were covered by graphene layers,taking responsibility for catalyzing the ORR and OER,*** addition,the in-situ formed graphene layers with an interconnected structure facilitate the electron transport during the *** Janus-feature of DCN-M in structures ensures superior bifunctional activity and good stability towards ORR/OER for the rechargeable Zn-air *** work provides an effective strategy to design multifunctional electrocatalysts by heteroatom filling into vacancies of carbon materials.

关键词： carbon catalyst Vacancies/Defects Heteroatom filling Bifunctional oxygen electrocatalysis Rechargeable Zn-air battery

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

炼钢渣和炭的混合物用于微波辅助甲烷干气重整反应(英文)

引用

催化学报 2012年第7期33卷 1115-1118页

作者： Jose M. BERMUDEZ Beatriz FIDALGO Ana ARENILLAS J. Angel MENENDEZ Instituto Nacional del Carbón CSIC Apartado 73 Oviedo 33080 Spain

The use of steel-making slag as catalysts for microwave-assisted dry reforming of CH4 was studied. Two carbon materials (an activated carbon and a metallurgical coke), mixtures of the carbon materials and Fe-rich slag, and mixtures of the carbon materials and Ni/Al2O3 were tested as catalysts. The mixtures of slag with carbons gave rise to higher and steadier conversions than those achieved over the carbon materials alone. In addition, the use of the metallurgical coke mixed with metal-rich catalysts gave rise to remarkable results. Thus, no CH4 and CO2 conversions were achieved when coke was used alone, whereas high conversions were obtained when it was mixed with the metal-rich catalysts.

关键词： steel-making slag carbon catalyst dry reforming microwave heating

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Electrocatalytic generation of hydrogen peroxide on cobalt nanoparticles embedded in nitrogen-doped carbon

引用

Chinese Journal of Catalysis 2021年第12期42卷 2296-2305页

作者： Basil Sabri Rawah Wenzhen Li Chemical and Biological Engineering Department Biorenewables Research LaboratoryIowa State UniversityAmesIA 50011USA Chemical and Biological Engineering Department University of JeddahJeddah 23890Saudi Arabia

Electrocatalytic reduction of oxygen is a growing synthetic technique for the sustainable production of hydrogen peroxide(H_(2)O_(2)).The current challenges concern seeking low-cost,highly active,and selective ***-nitrogen-doped carbon containing catalytically active cobalt-nitrogen(Co-N_(x))sites is an emerging class of materials that can promote the electrochemical generation of H_(2)O_(2).Here,we report a straightforward method for the preparation of cobalt-nitrogen-doped carbon composed of a number of Co-N_(x)moieties using low-energy dry-state ball milling,followed by controlled *** scalable method uses inexpensive materials containing cobalt acetate,2-methylimidazole,and Ketjenblack EC-600JD as the metal,nitrogen,and carbon precursors,*** measurements in an acidic medium show the present material exhibits a significant increase in the oxygen reduction reaction current density,accompanied by shifting the onset potential into the positive *** current catalyst has also demonstrated an approximate 90%selectivity towards H_(2)O_(2)across a wide range of *** H_(2)O_(2)production rate,as measured by H_(2)O_(2)bulk electrolysis,has reached 100 mmol g_(cat).^(–1)h^(–1)with high H_(2)O_(2)faradaic efficiency close to 85%(for 2 h at 0.3 V ***).Lastly,the catalyst durability has been tested(for 6 h at 0.3 V ***).The catalyst has shown relatively consistent performance,while the overall faradic efficiency reaches approximate 85%throughout the test cycle indicating the promising catalyst durability for practical *** formed Co-N_(x)moieties,along with other parameters,including the acidic environment and the applied potential,likely are the primary reasons for such high activity and selectivity to H_(2)O_(2)production.

关键词： Hydrogen peroxide Two-electron oxygen reduction carbon catalyst Electrocatalysis

来源：

维普期刊数据库

同方期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

用于甲烷分解和甲烷二氧化碳重整的碳材料催化剂研究进展(英文)

引用

催化学报 2011年第2期32卷 207-216页

作者： Beatriz FIDALGO J.ngel MENNDEZ Instituto Nacional del Carbón (CSIC)

The decomposition and CO2 reforming of methane,respectively,are promising alternatives to industrial steam methane reforming. In recent years,research has been focused on the development of catalysts that can operate without getting deactivated by carbon deposition,where,in particular,carbon catalysts have shown positive results. In this work,the role of carbon materials in heterogeneous catalysis is assessed and publications on methane decomposition and CO2 reforming of methane over carbon materials are reviewed. The influence of textural properties(BET surface area and micropore volume,etc.) and oxygen surface groups on the catalytic activity of carbon materials are discussed. In addition,this review examines how activated carbon and carbon black catalysts,which are the most commonly used carbon catalysts,are deactivated. Characteristics of the carbon deposits from methane are discussed and the influence of the reactivity to CO2 of fresh carbon and carbonaceous deposits for high and steady conversion during CO2 reforming of CH4 are also considered.

关键词： carbon catalyst catalytic activity decomposition methane reforming

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

欢迎您,

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案：

请选择收藏分类：

通借通还

欢迎您,

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：