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Fluid inclusions,C-H-O-S-Pb isotope systematics,geochronology and geochemistry of the budunhua cu deposit,northeast China:Implications for ore genesis

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Geoscience Frontiers 2020年第4期11卷 1145-1161页

作者： Kaituo Shi Keyong Wang Xueli Ma Shunda Li Jian Li Rui Wang College of Earth Sciences Jilin UniversityChangchun130061China College of Geology and Mining Engineering Xinjiang UniversityUrumqi830047China MNR Key Laboratory of Mineral Resources Evaluation in Northeast Asia Changchun130061China

The budunhua cu deposit is located in the Tuquan ore-concentrated area of the southern Great Xing’an Range,NE China.This deposit includes the southern Jinjiling and northern Kongqueshan ore blocks,separated by the budunhua granitic pluton.cu mineralization occurs mainly as stockworks or veins in the outer contact zone between tonalite porphyry and Permian metasandstone.The ore-forming process can be divided into four stages involving stage Ⅰ quartz-pyrite-arsenopyrite;stage Ⅱ quartz-pyrite-chalcopyrite-pyrrhotite;stage Ⅲ quartz--polynetallic sulfides;and stage IV quartz-calcite.Three types of fluid inclusions(FIs) can be distinguished in the budunhua deposit:liquid-rich two-phase aqueous FIs(L-type),vapour-rich aqueous FIs(V-type),and daughter mineral-bearing multi-phase FIs(S-type).Quartz of stages Ⅰ-Ⅲ contains all types of FIs,whereas only L-type FIs are evident in stage Ⅳ veins.The coexisting V-and S-type FIs of stages Ⅰ-Ⅲ have similar homogenization temperatures but contrasting salinities,which indicates that fluid boiling occurred.The FIs of stages Ⅰ,Ⅱ,Ⅲ,and Ⅳyield homogenization temperatures of 265-396℃,245-350℃,200-300℃,and 90-228℃ with salinities of3.4-44.3 wt.%,2.9-40.2 wt.%,1.4-38.2 wt.%,and 0.9-9.2 wt.% NaCl eqv.,respectively.Ore-forming fluids of the budunhua deposit are characterized by high temperatures,moderate salinities,and relatively oxidizing conditions typical of an H2 O-NaCl fluid system.Mineralization in the budunhua deposit occurred at a depth of0.3-1.5 km,with fluid boiling and mixing likely being responsible for ore precipitation.C-H-O-S-Pb isotope studies indicate a predominantly magmatic origin for the ore-forming fluids and materials.LA-ICP-MS zircon U-Pb analyses indicate that ore-forming tonalite porphyry and post-ore dioritic porphyrite were formed at 151.1±1.1 Ma and 129.9±1.9 Ma,respectively.Geochemical data imply that the primary magma of the tonalite porphyry formed through partial melting of Neoproterozoic lower crust.On the basis of available evidence,we suggest that the Budun

关键词： Fluid inclusion C-H-O-S-Pb isotopes Zircon U-Pb geochronology Whole-rock geochemistry budunhua cu deposit Southern great Xing’an range

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