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Mechanism of internal thermal runaway propagation in blade batteries

Journal of Energy Chemistry 2024年第2期89卷 184-194,I0005页

作者： Xuning Feng Fangshu Zhang Wensheng Huang Yong Peng Chengshan Xu Minggao Ouyang School of Vehicle and Mobility Tsinghua UniversityBeijing 100084China

blade batteries are extensively used in electric vehicles,but unavoidable thermal runaway is an inherent threat to their safe *** study experimentally investigated the mechanism underlying thermal runaway propagation within a blade battery by using a nail to trigger thermal runaway and thermocouples to track its propagation inside a *** results showed that the internal thermal runaway could propagate for up to 272 s,which is comparable to that of a traditional battery *** velocity of the thermal runaway propagation fluctuated between 1 and 8 mm s^(-1),depending on both the electrolyte content and high-temperature gas *** the early stages of thermal runaway,the electrolyte participated in the reaction,which intensified the thermal runaway and accelerated its *** the battery temperature increased,the electrolyte evaporated,which attenuated the acceleration *** diffusion affected thermal runaway propagation through both heat transfer and mass *** experimental results indicated that gas diffusion accelerated the velocity of thermal runaway propagation by 36.84%.We used a 1D mathematical model and confirmed that convective heat transfer induced by gas diffusion increased the velocity of thermal runaway propagation by 5.46%-17.06%.Finally,the temperature rate curve was analyzed,and a three-stage mechanism for internal thermal runaway propagation was *** Stage I,convective heat transfer from electrolyte evaporation locally increased the temperature to 100℃.In Stage II,solid heat transfer locally increases the temperature to trigger thermal *** StageⅢ,thermal runaway sharply increases the local *** proposed mechanism sheds light on the internal thermal runaway propagation of blade batteries and offers valuable insights into safety considerations for future design.

关键词： Lithium-ion battery blade battery Thermal runaway Internal thermal runaway propagation

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