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Polyoxometalates‐doped Bi_(2)O_(3–x)/Bi photocatalyst for highly efficient visible‐light photodegradation of tetrabromobisphenol A and removal of NO

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Chinese Journal of Catalysis 2022年第3期43卷 771-781页

作者： Yingnan Zhao Xing Qin Xinyu Zhao Xin Wang Huaqiao Tan Huiying Sun Gang Yan Haiwei Li Wingkei Ho Shun‐cheng Lee Department of Science and Environmental Studies The Education University of Hong KongHong KongChina Key Laboratory of Polyoxometalate and Reticular Material Chemistry of Ministry of Education Faculty of ChemistryNortheast Normal UniversityChangchun 130024JilinChina College of Material Science and Engineering Jilin Jianzhu UniversityChangchun 130018JilinChina Department of Civil and Environmental Engineering The Hong Kong Polytechnic UniversityHong KongChina

bismuth‐based photocatalysts are a class of excellent visible‐light photocatalysts;however,their redox activity is relatively poor and the efficiency of photogenerated carrier separation is low,limiting their development and application in the field of *** address these issues,a series of polyoxometalate PW_(12)O_(40)^(3–)‐doped Bi_(2)O_(3–x)/Bi Schottky photocatalysts PW_(12)@Bi_(2)O_(3–x)/Bi‐n(PBOB‐n,where n is the amount of NaBH4,i.e.,6,12,18,24,and 48 mg)were prepared by a simple electrospinning/calcination/in‐situ NaBH4 reduction *** this composite photocatalyst,the doping of PW_(12) could effectively adjust the electronic structure of Bi_(2)O_(3–x) and improve its redox *** a shallow electron trap,PW_(12) promoted the separation of the photogenerated ***,desirable Schottky junction between the metal Bi nanoparticles and PW_(12)@Bi_(2)O_(3–x) further accelerated the separation of the photogenerated *** synergistic effect of the aforementioned factors endowed PBOB‐n with excellent photocatalytic *** the samples,PBOB‐18 exhibited superior photocatalytic *** visible‐light irradiation,93.7%(20 mg catalyst)of 20 ppm tetrabromobisphenol A(TBBPA,20 mL)was degraded in 60 *** activity was 4.4 times higher than that of Bi_(2)O_(3).PBOB‐18 also exhibited an ultrahigh photocatalytic performance for the removal of *** removal rate(600 ppb)reached 83.3%in 30 min,making it one of the most active Bi‐based ***,the photocatalytic mechanisms of PBOB‐18 for TBBPA and NO have been *** work provides a new direction and reference for the design of low‐cost,efficient,stable,and versatile photocatalysts.

关键词： bismuth‐based photocatalyst Polyoxometalates Bi Photocatalytic degradation NO removal

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