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Exploring aramid as emerging contender for CO_2 capture

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Chinese Journal of Chemical Engineering 2016年第7期24卷 850-855页

作者： Sonia Zulfiqar Muhammad Ilyas Sarwar Department of Chemistry School of Natural Sciences (SNS) National University of Sciences and Technology (NUST) Department of Chemistry Quaid-i-Azam University

To prevent CO_2 accumulation in the atmosphere generated from scorching of fossil fuels, carbon capture and sequestration(CCS) technology is considered as a potential route to mitigate the emissions of CO_2 from reaching the atmosphere. Power generation from sources such as gas, coal and biomass can fulfill the energy demand more readily than many other sources of electricity production. Thus these sources may be retained as important alternative option in the global energy cycle. In order to curtail CO_2, porous aramid network was fabricated by the condensation of 1,3,5-benzenetricarbonyl trichloride and 1,3-phenylenediamine in 1,4-dioxane solvent. aramid was characterized for various analyses including FTIR, XRD, TGA, BET surface area and pore size analysis, FESEM and CO_2 adsorption measurements. Excellent thermal stability was provided by strong amide linkages in the polymer backbone. Optimum CO_2 uptake of aramid was achieved to be 23.14 mg·g^(-1) at 273 K at 0.1 MPa. The basic amide groups of network structure showed greater affinity for CO_*** thermal stability of aramid makes it a promising sorbent for CO_2 capture in adverse conditions.

关键词：二氧化碳捕获竞争对手芳纶 BET比表面积 aramid 热稳定性生物质发电

Facile and effective synthesis strategy for terbium-doped hydroxyapatite toward photoelectric devices and flexible functional fibers

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Rare Metals 2024年第4期43卷 1713-1723页

作者： Xiao-Dong Zhang Kun Nie Zi-Yao Hu Ran-Ran Zhou Xiu-Qiang Duan Wu-Bin Dai Song-Song Nie Song-Jun Yao Luo-Xin Wang Le-Fu Mei Hua Wang Yi-Yi Yao Xiao-Xue Ma Hubei Key Laboratory for New Textile Materials and Applications and State Key Laboratory of New Textile Materials and Advanced Processing Technology School of Materials Science and EngineeringWuhan Textile UniversityWuhan430200China Key Laboratory of Testing and Tracing of Rare Earth Products for State Market Regulation Jiangxi University of Science and TechnologyGanzhou341000China Hubei Key Laboratory of Plasma Chemistry and Advanced Materials and Key Laboratory of Green Chemical Engineering Process of Ministry of Education Wuhan Institute of TechnologyWuhan430205China

As a material with good biocompatibility,hydroxyapatite(HAP)can have optical properties after doping with various rare earth *** a biocompatible fluorescent material,doped HAP could have broad applications in biological probes,drug delivery,optoelectronic materials,fluorescence anti-counterfeiting,and other *** this paper,we put forward the preparation of HAP doped with terbium(Ⅲ)ions(Tb^(3+))by hydrothermal *** controlling the Tb^(3+)doping content in reaction and the reaction time,the changes in HAP's structure,morphology,and luminescence properties under different conditions were *** the doping amount of Tb^(3+)reached an optimal value,the dipole-quadrupole would occur and the concentration would be *** control experiment showed that the optimal Tb3+content was 7.5×10^(-5)mol,which showed the best fluorescence ***,a non-luminous material,was rarely used in the field of fluorescent anti-counterfeiting and photoelectric *** proposed to prepare a luminescent aramid/polyphenylene sulfide(ACFs/PPS)fiber paper and a new light-emitting diode(LED)using the Tb-doped HAP *** composite sample exhibited an excellent stability and fluorescence performance,which also demonstrated a possibility of HAP applications in anticounterfeiting and *** introduction of Tb3+dopant HAP was done to give HAP optical properties and broaden the application range of HAP.

关键词： Hydroxyapatite Rare earth luminescence Photoelectric device aramid Polyphenylene sulfide fiber paper Luminescent fiber

Effect of the Weaving Density of aramid Fabrics on Their Resistance to Ballistic Impacts

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Engineering（科研） 2012年第12期4卷 944-949页

作者： Jung Seop Lim Bum Hoon Lee Chang Bae Lee In-Sik Han Kolon Central Research Park Kolon Industries Inc. Cumi-Si Korea R&D Center LG Hausys Anyang City Korea

Two Heracron? woven fabrics, HT600-1 and HT600-2, were fabricated with different weaving densities and their resistance to ballistic impact was investigated. While HT600-1 was inherently stronger along the weft than HT600-2, the latter exhibited a higher tensile strength along the warp. Crimp values indicate that HT600-1, which possesses a relatively larger weft weaving density, induces an excess in the warp crimp ratio, thereby weakening the fabric along the warp. The dimensionless fiber property U*, which is defined as the product of the specific fiber toughness and the strain wave velocity, was calculated for each fabric. The U* values of HT600-1 were lower than those of HT600-2;U* values along the warp of HT600-1 were extremely low. These analyses show that HT600-2 exhibited improved ballistic properties over those of HT600-1. These findings further indicate the existence of an optimal weave that would minimize damage to both yarn and fabric. Establishing these optimal conditions can be crucial in implementing better ballistic properties into fabrics.

关键词： aramid Fiber Fabrics/Textiles Impact Behavior

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卷曲性的芳纶（aramid）纤维

技术创新 2003年第2期 14-15页

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芳族聚酰胺(aramid)纤维摩擦片

世界汽车 1986年第4期 55-60页

作者： U.Schwartzkopff 吴自勤

一、芳族聚酰胺(aramid)纤维的化学结构 aramid纤维是一种工程上用的有机化学纤维。它的化学符号为Poly(P-苯基亚邻苯乙酰胺),见图1。其原始单体是: (a)对苯二胺(Para-Phenylendia-

关键词：衬片构成成分制动器机械元件 aramid 石棉线芳族

基于三维芳纶纳米纤维骨架的柔性高压复合电解质膜及其固态锂金属电池

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Science China Materials 2020年第5期63卷 703-718页

作者：刘乐浩吕婧莫金珊彭鹏李静如姜冰褚立华李美成 State Key Laboratory of Alternate Electrical Power System with Renewable Energy Sources School of Renewable EnergyNorth China Electric Power UniversityBeijing 102206China Suzhou Institute of Nano-tech and Nano-bionics Chinese Academy of SciencesSuzhou 215123China

聚合物电解质在锂金属电池中的应用受限于锂枝晶生长、电化学不稳定性及较低的离子电导率.为解决这些问题,本文通过向三维多孔芳纶纳米纤维(ANF)中填充聚环氧乙烷(PEO)-双三氟甲基磺酰亚胺锂(LiTFSI)电解质,制备了基于三维芳纶纳米纤维... 详细信息

聚合物电解质在锂金属电池中的应用受限于锂枝晶生长、电化学不稳定性及较低的离子电导率.为解决这些问题,本文通过向三维多孔芳纶纳米纤维(ANF)中填充聚环氧乙烷(PEO)-双三氟甲基磺酰亚胺锂(LiTFSI)电解质,制备了基于三维芳纶纳米纤维网络骨架的柔性ANF/PEO-LiTFSI复合电解质薄膜.由于其独特的构造及离子在三维ANF/PEO-LiTFSI界面中的连续输运,该复合电解质膜具有比PEO-LiTFSI电解质膜更高的力学强度(10.0 MPa)、热稳定性、电化学稳定性(60℃下达4.6 V)和离子电导率,以及较强的抑制锂枝晶能力.基于该复合电解质的固态LiFePO4/Li电池表现出优异的循环性能(在0.4 C下充放电百次后的容量达130 mA h g-1、保持率为93%).该研究提供了一种基于三维骨架设计和制备高性能电解质的有效方法,有望应用于固态锂金属电池.

关键词： composite electrolyte aramid nanofiber threedimensional scaffold mechanical stability Li metal battery

国产芳纶上浆剂对聚三唑复合材料力学性能的影响

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表面技术 2014年第4期43卷 17-23,42页

作者：李智鹏扈艳红杜磊刘冬冬华东理工大学材料科学与工程学院上海200237 特种功能高分子材料及相关技术教育部重点实验室(华东理工大学) 上海200237

目的研究国产芳纶纤维DAF-III表面上浆剂的主要成分及其对复合材料界面性能的影响。方法用丙酮溶剂抽提纤维一定时间,分析对比去除上浆剂前后的纤维和抽提溶液,并制备DAF-III增强的聚三唑树脂复合材料,测试复合材料的力学性能。结果国产... 详细信息

目的研究国产芳纶纤维DAF-III表面上浆剂的主要成分及其对复合材料界面性能的影响。方法用丙酮溶剂抽提纤维一定时间,分析对比去除上浆剂前后的纤维和抽提溶液,并制备DAF-III增强的聚三唑树脂复合材料,测试复合材料的力学性能。结果国产DAF-III芳纶纤维的主体结构是聚酰胺苯并咪唑,表面上浆剂主要组分是脂肪族酯类低聚物。溶剂抽提去除了纤维表面大部分上浆剂,裸露的纤维本体存在制备过程中形成的沿纤维方向的大量沟壑;去除上浆剂后,复合材料的ILSS和弯曲强度分别提高了181.2%和56.20%。结论纤维表面上浆剂对纤维以及纤维增强的复合材料力学性能影响显著,纤维与树脂通过机械锚合和氢键作用改善界面粘接。

关键词：上浆剂纤维增强复合材料聚酰胺苯并咪唑 domestic aramid fiber (DAF-III)

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芳纶Ⅲ与芳纶Ⅱ防弹性能研究

高科技纤维与应用 2014年第1期39卷 40-44页

作者：刘克杰高虹黄继庆黄献聪王凤德彭涛中蓝晨光化工研究设计院有限公司成都610041 北京雷特新技术实业公司北京100074 总后勤部军需装备研究所北京100010

选用两种不同型号芳纶,通过单向复合工艺分别制造成靶板。以NIJⅢA标准通过弹道试验,测试出两种靶板的弹坑凹陷深度与子弹穿透层数差异,并进一步通过测试两种芳纶SEA值比较其防弹性能差别,结果表明,芳纶Ⅲ抗弹性能比芳纶Ⅱ提高近30%。... 详细信息

选用两种不同型号芳纶,通过单向复合工艺分别制造成靶板。以NIJⅢA标准通过弹道试验,测试出两种靶板的弹坑凹陷深度与子弹穿透层数差异,并进一步通过测试两种芳纶SEA值比较其防弹性能差别,结果表明,芳纶Ⅲ抗弹性能比芳纶Ⅱ提高近30%。最后讨论了纤维力学性能对其防弹性能的影响,指出更高的拉伸强度和断裂伸长率是芳纶Ⅲ抗弹性能更优的主要原因,并预测芳纶Ⅲ的抗弹性能还有进一步提升的空间。

关键词：芳纶Ⅲ 芳纶Ⅱ 防弹性能研究 aramid Ⅲ aramid Ⅱ

Ballistic Behavior of Heracron<sup>&reg</sup>-Based Composites: Effect of the Number Multifilaments on High-Speed Projectiles

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Modeling and Numerical Simulation of Material Science 2013年第3期3卷 84-89页

作者： Jung Seop Lim Samsung Electronics Suwon South Korea

In this study, two Heracron? woven fabrics, HT840-1 and HT840-2, were fabricated with different multifilament fibers, and their resistance to ballistic impact was investigated. For the same weight and number of plies, the HT840-2 fabric showed improved ballistic properties, compared with HT840-1;this result is contrary to the fiber and fabric properties. With the exception of the yarn’s physical properties, this behavior can be explained in terms of the number of multifilaments, which strongly influenced the ballistic mechanism, i.e., a greater number of multifilament fibers facilitates energy dissipation from a high-speed ballistic projectile. In summary, establishing this optimal number of multifilaments is the key to optimizing the ballistic properties of any given fabric.

关键词： aramid Fiber Ballistic Behavior Heracron Soft Armor