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amine axial ligand-coordinated cobalt phthalocyanine-based catalyst for flow-type membraneless hydrogen peroxide fuel cell or enzymatic biofuel cell

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Journal of Energy Chemistry 2021年第7期30卷 463-471页

作者： Heeyeon An Hyewon Jeon Jungyeon Ji Yongchai Kwon Yongjin Chung Department of Chemical and Biological Engineering Korea National University of Transportation50 Daehak-roChungjuChungbuk 27469Republic of Korea Graduate School of Energy and Environment Seoul National University of Science and Technology 232 Gongneung-roNowon-guSeoul 01811Republic of Korea Department of Chemical and Biomolecular Engineering Seoul National University of Science and Technology232 Gongneung-roNowon-guSeoul 01811Republic of Korea Department of ITÁEnergy Convergence(BK21 FOUR) Korea National University of Transportation50 Daehak-roChungjuChungbuk 27469Republic of Korea

In this study,an amine-coordinated cobalt phthalocyanine(CoPc)-based anodic catalyst was fabricated by a facile process,to enhance the performance of hydrogen peroxide fuel cells(HPFCs) and enzymatic biofuel cells(EBCs).For this purpose,polyethyleneimine(PEI) was added onto the reduced graphene oxide and CoPc composite(RGO/CoPc) to create abundant NH2 axial ligand groups,for anchoring the Co core within the *** to the PEI addition,the onset potential of the hydrogen peroxide oxidation reaction was shifted by 0.13 V in the negative direction(0.02 V) and the current density was improved by 1.92 times(1.297 mA cm^(-2)),compared to those for RGO/CoPc(0.15 V and 0.676 mA cm^(-2),respectively),due to the formation of donor-acceptor dyads and the prevention of CoPc from leaching *** biocatalyst using glucose oxidase(GOx)([RGO/CoPc]/PEI/GOx) showed a better onset potential and catalytic activity(0.15 V and 318.7 μA cm^(-2)) than comparable structures,as well as significantly improved operational durability and long-term *** is also attributed to PEI,which created a favorable microenvironment for the *** maximum power densities(MPDs) and open-circuit voltages(OCVs) obtained for HPFCs and EBCs using the suggested catalyst were 105.2±1.3 μW cm^(-2)(0.317±0.003 V) and 25.4±0.9 μW cm^(-2)(0.283±0.007 V),*** shows that the amine axial ligand effectively improves the performance of the actual driving HPFCs and EBCs.

关键词： Hydrogen peroxide fuel cell Enzymatic biofuel cell amine axial ligand Hydrogen peroxide oxidation reaction Membraneless

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