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The latest development on amine functionalized solid adsorbents for post-combustion CO_(2)capture:Analysis review

Chinese Journal of Chemical Engineering 2021年第7期34卷 17-43页

作者： Peiyu Zhao Guojie Zhang Huangyu Yan Yuqiong Zhao Heze Branch Qilu University of Technology(Shandong Academy of Sciences)Biological Engineering Technology Innovation Center of Shandong ProvinceHeze 274000China Key Laboratory of Coal Science and Technology Ministry of Education and Shanxi ProvinceTaiyuan University of TechnologyTaiyuan 030024China

Global warming and associated global climate change have led to serious efforts towards reducing CO_(2)emissions through the CO_(2)capture from the major emission ***_(2)capture using the amine functionalized adsorbents is regard as a direct and effective way to reducing CO_(2)emissions due to their large CO_(2)adsorption amount,excellent CO_(2)adsorption selectivity and lower energy requirements for adsorbent ***,large number of achievements on the amine functionalized solid adsorbent have been recorded for the enhanced CO_(2)capture in the past few *** view of this,we review and analyze the recent advances in amine functionalized solid adsorbents prepared with different supporting materials including mesoporous silica,zeolite,porous carbon materials,metal organic frameworks(MOF)and other composite porous *** addition,amine functionalized solid adsorbents derived from waste resources are also reviewed because of the large number demand for cost-effective carbon dioxide adsorbents and the processing needs of waste *** the importance of the stability of the adsorbent in practical applications,advanced research in the capture cycle stability has also been summarized and ***,we summarize the review and offer the recommendations for the development of amine-based solid adsorbents for carbon dioxide capture.

关键词： Solid adsorbents amine functionalized CO_(2)capture Adsorption Review

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Synthesis and Structure of a Host-Guest Inclusion System between C-propyl-o-toluidine-methyl-resorcin[4]arene and Ethanol Solvate

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Journal of Materials Science and Chemical Engineering 2023年第12期11卷 22-33页

作者： Lusi Chen Rurou Jiang Huatian Shi Aiquan Jia Qianfeng Zhang Institute of Molecular Engineering and Applied Chemistry Anhui University of Technology Ma’anshan China

Tetra-bromo-methyl-resorcin[4]arene cavitands were synthesized and C-2 position amine functionalized to obtain C-propyl-o-toluidine-methyl-resorcin[4]arene cavitand 4, and the crystal containing one solvate molecule of ethanol was obtained in a dichloromethane-ethanol solvent system, its structure crystallized in the monoclinic space group P21/n, with a = 12.521(3) Å, b = 21.738(6) Å, c = 25.353(6) Å, α = 90˚, β = 102.372(4)˚, γ = 90˚, and Z = 4. The compound was determined by single-crystal X-ray diffraction and characterized by 1H NMR, FT-IR and elemental analyses.

关键词： Resorcinarene Cavitand amine functionalized Dichloromethane-Ethanol

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