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AN IMPROVED METHOD FOR PREPARING 2—alkoxy—5—FLUORO—3H—4—PYRIMIDONE~△

Chinese Chemical Letters 1993年第7期4卷 591-592页

作者： Chang Jun SUN Zai Cheng CHEN Yi MENG Yi Gui WANG Peng XUE Jian Guo ZHANG Gui Xiang CUI Department of Chemistry, Shandong University, Jinan 250100

In this paper, we report an improved method for preparing 2--alkoxy 5 fluoro--3H --4--pyrimidone from 2--chloro--5--fluoro--3H--4--pyrimidone and sodium alkoxide under normal pressure at reflux temperature. Some new c... 详细信息

关键词： alkoxy AN IMPROVED METHOD FOR PREPARING 2 FLUORO PYRIMIDONE

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SYNTHESIS AND POLYMERIZATION OF γ-alkoxy β-HYDROXYPROPYL ACRYLATES

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Chinese Science Bulletin 1980年第2期25卷 149-153页

作者：陆承勋程乃春顾忠伟冯新德 VOONG SING-TUH) (Department of Chemistry Beijing University

As a biomedical hydrogel, poly(β-hydroxyethyl methacrylate)has been widely studied and discussed, but studies on the synthesis and polymerization of those acrylates which contain both hydrophilic hydroxy group and alkoxy group in the same ester group have received comparatively less attention. However Mikhailov first reported the synthesis of some γ-alkoxy-β-hydroxypropyl methacrylates and γ-aryloxy β-hydroxypropyl methacrylates from methacrylic acid and γ-alkoxy propylene or γ-

关键词： hydroxypropyl hydroxyethyl methacrylate polymerization hydrophilic propylene biomedical alkoxy hydrogel initiator

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Hydrodeoxygenation of anisole over different Rh surfaces

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Chinese Journal of Catalysis 2019年第11期40卷 1721-1730页

作者： Nhung N. Duong Darius Aruho Bin Wang Daniel E. Resasco School of Chemical Biological and Materials Engineering (CBME) Center for Interfacial Reaction Engineering (CIRE) University of Oklahoma Norman OK 73019 USA School of Biotechnology International University Vietnam National University Ho Chi Minh City 700000 Vietnam

The cleavage of the alkoxy(Ar-O-R) ether bond present in anisole is an interesting hydrodeoxygenation(HDO) reaction, since this asymmetric group contains two different C–O bonds, Caryl–O or Calkyl–O, which could potentially cleave. Recent work on the HDO of anisole over Pt, Ru, and Fe catalysts has shown that a common phenoxy surface intermediate is formed on all three metals. The subsequent reaction path of this intermediate varies from metal to metal, depending on the metal oxophilicity. Over the less oxophilic Pt, phenol is the only primary product. By contrast, on the more oxophilic Fe catalyst, the sole primary product is benzene instead of phenol. On Ru, with intermediate oxophilicity, both benzene and phenol are primary products. In this contribution, we have investigated Rh catalysts of varying surface nanostructures. A combination of experimental measurements and computational calculations was used to explore the effects of varying metal coordination number, an additional parameter that can be used to control the oxophilicity of a metal. The results confirm that metal oxophilicity is a good descriptor for HDO performance of metal catalysts and it can be controlled via selection of metal type and/or metal extent of coordination. Small Rh metal clusters with low coordination metal sites are more active for the deoxygenation pathway but also quickly deactivated while large clusters with high coordination sites are more active toward hydrogenation and more stable.

关键词： Hydrodeoxygenation Anisole alkoxy Oxophilicity Phenolic Surface defects

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