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Chemical Research in Chinese Universities 2024年第1期40卷 127-135页

作者： Yan Jiali Yang Kaiying Wang Xi Zhai Jinli Zhu Wenjie Yang Daoli Luo Yongming Gao Xiaoya Faculty of Environmental Science and Engineering Kunming University of Science and TechnologyKunming650500P.R.China Innovation Team for Volatile Organic Compounds Pollutants Control and Resource Utilization of Yunnan Province Kunming650500P.R.China Higher Educational Key Laboratory for Odorous Volatile Organic Compounds Pollutants Control of Yunnan Province Kunming650500P.R.China

Maximizing the sustainable recycling of spent lithium-ion batteries(LIBs)shows economic and environmental significance.This study recovered lithium cobaltate(LiCoO_(2),LCO)from spent LIBs cathode powder.The recovered LCO was then combined with NaHSO_(3)to remove refractory organic pollutants of carbamazepine(CBZ)in water.The degradation of CBZ reached 80.0%within 60 min,by 1O_(2),SO_(4),OH and O_(2)^(-)generated in the LCO/NaHSO_(3)reaction.The electron transfer between Co(III)and Co(II)was beneficial to the generation of free radicals.The LCO/NaHSO_(3)degraded CBZ effectively in both secondary outlet water and tap water.However,high concentrations of inorganic ions(Cl^(−),HCO_(3)^(-),HPO_(4)^(2-),SO_(2)−4,NO_(3)^(-))and natural organic matter(humic acid,HA)could inhibit the degradation of CBZ.After three cycles,the stability of the LCO/NaHSO_(3)system was demonstrated by the maintained high efficiency in the degradation of CBZ.The obtained data indicate that the LCO/NaHSO_(3)system holds great application potential in the field of advanced oxidation degradation of pollutants.

关键词： Spent lithium-ion battery Lithium cobaltate Carbamazepine NaHSO_(3) advanced oxidation

Identification and characterization of Fe_(3)O_(4)/peroxodisulfate advanced oxidation products from sulfameter

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Journal of Environmental Sciences 2022年第12期34卷 227-235页

作者： Jie Du Zhijun An Yufeng Hu Xianliang Yi Hao Zhou Jingjing Zhan Minghuo Wu School of Ocean Science and Technology Dalian University of TechnologyPanjin 124221China

Sulfonamides(SAs)are one of the most widely used antibiotics and their residuals in the environment could cause some negative environmental issues.advanced oxidation such as Fenton-like reaction has been widely applied in the treatment of SAs polluted water.Degradation rates of 95%-99.7%were achieved in this work for the tested 8 SAs,including sulfisomidine,sulfameter(SME),phthalylsulfathiazole,sulfamethoxypyridazine,sulfamonomethoxine,sulfisoxazole,sulfachloropyridazine,and sulfadimethoxine,in the Fe_(3)O_(4)/peroxodisulfate(PDS)oxidation system after the optimization of PDS concentration and p H.Meanwhile,it was found that a lot of unknown oxidation products were formed,which brought up the uncertainty of health risks to the environment,and the identification of these unknown products was critical.Therefore,SME was selected as the model compound,from which the oxidation products were never elucidated,to identify these intermediates/products.With liquid chromatography-high resolution tandem mass spectrometry(LC-HRMS/MS),10 new products were identified,in which 2-amino-5-methoxypyrimidine(AMP)was confirmed by its standard.The investigation of the oxidation process of SME indicated that most of the products were not stable and the degradation pathways were very complicated as multiple reactions,such as oxidation of the amino group,SO_(2)extrusion,and potential cross-reaction occurred simultaneously.Though most of the products were not verified due to the lack of standards,our results could be helpful in the evaluation of the treatment performance of SAs containing wastewater.

关键词： advanced oxidation Sulfonamides LC-HRMS/MS Identification Degradation products

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Three-dimensional heterogeneous electro-Fenton system with reduced graphene oxide based particle electrode for Acyclovir removal

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Chinese Chemical Letters 2024年第1期35卷 424-430页

作者： Nan Cai Ge Bai Ting Zhang Yongqian Lei Pengran Guo Zhiliang Chen Jingwei Xu Guangdong Provincial Key Laboratory of Chemical Measurement and Emergency Test Technology Guangdong Provincial Engineering Research Center for Online Monitoring of Water PollutionInstitute of AnalysisGuangdong Academy of Sciences(China National Analytical CenterGuangzhou)Guangzhou 510070China College of Petrochemical Engineering Lanzhou University of TechnologyLanzhou 730000China Guangdong Engineering Technology Research Center of Heavy Metal Pollution Control and Restoration in Farmland Soil South China Institute of Environmental SciencesMEEGuangzhou 510535China

New pollutant pharmaceutical and personal care products(PPCPs),especially antiviral drugs,have received increasing attention not only due to their increase in usage after the outbreak of COVID-19 epidemics but also due to their adverse impacts on water ecological environment.Electro-Fenton technology is an effective method to remove PPCPs from water.Novel particle electrodes(MMT/rGO/Fe_(3)O_(4))were synthesized by depositing Fe3O4 nanoparticles on reduced graphene oxide modified montmorillonite and acted as catalysts to promote oxidation performance in a three-dimensional electro-Fenton(3D-EF)system.The electrodes combined the catalytic property of Fe3O4,hydrophilicity of montmorillonite and electrical conductivity of graphene oxides,and applied for the degradation of Acyclovir(ACV)with high efficiency and ease of operation.At optimal condition,the degradation rate of ACV reached 100%within 120 min,and the applicable pH range could be 3 to 11 in the 3D-EF system.The stability and reusability of MMT/rGO/Fe_(3)O_(4)particle electrodes were also studied,the removal rate of ACV remained at 92%after 10 cycles,which was just slightly lower than that of the first cycle.Potential degradation mechanisms were also proposed by methanol quenching tests and FT-ICR-MS.

关键词： advanced oxidation Three-dimensional electro-Fenton Reduced graphene oxide Acyclovir(ACV) Degradation

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Technique for advanced Electrochemical oxidation Treatment of Nanofiltration Concentrate of Landfill Leachate

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Wuhan University Journal of Natural Sciences 2014年第4期19卷 355-360页

作者： XIONG Changgui LI Guang ZHANG Zhiliang XIA Zhengwu LI Jian YE Hongji Sinosteel Wuhan Safety and Environmental Protection Research Institute Co. LTD Wuhan Weimeng Environmental Protection Technology Co. LTD

Landfill leachate treated with combined process of ＂pretreatment ＋biological treatment ＋advanced treatment （NF）＂ to produce nanofiltration concentrate, which bio-chemical ratio （B/C） is less than 0.1 and CODer concentration is 2 000-2 500 mg/L, high salt content. Which cannot be discharged under existing environ- mental standards. According to analysis based on electrochemical advanced oxidation mechanism, a two-step electrochemical tech- nique was recommended. In the first step, a pulse electrochemical technique was adopted. With Fe as consumption electrode and current density of 10 mA/cm2, the pollutants were removed by means of Fenton reaction, electroflotation and electrocoagulation. In the second step, a double function electrode was used to per- form electrocatalytic oxidation by means of titanium metallic oxi- dates. In the condition that current density being 12.5 mA/cm2, the pollutants were further removed by oxidation and electrolytic deposition. Result shows that the removing rate of CODer, NH3-N and CI were 70%-85%, 90% and 25%, respectively; average value of B/C ratio increased from 0.09 to 0.38 and conductivity reduced by 10%.

关键词： nanofiltration concentrate of landfill leachate elec-trochemistry advanced oxidation pulse electrode pollutants

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Performance of a Demonstrative (Scale-Pilot) Double advanced oxidation Wastewater Treatment Plant to Treat Discharges from a Small Community in Morelia, Michoacán, México

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Journal of Environmental Science and Engineering(B) 2021年第1期10卷 1-8页

作者： Alfonso Espitia-Cabrera Franciso Javier Barrón-Santos Berenice Quintana-Díaz Héctor Herrera-Bucio Rafael Soto-Espitia Griselda González-Cardoso Energy Department Metropolitan Autonomous UniversityAzcapotzalco CDMX 02200Mexico Postgraduate Department Occupational Health Safety and HygieneNational School of Medicine and HomeopathyNational Polytechnic InstituteCiudad de MéxicoCDMX 07320México Basic Sciences Department Metropolitan Autonomous UniversityAzcapotzalco CDMX 02200Mexico Construction HeBui Civil Engineering Faculty Michoacán UniversityUMSNHMorelia 58030MichoacanMexico

This paper,reports the performance of a wastewater treatment scale-pilot plant to treat 2 GPM(Gallons per Minute)discharges with 5,205 mg/L of pollutants expressed in COD(Chemical Oxygen Demand),from“Lomas de la Maestransa”a small community in Morelia City,Michoacan,Mexico.The scale-pilot plant is a train with(1)pretreatment with a triturated pump for floating solid,(2)primary treatment with“in line”coagulation,and rapid filtration to retain suspended colloids and dissolved solids higher of 5μm diameter,(3)double advanced oxidation as secondary treatment with ozone and heterogeneous photo catalysis to oxidize volatile solids,and(4)tertiary treatment with activated carbon to retain refractory compounds.Plant performance was analyzed by a certified laboratory that belongs to Potable Water,Sewage and Sanitation Department from Morelia City Government.Results show that treated water effluent complied with the Mexican Official Standard NOM-001-SEMARNAT-1996 for discharges into national waters,with exception of fecal coliforms,since the raw water contains an average of 64,228,351 MNP/100 mL of fecal coliforms,and in spite that we obtained a 99.998%efficiency,the maximum level allowable 2,000 MPN/100 mL standard,was exceeded by 400 MPN/100 mL.After this experience,the wastewater treatment plant is equipped with a residual chlorine tank to keep a 1.5 ppm chlorine residual concentration to keep the treated water clean.This project was possible because we had the support of the Morelia Sanitation Department.

关键词： Secondary treatment advanced oxidation heterogeneous photo catalysis “in line”coagulation nitrogen compound reduction.

DEGRADATION OF ATRAZINE BY advanced oxidation PROCESSES

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DEGRADATION OF ATRAZINE BY ADVANCED OXIDATION PROCESSES

Sustainable Generation of Sulfate Radicals and Decontamination of Micropollutants via Sequential Electrochemistry

Sixteenth International Water Technology Conference

作者： R.Kidak S.Dogan Cyprus International University Faculty of Engineering Department of Environmental Engineering Turkey

advanced oxidation processes like ozonation（O3） and ultrasonic irradiation（US） can be employed for the removal of recalcitrant compounds from water matrices. Atrazine is a pesticide which has been banned in the EU countries, since it is toxic and potentially carcinogenic even in very small concentrations. After their use in agricultural areas, the pesticides tend to leave residuals on the soil and in the surface waters or the groundwaters. The degradation of atrazine was studied by scientists before, but they could not get very high removal rates with the conventional wastewater treatment techniques. This study includes the investigation of the efficiency of O3 and US and also of their combined application（US + O3） for the degradation and potential mineralization of atrazine in water. Under the conditions applied, all three systems proved to be effective in inducing atrazine oxidation, leading to 95% removal for O3 and 78% for US after 90 min of treatment. The synergy observed in the combined schemes, mainly due to the effects of US in enhancing the O3 decomposition, led to higher removal（100%） for 20 min treatment. The synergy was so efficient that the results showed significantly higher removal level for shorter treatment duration.

关键词： Atrazine advanced oxidation Ultrasound Irradiation Ozonation

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Engineering 2023年第11期30卷 144-152页

作者： Wentian Zheng Shijie You Yuan Yao Nanqi Ren Bin Ding Fang Li Yanbiao Liu College of Environmental Science and Engineering Donghua UniversityShanghai 201620China State Key Laboratory of Urban Water Resource and Environment School of EnvironmentHarbin Institute of TechnologyHarbin 150090China MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage School of Chemistry and Chemical EngineeringHarbin Institute of TechnologyHarbin 150080China Innovation Center for Textile Science and Technology College of TextilesDonghua UniversityShanghai 200051China Shanghai Institute of Pollution Control and Ecological Security Shanghai 200092China

The removal of emerging micropollutants in the aquatic environment remains a global challenge.Conventional routes are often chemically,energetically,and operationally intensive,which decreases their sustainability during applications.Herein,we develop an advanced chemical-free strategy for micropollutants decontamination that is solely based on sequential electrochemistry involving ubiquitous sulfate anions in natural and engineered waters.This can be achieved via a chain reaction initiated by electrocatalytic anodic sulfate(SO_(4)^(2-))oxidation to produce persulfate(S_(2)O_(8)^(2-))and followed by a cathodic persulfate reduction to produce sulfate radicals(SO_(4)^(·-)).These SO_(4)^(·-)are powerful reactive species that enable the unselective degradation of micropollutants and yield SO_(4)^(2-)again in the treated water.The proposed flow-through electrochemical system achieves the efficient degradation(100.0%)and total organic carbon removal(65.0%)of aniline under optimized conditions with a single-pass mode.We also reveal the effectiveness of the proposed system for the degradation of a wide array of emerging micropollutants over a broad pH range and in complex matrices.This work provides the first proof-ofconcept demonstration using ubiquitous sulfate for micropollutants decontamination,making water purification more sustainable and more economical.

关键词： advanced oxidation Chain reaction Sulfate radical Micropollutants Sequential electrochemistry

Nonradical-dominated peroxymonosulfate activation through bimetallic Fe/Mn-loaded hydroxyl-rich biochar for efficient degradation of tetracycline

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Nano Research 2023年第1期16卷 155-165页

作者： Yihui Li Deying Lin Yongfu Li Peikun Jiang Xiaobo Fang Bing Yu State Key Laboratory of Subtropical Silviculture Zhejiang Agriculture and Forestry UniversityHangzhou 311300China School of Environment and Resources Zhejiang Agriculture and Forestry UniversityHangzhou 311300China

Biochar-based transition metal catalysts have been identified as excellent peroxymonosulfate(PMS)activators for producing radicals used to degrade organic pollutants.However,the radical-dominated pathways for PMS activation severely limit their practical applications in the degradation of organic pollutants from wastewater due to side reactions between radicals and the coexisting anions.Herein,bimetallic Fe/Mn-loaded hydroxyl-rich biochar(FeMn-OH-BC)is synthesized to activate PMS through nonradical-dominated pathways.The as-prepared FeMn-OH-BC exhibits excellent catalytic activity for degrading tetracycline at broad pH conditions ranging from 5 to 9,and about 85.0%of tetracycline is removed in 40 min.Experiments on studying the influences of various anions(HCO_(3)^(−),NO_(3)^(−),and H_(2)PO_(4)^(−))show that the inhibiting effect is negligible,suggesting that the FeMn-OHBC based PMS activation is dominated by nonradical pathways.Electron paramagnetic resonance measurements and quenching tests provide direct evidence to confirm that 1O2 is the major reactive oxygen species generated from FeMn-OH-BC based PMS activation.Theoretical calculations further reveal that the FeMn-OH sites in FeMn-OH-BC are dominant active sites for PMS activation,which have higher adsorption energy and stronger oxidative activity towards PMS than OH-BC sites.This work provides a new route for driving PMS activation by biochar-based transition metal catalysts through nonradical pathways.

关键词： biochar peroxymonosulfate activation tetracycline degradation advanced oxidation nonradical pathways

Reviews:Microwave-induced oxidation technology and its applications

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Progress in Natural Science:Materials International 2022年第6期32卷 665-673页

作者： Lintao Tian Guocheng Lv Meng Liu Xinyu Lei Wenxiu Rao Libing Liao Beijing Key Laboratory of Materials Utilization of Nonmetallic Minerals and Solid Wastes National Laboratory of Mineral Materials School of Materials Science and Technology China University of Geosciences

Microwave-induced oxidation,as a new,efficient and green technology,is favored by researchers for its advantage of fast,high efficiency and no secondary pollution.It is known as "green chemistry" for its characteristics of reducing energy consumption and pollution.The representative results review the research progress of microwave-induced oxidation technology in the treatment of organic wastewater and volatile organic compounds,hydrogen production and combination with other technologies to induce oxidation,and the development direction and prospects of microwave-induced oxidation technology have been summarized in this paper.

关键词： Microwave-induced oxidation Organic wastewater Hydrogen production advanced oxidation

Application of Fe-Based Amorphous Alloy in Industrial Wastewater Treatment:A Review

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Journal of Renewable Materials 2022年第4期10卷 969-991页

作者： Liefei Pei Xiangyun Zhang Zizhou Yuan School of Materials Science and Engineering Lanzhou University of TechnologyLanzhou730050China

Amorphous alloy(MGs)is a solid alloy with disordered atomic accumulation obtained by ultra-rapid solidification of alloy melt.The atom deviates from the equilibrium position and is in metastable state.Up to now,a large number of MGs have been applied to the treatment of dye and heavy metal contaminated wastewater and ideal experimental results have been obtained.However,there is no literature to systematically summarize the chemical reaction and degradation mechanism in the process of degradation.On the basis of reviewing the classification,application,and synthesis of MGs,this paper introduces in detail the chemical reactions such as decolorization,mineralization,and ion leaching of Fe-based amorphous alloy(Fe-MGs)in the degradation of organic and inorganic salt wastewater through direct reduction or advanced oxidation mechanism.Compared with crystalline materials,the higher reaction rate of Fe-MGs can be attributed to lower activation energy,negative redox potential,loose product layer,and band structure with downward shift of valence band top.Finally,some suggestions and prospects are put forward for the limitations and research prospects of MGs in the environmental field,which provides a new idea for the synthesis of new environmental functional materials.

关键词： Amorphous alloy industrial waste water direct reduction advanced oxidation reaction activity