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Identification and functional characterization of female antennae-biased odorant receptor 23 involved in acetophenone detection of the Indian meal moth Plodia interpunctella

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Insect Science 2024年第1期31卷 59-78页

作者： Qi Chen Xiaoyan Zhu Guoqing Kang Qiling Yu Qingxin Liu Lin Du Yi Yang Xinyu He Ying Zhao Junjie Zhang Ying Hu Bingzhong Ren Jilin Provincial Key Laboratory of Animal Resource Conservation and Utilization School of Life SciencesNortheast Normal UniversityChangchunChina Key Laboratory of Vegetation Ecology Ministry of EducationNortheast Normal UniversityChangchunChina Jilin Provincial Engineering Laboratory of Avian Ecology and Conservation Genetics Northeast Normal UniversityChangchunChina Engineering Research Center of Natural Enemies Institute of Biological ControlJilin Agricultural UniversityChangchunChina

The Indian meal moth,Plodia interpunctella(Lepidoptera:Pyralidae),a globally distributed storage pest,relies on odors that are emitted from stored foods to select a suitable substrate for ***,the molecular mechanism underlying the chemical communication between *** and its host remains *** this study,130 chemosensory genes were identified from the transcriptomes of 7 *** tissues,and the quantitative expression levels of all 56 *** odorant receptor genes(PintORs)were validated using real-time quantitative polymerase chain *** functional characteristics of 5 PintORs with female antennae-biased expression were investigated using 2-electrode voltage clamp recordings in Xenopus laevis ***23 was found to be specifically tuned to *** could elicit a significant electrophysiological response and only attracted mated females when compared with males and virgin *** addition,molecular docking predicted that the hydrogen bonding sites,TRP-335 and ALA-167,might play key roles in the binding of PintOR23 to *** study provides valuable insights into the olfactory mechanism of oviposition substrate detection and localization in *** and points toward the possibility of developing eco-friendly odorant agents to control pests of stored products.

关键词： acetophenone docking EAG odorant receptor Plodia interpunctella TEVC

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An Unexpected Discovery in the Willgerodt-Kindler Reaction of acetophenone--the Formation of the 4-（Benzoylthiocarbonyl）morpholine

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Chinese Journal of Chemistry 2006年第10期24卷 1472-1475页

作者：刘玮炜赵跃强许瑞波唐丽娟胡宏纹 Department of Chemical Engineering Huaihai Institute of Technology Lianyungang Jiangsu 222005 China Department of Chemistry Nanjing University Nanjing Jiangsu 210093 China

The Willgerodt-Kindler reaction of acetophenone was studied. Apart from the normal product 4-（benzylthiocarbonyl）morpholine, another product 4-（benzoylthiocarbonyl）morpholine was obtained unexpectedly. The structure of the latter was confirmed by 1R, IH NMR spectra and X-ray diffraction analysis. The mechanism of the reaction was discussed.

关键词： 4-(benzylthiocarbonyl)morpholine 4-(benzoylthiocarbonyl)morpholine acetophenone Willgerodt-Kindler reaction crystal structure

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High Selective Hydrogenation of acetophenone Catalyzed by Alumina Supported Platinum Nanoclusters

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Chinese Chemical Letters 2003年第5期14卷 533-534页

作者： Qin ZHANG Hong Xia MA Hua CHEN Jia Yuan HU Xian Jun LI Department of Chemistry Sichuan UniversityChengdu 610064

A new preparation and reduction method of ?Al2O3 supported and PVP stabilized platinum nanoclusters was studied. The catalyst exhibited very high activity and selectivity for acetophenone hydrogenation in isopropanol... 详细信息

关键词： Platinum nanoclusters acetophenone hydrogenation.

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Enantioselective hydrogenation of acetophenone by(1S,2S)-DPEN-Ru(Ⅱ)Cl_2(PPh_3)_2 encapsulated in Al-MCM-41

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Chinese Chemical Letters 2010年第7期21卷 802-806页

作者： Jian Hong Liu Dong Liang Bin Bin Fan Rui Feng Li Hua Chen Key Laboratory of Coal Science and Technology MOEInstitute of Special ChemicalsTaiyuan University of Technology Taiyuan 030024China College of Chemistry and Chemical Engineering Shanxi Datong UniversityDatong 037009China Key Laboratory of Green Chemistry and Technology MOEThe Institute of Homogeneous CatalysisCollege of Chemistry Sichuan UniversityChengdu 610064China

A chiral ruthenium complex[（1S,2S）-DPEN]-RuCl_2（PPh_3）_2（DPEN = 1,2-diphenylethylenediamine,PPh_3 = triphenylphosphine） was encapsulated in the channel of Al-MCM-41 by electrostatic adsorption and 1,1-dichlorosilacyclobutane *** prepared heterogeneous catalyst showed the same catalytic activity and enantioselectivity as the corresponding homogeneous catalyst in the asymmetric hydrogenation of acetophenone,and could be reused at least seven times without significant loss of catalytic activity and enantioselectivity.

关键词： Encapsulation Al-MCM-41 Heterogeneous enantioselective hydrogenation acetophenone S S-DPEN-Ru-Al-MCM-Si

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Efficient C_(2)-Symmetric Chiral Schiff Bases for Lanthanide-catalyzed Asymmetric Hydrogenation of acetophenone

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Chinese Chemical Letters 2006年第10期17卷 1297-1300页

作者： Peng Fei YAN Wen Bin SUN Guang Ming LI Chun Hong NIE Zheng Yu YUE School of Chemistry and Materials Science Heilongjiang University Harbin 150080

An array of C2-symmetric chiral Schiff bases of substituted salicylaldehyde （1R, 2R）-1, 2-cyclohexanediamine and （R）-（＋）-2, 2＇-diamino-1, 1＇-binaphthalene, incorporated with lanthanide complexes, have been applied as catalysts for asymmetric hydrogenation of acetophenone for the first time. Highly enantioselective product with 90% enantiomeric excess （e.e.） was obtained when the catalyst, hybridized by the bulky electron-donating 3, 5-di-tert-butyl substituted Schiff base （2） and SmCl3.4THF, was employed.

关键词： Chiral Schiff base lanthanide (HI) complexes asymmetric hydrogenation acetophenone 2-propanol.

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Microbial Transformation of acetophenone to 2-Phenylethanol

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Tsinghua Science and Technology 2003年第4期8卷 471-475页

作者：蔺兆星郝宁陈国强 Department of Biological Sciences and Biotechnology Tsinghua University Beijing 100084 China

Microorganisms are commonly used to transform chemicals to chiral compounds. Pseudomonas cepacia 1813, Pseudomonas stutzeri 1317, Saccharomyces cerevisiae 1912, and 5 Escherichia coli strains were used to transform acetophenone to 2 phenylethanol. The results show that the E. coli strains have the poorest biotransformation ability. P. stutzeri 1317 provides the best transformation ability with a transformation rate of 30% achieved with either whole or broken P. stutzeri 1317 cells for a reaction pH of 8.2 and an initial acetophenone concentration of 2 g/L. An acetophenone concentration of 10 g/L strongly inhibits the biotransformation for a pH of 8.2. Crude alcohol dehydrogenase obtained from S. cerevisiae 1912 transforms acetophenone to 2 phenylethanol when nicotinamide adenine dinucleotide reduced (NADH) is added.

关键词： acetophenone 2 phenylethanol biotransformation Pseudomonas stuzteri

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Synthesis of Chiral Tetra-dentate Ligands and Use in Asymmetric Transfer Hydrogenation(ATH)of acetophenone

Synthesis of Chiral Tetra-dentate Ligands and Use in Asymmet...

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2013广东材料发展论坛——战略性新兴产业发展与新材料科技创新研讨会

作者： ZHAO Ying YU Huijuan YU Lin School of Chemical Engineering and Light Industry

A series of chiral tetra-dentate ligands were synthesized and fully characterized by IR spectros-copy, multinuclear one-and two-dimensional NMR spectroscopy,mass *** transfer hydrogenation of acetophenone with the catalysts prepared in situ from Rh-,It- and Ru-complexes and ch-iral tetra-dentate ligands in i-PrOH gave the corresponding optically active secondary alcohols in high co-nversions under mild reaction conditions.

关键词： Chiral ligands Asymmetric transfer hydrogenation acetophenone

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Efficient Synthesis of 2,6-Diphenyl-4-arylpyrylium Tetrafluoroborate

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Chinese Chemical Letters 2002年第7期13卷 605-606页

作者： Shrong Shi LIN Cheng Yong LI Xuan WANG Department of Chemistry Peking UniversityBeijing 100871

Four pyrylium salts, (2,6-diphenyl-4-arylpyrylium tetrafluoroborate, aryl = C6H5, 4-MeO C6H4, 4-Me2NC6H4, 4-NO2C6H4) were synthesized efficiently and economically from acetophenone and substituted chalcones in the pre... 详细信息

关键词： Diphenyl-4-arylpyrylium tetrafluoroborate chalcone acetophenone borontrifuo- ride.

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Chiral Borated Esters in Asymmetric Synthesis: 1. The First Asymmetric Reaction Catalyzed by Chiral Spiroborated Esters with an O_3BN Framework

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Chinese Journal of Chemistry 2004年第11期22卷 1336-1340页

作者：刘德军单自兴秦金贵 Department of Chemistry Wuhan University Wuhan Hubei 430072 China

The first asymmetric reaction catalyzed by chiral spiroborated esters with an O3BN framework was reported. In the presence of 0.1 equivalent of (R,S)-1 or (S,S)-1, acetophenone was reduced by 0.6 equivalent of borane in THF at 0—5 ℃ for 2 h to give (R)-1-phenylethanol of up to 76% ee and 73% isolated yield. Influence of reaction con-ditions on the stereoselectivity of the reduction was investigated and a possible catalytic mechanism of the chiral spiroborated esters toward the reduction was also suggested.

关键词： asymmetric catalysis reduction chiral spiroborated ester acetophenone

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Hartree-Fock and Density Functional Theory Studies on the Molecular Recognition of the Cyclodextrin

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Chinese Chemical Letters 1999年第12期10卷 0-0,0-0页

作者： Lei LIU Xiao Song LI Qing Xiang GUO You Cheng LIUDepartment of Chemistry, University of Science and Technology of China, Hefei 230026) Department of Chemistry Univ. of Sci. and Technol. of China Hefei 230026 China

This study involves initial Hartree-Fock and Density Functional theory calculations onthe molecular recognition of the cyclodextrins. The α-cyclodextrin-acetophenone complexationsystem was investigated with PM3, HF/3-21G* and B3LYP/3-21G* methods. The results indicatedthat the inclusion orientation in which the acetyl group of the acetophenone points towards thesecondary hydroxyls of the a-cyclodextrin was preferable in energy. The steric effect wassupposed as the physical reason of such a behavior Hence, the simple rule the anti-parallelarrangement of the dipoles of the host and guest molecules in the cyclodextrin complexqtion is notgenerally applicable.

关键词： ab initio acetophenone cyclodextrin density functional theory molecular recognition

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