检索结果-南通市图书馆

Z-scheme Bi4O5Br2/NH2-MIL-125（Ti） heterojunctions enable exceptional visible photocatalytic degradation of organic pollutant

引用

Rare Metals 2024年第7期43卷 3161-3172页

作者： Feng Huang Muhammad Humayun Gang Li Ting-Ting Fan Wen-Lin Wang Yu-Lin Cao Anton Nikiforov Chun-Dong Wang Jing Wang Key Laboratory of Analytical Science and Technology of Hebei Province Key Laboratory of Medicinal Chemistry and Molecular Diagnosis of the Ministry of EducationState Key Laboratory of New Pharmaceutical Preparations and ExcipientsCollege of Chemistry and Materials ScienceHebei University Energy Water and Environment LabCollege of Humanities and SciencesPrince Sultan University Baoding Green Yijia Environmental Protection Technology Ltd Physics Laboratory Industrial Training CenterShenzhen Polytechnic University Department of Applied Physics Ghent University School of Integrated Circuits Wuhan National Laboratory for OptoelectronicsHuazhong University of Science and Technology

One key strategy to enhance photocatalytic performance is to improve the transfer and separation efficiency of photogenerated carriers by building optimized ***,novel Bi4O5Br2/NH2-MIL-125（Ti）Z-scheme heterojunctions are fabricated and used as photocatalysts for organic pollutant *** NH2-MIL-125（Ti） nanosheets are exfoliated via a self-developed alkali solution stripping approach and then uniformly decorated on *** as-prepared Bi4O5Br2/NH2-MIL-125（Ti） presents more than 90% degradation of various pollutants,outperforming the counterpart individual *** various characterization results suggest that the enhanced degradation rate is due to the more intimate face-to-face interfacial contact of the lamellar Z-scheme heterojunction materials,in which the migration path of carriers from the material's interior to the surface can be reduced,in turn enhancing migration efficiency and separation capability significantly.A possible photocatalytic reaction mechanism is proposed based on the photoelectric behaviors,radical trapping experiments and liquid chromatography mass spectrometry *** work promotes the development of new photocatalytic materials for heterojunctions with face-to-face interfacial contacts,as well as the effective purification of wastewater in environmental remediation.

关键词： Z-scheme heterojunctions Photocatalysis Alkaline solution stripping Bi 4 O 5 Br 2 NH 2 -MIL-125(Ti)

来源：

同方期刊数据库评论

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

肿瘤血管破坏剂5,6-二甲基黄嘌呤-4-乙酸对小鼠Lewis肺癌转移的抑制作用及机制

引用

中国药理学与毒理学杂志 2024年第3期38卷 161-169页

作者：崔霞何微肖智勇王莹刘峰周文霞南京中医药大学江苏南京210023 军事科学院军事医学研究院毒物药物研究所国家安全特需药品全国重点实验室北京100850

目的探讨肿瘤血管破坏剂5,6-二甲基黄嘌呤-4-乙酸(DMXAA)对小鼠Lewis肺癌(LLC)转移的抑制作用及其机制。方法制备2种小鼠肿瘤模型(LLC异位移植瘤小鼠模型和转移型LLC小鼠模型),评价DMXAA对LLC转移的抑制作用。LLC异位移植瘤小鼠模型制... 详细信息

目的探讨肿瘤血管破坏剂5,6-二甲基黄嘌呤-4-乙酸(DMXAA)对小鼠Lewis肺癌(LLC)转移的抑制作用及其机制。方法制备2种小鼠肿瘤模型(LLC异位移植瘤小鼠模型和转移型LLC小鼠模型),评价DMXAA对LLC转移的抑制作用。LLC异位移植瘤小鼠模型制备成功后,随机分为3组:模型组(含1%DMSO的生理盐水,ip,2天1次)、模型+苏尼替尼组(30 mg·kg^(-1),ip,2天1次)和模型+DMXAA组(25 mg·kg^(-1),ip,给药1次)。首次给药后每隔1天测量小鼠移植瘤体积,并绘制移植瘤体积生长曲线和小鼠体重变化曲线;给药后2和5 d剥瘤称取瘤重,并将瘤组织进行免疫荧光染色,测定血小板内皮细胞黏附分子1(CD31)和α平滑肌肌动蛋白(α-SMA)阳性表达,计算α-SMA/CD31荧光强度比值,表示移植瘤组织血管表面周细胞覆盖率;哌莫硝唑(pimonidazole)染色检测瘤组织低氧程度。转移型LLC小鼠模型制备成功后,随机分为3组:模型组(含1%DMSO的生理盐水,ip,1周2次)、模型+苏尼替尼组(60 mg·kg^(-1),ip,1周2次)和模型+DMXAA组(25 mg·kg^(-1),ip,给药1次)。首次给药后2和5周用小动物活体成像系统观察小鼠体内肿瘤转移,并进行荧光定量分析。结果与模型组相比,模型+苏尼替尼组和模型+DMXAA组移植瘤体积和重量均显著减小(P5,P5),而模型+DMXAA组则无显著差异。与模型组相比,苏尼替尼对LLC转移无影响,而给药后2周DMXAA明显抑制LLC转移(P5 d,模型+苏尼替尼组和模型+DMXAA组移植瘤组织中周细胞覆盖率均显著升高(P5);模型+苏尼替尼组瘤组织低氧面积无明显变化,模型+DMXAA组瘤组织低氧面积显著降低(P<0.01)。结论肿瘤血管破坏剂DMXAA显著抑制小鼠LLC生长和转移,其机制可能与其诱导肿瘤血管正常化和改善瘤组织低氧微环境有关。

关键词：肿瘤血管破坏剂 5 6-二甲基黄嘌呤-4-乙酸苏尼替尼转移低氧

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Coronatine promotes maize water uptake by directly binding to the aquaporin ZmPIP2;5 and enhancing its activity

引用

Journal of Integrative Plant Biology 2023年第3期65卷 703-720页

作者： Rui He Huiqing Su Xing Wang Zhijie Ren Kun Zhang Tianyu Feng Mingcai Zhang Zhaohu Li Legong Li Junhong Zhuang Zhizhong Gong Yuyi Zhou Liusheng Duan State Key Laboratory of Plant Physiology and Biochemistry Engineering Research Center of Plant Growth RegulatorMinistry of Education&College of Agronomy and BiotechnologyChina Agricultural UniversityBeijing 100193China College of Plant Protection China Agricultural UniversityBeiing 100193China Key Laboratory of Plant Gene Resources and Biotechnology for Carbon Reduction and Environmental Improvement Beijing Municipal GovernmentCollege of Life SciencesCapital Normal UniversityBeijing 100048China Center for Crop Functional Genomics and Molecular Breeding China Agricultural UniversityBeijing 100193China State Key Laboratory of Plant Physiology and Biochemistry College of Biological SciencesChina Agricultural UniversityBeijing 100193China

Water uptake is crucial for crop growth and development and drought stress tolerance. The water channel aquaporins(AQP) play important roles in plant water uptake. Here, we discovered that a jasmonic acid analog, coronatine(COR), enhanced maize(Zea mays) root water uptake capacity under artificial water deficiency conditions. COR treatment induced the expression of the AQP gene Plasma membrane intrinsic protein 2;5(ZmPIP2;5).In vivo and in vitro experiments indicated that COR also directly acts on ZmPIP2;5 to improve water uptake in maize and Xenopus oocytes. The leaf water potential and hydraulic conductivity of roots growing under hyperosmotic conditions were higher in ZmPIP2;5-overexpression lines and lower in the zmpip2;5 knockout mutant, compared to wild-type plants. Based on a comparison between ZmPIP2;5 and other PIP2s, we predicted that COR may bind to the functional site in loop E of ZmPIP2;5. We confirmed this prediction by surface plasmon resonance technology and a microscale thermophoresis assay, and showed that deleting the binding motif greatly reduced COR binding. We identified the N241 residue as the COR-specific binding site, which may activate the channel of the AQP tetramer and increase water transport activity,which may facilitate water uptake under hyperosmotic stress.

关键词： coronatine osmotic stress water uptake capacity ZmPIP2 5

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Evaluating the Efficiency of Cadmium Removal by Alginate Hydrogels from Water Using 5,7-Dibromo-8-hydroxyquinoline as a Complexing Reagent

引用

Precision Chemistry 2023年第9期1卷 538-547页

作者： Abhijit B.Phalke Varuna S.Watwe Sunil D.Kulkarni Preeti S.Kulkarni Post Graduate and Research Center Department of ChemistryMES Abasaheb Garware CollegePune 411004 MaharashtraIndia Affiliated with Savitribai Phule Pune University(Formerly University of Pune) Pune 411007 MaharashtraIndia

Cadmium toxicity in wastewater is a rising concern due to industries like batteries,metallurgy,electroplating,plastic stabilizers,and *** quantitative detection of Cd^(2+)and its remediation from wastewater samples are of major concern from an environmental point of *** the present work,an effective spectrophotometric method has been reported using 5,7-dibromo-8-hydroxyquinoline(DBHQ)as a complexing agent for Cd^(2+).This method has advantages like using recyclable,less toxic solvents and easy sample *** limit of detection,limit of quantification,and sensitivity of the proposed method were found to be 33.30,36.70 mg L^(−1),and 2×10^(−3),*** DBHQ method was validated using atomic absorption spectroscopy,and the recovery percentage was more than 98%.These results indicate that DBHQ can be effectively used for monitoring Cd^(2+)in aqueous *** method developed was further employed for monitoring Cd^(2+)adsorption on calcium alginate(AL)*** adsorption studies were done to optimize parameters of Cd^(2+)removal using AL hydrogels,and the data obtained were used for kinetic and thermodynamic *** studies indicated that the pseudo-first-order model showed better fitting,and thermodynamic studies showed Freundlich-like *** maximum adsorption capacity of Cd^(2+)on AL hydrogels was found to be 56.45 mg g^(−1).The validation studies of DBHQ were performed using statistical analysis methods like t-tests and one-way variance.

关键词： cadmium toxicity 5 7-dibromo-8-hydroxyquinoline spectrophotometric method adsorption studies wastewater remediation calcium alginate hydrogels

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Landsat 5 TM沙丘迁移场的误差消除与时序反演:以毛乌素沙地西北部沙丘为例

引用

遥感学报 2023年第11期27卷 2552-2564页

作者：杨定江冯光财冯志雄李国帅张洁中南大学地球科学与信息物理学院雷达遥感实验室长沙410083 中国科学院青藏高原研究所环境变化与地表过程重点实验室&国家青藏高原科学数据中心北京100101 中国科学院青藏高原研究所青藏高原地球系统科学国家重点实验室北京100101 青海省基础测绘院西宁810001

通过COSI-Corr软件处理Landsat 5 TM可以较好地量化沙丘的迁移模式和速度大小,为防沙治沙工程的实施提供具体的指导和建议。目前关于Landsat 5 TM迁移场误差源分析和时序反演研究仍然较少。本文以毛乌素沙地西北部为研究区域获取了1991... 详细信息

通过COSI-Corr软件处理Landsat 5 TM可以较好地量化沙丘的迁移模式和速度大小,为防沙治沙工程的实施提供具体的指导和建议。目前关于Landsat 5 TM迁移场误差源分析和时序反演研究仍然较少。本文以毛乌素沙地西北部为研究区域获取了1991年—2000年的沙丘迁移时间序列和年平均速度场,发现Landsat 5 TM迁移场的主要误差为轨道误差、姿态角误差和失相关噪声,这些误差消除后,精度相继提升23%—34%、4%—20%、2%—5%,再利用最小二乘法反演后可提升13%—14%。监测结果表明,1991年—2000年毛乌素沙地西北部沙丘向东南方向持续推进,最大速度可超过6 m/a,但受到西北—东南向的风力作用下,沿西北—东南向存在周期性往返运动;研究区域速度为0—1 m/a的占63.9%,大于3 m/a的则只有4.2%。Landsat 5 TM的误差消除和时序反演能有效地提高迁移场精度,进而获取更加准确可靠的时间序列。与以往研究不同的是,沙丘迁移场的误差消除和时序反演后可以更细致地反映出沙丘地表的实际风能环境。

关键词： Landsat 5 TM COSI-Corr 误差分析沙丘迁移毛乌素沙地

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Correlation between microstructure and impact toughness of weld heat-affected zone in 5 wt.% manganese steels

引用

Journal of Iron and Steel Research(International) 2019年第7期26卷 761-770页

作者： Jun-hui Li Hong-hong Wang Qiang Luo Li Li Chao Sun R.D.K. Misra The State Key Laboratory of Refractories and Metallurgy Wuhan University of Science and Technology Wuhan 430081 Hubei China Research Institute of Nanjing Iron and Steel Co. Ltd. Nanjing 210035 Jiangsu China Laboratory for Excellence in Advanced Steel Research Department of Metallurgical Materials and Biomedical Engineering University of Texas at El Paso El Paso TX 7996& USA

The microstructure in welding heat-affected zones of 5 wt.% manganese steels was studied, and its effect on impact toughness was analyzed. The simulated coarse-grained heat-affected zone (CGHAZ) had the lowest impact toughness of ~39 J at — 40℃ because of coarse-grained structure and least volume fraction of retained austenite (RA) of 1.2 vol.%. The impact toughness of simulated intercritical heat-affected zone (ICHAZ) and fine-grained heat-affected zone (FGHAZ) were ~165 and ~45 J, respectively, at — 40℃. The effective grain size of simulated FGHAZ was smaller than that of the simulated ICHAZ. Furthermore, microstructural investigation revealed that the simulated FGHAZ and ICHAZ had similarity in volume fraction and stability of RA. However, tempered martensite was present in ICHAZ and absent in FGHAZ. It is proposed that the presence of tempered martensite contributed to good impact toughness in simulated ICHAZ.

关键词： 5 wt.% manganese steel Welding heat-affected zone Retained austenite Tempered martensite Impact toughness

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Synthesis and Crystal Structure of 1,4-Bis-(benztriazol-1-ylmethyl)-2,3,5,6-tetramethylbenzene

引用

Chinese Journal of Structural Chemistry 2005年第3期24卷 279-282页

作者： CAI Yue-Peng HE Guang-Ping CAI Yi ZHANG Chi SU Cheng-Yong KANG Bei-Sheng Dearment of Chemistr South China Normal UniversiyGuanzhou 510631China School of Chemisiry and Chemical Engineering Sun Yer-sen UniversitGuangzhou 510275China School of Pharmacaceutical Sciences Anhui Collegeof Traditional Chinese MedicineHefei 230038China

The title compound 1,4-bis(benztriazol-1-ylmethyl)-2,4,5,6-trimethylbenzene crys- tallizes in the monoclinic system, space group Pbca with a = 9.842(5), b = 9.455(5), c = 22.165(12) ?, V = 2062.6(18) ?3, Dc = 1.277 g/cm3, Z = 4, C24H24N6, Mr = 396.49, μ(MoKa) = 0.079 mm-1 and F(000) = 840. The structure was refined to R = 0.0662 and wR = 0.1891 for 1163 observed reflections (I > 2σ(I)). The title molecule has trans-conformation about the central phenyl ring. The zigzag-like molecules are connected by face-to-face π…π stacking to form an infinite 2D layer.

关键词： bis(benztriazol-1-ylmethyl)-2 4 5 6-trimethylbenzene synthesis crystal structure face-to-faceπ…πinteraction 2D layer

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

X-RAY POWDER DIFFRACTION DATA AND STRUCTURAL REFINEMENT OF Er₃Co₆Sn₅

引用

中国有色金属学会会刊：英文版 1999年第1期9卷 88-90页

作者： He, Wei Zeng, Lingmin Qin, Wen Yan, Jialin Hao, Jianmin Univ of Science and Technology of China Hefei China

１ＩＮＴＲＯＤＵＣＴＩＯＮＲａｒｅｍｅｔａｌｓａｎｄｔｈｅｉｒｃｏｍｐｏｕｎｄｓｈａｖｅｏｕｔｓｔａｎｄｉｎｇｐｒｏｐｅｒｔｉｅｓａｎｄａｒｅｐａｉｄｉｎｃｒｅａｓｉｎｇａｔｅｎｔｉｏｎｔｏ．Ｎｕｍｅｒｏｕｓｉｎ... 详细信息

１ＩＮＴＲＯＤＵＣＴＩＯＮＲａｒｅｍｅｔａｌｓａｎｄｔｈｅｉｒｃｏｍｐｏｕｎｄｓｈａｖｅｏｕｔｓｔａｎｄｉｎｇｐｒｏｐｅｒｔｉｅｓａｎｄａｒｅｐａｉｄｉｎｃｒｅａｓｉｎｇａｔｅｎｔｉｏｎｔｏ．Ｎｕｍｅｒｏｕｓｉｎｖｅｓｔｉｇａｔｉｏｎｓｉｎｔｈｅ...

关键词： Er 3Co 6Sn 5 X ray powder diffraction Rietveld structural refinement

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Heat generation properties in AC magnetic field for composite powder material of the Y3Fe5O12-nSiC system prepared by reverse coprecipitation method

引用

Journal of Advanced Ceramics 2016年第3期5卷 262-268页

作者： Hiromichi AONO Yuhi YAMANO Takashi NAOHARA Yoshiteru ITAGAKI Tsunehiro MAEHARA Hideyuki HIRAZAWA Graduate School of Science and Engineering Ehime University Matsuyama 790-8577 Japan National Institute of Technology Niihama College Niihama 792-8580 Japan

Composite powder material of the Y3Fe5O12–nSiC system was synthesized by a reverse coprecipitation method to study its heat generation property in an AC magnetic field. For Y3Fe5O12 (n = 0), the maximum heat generation ability of 0.45 W·g−1 in an AC magnetic field (370 kHz, 1.77 kA·m−1) was obtained for the sample calcined at 1100 °C. The SiC addition helped to suppress the particle growth for Y3Fe5O12 at the calcination temperature. The heat generation ability was improved by the addition of the SiC powder, and the maximum value of 0.93 W·g−1 was obtained for the n = 0.3 sample calcined at 1250 °C. The heat generation ability and the hysteresis loss value were proportional to the cube of the magnetic field (H 3). The heat generation ability (W·g−1) of the Y3Fe5O12–0.3SiC sample calcined at 1250 °C could be expressed by the equation 4.5×10−4 · f · H 3 using the frequency f (kHz) and the magnetic field H (kA·m−1).

关键词： magnetic materials composite material Y 3 Fe 5 O 12 SiC heat generation ability AC magnetic field

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Oxidation of 2,2'-Dihydroxy-3,3'-di-tert-buty-5,5'-dimethoxyl-biphenyl to 3,3'-Di-tert-butylbiphenyl-2,5,2',5'-diquinone with Copper(Ⅱ)Chloride as Catalyst:Synthesis,Structure and Spectral Properties of Diquinone

引用

Chinese Journal of Structural Chemistry 2011年第10期30卷 1469-1476页

作者：李俊霞王建革黄唯平 College of Chemistry and Chemical Engineering Luoyang Normal UniversityLuoyang College of Chemistry Nankai University

Use of free air as oxidant and copper（II）chloride as catalyst,3,3＇-di-tert-butylbi-phenyl-2,5,2＇,5＇-diquinone（BBDQ）was prepared via catalytic oxidation of 2,2＇-dihydroxy-3,3＇-di-tert-butyl-5,5＇-dimethoxy-biphenyl（di-BHA）.The yield of reaction attained 95% and the selectivity for BBDQ was 100%.The single-crystal X-ray diffraction analysis reveals that the dihedral angle between two rings（benzene rings for di-BHA and quinone rings for BBDQ）changes from 89.8 to 45.3o,indicating the steric hindrance effects of methyl disappear in the oxidation *** crystal structures of di-BHA and BBDQ are further confirmed by their spectral *** probable mechanism for this oxidation process is also discussed.

关键词： catalytic oxidation 3 3'-di-tert-butylbiphenyl-2 5 2' 5'-diquinone 2 2'-dihydroxy-3 3'-di-tert-butyl-5 5'-dimethoxybiphenyl copper(II)chloride

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

欢迎您,

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案：

请选择收藏分类：

通借通还

欢迎您,

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：