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Enantioselective recognition based on aggregation-induced emission

Chinese Chemical Letters 2023年第6期34卷 70-80页

作者： Pu Chen Panpan Lv Chang-Sheng Guo Rui-Peng Wang Xiaolong Su Hai-Tao Feng Ben Zhong Tang AIE Research Center Shaanxi Key Laboratory of PhytochemistryCollege of Chemistry and Chemical EngineeringBaoji University of Arts and SciencesBaoji 721013China Shenzhen Institute of Aggregate Science and Technology School of Science and EngineeringThe Chinese University of Hong KongShenzhen 518172China

Chirality is one of the most important features of the *** recognition of enantiomers plays significant roles in the field of life science,pharmaceutical analysis and food *** various recognition methods,fluorescence spectrometry has attracted much attention of researchers thanks to its high sensitivity and easy *** with traditional fluorescent probes,chiral molecules with aggregation-induced emission(AIE)have drawn increasing interests due to their huge potential in high-efficiency chemo/biosensors and solid *** AIE luminogens(AIEgens)can not only discriminate two enantiomers with excellent enantioselectivity,but also show general applicability for many chiral analytes,such as chiral acids,amino acids,amines,*** this review,we mainly summarized the recent development of chiral probes with AIE properties,including chiral tetraphenylethylene(TPE)derivatives,α-cyanostilbene derivatives,Schiff base derivatives and other *** synthetic routes,recognition capabilities and possible working mechanisms were well *** is envisioned that the present review can give some significant guidance for design and synthesis of chiral AIEgens with good enantioselectivity and inspire more readers to join the research of chiral AIE.

关键词： Aggregation-induced emission Enantioselective recognition Fluorescent probe Host-guest interaction Tetraphenylethylene derivatives α-cyanostilbene derivatives Schiff base derivatives

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