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Mainchain conformation ordering self-assembly tailored room temperature phosphorescence emission

Science China Chemistry 2025年第01期 329-336页

作者： Yuzhu Li Yumeng Gao Feng Tian Yu Wang Yuan Yao Shaoliang Lin Xiang Ma Binbin Xu shanghai Key Laboratory of Advanced Polymeric Materials Key Laboratory for Ultrafine Materials of Ministry of Education School of Materials Science and Engineering East China University of Science and Technology shanghai Synchrotron Radiation Facility Shanghai Advanced Research Institute Chinese Academy of Sciences Key Laboratory for Advance Materials and Feringa Noble Prize Scientist Joint Research Centre Frontiers Science for Materiobiology and Dynamic Chemistry School of Chemistry and Molecular Engineering East China University of Science & Technology

Developing organic room-temperature phosphorescence （RTP） materials with a wide range of tunable-emission is significant in expanding the applications of RTP ***,we rationally designed amphiphilic alternating copolymers poly(1,2-bis（4-alkoxyphenyl）ethane-1,2-dione-alt-（ethylene glycol）x)(P（Bz-alt-EGx）) that combined the advantage of alternating benzil and EGxskeleton,and tunable mainchain *** a mainchain conformation ordering assembly （COA） process,P（Bz-alt-EGx） self-assembled into well-defined platelets,and such assemblies emitted blue RTP at ca.425 nm due to the ordered folded-chain conformation and confined *** contrast,traditional self-assembly （TA） of P（Bz-alt-EGx） obtained less ordered aggregates,such as asymmetric worms,vesicles,and rod-like *** resultant less ordered aggregates exhibited yellow-green RTP at ca.550 *** wide-tuning RTP emission in solution （between blue and yellow-green,over125 nm） is realized using the P（Bz-alt-EGx） alternating copolymers under the treatment of different self-assembly *** study uncovers a new strategy to tailor the RTP emission through different self-assembly pathways and holds great promise for the fabrication of advanced optical materials.

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Ambient ammonia production via electrocatalytic nitrite reduction catalyzed by a CoP nanoarray

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Nano Research 2022年第2期15卷 972-977页

作者： Guilai Wen Jie Liang Qian Liu Tingshuai Li Xuguang An Fang Zhang Abdulmohsen Ali Alshehri Khalid Ahmed Alzahrani Yonglan Luo Qingquan Kong Xuping Sun Chemical Synthesis and Pollution Control Key Laboratory of Sichuan Province School of Chemistry and Chemical EngineeringChina West Normal UniversityNanchong 637002China Institute of Fundamental and Frontier Sciences University of Electronic Science and Technology of ChinaChengdu 610054China Institute for Advanced Study Chengdu UniversityChengdu 610106China National Engineering Research Center for Nanotechnology No.28 East Jiang Chuan RoadShanghai 200241China Chemistry Department Faculty of ScienceKing Abdulaziz UniversityP.O.Box 80203Jeddah21589Saudi Arabia

Industrial-scale ammonia(NH_(3))production mainly relies on the energy-intensive and environmentally unfriendly Haber-Bosch *** issue can be avoided by electrocatalytic N_(2) reduction which however suffers from limited current efficiency and NH3 ***,we demonstrate ambient NH_(3) production via electrochemical nitrite(NO_(2)^(-))reduction catalyzed by a CoP nanoarray on titanium mesh(CoP NA/TM).When tested in 0.1 M PBS(pH=7)containing 500 ppm N0_(2)^(-),such CoP NA/TM is capable of affording a large NH_(3) yield of 2,260.7±51.5μg·h^(-1)·cm^(-2) and a high Faradaic efficiency of 90.0±2.3%at-0.2 V vs.a reversible hydrogen *** functional theory calculations reveal that the potential-determining step for NO_(2)^(-)reduction over CoP(112)is*NO2→*NO_(2)H.

关键词： CoP nanoarray NO_(2)^(-)reduction reaction ambient NH_(3)synthesis electrocatalysis density functional theory

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Tungsten and phosphate polyanion co-doping of Ni-ultrahigh cathodes greatly enhancing crystal structure and interface stability

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Chinese Journal of Chemical Engineering 2021年第9期34卷 144-151页

作者： Huawei Zhu Haifeng Yu Zhaofeng Yang Hao Jiang Chunzhong Li shanghai Engineering Research Center of Hierarchical Nanomaterials Frontiers Science Center for Materiobiology and Dynamic ChemistrySchool of Materials Science and EngineeringEast China University of Science&TechnologyShanghai 200237China

The Ni-ultrahigh cathode material is one of the best choices for further increasing energy-density of lithium-ion batteries(LIBs),but they generally suffer from the poor structure stability and rapid capacity ***,the tungsten and phosphate polyanion co-doped LiNi_(0.9)Co_(0.1)O_(2)cathode materials are successfully fabricated in terms of Li(Ni_(0.9)Co_(0.7))_(1-x)W_(x)O_(2-4y)(PO_(4))_(y) by the precursor modification and subsequent *** higher bonding energy of W—O(672 kJ·mol^(-1))can extremely stabilize the lattice oxygen of Ni-rich oxides compared with Ni—O(391.6 kJ·mol^(-1))and Co—O(368 kJ·mol^(-1)).Meanwhile,the stronger bonding of Ni—(PO_(4)^(3-))***—O could fix Ni cations in the transition metal layer,and hence suppressing the Li/Ni disorder during the charge/discharge ***,the optimized Li(Ni_(0.9)Co_(0.1))_(0.99)W_(0.01)O_(1.96)(PO_4)_(0.01)delivers a remarkably extended cycling life with 95.1%retention of its initial capacity of 207.4 mA·h·g^(-1)at 0.2 C after 200 ***,the heteroatoms doping does not sacrifice the specific capacity even at different rates.

关键词： LiNi_(0.9)Co_(0.1)O_(2) Co-doping Crystal stability Cycling life Li-ion batteries

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Azobenzene-based ultrathin peptoid nanoribbons for the potential on highly efficient artificial light-harvesting

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Science China Chemistry 2024年第5期67卷 1680-1686页

作者： Zichao Sun Lingrong Zhu Jingze Liu Fan Liu Pengchao Wu Pengliang Sui Haibao Jin Shaoliang Lin shanghai Key Laboratory of Advance Polymeric Materials Frontiers Science Center for Materiobiology and Dynamic ChemistrySchool of Materials Science and EngineeringEast China University of Science and TechnologyShanghai 200237China

The development of artificial light-harvesting systems based on long-range ordered ultrathin organic nanomaterials(i.e., below3 nm), which were assembled from stimuli-responsive sequence-controlled biomimetic polymers, remains challenging. Herein,we report the self-assembly of azobenzene-containing amphiphilic ternary alternating peptoids to construct photo-responsive ultrathin peptoids nanoribbons(UTPNRs) with a thickness of ~2.3 nm and the length in several micrometers. The pendants hydrophobic conjugate stacking mechanism explained the formation of one-dimensional ultrathin nanostructures, whose thickness was highly dependent on the length of side groups. The photo-isomerization of azobenzene moiety endowed the aggregates with a reversible morphology transformation from UTPNRs to spherical micelles(46.5 nm), upon the alternative irradiation with ultraviolet and visible light. Donor of 4-(2-hydroxyethylamino)-7-nitro-2,1,3-benzoxadiazole(NBD) and acceptor of rhodamine B(RB) were introduced onto the hydrophobic and hydrophilic regions, respectively, to generate photocontrollable artificial light-harvesting systems. Compared with the spheres-based systems, the obtained NBD-UTPNRs@RB composite proved a higher energy transfer efficiency(90.6%) and a lower requirement of RB acceptors in water. A proof-ofconcept use as fluorescent writable ink demonstrated the potential of UTPNRs on information encryption.

关键词： azobenzene-based peptoid ultrathin nanoribbon photo-responsive light-harvesting information encryption

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Polymeric assembled nanoparticles through kinetic stabilization by confined impingement jets dilution mixer for fluorescence switching imaging

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Chinese Journal of Chemical Engineering 2023年第4期56卷 89-96页

作者： Jingran Liu Yue Wu Jie Tang Tao Wang Feng Ni Qiumin Wu Xijiao Yang Ayyaz Ahmad Naveed Ramzan Yisheng Xu State Key Laboratory of Chemical Engineering East China University of Science and TechnologyShanghai 200237China shanghai Shyndec Pharmaceutical Co. LtdShanghai 200040China Department of Chemical Engineering Muhammad Nawaz Sharif University of Engineering and TechnologyMultanPakistan Faculty of Chemical Metallurgicaland Polymer EngineeringUniversity of Engineering&TechnologyLahorePakistan

Traditional fluorescence switching molecules achieving the state change between on and off states commonly based on UV irradiation. However, it is worth noting that UV irradiation is harmful to both the cancer cells and the normal cells. To achieve fluorescence switching under visible wavelength and avoid complicate molecular design, a fluorophore of 2,4,5,6-tetrakis(carbazol-9-yl)-1,3-dicyanobenzene(4Cz IPN) and a quencher of diarylethene(DAE) were physically incorporated within the biocompatible block copolymer poly(lactic-co-glycolic acid)-b-poly(ethylene glycol)(PLGA-b-PEG) to form 4Cz IPNDAE nanoparticles(NPs) through flash nanoprecipitation(FNP). By using the FNP method, the NPs were prepared within milliseconds in a confined impingement jets dilution(CIJ-D) mixer. Quenching and recovery of fluorescence could achieve in the presence of DAE under 475 nm and 560 nm *** structure and fluorescent properties of the nanoparticles can be tuned by external conditions for their efficient fluorescence resonance energy transfer(FRET) in a kinetic stabilization process. This NPs formation process was further optimized by varying the dilution ratio, Reynolds number(Re) and polymer concentration to modulate the mixing and particle nucleation and growth process. The size and fluorescence switching properties of the NPs were systematically investigated in solution and in cellular uptake experiments. This work is anticipated to provide a simple and highly effective engineering strategy for the modulation of fluorescence switching nanoparticles and beneficial to its engineering application.

关键词： Preparation Kinetic stabilization Flash nanoprecipitation Nanoparticles Fluorescence switch

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Carbon Fiber Supported Binary Metal Sulfide Catalysts with Multi-Dimensional Structures for Electrocatalytic Nitrogen Reduction Reactions Over a Wide pH Range

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Advanced Fiber Materials 2021年第4期3卷 229-238页

作者： Tianyi Zhang Wei Zong Yue Ouyang Yue Wu Yue-E Miao Tianxi Liu State Key Laboratory for Modification of Chemical Fibers and Polymer Materials College of Materials Science and EngineeringInnovation Center for Textile Science and TechnologyDonghua University2999 North Renmin RoadShanghai 201620People’s Republic of China Research Center for Analysis and Measurement Donghua UniversityShanghai 201620People’s Republic of China Key Laboratory of Synthetic and Biological Colloids Ministry of EducationSchool of Chemical and Material EngineeringJiangnan UniversityWuxi 214122People’s Republic of China

Green and environmentally friendly electrocatalytic nitrogen(N_(2))fixation to synthesize ammonia(NH3)is recognized as an effective method to replace the traditional Haber-Bosch ***,the difficulties in N_(2) adsorption and fracture of hard N≡N bond still remain major challenges in electrocatalytic N_(2) reduction reactions(NRR).From the perspectives of enhancing N_(2) adsorption and providing more catalytic sites,two-dimensional(2D)FeS_(2) nanosheets and three-dimensional(3D)metal organic framework-derived ZnS embedded within N-doped carbon polyhedras are grown on the carbon cloth(CC)template in this ***,a composite NRR catalyst with multi-dimensional structures,which is signed as FeS_(2)/ZnS-NC@CC,is obtained for using over a wide pH *** uniform distribution of hollow ZnS-NC frameworks and FeS_(2) nanosheets on the surface of CC largely increase the N_(2) enrichment efficiency and offer more active sites,while the CC skeleton acts as an independent conductive substrate and S-doping helps promote the fracture of N≡N bond during the NRR *** a result,the FeS_(2)/ZnS-NC@CC electrode achieves a high Faraday efficiency of 46.84%and NH3 yield of 58.52μg h^(−1) mg^(−1) at-0.5 V ***/AgCl in 0.1 M ***,the FeS_(2)/ZnS-NC@CC electrode displays excellent NRR catalytic activity in acidic and neutral electrolytes as well,which outperforms most previously reported electrocatalysts including noble ***,this work provides a new way for the design of multi-dimensional electrocatalysts with excellent electrocatalytic efficiency and stability for NRR applications.

关键词： Multi-dimensional structure Heteroatom doping Carbon fiber cloth Electrocatalytic nitrogen reduction

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Improving the intrinsic electronic conductivity of NiMo0_(4) anodes by phosphorous doping for high lithium storage

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Nano Research 2022年第1期15卷 186-194页

作者： Luchao Yue Chaoqun Ma Shihai Yan Zhenguo Wu Wenxi Zhao Qian Liu(ISl) Yonglan Luo Benhe Zhong Fang Zhang Yang Liu Abdulmohsen AN Alshehri Khalid Ahmed Alzahrani Xiaodong Guo Xuping Sun School of Chemical Engineering Sichuan UniversityChengdu 610065China Institute of Fundamental and Frontier Sciences University of Electronic Science and Technology of ChinaChengdu 610054China College of Chemistry and Pharmaceutical Sciences Qingdao Agricultural UniversityQingdao 266109China National Engineering Research Center for Nanotechnology No.28 East Jiang Chuan RoadShanghai 200241China School of Materials Science and Engineering Henan Normal UniversityXinxiang 453007China Chemistry Department Faculty of ScienceKing Abdulaziz UniversityP.O.Box 80203Jeddah 21589Saudi Arabia

Heteroatom doping is one of the most promising strategies toward regulating intrinsically sluggish electronic conductivity and kinetic reaction of transition metal oxides for enhancing their lithium ***,we designed phosphorus-doped NiMo0_(4) nanorods(P-NiMo0_(4))by using a facile hydrothermal method and subsequent low-temperature phosphorization *** doping played an indispensable role in significantly improving electronic conductivity and the Li+diffusion kinetics of NiMo0_(4) *** investigation and density functional theory calculation demonstrated that phosphorus doping can expand the interplanar spacing and alter electronic structures of NiMo0_(4) ***,the introduced phosphorus dopant can generate some oxygen vacancies on the surface of NiMo0_(4),which can accelerate Li+diffusion kinetics and provide more active site for lithium *** excepted,P-NiMo0_(4) electrode delivered a high specific capacity(1,130 mA·g^(-1) at 100 mA·g^(-1) after 100 cycles),outstanding cycling durability(945 mA·g^(-1) at 500 mA·g^(-1) over 200 cycles),and impressive rate performance(640 mA·g^(-1)at 2,000mA·g^(-1))for lithium ion batteries(LIBs).This work could provide a potential strategy for improving intrinsic conductivity of transition metal oxides as high-performance anodes for LIBs.

关键词： NiMo0_(4) phosphorus doping anode lithium ion batteries

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Pore Engineering for Covalent Organic Framework Membranes

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Chemical Research in Chinese Universities 2022年第2期38卷 364-372页

作者： YAO Jin LU Ya SUN Huihui ZHAO Xin Key Laboratory of Synthetic and Self-assembly Chemistry for Organic Functional Molecules Shanghai Institute of Organic ChemistryChinese Academy of SciencesShanghai 200032P.R.China School of Chemistry and Materials Science Hangzhou Institute for Advanced StudyUniversity of Chinese Academy of SciencesHangzhou 310024P.R.China College of Chemistry and Materials Science Shanghai Normal UniversityShanghai 200234P.R.China

Membrane technology is of particular significance for the sustainable development of society owing to its potential capacity to tackle the energy shortage and environmental *** materials are the core part of membrane *** have always been pursuing predictable structures of advanced membrane materials,which provides a possibility to fully unlock the potential of *** organic frameworks(COFs),with the advantage of controllable pore microenvironment,are considered to be promising candidates to achieve this design *** customizable function of COF membranes through pore engineering does well in the enhancement of selective permeability performance,which offers COF membranes with great application potentials in separation and transportation *** this context,COF-based membranes have been developed rapidly in recent ***,we present a brief overview on the strategies developed for pore engineering of COF membranes in recent years,including skeleton engineering,pore surface engineering,host-guest chemistry and membrane ***,the features of transmission or separation of molecules/ions based on COF membranes and corresponding applications are also *** the last part,the challenges and prospects of the development of COF membranes are discussed.

关键词： Membrane technology Covalent organic framework(COF) Pore engineering Separation Ion transportation

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N-doped carbon nanotubes supported CoSe_(2) nanoparticles:A highly efficient and stable catalyst for H_(2)O_(2) electrosynthesis in acidic media

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Nano Research 2022年第1期15卷 304-309页

作者： Longcheng Zhang Jie Liang Luchao Yue Zhaoquan Xu Kai Dong Qian Liu Yonglan Luo Tingshuai Li Xiaohong Cheng Guanwei Cui Bo Tang Abdulmohsen Ali Alshehri Khalid Ahmed Alzahrani Xiaodong Guo Xuping Sun School of Chemical Engineering Sichuan UniversityChengdu 610065China Institute of Fundamental and Frontier Sciences University of Electronic Science and Technology of ChinaChengdu 610054China Hubei Key Laboratory of Low Dimensional Optoelectronic Materials and Devices Hubei University of Arts and ScienceXiangyang 441053China College of Chemistry Chemical Engineering and Materials ScienceShandong Normal UniversityJinan 250014China Chemistry Department Faculty of Science&Center of Excellence for Advanced Materials ResearchKing Abdulaziz UniversityP.O.Box 80203Jeddah21589Saudi Arabia

Electrocatalytic oxygen reduction reaction(ORR)provides an attractive alternative to anthraquinone process for H_(2)O_(2) *** design of earth-abundant electrocatalysts for H_(2)O_(2) synthesis via a two-electron ORR process in acids is attractive but still:very *** this work,we report that nitrogen-doped carbon nanotubes as a multi-functional support for CoSe2 nanoparticles not only keep CoSe_(2) nanoparticles well dispersed but alter the crystal structure,which in turn improves the overall catalYtic behaviors and thereby renders high O_(2)-to-H_(2)O_(2) conversion *** 0.1 M HClO_(4),such CoSe_(2)@NCNTs hybrid delivers a high H_(2)O_(2) selectivity of 93.2% and a large H_(2)0_(2) yield rate of 172 ppm·h^(-1) with excellent durability up to 24 ***,CoSe_(2)@NCNTs performs effectively for organic dye degradation via electro-Fenton process.

关键词： cobalt selenide nitrogen-doped carbon nanotube electrocatalysis two-electron oxygen reduction reaction hydrogen peroxide

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Operando modeling and measurements:Powerful tools for revealing the mechanism of alkali carbonate-based sorbents for CO_(2)capture in real conditions

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Frontiers in Energy 2023年第3期17卷 380-389页

作者： Tianyi CAI Mengshi WANG Xiaoping CHEN Ye WU Jiliang MA Wu ZHOU School of Energy and Power Engineering Shanghai Key Laboratory of Multiphase Flow and Heat Transfer in Power EngineeringUniversity of Shanghai for Science and TechnologyShanghai 200093China Key Laboratory of Energy Thermal Conversion and Control of the Ministry of Education School of Energy and EnvironmentSoutheast UniversityNanjing 210096China Key Laboratory of Thermal Control of Electronic Equipment and Advanced Combustion Laboratory of the Ministry of Industry and Information Technology School of Energy and Power EngineeringNanjing University of Science and TechnologyNanjing 210094China

Alkalicarbonate-based sorbents(ACSs),including Na_(2)CO_(3)-and K2CO_(3)-based sorbents,are promising for CO_(2)***,the complex sorbent components and operation conditions lead to the versatile kinetics of CO_(2)sorption on these *** paper proposed that operando modeling and measurements are powerful tools to understand the mechanism of sorbents in real operating conditions,facilitating the sorbent development,reactor design,and operation parameter *** reviewed the theoretical simulation achievements during the development of *** elucidated the findings obtained by utilizing density functional theory(DFT)calculations,ab initio molecular dynamics(AIMD)simulations,and classical molecular dynamics(CMD)simulations as *** hygroscopicity of sorbent and the humidity of gas flow are crucial to shifting the carbonation reaction from the gas-solid mode to the gas-liquid mode,boosting the ***,it briefly introduced a machine learning(ML)approach as a promising method to aid sorbent ***,it demonstrated a conceptual compact operando measurement system in order to understand the behavior of ACSs in the real operation *** proposed measurement system includes a micro fluidizedbed(MFB)reactor for kinetic analysis,a multi-camera sub-system for 3D particle movement tracking,and a combined Raman and IR sub-system for solid/gas components and temperature *** is believed that this system is useful to evaluate the real-time sorbent performance,validating the theoretical prediction and promoting the industrial scale-up of ACSs for CO_(2)capture.

关键词： CO_(2)capture carbonation theoretical modeling operando techniques reaction visualization

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