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Guest-induced topological transformation and near-infrared photothermal conversion featuring the Cp*Rh unit via coordination-driven self-assembly

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science China Chemistry 2025年第04期68卷 1345-1354页

作者： Xin-Yu Wang Qiu-Shui Mu Xiang Gao Guo-Xin Jin shanghai Key Laboratory of Molecular Catalysis and Innovative Materials State Key Laboratory of Molecular Engineering of PolymersDepartment of ChemistryFudan University

Herein, we perform a topological transformation by guest induction, converting [2]catenane Rh-1 into the Rh-3 molecular figure-of-eight. The transformation involves the interaction of longer π-acceptor half-sandwich RhⅢbimetallic building block B1 [（Cp*Rh）2（TPPHZ）]（OTf）4and π-donor bipyridyl ligands 4,4'-bis(（pyridin-4-ylthio）methyl)-1,1'-biphenyl with four molecules of pyrene under ambient temperature in high yields. Intriguingly, despite the involvement of a single pyrene molecule in modifying [2]catenane Rh-2 by transitioning B1 to B2, the underlying skeleton of Rh-2 remains unaltered. Furthermore, we explored the application of these substances before and after the reaction for near-infrared（NIR） photothermal *** meticulous structural analysis, the π–π stacking interactions play a pivotal role in stabilizing the abovementioned structures, enhancing the nonradiative transitions and initiating photothermal conversion in solution. Based on the results, the introduction of pyrene significantly intensified the π–π stacking interactions but diminished the electron density between the adjacent NDI units, leading to a decrease in the NIR photothermal conversion efficiency（from 58.29% to 51.60%）. In this study,an innovative approach is introduced for fabricating valuable half-sandwich-structured NIR photothermal conversion materials,and this research has promising prospects for enhancing the field of materials science with potential candidates for future development.

关键词： topological transformation guest-induced self-assembly molecular figure-of-eight near-infrared photothermal conversion

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A comprehensive review on rectification and power management strategies for triboelectric nanogenerators

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science China(Technological sciences) 2025年第3期68卷 1-29页

作者： Zhongjie LI Bingyan CUI Biao WANG Fan SHEN Hao WU Ying GONG Yan PENG Hengyu GUO Dan ZHANG Institute of Artificial Intelligence School of Future TechnologyShanghai UniversityShanghai200444China School of Mechatronic Engineering and Automation Shanghai UniversityShanghai200444China Department of Applied Physics Chongqing UniversityChongqing400044China Engineering Research Center of Unmanned Intelligent Marine Equipment Shanghai UniversityShanghai200444China

Nanogenerators utilize nanomaterials to harvest mechanical or thermal energy at the micro-nano scale,thereby providing power for small self-sustaining *** to traditional generators,nanogenerators offer advantages such as compact size,high flexibility,and broad *** nanogenerators(TENGs),based on triboelectric theory,can collect energy from mechanical sources such as vibrations or sliding *** hold promise for powering small ***,the high pulse characteristics of their output voltage prevent them from directly charging electronic *** address the requirements of the internet of things(IoTs),this paper comprehensively reviews state-of-the-art power management systems used to enhance the current stability and output power of ***,the working principle and resistive load output characteristics of TENGs are *** management circuits(PMCs)based on full-wave rectifiers,half-wave rectifiers,and Bennet's doublers are subsequently analyzed and *** and electronic switches proposed to further improve rectifier performance are also *** switches are categorized as travel and voltagetriggered switches,while electronic switches include silicon-controlled rectifiers(SCRs),metal-oxide-semiconductor fieldeffect transistors(MOSFETs),and integrated *** conclusion,the characteristics and applications of PMCs are summarized,along with the identification of existing limitations in their ***,appropriate solutions and prospects for further development are explored.

关键词： triboelectric nanogenerators power management circuit rectifier switch

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Exploration of Gas‑Dependent Self‑Adaptive Reconstruction Behavior of Cu_(2)O for Electrochemical CO_(2) Conversion to Multi‑Carbon Products

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Nano-Micro Letters 2025年第3期17卷 280-296页

作者： Chaoran Zhang Yichuan Gu Qu Jiang Ziyang Sheng Ruohan Feng Sihong Wang Haoyue Zhang Qianqing Xu Zijian Yuan Fang Song State Key Laboratory of Metal Matrix Composites School of Materials Science and EngineeringShanghai Jiao Tong UniversityShanghai 200240People’s Republic of China

Structural reconstruction of electrocatalysts plays a pivotal role in catalytic performances for CO_(2)reduction reaction(CO_(2)RR),whereas the behavior is by far superficially ***,we report that CO_(2)accessibility results in a universal self-adaptive structural reconstruction from Cu_(2)O to Cu@CuxO composites,ending with feeding gas-dependent microstructures and catalytic *** CO_(2)-rich atmosphere favors reconstruction for CO_(2)RR,whereas the CO_(2)-deficient one prefers that for hydrogen evolution *** the assistance of spectroscopic analysis and theoretical calculations,we uncover a CO_(2)-induced passivation behavior by identifying a reductionresistant but catalytic active Cu(I)-rich amorphous layer stabilized by*CO ***,we find extra CO production is indispensable for the robust production of *** inverse correlation between durability and FECO/FEC2H4 is disclosed,suggesting that the selfstabilization process involving the absorption of*CO intermediates on Cu(I)sites is essential for durable *** by this insight,we design hollow Cu_(2)O nanospheres for durable and selective CO_(2)RR electrolysis in producing *** work recognizes the previously overlooked passivation reconstruction and self-stabilizing behavior and highlights the critical role of the local atmosphere in modulating reconstruction and catalytic processes.

关键词： CO_(2)reduction reaction Electrocatalysts Cu_(2)O Reconstruction Self-adaptive electrocatalysis

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Efficacy of ultrasound cyclo-plasty in patients with refractory glaucoma

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International Journal of Ophthalmology(English edition) 2025年第3期18卷 420-423页

作者： Hui-Min Zhong Xiao-Hong Liu Shou-Yue Huang Hui-Ping Yao Yi-Sheng Zhong Jing Wang Department of Ophthalmology Ruijin Hospital Affiliated Medical SchoolShanghai Jiao Tong UniversityShanghai 200025China Department of Ophthalmology Shanghai General Hospital(Shanghai First People’s Hospital)Shanghai Jiao Tong UniversityShanghai 200080China

AIM:To assess the efficacy and safety of ultrasound cycloplasty(UCP)in lowering intraocular pressure(IOP)among Chinese patients suffering from refractory ***:In this 12-month retrospective study,28 patients with refractory glaucoma(IOP≥25 mm Hg)were treated with 8-second UCP using either 8 or 10 probe *** principal measure of efficacy was the decrease in IOP at the following intervals after UCP:1d,1,3,6,and 12mo,with each measurement compared to ***:Mean IOP(in mm Hg)was reduced from 46.8±8.9 to 24.5±3.2,27.0±4.8,29.1±4.6,26.1±4.5,and 28.3±4.8 at 1d,1,3,6,and 12mo postoperatively,*** to baseline,IOP reductions at these time points were 45.0%,39.9%,35.3%,41.4%,and 36.7%,*** patients experienced relief from ocular pain after *** cases of choroidal detachment or hypotony was ***:UCP is effective in reducing IOP among Chinese patients with refractory glaucoma and shows a favorable safety profile.

关键词： ultrasound cyclo-plasty refractory glaucoma intraocular pressure

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Discovery of a novel thiophene carboxamide analogue as a highly potent and selective sphingomyelin synthase 2 inhibitor for dry eye disease therapy

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ACTA PHARMACEUTICA SINICA B 2025年第1期15卷 392-408页

作者： Yang, Jintong Lu, Yiteng Hu, Kexin Zhang, Xinchen Wang, Wei Ye, Deyong Mo, Mingguang Xiao, Xin Wan, Xichen Wu, Yuqing Zhang, Shuxian Huang, He Qu, Zhibei Hu, Yimin Cao, Yu Hong, Jiaxu Zhou, Lu Fudan Univ Sch Pharm Shanghai 201203 Peoples R China Fudan Univ Eye & ENT Hosp Dept Ophthalmol State Key Lab Med Neurobiol Shanghai 200031 Peoples R China NHC Key Lab Myopia & Related Eye Dis Shanghai 200031 Peoples R China shanghai Engn Res Ctr Synthet Immunol Shanghai 200032 Peoples R China Fudan Univ Childrens Hosp Natl Pediat Med Ctr China Dept Ophthalmol Shanghai 201102 Peoples R China shanghai Jiao Tong Univ Peoples Hosp 9 Inst Precis Med Sch Med Shanghai 200125 Peoples R China Fudan Univ Inst Metab & Integrat Biol Shanghai 200438 Peoples R China Quzhou Fudan Inst Quzhou 324002 Peoples R China

Dry eye disease (DED) is a prevalent and intractable ocular disease induced by a variety of causes. Elevated sphingomyelin (SM) levels and pro-inflammatory cytokines were detected on the ocular surface of DED patients, particularly in the meibomian glands. Sphingomyelin synthase 2 (SMS2), one of the proteins involved in SM synthesis, would light a novel way of developing a DED therapy strategy. Herein, we report the design and optimization of a series of novel thiophene carboxamide derivatives to afford 14l with an improved highly potent inhibitory activity on SM synthesis (IC50, SMS2 = 28 nmol/ L). Moreover, 14l exhibited a notable protective effect of anti-inflammation and anti-apoptosis on human corneal epithelial cells (HCEC) under TNF-a-hyperosmotic stress conditions in vitro, with an acceptable ocular specific distribution (corneas and meibomian glands) and pharmacokinetics (PK) profiles (t1/2, cornea = 1.11 h;t1/2, meibomian glands = 4.32 h) in rats. Furthermore, 14l alleviated the dry eye symptoms including corneal fluorescein staining scores and tear secretion in a dose-dependent manner in mice. Mechanically, 14l reduced the mRNA expression of Tnf-a, Il-1b and Mmp-9 in corneas, as well as the proportion of very long chain SM in meibomian glands. Our findings provide a new strategy for DED therapy based on selective SMS2 inhibitors. 2025 The Authors. Published by Elsevier B.V. on behalf of Chinese Pharmaceutical Association and Institute of Materia Medica, Chinese Academy of Medical sciences. This is an open access article under the CC BY-NC-ND license (http://***/licenses/by-nc-nd/4.0/).

关键词： Sphingomyelin synthase 2 Thiophene carboxamide SMS2 inhibitor Dry eye disease Tumor necrosis factor receptor 1 Human corneal epithelial cells Sphingomyelin Meibomian glands

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Mechanisms of nucleus accumbens deep brain stimulation in treating mental disorders

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Fundamental Research 2025年第1期5卷 48-54页

作者： Hanyang Ruan Geya Tong Minghui Jin Kathrin Koch Zhen Wang shanghai Mental Health Center Shanghai Jiao Tong University School of MedicineShanghai 200030China TUM-Neuroimaging Center(TUM-NIC) Technical University of MunichMunich 81675Germany Department of Neuroradiology School of MedicineKlinikum Rechts Der IsarTechnical University of MunichMunich 81675Germany School of Psychology Shanghai Jiao Tong UniversityShanghai 200030China shanghai Key Laboratory of Psychotic Disorders Shanghai 200030China

Growing evidence supports the effectiveness of deep brain stimulation(DBS)in treating various psychiatric *** has the potential to selectively stimulate specific subcortical brain areas thus providing high-frequency electric stimulation of these *** nucleus accumbens(NAc),a frequent DBS target,has shown promise in treating psychiatric conditions like depression,obsessive-compulsive disorder,and *** this review,we provide an overview across studies investigating the effects of NAc DBS in humans and animals and discuss potential mechanisms underlying its clinical *** address the anatomical properties of NAc and discuss,in particular,the frequently reported differential effects of NAc shell and NAc core ***,by outlining the various NAc cell types,transmitter systems(i.e.,predominantly GABAergic and dopaminergic systems)and anatomical pathways that have been shown to be relevant for NAc DBS stimulation effects,we aim to further elucidate the neurobiological determinants of NAc DBS ***,since treatment effects of NAc DBS are most probably also related to alterations in NAc connected circuits or networks,we review studies focusing on the investigation of NAc DBS network *** examining these various components that are assumed to be of relevance in the context of NAc DBS,this review will hopefully contribute to increasing our knowledge about the mechanisms underlying NAc DBS and optimizing future selection of optimal DBS targets.

关键词： Deep brain stimulation Nucleus accumbens Mental disorder Neuromodulation Neurophysiology

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The Hugoniot curve and sound velocity of forsterite to 1200 GPa

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Geoscience Frontiers 2025年第1期16卷 313-320页

作者： Jian Song Liang Sun Huan Zhang Xiaoxi Duan Zanyang Guan Lu Zhang Xiaokang Feng Weiming Yang Hao Liu Mengsheng Yang Yulong Li Dong Yang Zhebin Wang Jiamin Yang Wenge Yang Toshimori Sekine Youjun Zhang Zongqing Zhao Zhongqing Wu Laboratory of Seismic and Physics of Earth’s Interior School of Earth and Space SciencesUniversity of Science and Technology of ChinaHefei 230026China National Key Laboratory of Plasma Physics Laser Fusion Research Center(LFRC)Chinese Academy of Engineering PhysicsMianyang 621900China Center for High Pressure science and technology Advanced Research(HPSTAR) Shanghai 201203China Graduate School of Engineering Osaka UniversitySuitaJapan shanghai Key Laboratory of Material Frontiers Research in Extreme Environments(MFree) Shanghai Advanced Research in Physical Sciences(SHARPS)PudongShanghai 201203China Institute of Atomic and Molecular Physics Sichuan UniversityChengdu 610065China National Geophysical Observatory at Mengcheng University of Science and Technology of ChinaHefei 230026China CAS Center for Excellence in Comparative Planetology University of Science and Technology of ChinaHefei 230026China

The comprehension of the composition and physical state of the deep interiors of large planets,as well as the impact events pertinent to planetary formation and evolution,necessitates an understanding of the properties of planetary materials under extreme ***(Mg2SiO4),a significant geological mineral,has not been fully characterized in terms of its behavior under shock compression due to a lack of consensus among previous experiments and simulations aimed at determining its Hugoniot,as well as the absence of knowledge of sound velocity at high pressures,a critical parameter indicative of phase transformation and *** this study,we delineated the Hugoniot curve of the mineral forsterite up to immense pressures of 1200 *** the first time,we successfully constrained its sound velocity along the Hugoniot curve up to 760 GPa by combining laser-driven shock experiments with first-principles molecular dynamics *** measured Hugoniot data for forsterite corroborated previous findings and suggested the occurrence of incongruent melting during shock ***,along their respective Hugoniot curves,the sound velocity of forsterite was observed to fall between that of the minerals bridgmanite and *** remarkable agreement between the experimental results and simulation data provides reliable sound velocity measurements on the forsterite Hugoniot,which is critical for comprehensively understanding the phase transition and melting behavior of forsterite under ultra-high *** knowledge sheds invaluable light on the behavior of this significant geological mineral under extreme conditions akin to those found in the interiors of planets.

关键词： Forsterite Hugoniot Sound velocity First-principles molecular dynamics Shock compression Lateral release

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Causes and predictability of the “explosive” intensification of Super Typhoon Yagi after entering the South China Sea in 2024

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science China Earth sciences 2025年第04期68卷 1298-1302页

作者： Ruifen ZHAN Jie FENG Department of Atmospheric and Oceanic sciences/Institute of Atmospheric sciences Fudan University CMA-FDU Joint Laboratory of Marine Meteorology shanghai Key Laboratory of Ocean-land-atmosphere Boundary Dynamics and Climate Change

1. Introduction The intensification of nearshore tropical cyclones(TCs), particularly the process of rapid intensification(RI), poses a severe threat to coastal populations due to its short warning time and devastating impact. It also presents a significant challenge to operational TC forecasting. Therefore, understanding the physical mechanisms and predictability of nearshore TC intensification is of great importance.

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Merging bound states in the continuum in an open acoustic resonator

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science China(Physics,Mechanics & Astronomy) 2025年第1期68卷 120-127页

作者： Lujun Huang Bin Jia Artem S.Pilipchuk Sibo Huang Chen Shen Almas F.Sadreev Yong Li Andrey E.Miroshnichenko School of Physics and Electronic sciences East China Normal UniversityShanghai 200241China Institute of Acoustics Tongji UniversityShanghai 200092China L.V.Kirensky Institute of Physics Krasnoyarsk 660036Russia Department of Mechanical Engineering Rowan UniversityGlassboro 08028USA School of Engineering and technology University of New South Wales at CanberraACT 2610Australia

Bound states in the continuum(BICs)are perfectly localized resonances despite embedding in the continuum ***,an isolated BIC is very sensitive to the structure ***,we report merging acoustic BICs in a single open resonator,robust against the structure *** find that both symmetry-protected BIC and Friedrich-Wintgen BIC are sustained in a single coupled waveguide-resonator *** varying the height and length of the resonator,these two BICs move toward each other and merge into a single one at a critical *** to an individual BIC,the merged BIC is robust against fabrication error because its Q-factor is proportional toΔL^(−4),whereΔL embodies the structure *** essence of this extraordinary phenomenon is perfectly explained by the two-and three-level approximations of the effective non-Hermitian ***,we present direct experimental demonstrations of the moving and merging of BICs in a coupled 3D waveguide-resonator,which are evidenced by the vanishing of the linewidth of Fano resonance in the transmission *** results may find exciting applications in designing high-quality acoustic sources,sensors and filters.

关键词： acoustic resonances bound state in the continuum high-Q resonances

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Accurate prediction of essential proteins using ensemble machine learning

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Chinese Physics B 2025年第1期34卷 108-115页

作者： Dezhi Lu Hao Wu Yutong Hou Yuncheng Wu Yuanyuan Liu Jinwu Wang School of Medicine Shanghai UniversityShanghai 200444China shanghai Key Laboratory of Orthopaedic Implants Department of Orthopaedic SurgeryShanghai Ninth People’s HospitalShanghai Jiao Tong University School of MedicineShanghai 200011China University of shanghai for science and technology Shanghai 200093China

Essential proteins are crucial for biological processes and can be identified through both experimental and computational *** experimental approaches are highly accurate,they often demand extensive time and *** address these challenges,we present a computational ensemble learning framework designed to identify essential proteins more *** method begins by using node2vec to transform proteins in the protein–protein interaction(PPI)network into continuous,low-dimensional *** also extract a range of features from protein sequences,including graph-theory-based,information-based,compositional,and physiochemical ***,we leverage deep learning techniques to analyze high-dimensional position-specific scoring matrices(PSSMs)and capture evolutionary *** then combine these features for classification using various machine learning *** enhance performance,we integrate the outputs of these algorithms through ensemble methods such as voting,weighted averaging,and *** approach effectively addresses data imbalances and improves both robustness and *** ensemble learning framework achieves an AUC of 0.960 and an accuracy of 0.9252,outperforming other computational *** results demonstrate the effectiveness of our approach in accurately identifying essential proteins and highlight its superior feature extraction capabilities.

关键词： protein-protein interaction(PPI) essential proteins deep learning ensemble learning

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