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Electronic structural engineering of bimetallic Bi-Cu alloying nanosheet for highly-efficient CO_(2) electroreduction and Zn-CO_(2) batteries

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Nano Research 2024年第5期17卷 3684-3692页

作者： Wenbo Wu Jiaye Zhu Yun Tong Shuangfei Xiang Pengzuo Chen School of Chemistry and Chemical Engineering Key Laboratory of Surface and Interface Science of Polymer Materials of Zhejiang ProvinceZhejiang Sci-Tech UniversityHangzhou 310018China

Regulating the electronic structure of Bi-based materials by alloying engineering is promising to promote the electrocatalytic activity,but it remains some challenges to be *** this study,a facile electrochemical co-deposition strategy is developed to synthesize the bimetallic Bi_(9)Cu_(1) alloy nanosheet on carbon cloth(Bi_(9)Cu_(1)/CC),which represents a novel self-supporting electrode for the electrocatalytic carbon dioxide(CO_(2))reduction reaction(CO_(2)RR).The Bi_(9)Cu_(1)/CC catalyst has achieved a remarkable catalytic performance with high Faradaic efficiencies(FE)of over 90%for formate at wide potentials from-0.7 to-1.2 V *** hydrogen electrode(RHE).Moreover,the reversible Zn-CO_(2) battery can be driven by Bi_(9)Cu_(1)/CC cathode with a largest power density of 1.4 mW·cm^(-2),and superior operating *** systematic characterizations and electrochemical results confirm that the improved catalytic active sites,the enhanced mass/charge transport and the optimal reaction kinetics of Bi nanosheet are realized for CO_(2)RR by Cu *** situ attenuated total reflection infrared(ATR-IR)result confirms the bimetallic Bi-Cu active sites prefer to follow the^(*)OCHO conversion *** density functional theory(DFT)calculations suggest that the Cu alloying contributes to the increased density of states near the Fermi surface of Bi and the optimized adsorption of^(*)OCHO intermediates on the Bi sites,resulting in the excellent catalytic performance.

关键词： electronic regulation bismuth nanosheet copper alloying CO_(2)electroreduction Zn-CO_(2)batteries

Corrosion behavior and protection mechanism of carbon steel coated with ethylene chlorotrifluoroethylene(ECTFE)

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Journal of zhejiang university-science A(Applied Physics & Engineering) 2024年第6期25卷 502-515页

作者： Peihu SHEN Jun WEN Biqin DONG Hedong LI Minjia WANG School of Civil Engineering and Architecture Zhejiang Sci-Tech UniversityHangzhou310018China College of Civil and Transportation Engineering Shenzhen UniversityShenzhen518061China zhejiang Research Institute of Chemical Industry Co. Ltd.Hangzhou310023China

Ethylene chlorotrifluoroethylene(ECTFE)coating was applied to the surface of carbon steel through electrostatic spraying and low-temperature heat *** morphology and structure of the coating were analyzed using various characterization *** electrochemical data of the coated steel soaked in 3.5%(mass fraction)NaCl solution for 90 d at different periods were also *** findings indicate that the outer surface of the coating remains structurally stable before and after soaking.F can diffuse into the steel substrate,facilitating the bonding between the coating and the steel substrate,but the free F also induces a weakening effect on the crystalline *** to the thickness of the coating edge and the susceptibility to infiltration of the corrosive medium,under-film micro-zone corrosion occurs at a slow *** soaking for 90 d,the impedance modulus measures approximately 10^(4)Ω·cm^(2),and the open circuit potential(OCP)is−0.61 *** self-corrosion current density is 1.13×10^(−6)A/cm^(2),resulting in a calculated coating protection rate of 99.29%.In summary,despite edge corrosion occurring,the ECTFE coating provides excellent corrosion protection.

关键词： Coating Fluorine resin Edge corrosion Corrosive behavior Electrochemical performance

Accelerating solar driven CO_(2) reduction via sulfur-doping boosted water dissociation and proton transfer

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Nano Research 2024年第3期17卷 1056-1065页

作者： Ke Yan Liang Chen Yangguang Hu Ting Wang Cong Chen Chao Gao Youju Huang Benxia Li School of Chemistry and Chemical Engineering Key Laboratory of Surface&Interface Science of Polymer Materials of Zhejiang ProvinceZhejiang Sci-Tech UniversityHangzhou 310018China College of Material Chemistry and Chemical EngineeringKey Laboratory of Organosilicon Chemistry and Material TechnologyMinistry of EducationHangzhou Normal UniversityHangzhou 311121China School of Chemistry and Materials science University of Science and Technology of ChinaHefei 230026China

Exploring efficient photocatalysts for solar driven CO_(2) reduction with water(H_(2)O)as a proton donor is highly imperative but remains a great challenge because the synchronous enhancement of CO_(2) activation,H_(2)O dissociation and proton transfer is hardly achieved on a ***,the sluggish H_(2)O dissociation impedes the photocatalytic CO_(2) reduction reaction involving multiple proton–electron coupling transfer ***,a sulfur-doped BiOCl(S-BiOCl)photocatalyst with abundant oxygen vacancies(OV)is developed,which exhibits broadband-light harvesting across solar spectrum and distinct photothermal effect due to *** photocatalytic CO_(2) reduction with H_(2)O in a gas–solid system,the high CO yield of 49.76μmol·g_(cat)^(-1)·h^(-1) with 100%selectivity is achieved over the S-BiOCl catalyst under a simulated *** H_(2)O-assisted CO_(2) reduction reaction on S-BiOCl catalyst is triggered by photocatalysis and the photothermal heating further enhances the reaction *** kinetic isotope experiments indicate that the sluggish H_(2)O dissociation affects the whole photocatalytic CO_(2) reduction *** presence of oxygen vacancies promotes the adsorption and activation of H_(2)O and CO_(2),and the doped S sites play a crucial role in boosting H_(2)O dissociation and accelerating the dynamic migration of hydrogen *** a result,the ingenious integration of OV defects,S sites and photothermal effect in S-BiOCl catalyst conjointly contributes to the significant improvement in photocatalytic CO_(2) reduction performance.

关键词： BiOCl sulfur doping photocatalytic CO_(2)reduction H_(2)O activation proton feeding

On electro-acoustic characteristics of a marine broadband sparker for seismic exploration

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Journal of Oceanology and Limnology 2024年第3期42卷 760-771页

作者： Jing LI Kai LIU Liancheng ZHANG Chenguang LIU Yanliang PEI Baohua LIU Key Laboratory of Marine Geology and Metallogency First Institute of OceanographyMinistry of Natural ResourcesQingdao 266061China Laboratory of Marine Geology Laoshan LaboratoryQingdao 266237China Key Laboratory of Fluid Transmission technology of zhejiang Province Zhejiang Sci-Tech UniversityHangzhou 310018China Key Laboratory of Submarine Acoustic Investigation and Application of Qingdao(Preparatory) Qingdao 266061China Key Laboratory of Deep Sea Mineral Resources Development Shandong(Preparatory)Qingdao 266061China

The construction of major marine infrastructure projects and the exploration and development of deep-sea mineral resources require fine imaging of seabed strata and *** highresolution marine seismic exploration based on a high broadband sparker source is an important approach to reveal seabed stratum and reservoir structure,and identify *** optimize the performance of sparker seismic source,we investigated the electro-acoustic characteristics of spark discharge under conditions of different charging voltages and electrode *** show that the sound source level increased with the increase of the charging voltage,whereas the main frequency decreased when the charging voltage *** addition,it was found that the charging capacitance had more obvious influence on the main frequency than the sound source level *** the load energy decreased with increasing electrode number,the sound source level still increased but the main frequency ***,the primary to bubble(P/B)ratio increased with the increase of the electrode *** gain a deeper insight into the electro-acoustic characteristics,we investigate the relationship between sound source level and power peak,from which a good correlation was observed.A more practical statistical analysis on the rise rate of current was processed,and a perfect logarithmic function was ***,we found that the main frequency was most possibly subjected to the electrical energy,especially the charging energy per *** results indicate that the charging energy per electrode less than 10 J could increase the main frequency to above 300 *** last,the main frequency could be reduced to 20 Hz when the charging energy of a single-electrode discharge was enhanced to over 4 *** study shall be helpful in developing a sparker seismic source and improving the performance for marine engineering exploration and geohazard assessment.

关键词： high-resolution marine seismic exploration sparker seismic source sound source level main frequency electro-acoustic characteristics

Regularly Tuning Quantum Interference in Single-Molecule Junctions through Systematic Substitution of Side Groups with Varied Electron Effects

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Chinese Journal of Chemistry 2024年第11期42卷 1217-1222页

作者： Xianjing Xie Yirong Zhang Junrui Zhang Xingyuan Cui Wei Liu Xunshan Liu Key Laboratory of Surface&Interface science of Polymer Materials of zhejiang Province School of Chemistry and Chemical EngineeringZhejiang Sci-Tech University928 Second StreetHangzhouZhejiang310018 China State Key Laboratory of Rare Earth Resource Utilization Changchun Institute of Applied ChemistryChinese Academy of SciencesChangchunJilin130022 China School of Materials science and Engineering Nanjing University of Science and TechnologyNanjingJiangsu210094 China

Investigating the quantum interference effect in single molecules is essential to comprehensively understand the underlying mechanism of single-molecule charge *** this study,we employed the mother molecule m-OPE and introduced a series of side groups with various electronic effects at the 2-position of the central phenyl ring,creating four daughter m-OPE *** single molecular conductivities of these molecule wires were measured using the scanning tunneling microscope breaking junction *** findings demonstrate that the substitutions regularly modulate the destructive quantum interference occurring within the m-OPE *** combining optical and electrochemical investigations,along with density functional theory computations,we discover that the conductivity of the molecules corresponds to the electron-donating/withdrawing ability of the ***,by adjusting the electron structures of the molecular backbone,we can systematically tailor the destructive quantum interference in the m-OPE molecules.

关键词： Quantum interference Single-molecule junctions Electron effect substituents Charge transport Molecular devices

Equivariant Tautological Integrals on Flag Varieties

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Chinese Annals of Mathematics,Series B 2024年第3期45卷 463-486页

作者： Xiaobo ZHUANG Department of Mathematical sciences Zhejiang Sci-Tech UniversityHangzhou 310018China

The author apples the Atiyah-Bott-Berline-Vergne formula to the equivariant tautological integrals over flag varieties of types A,B,C,D,and recovers the formulas expressing the integrals as iterated residues at infini... 详细信息

关键词： Localization Flag variety Residue

Defect Engineering and Carbon Supporting to Achieve Ni‑Doped CoP_(3) with High Catalytic Activities for Overall Water Splitting

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Nano-Micro Letters 2024年第11期16卷 569-584页

作者： Daowei Zha Ruoxing Wang Shijun Tian Zhong‑Jie Jiang Zejun Xu Chu Qin Xiaoning Tian Zhongqing Jiang Department of Physics Zhejiang Sci-Tech UniversityHangzhou 310018People’s Republic of China Department of Materials and Chemical Engineering Ningbo University of TechnologyNingbo 315211People’s Republic of China Guangzhou Key Laboratory for Surface Chemistry of Energy Materials Guangdong Engineering and Technology Research Center for Surface Chemistry of Energy MaterialsCollege of Environment and EnergySouth China University of TechnologyGuangzhou 510006People’s Republic of China

This work reports the use of defect engineering and carbon supporting to achieve metal-doped phosphides with high activities and stabilities for the hydrogen evolution reaction(HER)and the oxygen evolution reaction(OER)in alkaline ***,the nitrogen-doped carbon nanofiber-supported Ni-doped CoP_(3) with rich P defects(Pv·)on the carbon cloth(p-NiCoP/NCFs@CC)is synthesized through a plasma-assisted phosphorization *** p-NiCoP/NCFs@CC is an efficient and stable catalyst for the HER and the *** only needs overpotentials of 107 and 306 mV to drive 100 mA cm^(-2) for the HER and the OER,*** catalytic activities are higher than those of other catalysts reported *** high activities of the p-NiCoP/NCFs@CC mainly arise from its peculiar structural *** density functional theory calculation indicates that the Pv·richness,the Ni doping,and the carbon supporting can optimize the adsorption of the H atoms at the catalyst surface and promote the strong electronic couplings between the carbon nanofiber-supported p-NiCoP with the surface oxide layer formed during the OER *** gives the p-NiCoP/NCFs@CC with the high activities for the HER and the *** used in alkaline water electrolyzers,the p-NiCoP/NCFs@CC shows the superior activity and excellent stability for overall water splitting.

关键词： Plasma Electrocatalysis Hydrogen evolution reaction Oxygen evolution reaction Water splitting

Multifunctional Peptide-Melanin Hybrid Nanodots with Robust Anti-Cutaneous Photoaging Activity

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Journal of Analysis and Testing 2024年第3期8卷 395-401页

作者： Peizhe Li Qiming Zhu Baozhu Wang Shanshan He Qi Xu Kaiyan Li Yongmiao Shen Miao Su Zhijun Zhang Key Laboratory of Surface & Interface science of Polymer Materials of zhejiang Province School of Chemistry and Chemical Engineering Zhejiang Sci-Tech University College of Textile science and Engineering (International Silk Institute) Zhejiang Sci-Tech University Shanghai Beautyart Biotechnology Co. Ltd. Shengzhou Innovation Research Institute of zhejiang scitech university

Skin aging is a systematic and complex process, mainly including intrinsic aging caused by time change and extrinsic aging caused by environmental factors. Photoaging caused by ultraviolet (UV) irradiation is the principle extrinsic factor of skin aging, which can directly or indirectly cause damage to DNA and other biomolecules, generate reactive oxygen species(ROS), and induce a decrease in collagen synthesis and other adverse eff ect. Herein, to address the causative factors and multiple side eff ects of skin photoaging, we constructed multifunctional peptide-melanin hybrid nanodots (PMHDs) to achieve multifaceted synergistic anti-skin aging by using melanin-like nanodots (MDs) and functional peptides as active *** them, the peptide has the activity of promoting collagen synthesis, while the MDs have the function of absorbing UV light and scavenging free radicals. Additionally, the MDs also act as a carrier to increase the cellular uptake of the *** anti-photoaging eff ects of the PMHDs were systematically verifi ed in a multidimensional manner at the biochemical,cellular and small animal levels, respectively.

关键词： Nanodots

Peroxidase-like nanozyme based microenvironment-responsive injectable hydrogel for bacteria-infected wound healing

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science china technological sciences 2024年第10期67卷 3247-3260页

作者： ZHOU Wei LI XiaNan TANG MengCheng PAN LingFeng WANG BeiBei ZHANG Hao ZHANG Han WANG ShiBo KONG XiangDong Institute of Smart Biomaterial Materials School of Materials Science and EngineeringZhejiang University of Science & Technology zhejiang-Mauritius Joint Research Center for Biomaterials and Tissue Engineering Zhejiang University of Science & Technology

Hydrogel stands out as one of the most attractive wound dressings due to its excellent moisturizing properties and capacity to absorb wound exudates. However, conventional hydrogel dressings often lack responsiveness to the microenvironment, merely acting as protective barriers for the wound. Consequently, they exhibit limited effectiveness in preventing infection and facilitating wound repair. To address these problems, we have developed a multifunctional injectable hydrogel, CF/MS@HG, based on peroxidase-like nanozymes, aiming at rapidly healing bacterial-infected wounds. The hydrogel is mainly composed of oxidized sodium alginate, aminated gelatin, and polylysine, encapsulating MIL-101(CuFe) NPs(CF) and manganese selenide nanoparticles(MnSe2NPs, or MS NPs). After injection, the complex rapidly gelatinizes at the infected wound site through a Schiff base reaction. In vitro experiments have demonstrated the hydrogel's strong adhesion and self-healing ***, CF exhibiting peroxidase(POD)-like activity, catalyzes in situ hydrogen peroxide(H2O2) to generate highly toxic hydroxyl radicals(·OH) within the wound microenvironment, inducing oxidative damage to bacteria. Meanwhile, MS decomposes into H2Se in the slightly acidic wound microenvironment, disrupting bacterial metabolism and inhibiting *** addition of polylysine further enhances the hydrogel's antibacterial properties. In vivo experiments have shown that the hydrogel exhibits excellent biological safety and significantly promotes wound healing. This multifunctional smart hydrogel holds great promise for the treatment of bacterial-infected wounds.

关键词： peroxidase-like nanozyme manganese selenide injectable hydrogel bacterial infection wound healing