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Improved performance of LiMn_(0.8)Fe_(0.2)PO_(4) by addition of fluoroethylene carbonate electrolyte additive

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Chinese Chemical Letters 2024年第6期35卷 229-233页

作者： Guihuang Fang Wei Chen Hongwei Yang Haisheng Fang Chuang Yu Maoxiang Wu Faculty of Metallurgy and Energy Engineering Kunming University of Science and TechnologyKunming 650093China Key Laboratory of Optoelectronic Materials Chemistry and Physics Fujian Institute of Research on the Structure of MatterChinese Academy of SciencesFuzhou 350002China State Key Laboratory of Advanced Electromagnetic Engineering and Technology School of Electrical and Electronic EngineeringHuazhong University of Science and TechnologyWuhan 430074China

The addition of electrolyte additives is an effective strategy for tuning the property of the electrolyte to engineer the electrode/electrolyte interface,and there exist obvious discrepancies regarding the effect of fluoroethylene carbonate(FEC)as an electrolyte additive on the performance of *** FEC is introduced into the electrolyte of the LiMn_(0.8)Fe_(0.2)PO_(4)/Li cell and its effect on the properties of the LiMn_(0.8)Fe_(0.2)PO_(4) is *** is found that the addition of FEC in the electrolyte has a positive effect on the performance of the LiMn_(0.8)Fe_(0.2)PO_(4) cathode,which can be attributed to the reduced products generated by the interfacial side-reactions on the LiMn_(0.8)Fe_(0.2)PO_(4) cathode surface and the decreased metal dissolution in the FEC-containing electrolyte,thanks to the higher oxidation resistance of FEC and the easier and stronger binding of FEC and PF_6^(-).

关键词： Lithium-ion batteries LiMn_(0.8)Fe_(0.2)PO_(4) Cathode Electrolyte additives Fluoroethylene carbonate

Simulation design of thin film lithium niobate electro-optic modulator with bimetallic layer electrodes

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Optoelectronics Letters 2024年第6期20卷 339-345页

作者： WU Qiulin FENG Xinkai CHEN Jiaying MA Lei CHEN Huaixi LIANG Wanguo Fujian Institute of Research on the Structure of Matter Chinese Academy of SciencesFuzhou 350108China University of Chinese Academy of Sciences Beijing 100059China Fujian Science&Technology Innovation Laboratory for Optoelectronic Information of China Fuzhou 350108China1

Thin-film lithium niobate electro-optical modulator will become the key device in the future optical communication,which has the advantages of high modulation rate,low half-wave voltage,large bandwidth,and easy integration compared with conventional bulk lithium niobate ***,because the electrode gap of the lithium niobate film modulator is very narrow,when the microwave frequency gets higher,it leads to higher microwave loss,and the electro-optical performance of the modulator will be greatly ***,we propose a thin film lithium niobate electro-optic modulator with a bimetallic layer electrode structure to achieve microwave loss less than 8 dB/cm in the range of 200 GHz,exhibiting a voltage-length product of 1.1 V·cm and a 3 dB electro-optic bandwidth greater than 160 ***-speed data transmission test has been performed,showing good performance.

关键词： Simulation design of thin film lithium niobate electro-optic modulator with bimetallic layer electrodes

Fabrication and characterization of high-damage resistance Zn-diffused MgO:PPLN ridge waveguides

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Optoelectronics Letters 2024年第1期20卷 12-17页

作者： CHENG Xing FENG Xinkai MA Lei CHEN Jiaying CHEN Huaixi LIANG Wanguo College of Chemistry Fuzhou UniversityFuzhou 350108China Fujian Institute of Research on the Structure of Matter Chinese Academy of SciencesFuzhou 350108China Fujian Science&Technology Innovation Laboratory for Optoelectronic Information of China Fuzhou 350108China

This study investigates the fabrication process of Zn-diffused ridge waveguides in periodically poled magnesium-doped lithium niobate(PPMgO:LN).A controlled variable method is used to study the effects of diffusion temperature,diffusion time,ZnO film thickness,and barrier layer thickness on the surface domain depolarization and waveguide quality of PPMgO:LN.A special barrier layer is proposed that can automatically lift off from the sample surface,which increases the depth of Zn doping and reduces the surface loss of the *** optimizing the process parameters,we fabricate Zn-diffused PPMgO:LN ridge waveguides with a length of 22.80 mm and a period of 18.0μ*** above waveguides can make a second harmonic generation(SHG)at 775 nm with an output power of 90.20 mW by a pump power of 741 mW at 1550 *** corresponding conversion efficiency is 3.160%/W·cm2,and the waveguide loss is approximately 0.81 dB/*** results demonstrate that high-efficiency devices can be obtained through the fabrication process described in this paper.

关键词： waveguide waveguides pump

Highly crystalline Y3Al5O12:Ce3+ phosphor-in-silica glass ceramics for high-power solid-state lighting

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Journal of Rare Earths 2024年第11期42卷 2051-2057页

作者： Shisheng Lin Hang Lin Hongyi Yang Pengfei Wang Ping Sui Ju Xu Yao Cheng Yuansheng Wang Key Laboratory of Optoelectronic Materials Chemistry and Physics Fujian Institute of Research on the Structure of MatterChinese Academy of Sciences Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China Xiamen Institute of Rare-earth Materials Haixi InstitutesChinese Academy of Sciences College of Chemistry and Materials Science Fujian Normal University

The pursuit of high-brightness solid-state lighting（SSL） stimulates the development of all-inorganic color converters with high *** is required that the fluorescent material is able to cope with the extreme condition generated from the irradiation of high-power-density excitation *** such,in this work,we developed a new composite color converter,i,e.,Y3Al5O12:Ce3+phosphor-in-silica glass ceramic(YAG:Ce3+PiSGC).Remarkably,the amorphous SiO2matrix spontaneously transforms into tetragonal SiO2crystallites during co-sintering with crystallization fraction reaching up to>90%（almost full ceramization）.The activation energy for crystallization Ecand Avrami index n of amorphous silica oxide are 298.5 kJ/mol and 1.71,indicating the diffusion-controlled glass crystallization *** fabricated prototype high-power phosphor-converted white light-emitting diode（pc-wLED） and phosphor-converted white laser diode（pc-wLD） based on YAG:Ce3+PiSGC show satisfactory photometric/colorimetric *** developed color co nverters have combined merits of environmental protection property,cost-effective manufacturing,good luminescent performance,and easy *** study highlights a new kind of opto-functional composite material and its application as an efficient color converter in high-power solid-state lightings.

关键词： Glass ceramics Laser-driven white light Rare earths White light-emitting diode Y3Al5O12:Ce3+

Dynamically Securing the Data by^(1)O_(2)Sensitization of Fluorescent Composites with a High Latency and Uncrackable Features

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Chinese Journal of Chemistry 2024年第14期42卷 1651-1658页

作者： Yuanyuan Chen Jiamao Chen Huacan Wu Yifan Liu Donghui Wang Weiguo Huang College of Chemistry and Materials Science Fujian Normal UniversityFuzhouFujian350002 China State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of MatterChinese Academy of Sciences155 Yangqiao West RoadFuzhouFujian350002 China University of Chinese Academy of Sciences 19A Yuquan RoadBeijing100049 China

Dynamic fluorescent materials play a crucial role in secure inks for data encryption;however,they are still plagued by issues such as photodegradation,poor latency,and susceptibility to unauthorized ***,we propose a photochemically modulated dynamic fluorescent encryption system based on^(1)O_(2)sensitization of fluorescent composites,comprising a^(1)O_(2)-sensitive fluorophore(F2)and non-emissive *** UV irradiation,in-situ generated^(1)O_(2)from the polymer effectively binds with F2 to form endoperoxides(F2EPO),resulting in a significant redshift in emission,up to 150 ***^(1)O_(2)concentration is closely related to the irradiation time,rendering different fluorescent colors in a time-gated ***,the emission of F2EPO can be regulated by polymer chemical structure,molecular weight,and crosslinking *** on these merits,we develop a dynamic data encryption method with various non-emissive polymers as the data storage media,UV light irradiation as the data encoder,and F2 as the data *** light irradiation of diverse polymer solutions generates^(1)O_(2)at different concentrations,effectively encoding the data,which remains invisible under both UV and natural *** addition of F2 to these irradiated polymer solutions produces different redshifted fluorescence,enabling secure data *** to the non-emissive nature of the polymers,time-gated readout fashion,excellent latency of^(1)O_(2),and subtle interactions between^(1)O_(2)and F2,this data encryption is nearly *** work offers an advantage data encryption approach beyond the reach of conventional fluorophores.

关键词： Dynamic fluorescent materials Photochemically modulation ^(1)O_(2)-sensitive fluorophore High latency Data encryption Fluorescence Photochemistry Singlet oxygen

Study on synergistic leaching of potassium and phosphorus from potassium feldspar and solid waste phosphogypsum via coupling reactions

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Chinese Journal of Chemical Engineering 2024年第1期65卷 117-129页

作者： Chao Li Shizhao Wang Yunshan Wang Xuebin An Gang Yang Yong Sun School of Chemical Engineering and Technology Hebei University of TechnologyTianjin 300130China National Engineering Research Center of Green Recycling for Strategic Metal Resources Chinese Academy of SciencesBeijing 100190China School of Engineering Edith Cowan University270 Joondalup DriveJoondalupWA 6027Australia Key Laboratory of Carbonaceous Wastes Processing and Process Intensification of Zhejiang Province The University of Nottingham Ningbo ChinaNingbo 315100China

To achieve the resource utilization of solid waste phosphogypsum(PG)and tackle the problem of utilizing potassium feldspar(PF),a coupled synergistic process between PG and PF is proposed in this *** study investigates the features of P and F in PG,and explores the decomposition of PF using hydrofluoric acid(HF)in the sulfuric acid system for K leaching and leaching of P and F in *** impact factors such as sulfuric acid concentration,reaction temperature,reaction time,material ratio(PG/PF),liquid–solid ratio,PF particle size,and PF calcination temperature on the leaching of P and K is systematically investigated in this *** results show that under optimal conditions,the leaching rate of K and P reach more than 93%and 96%,*** study using shrinking core model(SCM)indicates two significant stages with internal diffusion predominantly controlling the leaching of *** apparent activation energies of these two stages are 11.92 kJ·mol^(-1)and 11.55 kJ·mol^(-1),respectively.

关键词： Phosphogypsum Potassium feldspar Coupling reaction Leaching Waste treatment Kinetics

Liquid-phase epitaxial layer by layer brushing fabrication of metalorganic frameworks films

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Nano Research 2024年第6期17卷 5698-5704页

作者： Li-Mei Chang Rui Zhai Zhi-Zhou Ma Jian-Dong Huang Zhi-Gang Gu Jian Zhang College of Chemistry Fuzhou UniversityFuzhou 350108China State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of MatterChinese Academy of SciencesFuzhou 350002China University of Chinese Academy of Sciences Beijing 100049China

Development of metal-organic framework(MOF)films is of great importance to expand their ***,we report a facile and universal method of liquid-phase epitaxial(LPE)layer by layer(LBL)brushing approach for fabricating MOF films on various substrates in a high-throughput *** MOF films preparation method offers a great prospective to cost-effectively construct films with short preparation time and little reagent ***,this LBL brushing approach has been implemented successfully to assemble various MOF films,including HKUST-1,zeolitic imidazolate framework-8(ZIF-8),Cu(bdc),and Cu_(2)(L)_(2)P(L=bdc,ndc,and cam;P=dabco and bipy).Afterwards,the classic MOF HKUST-1 and ZIF-8 films were grown on sensor chip electrode and porous fiber support for good volatile organic compounds(VOCs)selective sensing and water purification *** study demonstrates that this LBL brushing preparation method can be employed to synthesize various MOF films with a variety of characteristics to realize their sensing and separation applications.

关键词： metal-organic framework porous materials layer by layer fabrication film

A novel strategy of tannery sludge disposal–converting into biochar and reusing for Cr(Ⅵ)removal from tannery wastewater

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Journal of Environmental Sciences 2024年第4期138卷 637-649页

作者： Zhiwei Li Di Yu Xingdong Wang Xuejiao Liu Zhen Xu Yin Wang CAS Key Laboratory of Urban Pollutant Conversion Institute of Urban EnvironmentChinese Academy of SciencesXiamen 361021China University of Chinese Academy of Sciences Beijing 100049China Zhejiang Key Laboratory of Urban Environmental Processes and Pollution Control CAS Haixi Industrial Technology Innovation Center in BeilunNingbo 315830China Key Laboratory of Urban Environment and Health Ningbo Observatio

Tannery sludge with high chromium content has been identified as hazardous solid waste due to its potential toxic *** safety disposal and valorization of the tannery sludge remains a *** this study,the chromium stabilization mechanism was systematically investigated during chromium-rich tannery sludge was converted to biochar and the removal performance of the sludge biochar(SBC)for Cr(Ⅵ)from tannery wastewater was also *** results showed that increase in pyrolysis temperature was conductive to the stabilization of Cr and significant reduction of the proportion of Cr(Ⅵ)in *** was confirmed that the stabilization of chromium mainly was attributed to the embedding of chromium in the C matrix and the transformation of the chromium-containing substances from the amorphous Cr(OH)_(3)to the crystalline state,such as(FeMg)Cr_(2)O_(5).The biochar presented high adsorption capacity of Cr(Ⅵ)at low pH and the maximal theoretical adsorption capacity of SBC produced at 800°C can reach 352 mg Cr(Ⅵ)/g,the process of which can be well expressed by Langmuir adsorption isotherm and pseudo second order *** electrostatic effect and reduction reaction were dominantly responsible for the Cr(Ⅵ)adsorption by ***,this study provided a novel strategy for the harmless disposal and resource utilization for the solid waste containing chromium in leather industry.

关键词： Chromium-rich tannery sludge Pyrolysis Biochar Stabilizationmechanisms Cr(Ⅵ)adsorption

Metal–Organic Framework‑Based Photodetectors

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Nano-Micro Letters 2024年第11期16卷 675-703页

作者： Jin‑Biao Zhang Yi‑Bo Tian Zhi‑Gang Gu Jian Zhang State Key Laboratory of Structural Chemistry Structure of MatterFujian Institute of ResearchChinese Academy of SciencesFuzhouFujian 350002People’s Republic of China College of Chemistry and Materials Science Fujian Nornal UniversityFuzhou 350007FujianPeople’s Republic of China Fujian Science&Technology Innovation Laboratory for Optoelectronic Information of China Fuzhou 350108FujianPeople’s Republic of China University of Chinese Academy of Science Beijing 100049People’s Republic of China

The unique and interesting physical and chemical properties of metal–organic framework(MOF)materials have recently attracted extensive attention in a new generation of photoelectric *** this review,we summarized and discussed the research progress on MOF-based *** methods of preparing MOF-based photodetectors and various types of MOF single crystals and thin film as well as MOF composites are introduced in ***,the photodetectors applications for X-ray,ultraviolet and infrared light,biological detectors,and circularly polarized light photodetectors are ***,summaries and challenges are provided for this important research field.

关键词： Metal-organic frameworks Semiconductor Photodetectors