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China Foundry 2024年第5期21卷 427-444页

作者： Hai-dong Zhao Xue-ling Wang Qian Wan Wen-hui Bai Fei Liu School of Mechanical and Automotive Engineering South China University of TechnologyGuangzhou 510640China

Al and Mg alloy high pressure die castings(HPDC)are increasingly used in automotive *** microstructures in the castings have decisive effect on the casting mechanical properties,in which the microstructure characteristics are fundamental for the investigation of the microstructure-property *** the past decade,the microstructure characteristics of HPDC Al and Mg alloys,especially micro-pores andα-Fe,have been investigated from two-dimensional(2D)to threedimensional with X-ray micro-computed tomography(μ-CT).This paper provides an overview of the current understanding regarding the 3D characteristics and formation mechanisms of microstructures in HPDC alloys,their spatial distributions,and the impact on mechanical ***,it outlines future research directions for the formation and control of heterogeneous microstructures in HPDC alloys.

关键词： high pressure die casting microstructure three-dimensional characteristics distribution Al and Mg alloys

Isolation and microbial transformation of tea sapogenin from seed pomace of Camellia oleifera with anti-inflammatory effects

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Chinese Journal of Natural Medicines 2024年第3期22卷 280-288页

作者： SHEN Pingping JIANG Xuewa ZHANG Jingling WANG Jiayi Raj Richa LI Guolong GE Haixia WANG Weiwei YU Boyang ZHANG Jian State Key Laboratory of Natural Medicines China Pharmaceutical UniversityNanjing 210009China Co-construction Collaborative Innovation Center for Chinese Medicine Resources Industrialization by Shaanxi&Education Ministry Shaanxi Province Key Laboratory of New Drugs and Chinese Medicine Foundation ResearchShaanxi University of Chinese MedicineXianyang 712046China School of Life Sciences Huzhou UniversityHuzhou 313000China Nanjing Hospital of Chinese Medicine Affiliated to Nanjing university of Chinese Medicine Nanjing 210046China Jiangsu Key Laboratory of TCM Evaluation and Translational Research China Pharmaceutical UniversityNanjing 211198China

In the current study,tea saponin,identified as the primary bioactive constituent in seed pomace of Camellia oleifera Abel.,was meticulously extracted and hydrolyzed to yield five known sapogenins:16-O-tiglogycamelliagnin B(a),camelliagnin A(b),16-O-angeloybarringtogenol C(c),theasapogenol E(d),theasapogenol F(e).Subsequent biotransformation of compound a facilitated the isolation of six novel metabolites(a1−a6).The anti-inflammatory potential of these compounds was assessed using pathogenassociated molecular patterns(PAMPs)and damage-associated molecular patterns molecules(DAMPs)-mediated cellular inflammation ***,compounds b and a2 demonstrated significant inhibitory effects on both lipopolysaccharide(LPS)and high-mobility group box 1(HMGB1)-induced inflammation,surpassing the efficacy of the standard anti-inflammatory agent,***,compounds d,a3,and a6 selectivity targeted endogenous HMGB1-induced inflammation,showcasing a pronounced *** results underscore the therapeutic promise of *** seed pomace-derived compounds as potent agents for the management of inflammatory diseases triggered by infections and tissue damage.

关键词： Camellia oleifera Seed pomace Tea sapogenin Microbial transformation Damage-associated molecular patterns and Pathogen-associated molecular patterns Anti-inflammatory activity

Natural hydrogel dressings in wound care: Design, advances, and perspectives

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Chinese Chemical Letters 2024年第10期35卷 28-38页

作者： Xiaoliu Liang Chunliu Huang Hui Liu Hu Chen Jiabao Shou Hongwei Cheng Gang Liu State Key Laboratory of Infectious Disease Vaccine Development Xiang An Biomedicine LaboratoryNational Innovation Platform for Industry-Education Integration in Vaccine ResearchState Key Laboratory of Molecular Vaccinology and Molecular DiagnosticsCenter for Molecular Imaging and Translational MedicineSchoolofPublicHealthXiamenUniversityXiamen361102China Department of Burns and Plastics Surgery Liuzhou Worker's HospitalFourth Afliated Hospital of Guangxi Medical UniversityLiuzhou 545000China Institute of Applied Physics and Materials Engineering Zhuhai UM Science&Technology Research InstituteUniversity of MacaoMacao SAR 999078China

Natural hydrogels have emerged as a pivotal innovation in wound care,offering a unique combination of high absorbency,biocompatibility,and ***,due to the complexity of wound healing,the physiological state of the wound varies dynamically,and the mechanism of natural hydrogels that boost wound healing is still *** this review,we firstly provide a comprehensive introduction to the bio-logical process of wound healing,emphasizing the critical stages and factors affecting *** work concludes the composition and properties of natural hydrogels,including collagen,gelatin,hyaluronic acid,chitosan,alginates,cellulose,and fibroin,highlighting their biocompatibility and *** focus shifts to the various crosslinking strategies employed to enhance the structural integrity and functionality of natural *** review further investigates the biological effects of natural hydro-gels in wound healing,detailing their antibacterial,antioxidant,anti-inflammatory,adhesive,and hemo-static ***,we propose the challenges and future perspectives of natural hydrogels in practical *** review offers a comprehensive overview of the current state and poten-tial future advancements in natural hydrogel dressings for wound care,highlighting their critical role in addressing complex and hard-to-heal wounds.

关键词： Natural hydrogel Wound dressing Crosslinking strategy Antibacterial Anti-inflammation

Modeling of LF refining process:a review

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Journal of Iron and Steel Research International 2024年第2期31卷 289-317页

作者： Zi-cheng Xin Jiang-shan Zhang Kai-xiang Peng Jun-guo Zhang Chun-hui Zhang Qing Liu State Key Laboratory of Advanced Metallurgy University of Science and Technology BeijingBeijing100083China School of Automation and Electrical Engineering University of Science and Technology BeijingBeijing100083China Tangshan Branch Hebei Iron and Steel Co.Ltd.Tangshan063000HebeiChina Xinjiang Bayi Iron and Steel Co. Ltd.Baosteel GroupWulumuqi830022XinjiangChina

With the increasing demand for energy conservation and emission reduction,more attentions have been paid to the intelligentization,greenization and low carbonization during the transformation and upgrading of steelmaking *** furnace(LF)refining is one of the key procedures in steelmaking process and has been widely used in steelmaking plants for its high equipment matching degree,low equipment investment and outstanding refining *** to the main tasks of LF refining process,the modeling methods of temperature prediction model,slag-making model,alloying model,argon blowing model and model of inclusions behavior were systematically reviewed,and the advantages and disadvantages of each modeling method were *** addition,the technical framework for the future has also been proposed based on existing works,including classification of raw materials,graphic representation of knowledge,introduction,upgradation and management of device/equipment,customization of steelmaking,modeling of refining process,synergy of models,intelligentization of decision-making,automation of control,and digitization of processes and operations,aiming to provide a reference for the modeling and intelligent development of LF refining process.

关键词： LF refining Temperature prediction Slag-making Alloying Argon blowing Inclusion behavior Modeling method

Grain boundary-induced drastic sensing performance enhancement of Fe_(2)O_(3) gas sensors for acetone

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Rare Metals 2024年第9期43卷 4412-4424页

作者： Tian-Jun Hu Yi-Fan Li Yu-Zhu Tian Ying Wang Ya-Ru Chen Jun-Ming Zhang Er-Gui Luo Jian-Feng Jia Key Laboratory of Magnetic Molecules&Magnetic Information Materials Ministry of Education School of Chemical and Material ScienceShanxi Normal UniversityTaiyuan 030032China

Exploring the structure-activity relationship between the performance of gas sensors and the structure of semiconductor metal oxide(SMO)nanomaterials is crucial for understanding and designing gas-sensing materials and overcoming the application limitations of SMO-based gas *** of a single SMO microstructure provides a promising solution to address this scientific problem due to its controllable *** this study,we control the grain boundary(GB)density of Fe_(2)O_(3)nanomaterials using a simple solvothermal *** have similar chemical compositions and crystal phases,providing an ideal platform for studying the influence of the GB density on the gas-sensing ***-sensing tests showed that the Fe_(2)O_(3)-1 sensor with medium GB density and the Fe_(2)O_(3)-2 sensor with high GB density had higher sensitivity and selectivity than the Fe_(2)O_(3)-0 sensors with low GB density before reaching the optimal operating ***,when the GB density increased,the response to acetone decreased slightly,whereas the optimal operating temperature *** work highlights the unique performance of the GB density in enhancing the gas sensitivity of a single SMO.

关键词： Semiconductor metal oxide(SMO) Grain boundary(GB)density Oxygen adsorption Charge transfer Gas sensors

ON DE FINETTI'S OPTIMAL IMPULSE DIVIDEND CONTROL PROBLEM UNDER CHAPTER 11 BANKRUPTCY

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Acta Mathematica Scientia 2024年第1期44卷 215-233页

作者：王文元明瑞星胡亦钧 School of Mathematics and Statistics Fujian Normal UniversityFuzhou350007China School of Mathematical Sciences Xiamen UniversityXiamen361005China School of Statistics and Mathematics Zhejiang Gongshang UniversityHangzhou310018China School of Mathematics and Statistics Wuhan UniversityWuhan430071China

Motivated by recent advances made in the study of dividend control and risk management problems involving the *** code,in this paper we follow[44]to revisit the De Finetti dividend control problem under the reorganization process and the regulator's intervention documented in *** 11 *** do this by further accommodating the fixed transaction costs on dividends to imitate the real-world procedure of dividend *** the fixed transaction costs transforms the targeting optimal dividend problem into an impulse control problem rather than a singular control problem,and hence computations and proofs that are distinct from[44]are *** account for the financial stress that is due to the more subtle concept of Chapter 11 bankruptcy,the surplus process after dividends is driven by a piece-wise spectrally negative Lévy process with endogenous regime *** explicit expressions of the expected net present values under a double barrier dividend strategy,new to the literature,are established in terms of scale *** the help of these expressions,we are able to characterize the optimal strategy among the set of admissible double barrier dividend *** the tail of the Lévy measure is log-convex,this optimal double barrier dividend strategy is then verified as the optimal dividend strategy,solving our optimal impulse control problem.

关键词： spectrally negative Lévy process Chapter 11 bankruptcy De Finetti's dividend problem double barrier strategy impulse control

Polygon search algorithm for ultra-compact multifunctional integrated photonics design

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Photonics Research 2024年第7期12卷 1527-1541页

作者： TE DU ZHENG PENG PEIXIN HUANG ZHAOJIAN ZHANG HANSI MA XINPENG JIANG JIE HUANG MINGYU LUO HONGXIN ZOU JUNBO YANG Center of Material Science College of ScienceNational University of Defense TechnologyChangsha 410073China Institute for Quantum Science and Technology College of ScienceNational University of Defense TechnologyChangsha 410073China College of Computer National University of Defense TechnologyChangsha 410073China College of Systems Engineering National University of Defense TechnologyChangsha 410073China Defense Innovation Institute Academy of Military SciencesBeijing 100071China Photonics Research Institute Department of Electrical and Electronic EngineeringThe Hong Kong Polytechnic UniversityHong Kong 999077China Hunan Key Laboratory of Mechanism and Technology of Quantum Information Changsha 410073China

Ultra-compact multifunctional integrated photonic modules have great practical significance to photonic integrated circuits (PICs).However,the design effect and efficiency of the existing mainstream inverse design algorithms are incompetent when designing these *** analyze their shortcomings in this task,and propose a new,to our knowledge,inverse design algorithm named polygon search (PS) algorithm to address these *** utilize the PS algorithm to design an integrated dual-channel mode-conversion-crossing waveguide *** module integrates three functions:interconversion between TE_(0) and TE_(1),interconversion between TE_(0) and TE_(2),and channel crossing within only a 4μm×4μm footprint,and its performance is verified by experimental *** not only greatly reduces the total footprint of many PICs but also greatly improves their fabricating ***,we propose a PS-designed mode mixer and a PS-designed bending waveguide,and connect them with the integrated modules to form a four-channel crossing-mode-division-multiplexing *** system can provide multiple modes on the basis of channel crossing and transmit the output signal in the same direction in parallel within a single output waveguide,which significantly increases the communication bandwidth and decreases the footprint of *** last,we demonstrate the effect and efficiency advantages of the PS algorithm over several mainstream inverse design algorithms by a comprehensive contrast experiment and explain these advantages in theory from several perspectives.

关键词： waveguide mixer algorithm

Nature-Inspired pH-Responsive Hydrogels with Rapid and High Contrast Changes in Color, Fluorescence, and Shape Simultaneously

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Chinese Journal of Polymer Science 2024年第11期 1758-1767页

作者： Le-Ping Xiao Lv-Ming Qiu Zhen Wu Guo-Jie Wang School of Materials Science and Engineering University of Science and Technology Beijing

To realize single-stimulus-induced simultaneous multi-behaviors in hydrogels is still quite challenging ***,an intelli gent pH-responsive hydrogel （BP4VA/PAS） with rapid and high contrast changes in color,fluorescence,and shape simultaneously is reported The BP4VA/PAS hydrogel is fabricated by incorporating styryl anthracene derivative （BP4VA） into copolymer networks （PAS） of acrylamide and sodium 4-styrene *** acid conditions,the protonation of BP4VA generates a rapid change with high color contrast from yellow to red and a fluorescence switch between bright green and weak red *** the same time,the electrostatic interactions between 2H-BP4VA2+and sulfonate anions suspended on PAS trigger BP4VA/PAS hydrogels to *** alkaline treatment,the 2H-BP4VA2+/PAS hydrogel deproto nates and recovers to its original color,fluorescence,and ***,utilizing rapid and remarkable pH-responsive properties o BP4VA/PAS hydrogels,we successfully demonstrated its applications in biomimicry,camouflage,and multistage information *** tively,this work provided an elegant strategy to develop intelligent hydrogels in applications of biomimetic smart materials and information en cryption.

关键词：

Supercritical fluid technology:A game-changer for biomacromolecular nanomedicine preparation and biomedical application

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Chinese Chemical Letters 2024年第7期35卷 89-99页

作者： Yating Zheng Yulan Huang Jing Luo Xuqi Peng Xiran Gui Gang Liu Yang Zhang State Key Laboratory of Vaccines for Infectious Diseases Xiang An Biomedicine LaboratoryNational Innovation Platform for Industry-Education Integration in Vaccine ResearchState Key Laboratory of Molecular Vaccinology and Molecular DiagnosticsCenter for Molecular Imaging and Translational MedicineSchool of Public HealthXiamen UniversityXiamen 361102China Shen Zhen Research Institute of Xiamen university Shenzhen 518057China Division of Urology and Department of Surgery Brigham and Women's HospitalHarvard Medical SchoolBostonMA 02115United States Innovation Laboratory for Sciences and Technologies of Energy Materials of Fujian Province(IKKEM) Xiamen 361102China

Biomacromolecules are attractive in biomedical applications as therapeutic agents and potential drug carriers due to their natural active components,good biocompatibility,and high ***,their large relative molecular weight,complex structure,susceptibility to degradation,and poor stability limit their *** can address these issues by improving the therapeutic value,bioavailability,permeability,and absorption of biomacromolecules while regulating their retention time in the ***,compelling evidence has been reported that supercritical fluid(SCF)technology has emerged as an alternative that maintains the integrity of biomacromolecules and reduces environmental *** this review,we highlight a set of unique nanosizing strategies based on SCF technology for biomacromolecular nanomedicine,and extensively discuss their characteristics and *** particular,the protein-based,nucleic acid-based,and polysaccharide-based nanomedicine preparations via SCF technology and their biomedical applications are summarized,and the potential for industrial production of biomacromolecular drugs is also *** further provide perspectives on the opportunities and challenges in this excellent field of biomacromolecular drugs nanotechnology.

关键词： Biomacromolecules Supercritical fluid technology Therapeutic proteins Gene therapy Nanomedicine

Nanoscratch behaviors of La_(0.7)Sr_(0.3)MnO_(3+δ) thin films

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Journal of Rare Earths 2008年第6期26卷 809-812页

作者：江少群马欣新唐光泽孙明仁王刚 School of Materials Science and Engineering Harbin Institute of Technology

The nanoscratch behaviors of La0.7Sr0.3MnO3＋δ films, which were deposited with ratio of O2/（O2＋Ar）, ranging from 4.4% to 45.6% by DC magnetron sputter, were investigated by a nanoindentation technique. The results indicated that the friction coefficient between the films and the diamond tip depended on the loading critical load. The friction coefficient was about 0.08-0.12 when the loading normal load was less than the loading critical load. The films displayed excellent elastic recovery after unloading. When the loading load was larger than the loading critical load, plastic deformation and ploughing appeared for the films. The friction coefficient was about 0.43 when the film was damaged completely. The suitable decrease in ratio of O2/（O2＋Ar） could improve the nanoscratch resistance of the films. The film deposited with O2/（O2＋Ar）=25% possessed better scratch resistance due to good elastic recovery, high nanohardness, and critical load. The loading critical load of the film was larger than 80 raN.

关键词： La1-xSrxMnO3 magnetic recording scratch testing nanoindentation hardness rare earths