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Ionic liquid-assisted preparation of hydroxyapatite and its catalytic performance for decarboxylation of itaconic acid

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Chinese Journal of Chemical Engineering 2024年第3期67卷 9-15页

作者： Shutong Pang Hualiang An Xinqiang Zhao Yanji Wang hebei Provincial Key Laboratory of Green Chemical Technology and Efficient Energy Saving Tianjin Key Laboratory of Chemical Process SafetySchool of Chemical Engineering and TechnologyHebei University of TechnologyTianjin 300130China

The synthesis of methacrylic acid from biomass-derived itaconic acid is a green route,for it can get rid of the dependence on fossil *** order to solve the problems on this route such as use of a preciousmetal catalyst and a corrosive homogeneous alkali,we prepared a series of hydroxyapatite catalysts by an ionic liquid-assisted hydrothermal method and evaluated their catalytic *** results showed that the ionic liquid[Bmim]BF_(4) can affect the crystal growth of hydroxyapatite,provide fluoride ion for fluorination of hydroxyapatite,and adjust the surface acidity and basicity,morphology,textural properties,crystallinity,and composition of ***[Bmim]BF4 dosage and hydrothermal temperature can affect the fluoride ion concentration in the hydrothermal system,thus changing the degree of fluoridation of *** fluoride-ion concentration can lead to the formation of CaF_(2) and thus significantly decrease the catalytic performance of *** hydrothermal time mainly affects the growth of hydroxyapatite crystals on the c axis,leading to different catalytic *** suitable conditions for the preparation of this fluoridized hydroxyapatite are as follows:a mass ratio of[Bmim]BF4 to calcium salt=0.2:1,a hydrothermal time of 12 h,and a hydrothermal temperature of 130℃.A maximal methacrylic acid yield of 54.7%was obtained using the fluoridized hydroxyapatite under relatively mild reaction conditions(250℃ and 2 MPa of N_(2))in the absence of a precious-metal catalyst and a corrosive homogeneous alkali.

关键词： Ionic liquid Hydroxyapatite Itaconic acid Methacrylic Decarboxylation reaction

Indentation behavior of a semi-infinite piezoelectric semiconductor under a rigid flat-ended cylindrical indenter

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Applied Mathematics and Mechanics(English Edition) 2024年第4期45卷 649-662页

作者： Shijing GAO Lele ZHANG Jinxi LIU Guoquan NIE Weiqiu CHEN State Key Laboratory of Mechanical Behavior and System Safety of Traffic Engineering Structures Shijiazhuang Tiedao UniversityShijiazhuang 050043China School of Mechanical Engineering Shijiazhuang Tiedao UniversityShijiazhuang 050043China hebei Key Laboratory for Mechanics of Intelligent Materials and Structures Department of Engineering MechanicsShijiazhuang Tiedao UniversityShijiazhuang 050043China State Key Laboratory of Computer Aided Design and Computer Graphics Key Laboratory of Soft Machines and Smart Devices of Zhejiang ProvinceDepartment of Engineering MechanicsZhejiang UniversityHangzhou 310027China

This paper theoretically studies the axisymmetric frictionless indentation of a transversely isotropic piezoelectric semiconductor(PSC)half-space subject to a rigid flatended cylindrical *** contact area and other surface of the PSC half-space are assumed to be electrically *** the Hankel integral transformation,the problem is reduced to the Fredholm integral equation of the second *** equation is solved numerically to obtain the indentation behaviors of the PSC half-space,mainly including the indentation force-depth relation and the electric potential-depth *** results show that the effect of the semiconductor property on the indentation responses is limited within a certain range of variation of the steady carrier *** dependence of indentation behavior on material properties is also analyzed by two different kinds of *** element simulations are conducted to verify the results calculated by the integral equation technique,and good agreement is demonstrated.

关键词： piezoelectric semiconductor(PSC) insulating indenter electromechanical response singular integral equation finite element simulation

Genome-wide identification of the CONSTANS-LIKE(COL)family and mechanism of fruit senescence regulation by PpCOL8 in sand pear(Pyrus pyrifolia)

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Journal of Integrative Agriculture 2024年第4期23卷 1222-1237页

作者： Yue Xu Shurui Song Huiying Wang Xilong Cao Xinran Zhao Wenli Wang Liyue Huo Yawei Li Misganaw Wassie Bin Lu Liang Chen Haiyan Shi College of Horticulture Hebei Agricultural UniversityBaoding 071001China Wuhan Botanical Garden Chinese Academy of SciencesWuhan 430074China

Pyrus pyrifolia Nakai‘Whangkeumbae'is a sand pear fruit with excellent nutritional quality and ***,the industrial development of pear fruit is significantly limited by its short shelf *** acid(SA),a well-known phytohormone,can delay fruit senescence and improve shelf ***,the mechanism by which SA regulates CONSTANS-LIKE genes(COLs)during fruit senescence and the role of COL genes in mediating fruit senescence in sand pear are poorly *** this study,22 COL genes were identified in sand pear,including four COLs(Pp COL8,Pp COL9a,Pp COL9b,and Pp COL14)identified via transcriptome analysis and 18 COLs through genome-wide *** COL genes were divided into three subgroups according to the structural domains of the COL *** COL8,with two B-box motifs and one CCT domain,belonged to the first *** contrast,the other three Pp COLs,Pp COL9a,Pp COL9b,and Pp COL14,with similar conserved protein domains and gene structures,were assigned to the third *** four COLs showed different expression patterns in pear tissues and were preferentially expressed at the early stage of fruit ***,the expression of Pp COL8 was inhibited by exogenous SA treatment,while SA up-regulated the expression of Pp COL9a and Pp ***,Pp COL8 interacts with Pp MADS,a MADS-box protein preferentially expressed in fruit,and SA up-regulated its *** the production of ethylene and the content of malondialdehyde(MDA)were increased in Pp COL8-overexpression sand pear fruit,the antioxidant enzyme(POD and SOD)activity and the expression of Pp POD1 and Pp SOD1 in the sand pear fruits were down-regulated,which showed that Pp COL8 promoted sand pear fruit *** contrast,the corresponding changes were the opposite in Pp MADS-overexpression sand pear fruits,suggesting that Pp MADS delayed sand pear fruit *** co-transformation of Pp COL8 and Pp MADS also delayed sand pear fruit *** re

关键词： Pyrus pyrifolia CONSTANS-LIKE gene salicylic acid fruit senescence MADS

Multiple-dimensioned defect engineering for graphite felt electrode of vanadium redox flow battery

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Carbon Energy 2024年第2期6卷 143-153页

作者： Yingqiao Jiang Yinhui Wang Gang Cheng Yuehua Li Lei Dai Jing Zhu Wei Meng Jingyu Xi Ling Wang Zhangxing He School of Chemical Engineering North China University of Science and TechnologyTangshanChina Tsinghua Shenzhen International Graduate School Institute of Materials ResearchTsinghua UniversityShenzhenChina

The scarcity of wettability,insufficient active sites,and low surface area of graphite felt(GF)have long been suppressing the performance of vanadium redox flow batteries(VRFBs).Herein,an ultra-homogeneous multipledimensioned defect,including nano-scale etching and atomic-scale N,O codoping,was used to modify GF by the molten salt ***_(4)Cl and KClO_(3) were added simultaneously to the system to obtain porous N/O co-doped electrode(GF/ON),where KClO_(3) was used to ultra-homogeneously etch,and O-functionalize electrode,and NH4Cl was used as N dopant,***/ON presents better electrochemical catalysis for VO_(2)+/VO_(2)+ and V3+/V2+ reactions than only O-functionalized electrodes(GF/O)and *** enhanced electrochemical properties are attributed to an increase in active sites,surface area,and wettability,as well as the synergistic effect of N and O,which is also supported by the density functional theory ***,the cell using GF/ON shows higher discharge capacity,energy efficiency,and stability for cycling performance than the pristine cell at 140 mA cm^(−2) for 200 ***,the energy efficiency of the modified cell is increased by 9.7% from 55.2% for the pristine cell at 260 mA cm^(−2).Such an ultra-homogeneous etching with N and O co-doping through“boiling”molten salt medium provides an effective and practical application potential way to prepare superior electrodes for VRFB.

关键词： graphite felt molten salt N O co-doping ultra-homogeneous etching vanadium redox flow battery

Effects of Sinusoidal Vibration of Crystallization Roller on Composite Microstructure of Ti/Al Laminated Composites by Twin-Roll Casting

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Journal of Wuhan University of Technology(Materials science) 2024年第1期39卷 196-205页

作者：李励杜凤山 National Engineering Research Center for Equipment and Technology of Cold Strip Rolling Yanshan UniversityQinhuangdao 066004China College of Mechanical Engineering Yanshan UniversityQinhuangdao 066004China

A new,innovative vibration cast-rolling technology of “electromagnetic stirring+dendrite breaking+asynchronous rolling” was proposed with the adoption of sinusoidal vibration of crystallization roller to prepare Ti/Al laminated composites,and the effect of sinusoidal vibration of crystallization roller on composite microstructure was investigated in *** results show that the metallurgical bonding of titanium and aluminum is realized by mesh interweaving and mosaic meshing,instead of transition bonding by forming metal compound *** meshing depth between titanium and aluminum layers (6.6μm) of cast-rolling materials with strong vibration of crystallization roller (amplitude 0.87 mm,vibration frequency 25 Hz) is doubled compared with that of traditional cast-rolling materials (3.1μm),and the composite interfacial strength(27.0 N/mm) is twice as high as that of traditional cast-rolling materials (14.9 N/mm).This is because with the action of high-speed superposition of strong tension along the rolling direction,strong pressure along the width direction and rolling force,the composite linearity evolves from "straight line" with traditional casting-rolling to "curved line",and the depth and number of cracks in the interface increases greatly compared with those with traditional cast-rolling,which leads to the deep expansion of the meshing area between interfacial layers and promotes the stable enhancement of composite quality.

关键词： laminated composites sinusoidal vibration composite microstructure

Well-dispersed Sb particles embedded on N-doped carbon nanofibers toward high-performance Li-ion battery

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Rare Metals 2024年第7期43卷 2994-3006页

作者： Ying Li Yi-Han Zhao Lu-Lu Zhao Peng-Fei Wang Ying Xie Ting-Feng Yi School of Materials science and Engineering Northeastern University Key Laboratory of Dielectric and Electrolyte Functional Material hebei province School of Resources and MaterialsNortheastern University at Qinhuangdao Key Laboratory of Functional Inorganic Material Chemistry Ministry of EducationSchool of Chemistry and Materials ScienceHeilongjiang University

The alloy-type material Sb is widely used in the anode materials of lithium-ion batteries（LIBs） due to its high theoretical specific ***,its serious volume expansion problem during alloying/dealloying of Li+limits its practical *** this work,C-Sb composite was constructed as anode material of LIBs by electrospinning route for the first time,Sb was introduced into the polyacrylonitrile-based hard carbon and coal tar pitch-based soft carbon composite amorphous carbon fiber with a diameter of 300-600 nm,which realized high cycling *** C-Sb-2（the mass ratio of polyacrylonitrile to Sb source is 1:2） electrode displayed charge capacities of 1098.5,930.3,841.7,753.5,643.9 and 545.8 mAh·g-1at 0.1,0.2,0.3,0.5,1 and 2 A·g-1,*** when the current density returned to 0.1 A·g-1,the charge capacity was 939.3 mAh·g-1,revealing good stability and *** introduction of Sb into the amorphous carbon improved its conductivity and addressed the volume expansion issue of high specific capacity Sb during charge/***-situ XRD analysis confirmed the high reversibility of the C-Sb-2 during charging and *** functional theory（DFT） calculations revealed the gradual enhancement of the interface interaction between SbxLiyand amorphous carbon（AMC） with increasing lithium content,contributing to the anchoring of alloy nanoparticles on the AMC surface and buffering the volume change of the ***,the gradual lithiation of Sb facilitated the electron transfer from SbxLiyto *** findings hold promise for designing lithium storage materials with exceptional performance,highlighting the potential of C-Sb composites as anode materials for efficient next-generation lithium storage.

关键词： Li-ion battery Metallic Sb Carbon Electrospinning Cycling stability

Verifiable quantum secret sharing scheme based on orthogonal product states

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Chinese Physics B 2024年第7期33卷 178-187页

作者：白晨明刘璐张素娟 Department of Mathematics and Physics Shijiazhuang Tiedao UniversityShijiazhuang 050043China

In the domain of quantum cryptography,the implementation of quantum secret sharing stands as a pivotal *** this paper,we propose a novel verifiable quantum secret sharing protocol using the d-dimensional product state and Lagrange interpolation *** protocol is initiated by the dealer Alice,who initially prepares a quantum product state,selected from a predefined set of orthogonal product states within the C~d■C~d ***,the participants execute unitary operations on this product state to recover the underlying ***,we subject the protocol to a rigorous security analysis,considering both eavesdropping attacks and potential dishonesty from the ***,we conduct a comparative analysis of our protocol against existing *** scheme exhibits economies of scale by exclusively employing quantum product states,thereby realizing significant cost-efficiency *** terms of access structure,we adopt a(t, n)-threshold architecture,a strategic choice that augments the protocol's practicality and suitability for diverse ***,our protocol includes a rigorous integrity verification mechanism to ensure the honesty and reliability of the participants throughout the execution of the protocol.

关键词： quantum secret sharing quantum product state threshold scheme unitary operations

Fine particle trace elements at a mountain site in southern china:Source identification,transport,and health risks

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Journal of Environmental sciences 2024年第7期141卷 166-181页

作者： Jiaoping Xing Runping Ding Feifeng Chen Linyu Peng Wenhua Wang Xiaoyan Song Qing Ye Yuanqiu Liu Key Laboratory of State Forestry and Grassland Administration on Forest Ecosystem Protection and Restoration of Poyang Lake Watershed School of ForestryJiangxi Agricultural UniversityNanchang 330045China School of Resources and Materials Northeastern University at QinhuangdaoQinhuangdao 066004China College of Geosciences and Engineering North China University of Water Resources&Electric PowerZhengzhou 450046China

Trace elements in atmospheric particulate matter play a significant role in air quality,human health,and biogeochemical *** this study,the trace elements(Ca,Al,K,Fe,Na,Mg,Zn,Pb,Mn,Ti,Cu,Cr,Sr,Ni)in PM2.5samples collected at the summit of *** were analyzed to quantify their abundance,source,transport,and health *** the whole sampling period,the major trace elements was Ca,Al,and *** the trace metals with the lowest concentrations were Sr,Ni,Rb,and *** trace elements were influenced by air mass transport routes,exhibiting an increasing trend of crustal elements in the northwesterly airmass and anthropogenic elements(Zn,Mn,Cu,and Ni)in the easterly air *** dust,coal+biomass burning,vehicle emission,urban nitrate-rich+urban waste incineration emissions,and soil dust+industry emissions were common sources of PM2.5on *** air mass transport routes had various source contribution *** results indicate that trace elements at *** are influenced by regional anthropogenic emissions and monsoon-dominated trace element *** total resulting cancer risk value that these elements posed were below the acceptable risk value of 1×10^(-6),while the non-carcinogenic risk value(1.72)was higher than the safety level,suggesting that non-carcinogenic effects due to these trace elements inhalation were likely to *** emission and coal+biomass burning were the common dominant sources of non-cancer risks posed by trace elements at ***.

关键词： Trace elements Risk assessment Cluster analysis Source apportionment

Progress and challenges of electrolyte modulation in aqueous zinc-ion batteries

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Rare Metals 2024年第7期43卷 2940-2967页

作者： Qi-Hang Yang Lu-Fei Wang Xiao-Yu Wang Meng-Meng Zhen Tianjin Key Laboratory of Clean Energy and Pollution Control School of Energy and Environmental EngineeringHebei University of Technology

As a new type of green battery system,aqueous zinc-ion batteries（AZIBs） have gradually become a research hotspot due to their low cost,high safety,excellent stability,high theoretical capacity(820 mAh·g-1) of zinc anode,and low redox potential(-0.76 V *** hydrogen electrode（SHE）).AZIBs have been expected to be an alternative to lithium-ion batteries for large-scale commercial energy storage ***,they are facing thorny issues such as degradation of cycling performance,zinc dendrites,and side *** the same time,these problems cause short cycling life of batteries,thus severely limiting their commercial *** recent years,many more researches have been conducted on the modification of anode and cathode materials of AZIBs,but there is a lack of in-depth discussion on the characteristics and mechanism of electrolyte *** this review,we will make a systematic summary of the current problems with two electrodes in AZIBs,as well as the types and functions of electrolyte ***,we further systematically describe the modulation mechanism of electrolyte additives in the performance of the cathode and *** prospects and development directions of additive modulation strategies for AZIBs electrolytes are prospected.

关键词： Electrolyte additives Aqueous zinc-ion batteries Zinc anode protection Cathode chemistry