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IEEE/CAA Journal of Automatica Sinica 2024年第4期11卷 893-906页

作者： Zhipeng Chen Xinyi Wang Weihua Gui Jilin Zhu Chunhua Yang Zhaohui Jiang The authors are with the School of Automation Central South UniversityChangsha 410083China

Blast furnace(BF)burden surface contains the most abundant,intuitive and credible smelting information and acquiring high-definition and high-brightness optical images of which is essential to realize precise material charging control,optimize gas flow distribution and improve ironmaking *** has been challengeable to obtain high-quality optical burden surface images under high-temperature,high-dust,and extremelydim(less than 0.001 Lux)*** on a novel endoscopic sensing detection idea,a reverse telephoto structure starlight imaging system with large field of view and large aperture is *** with a water-air dual cooling intelligent self-maintenance protection device and the imaging system,a starlight high-temperature industrial endoscope is developed to obtain clear optical burden surface images stably under the harsh *** on an endoscope imaging area model,a material flow trajectory model and a gas-dust coupling distribution model,an optimal installation position and posture configuration method for the endoscope is proposed,which maximizes the effective imaging area and ensures large-area,safe and stable imaging of the device in a confined *** experiments and applications indicate that the proposed method obtains clear and reliable large-area optical burden surface images and reveals new BF conditions,providing key data support for green iron smelting.

关键词： Blast furnace(BF) burden surface extremely dim light industrial endoscope sensing imaging starlight

Modification of streamer-to-leader transition model based on radial thermal expansion in the sphere-plane gap discharge at high altitude

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Plasma science and Technology 2024年第1期26卷 42-49页

作者：耿江海林果王平丁玉剑丁杨俞华 Department of Electric Power Engineering North China Electric Power UniversityBaoding 071003People’s Republic of China china Electric Power Research Institute Beijing 100192People’s Republic of China Xinjiang Electric Power Company Research Institute Urumchi 830000People’s Republic of China Shanxi Electric Power Company Research Institute Taiyuan 030001People’s Republic of China

Historically,streamer-to-leader transition studies mainly focused on the rod-plane gap and low altitude analysis,with limited attention paid to the sphere-plane gap at high altitude *** this work,sphere-plane gap discharge tests were carried out under the gap distance of 5 m at the Qinghai Ultra High Voltage(UHV)test base at an altitude of 2200 *** experiments measured the physical parameters such as the discharge current,electric field intensity and instantaneous optical *** duration of the dark period and the critical charge of streamer-toleader transition were obtained at high *** on radial thermal expansion of the streamer stem,we established a modified streamer-to-leader transition model of the sphere-plane gap discharge at high altitude,and calculated the stem temperature,stem radii and the duration of streamer-to-leader *** with the measured duration of sphere-plane electrode discharge at an altitude of 2200 m,the error rate of the modified model was 0.94%,while the classical model was 6.97%,demonstrating the effectiveness of the modified *** the comparisons and analysis,several suggestions are proposed to improve the numerical model for further quantitative investigations of the leader inception.

关键词： streamer-to-leader transition model high altitude streamer stem convective diffusion radial thermal expansion

Annulation Cascades of Cyclosulfonium Salts and Alkenes towards Sulfur-Containing N-Heterocycles by Visible Light/Copper Catalysis

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Chinese Journal of Chemistry 2024年第14期42卷 1637-1643页

作者： Jie Ma Xufeng Li Yuqing Chen Yongjia Shi Xiuyan Song Jian Lv Daoshan Yang Key Laboratory of Optic-electric Sensing and Analytical Chemistry for Life science MOECollege of Chemistry and Molecular EngineeringQingdao University of Science and TechnologyQingdaoShandong266042 China Zhejiang Wansheng Co. Ltd.LinhaiZhejiang317000 China national Engineering Research Center of Low-Carbon Processing and Utilization of Forest Biomass Nanjing Forestry UniversityNanjingJiangsu210037 China

Although,great achievements have been made in the synthesis of heterocycles using radical addition/cyclization strategy,developing versatile alkyl radical precursors,especially the non-stabilized long chain alkyl radicals for this strategy still remains a huge ***,we report an efficient annulation cascade reaction between cyclosulfonium salts and alkenes for the synthesis of sulfur-containing N-heterocycles by visible light/copper catalysis under mild *** C—S bond cleavage/radical cascade reaction delivers a variety of corresponding N-heterocycles containing aryl alkyl thioether motifs with good functional group ***,the current system could be used for the late-stage functionalization of complex bioactive molecules.

关键词： Visible light Radical reactions C-C coupling Sulfur heterocycles Photoredox catalysis

Reversible Mn^(2+)/Mn^(4+)double-electron redox in P3-type layer-structured sodium-ion cathode

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Journal of Energy Chemistry 2024年第2期89卷 79-88,I0004页

作者： Jie Zeng Jian Bao Ya Zhang Xun-Lu Li Cui Ma Rui-Jie Luo Chong-Yu Du Xuan Xu Zhe Mei Zhe Qian Yong-Ning Zhou Department of Materials science Fudan UniversityShanghai 200433China Shanghai Xuanyi New Energy Development Co. LtdShanghai 201800China Global Institute of Future Technology Shanghai Jiao Tong UniversityShanghai 200240China

The balance between cationic redox and oxygen redox in layer-structured cathode materials is an important issue for sodium batteries to obtain high energy density and considerable cycle *** redox can contribute extra capacity to increase energy density,but results in lattice instability and capacity fading caused by lattice oxygen gliding and oxygen *** this work,reversible Mn^(2+)/Mn^(4+)redox is realized in a P3-Na_(0.65)Li_(0.2)Co_(0.05)Mn_(0.75)O_(2)cathode material with high specific capacity and structure stability via Co *** contribution of oxygen redox is suppressed significantly by reversible Mn^(2+)/Mn^(4+)redox without sacrificing capacity,thus reducing lattice oxygen release and improving the structure *** X-ray techniques reveal that P3 phase is well maintained in a wide voltage window of 1.5-4.5 V ***^(+)/Na even at 10 C and after long-term *** is disclosed that charge compensation from Co/Mn-ions contributes to the voltage region below 4.2 V and O-ions contribute to the whole voltage *** synergistic contributions of Mn^(2+)/Mn^(4+),Co^(2+)/Co^(3+),and O^(2-)/(O_n)^(2-)redox in P3-Na_(0.65)Li_(0.2)Co_(0.05)Mn_(0.75)O_(2)lead to a high reversible capacity of 215.0 m A h g^(-1)at 0.1 C with considerable cycle *** strategy opens up new opportunities for the design of high capacity cathode materials for rechargeable batteries.

关键词： Sodium batteries Cathode materials Layered structure Co substitution

The principle and amelioration of lithium plating in fast-charging lithium-ion batteries

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Journal of Energy Chemistry 2024年第10期97卷 453-459页

作者： Yi Yang Xia-Lin Zhong Lei Xu Zhuo-Lin Yang Chong Yan Jia-Qi Huang School of Materials science and Engineering Beijing Institute of Technology Advanced Research Institute of Multidisciplinary science Beijing Institute of Technology Beijing Key Laboratory of Green Chemical Reaction Engineering and Technology Department of Chemical Engineering Tsinghua University Yangtze River Delta Graduate School of Beijing Institute of Technology

Fast charging is restricted primarily by the risk of lithium（Li） plating,a side reaction that can lead to the rapid capacity decay and dendrite-induced thermal runaway of lithium-ion batteries（LIBs）.Investigation on the intrinsic mechanism and the position of Li plating is crucial to improving the fast rechargeability and safety of ***,we investigate the Li plating behavior in porous electrodes under the restricted transport of Li+.Based on the theoretical model,it can be concluded that the Li plating on the anodeseparator interface（ASI） is thermodynamically feasible and kinetically ***,the prior deposition of metal Li on the ASI rather than the anode-current collector interface（ACI） is verified *** order to facilitate the transfer of Li+among the electrode and improve the utilization of active materials without Li plating,a bilayer asymmetric anode composed of graphite and hard carbon（GH） is *** and simulation results suggest that the GH hybrid electrode homogenizes the lithiated-rate throughout the electrode and outperforms the pure graphite electrode in terms of the rate performance and inhibition of Li *** work provides new insights into the behavior of Li plating and the rational design of electrode structure.

关键词： Fast charging Graphite Hard carbon Lithium plating Lithium-ion batteries

Analytical model for predicting folding stable state of bistable deployable composite boom

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Chinese Journal of Aeronautics 2024年第8期37卷 460-469页

作者： Tianwei LIU Jiangbo BAI Nicholas FANTUZZI School of Transportation science and Engineering Beihang UniversityBeijing 100191China Jingdezhen Research Institute of Beihang University Jingdezhen 333000China DICAM Department University of BolognaBologna 40136Italy

Bistable Deployable Composite Boom(Bi-DCB)can achieve bistable function by storing and releasing strain energy,which has a good application prospect in space *** example,it serves as the main support section of deployable structures(e.g.,solar arrays and antennas).This paper investigates folding stable state of Bi-DCB through the analytical *** on Archimedes’helix and energy principle,an analytical model for predicting folding stable state of Bi-DCB was *** failure index of Bi-DCB in folding stable state were analyzed using the Tsai-Hill criterion and the maximum stress ***,a 2400 mm long Bi-DCB was fabricated using autoclave *** prediction results of the proposed model were compared with experiments and results of two other analytical *** is shown that the proposed model shows good prediction ***,the effect of geometric parameters on folding stable state of Bi-DCB was further investigated with the aid of the proposed model.

关键词： Bistable Deployable composite boom Solar arrays Antennas Archimedes’helix Folding Failure analysis

Halogen-bond induced unusual polyhalogen anions formation in hydrogen-bonded frameworks to secure iodine sequestration

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Nano Research 2024年第7期17卷 6766-6772页

作者： Yi Xie Pengling Huang Qiang Gao Shiyu Wang Jianchen Wang Gang Ye Collaborative Innovation Center of Advanced Nuclear Energy Technology Institute of Nuclear and New Energy TechnologyTsinghua UniversityBeijing 100084China

Safe confinement of fission iodine isotopes for long-term radioactive waste disposal remains a formidable challenge,as conventional sorbents provide inherently weak iodine-host *** report here a novel halogen bond(X-bond)directed strategy to sequester volatile iodine in hydrogen-bonded(H-bonded)frameworks with unprecedented ***-assisted Hbonded frameworks bearing open halide sites are developed,showing distinctive iodine encapsulation behaviors without compromising the *** crystallographic evidence indicates the formation of X-bonds,i.e.,I–I···Cl^(−) and I–I···Br^(−),within the confined pore *** polyhalogen anions,i.e.,[I_(2)Cl_(2)]^(2−)and[I_(2)Br_(2)]^(2−),sustained in H-bonded frameworks are identified for the first *** X-bond reinforced host-guest interaction affords robust iodine trapping without leaking out even at elevated temperatures up to 180℃.By integrating the halogen-bond chemistry with H-bonded frameworks,this study offers fresh concepts for developing effective host reservoirs to secure fission iodine isotopes from spent fuel reprocessing off-gases.

关键词： halogen-bond chemistry anion coordination chemistry hydrogen-bonded organic frameworks polyhalogen anions iodine confinement

Investigation of stress distribution and damage behavior caused by forced installation of a composite bolted joint with a hole-location error

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Chinese Journal of Aeronautics 2024年第1期37卷 201-217页

作者： chinan LIU Yuan LI Yi CHENG An’an ZHAO Kunpeng DU Yue SHI Ximing LI Hui CHENG School of Mechanical Engineering Northwestern Polytechnical UniversityXi’an 710072China AVIC Xi’an Aircraft Industry Group Company LTD Xi’an 710089China

In this paper,the influence of forced installation caused by a hole-location error on the 3D stress distribution and damage of a composite bolted joint is *** analytical model of stress distributed on composite holes is promoted,in view of non-uniform extrusion caused by forced *** first,non-uniform extrusion of the hole edge caused by forced installation is *** to the contact state,expression of hole deformation is ***,based on Hertz theory,the maximum extrusion load is obtained with help of deformation *** constructing an elastic foundation beam model,3D stress distributed on a hole could be analyzed according to the extrusion ***,stress distribution predicted by the above analytical method is compared with that provided by FE considering composite ***,a forced installation experiment is carried out to analyze the damage distribution of the *** show that a central-symmetrically distributed stress is introduced by the hole-location *** an increment of the error,strength of composite decreases due to extrusion ***,stress presents a concave distribution on the *** the hole-location error exceeding 3%,stress decreases gradually due to failure of *** of holes does not exhibit a centrosymmetric *** damage is mainly distributed on the entrance of the hole at the lower sheet.

关键词： Hole-location error Composite joint Forced installation Stress distribution Damage

Temperature-Dependent Tearing Behavior of Rubber Materials:Characterization and Modeling

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Acta Mechanica Solida Sinica 2024年第2期37卷 316-326页

作者： Qinyuan Yao Feilong Zhang Pan Dong Ziyuan Zhao Yi He Weiguo Li Liming Chen State Key Laboratory of Coal Mine Disaster Dynamics and Control Chongqing UniversityChongqing400044China College of Aerospace Engineering Chongqing UniversityChongqing400044China

With the increasingly widespread application of rubber in many fields,there is a growing demand for quantitative characterization of temperature-dependent mechanical properties in high-temperature service *** critical tearing energy is an important criterion for determining whether rubber materials will experience tearing instability,while tear strength is a key parameter for rubber materials to resist *** is necessary to quantitatively characterize their evolution with *** theoretical research mainly relies on fitting a large amount of experimental data,which is not convenient for engineering ***,in this work,a temperature-dependent critical tearing energy model is firstly developed based on the force-heat equivalence energy density *** model considers the equivalent relationship between the critical tearing energy required for crack instability propagation and the thermal energy stored in the rubber *** is demonstrated that our model has higher prediction accuracy when compared to other ***,combining with the Griffith fracture theory,temperature-dependent tear strength models applicable to three different crack modes are separately *** models are validated using experimental data for Mode I opening cracks and ModeⅢtearing cracks,and good consistency is ***,a quantitative analysis of the influence of elastic modulus on tear strength at different temperatures is *** work provides a reliable way for predicting temperature-dependent tearing instability behavior and offers beneficial suggestions for improving the tear strength of rubber materials at different temperatures.

关键词： Temperature-dependent Critical tearing energy Tear strength Rubber Theoretical model

Advances in depressants for flotation separation of Cu–Fe sulfide minerals at low alkalinity:A critical review

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International Journal of Minerals,Metallurgy and Materials 2024年第1期31卷 1-17页

作者： Qicheng Feng Wenhang Yang Maohan Chang Shuming Wen Dianwen Liu Guang Han State Key Laboratory of Complex Nonferrous Metal Resources Clean Utilization Faculty of Land Resource EngineeringKunming University of Science and TechnologyKunming 650093China Yunnan Key Laboratory of Green Separation and Enrichment of Strategic Mineral Resources Kunming University of Science and TechnologyKunming 650093China

The flotation separation of Cu–Fe sulfide minerals at low alkalinity can be achieved using selective *** the flotation system of Cu–Fe sulfide minerals,depressants usually preferentially interact with the pyrite surface to render the mineral surface hydrophilic and hinder the adsorption of the *** review summarizes the advances in depressants for the flotation separation of Cu–Fe sulfide minerals at low *** advances include use of inorganic depressants (oxidants and sulfur–oxygen compounds),natural polysaccharides (starch,dextrin,konjac glucomannan,and galactomannan),modified polymers (carboxymethyl cellulose,polyacrylamide,lignosulfonate,and tricarboxylate sodium starch),organic acids (polyglutamic acid,sodium humate,tannic acid,pyrogallic acid,salicylic acid,and lactic acid),sodium dimethyl dithiocarbamate,and *** potential application of specific inorganic and organic depressants in the flotation separation of Cu–Fe sulfide minerals at low alkalinity is *** advances in the use of organic depressants with respect to the flotation separation of Cu–Fe sulfide minerals are comprehensively ***,the depression performances and mechanisms of different types of organic depressants on mineral surfaces are ***,several perspectives on depressants vis-à-vis flotation separation of Cu–Fe sulfide minerals at low alkalinity are proposed.

关键词： Cu–Fe sulfide minerals flotation separation selective depressants depression mechanism