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Aortic Dissection Research in china:Analysis of Studies Funded by the national natural science foundation of china

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Current Medical science 2023年第1期43卷 206-212页

作者： Zhang YUE Da-shuai WANG Sheng LE Jia-hong XIA Ping YE Xiao-fan HUANG Department of Cardiovascular Surgery Union HospitalTongji Medical CollegeHuazhong University of Science and TechnologyWuhan430022China Department of Cardiovascular Surgery The First Affiliated Hospital of Zhengzhou UniversityZhengzhou450052China Department of Cardiology The Central Hospital of WuhanTongji Medical CollegeHuazhong University of Science and TechnologyWuhan430014China

Objective The national natural science foundation of china(NSFC)has made great progress in promoting the development of aortic dissection research in recent *** study aimed to examine the development and research status of aortic dissection research in china so as to provide references for future *** The NSFC projects data from 2008 to 2019 were collected from the Internet-based science Information System and other websites utilized as search *** publications and citations were retrieved by Google Scholar,and the impact factors were checked by the InCite Journal Citation Reports *** investigator’s degree and department were identified from the institutional faculty *** A total of 250 grant funds totaling 124.3 million Yuan and resulting in 747 publications were *** funds in economically developed and densely populated areas were more than those in underdeveloped and sparsely populated *** was no significant difference in the amount of funding per grant between different departments’***,the funding output ratios of the grants for cardiologists were higher than those for basic science *** amount of funding for clinical researchers and basic scientific researchers in aortic dissection was also *** researchers were better in terms of the funding output *** These results suggest that the medical and scientific research level of aortic dissection in china has been greatly ***,there are still some problems that urgently need to be solved,such as the unreasonable regional allocation of medical and scientific research resources,and the slow transition from basic science to clinical practice.

关键词： national natural science foundation of china aortic dissection grant funding funding output ratio

Numerical Simulation of Radiation Transport to Improve Microalgae Cultivation in an Air-Lift Photobioreactor

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Journal of Thermal science 2025年第1期34卷 62-76页

作者： ZHANG Xianbin LI Mingjia HUNG Tzuchen ZHANG Zixun Key Laboratory of Thermo-Fluid science and Engineering of Ministry of Education School of Energy and Power EngineeringXi'an Jiaotong UniversityXi'an 710049China School of Mechanical Engineering Beijing Institute of TechnologyBeijing 100081China Department of Mechanical Engineering Taipei University of TechnologyTaipei 106344China

A comprehensive numerical model is developed to simulate the growth of microalgae under light/dark cycling *** purpose of this study is to predict the growth rate of Chlorella vulgaris cultivated in photobioreactors(PBRs)in order to improve the light conditions for microalgae and enhance the photosynthetic *** fluid dynamics(CFD)is used to simulate its internal hydrodynamic *** Lagrangian method is employed to track the movement of microalgae *** radiative transfer equation(RTE)is used to obtain light intensity *** combination of light radiation field and microalgae cell motions is used to construct the light history and they are integrated into the model of the photosynthetic units(PSU)to calculate the microalgae growth *** numerical results demonstrate that enhanced light/dark cycling frequency with ordered mixing can promote efficient microalgae *** effect of the vortex flow field generated by the baffles in an air-lift PBR is analyzed for increasing microalgae growth *** using the 1:1 baffle spacing,the biomass production of microalgae is increased by 41.8% compared to the original PBR.

关键词： photobioreactor light distribution particle tracking structure optimization

In situ synthetic C encapsulatedδ-MnO_(2with)O vacancies:a versatile programming in bio-engineering

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science Bulletin 2025年第2期70卷 203-211页

作者： Wei Lv Zilei Shen Junlin Liu Xudong Li Fang Ding Dongyue Zhang Licheng Miao Xuefeng Lyu Ruijie Li Miaomiao Wang Yiming Li Jingwen Meng Chao Xu Institute of Energy Power Innovation North China Electric Power UniversityBeijing 102206China Key Laboratory of Epigenetic Regulation and Intervention Institute of BiophysicsChinese Academy of SciencesBeijing 100101China Key Laboratory of Advanced Energy Materials Chemistry(Ministry of Education) College of ChemistryNankai UniversityTianjin 300071China Collaborative Innovation Center of Integrated Exploitation of Bayan Obo Multi-Metal Resources Inner Mongolia University of Science and TechnologyBaotou 014010China

In this study,we successfully synthesized aδ-MnO_(2)cathode with O vacancies,encapsulated by C derived from pyromellitic acid,using a facile hydrothermal method followed by annealing in an Ar *** cathode’s structural stability and charge transfer kinetics are enhanced by inhibiting the formation of the by-product Zn_(4)SO_(4)(OH)_(6)4H_(2)O,regulating the Mn valence state,and suppressing the Jahn–Teller effect through the synergy of C encapsulation and O *** results in remarkable electrochemical performance,including a large capacity of 421.2 mAh g^(-1)at 0.1 A g^(-1),a high specific energy density of595.53 Wh kg^(-1),and exceptional long-cycle life stability with 90.88%over 4000 cycles at 10 A g^(-1),together with superior coulombic efficiency(~100%)in pure ZnSO_(4)***,the cathode materials demonstrate specific antitumor *** brief,this work introduces an in situ synthetic C encapsulatedδ-MnO_(2)with O vacancies expected to be applied in both large-scale energy storage and biomedicine.?2024 science china *** by Elsevier *** science china *** rights are reserved,including those for text and data mining,AI training,and similar technologies.

关键词： Zn-ion batteries C encapsulation O vacancies Synergistic effect Bio-engineering

Local magnetic moment oscillation around an Anderson impurity on graphene

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science china(Physics,Mechanics & Astronomy) 2025年第1期68卷 188-197页

作者： Shuai Li Zhen Ma Jin-Hua Gao School of science Hebei University of Science and TechnologyShijiazhuang 050018China School of Electronics and Information Zhengzhou University of Light IndustryZhengzhou 450002China School of Physics and Wuhan national High Magnetic Field Center Huazhong University of Science and TechnologyWuhan 430074China

We theoretically investigate the spin resolved Friedel oscillation(FO)and quasiparticle interference(QPI)in graphene induced by an Anderson *** the impurity becomes magnetic,the resulted FO becomes spin dependent,which gives rise to a local magnetic moment oscillation with an envelop decaying as r^(-2) in real space in the doping ***,at half filling,the electron density and local magnetic moment will not oscillate but decay as r^(-3).Such spin resolved FO has both sublattice and spin ***,the local magnetic moment decay at half filling only occurs at one sublattice of graphene,which is quite like the phenomenon observed in the STM experiment(***ález-Herrero et al.,science 352,437(2016)).We further give an analytic formula about such spin dependent FO based on the stationary phase ***,we study the interference of quasiparticles around the magnetic impurity by calculating the spin dependent Fourier-transformed local density of states(FT-LDOS).Our work gives a comprehensive understanding about the local magnetic moment oscillation around an Anderson impurity on graphene.

关键词： Friedel oscillation local magnetic moment graphene Anderson impurity

The authors acknowledge the financial support from the national natural science foundation of china(project No.31971247).

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International Journal of Oral science 2021年第2期13卷 148-155页

作者： Yan Wei Guixin Zhu Zifan Zhao Chengcheng Yin Qin Zhao Hudi Xu Jinyang Wang Jinglun Zhang Xiaoxin Zhang Yufeng Zhang Haibin Xia The State Key Laboratory Breeding Base of Basic science of Stomatology(Hubei-MOST)&Key Laboratory of Oral Biomedicine Ministry of Education School&Hospital of StomatologyWuhan UniversityWuhanChina Department of Oral Implantology School and Hospital of StomatologyWuhan UniversityWuhanChina

Mineralized tissue regeneration is an important and challenging part of the field of tissue engineering and *** present,autograft harvest procedures may cause secondary trauma to patients,while bone scaffold materials lack osteogenic activity,resulting in a limited *** with osteogenic induction growth factor can improve the osteoinductive performance of bone graft,but the explosive release of growth factor may also cause side *** this study,we innovatively used platelet-rich fibrin(PRF)-modified bone scaffolds(Bio-Oss®)to replace autograft,and used cytokine(BMP-2)to enhance ***,this mixture,which we named“Autograft Mimic(AGM)”,has multiple functions and advantages.(1)The fiber network provided by PRF binds the entire bone scaffold together,thereby shaping the bone grafts and maintaining the space of the defect area.(2)The sustained release of BMP-2 from bone graft promoted bone regeneration continuously.(3)AGM recruited bone marrow mesenchymal stem cells(BMSCs)and promote their proliferation,migration,and osteogenic ***,AGM developed in this study can improve osteogenesis,and provide new guidance for the development of clinical bone grafts.

关键词： sustained graft replace

Oxidative degradation and upcycling of polyethylene wastes

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science china Chemistry 2025年第2期68卷 430-443页

作者： Yizhen Che Yanfen Wu Zhiqiang Niu State Key Laboratory of Chemical Engineering Department of Chemical EngineeringTsinghua UniversityBeijing 100084China Ordos Laboratory Ordos 017010China

Plastics have become omnipresent in modern life due to their versatility and ***,this convenience comes at the cost of substantial waste *** inherent chemical stability of plastics complicates its recycling,leading to environmental pollution and ecological *** mini-review highlights recent advancements in addressing this challenge by oxidative transformation of polyethylene(PE)into new functional polymers,value-added chemicals,and carbon-based *** first discuss the introduction of hydroxyl,carbonyl groups onto PE with a focus on the functionalization degree and ***,approaches for PE oxidation into dicarboxylic acids and short-chain oxidized PE are described and compared,with an emphasis on the tandem reactions for converting mixed dicarboxylic acids into other value-added *** also briefly discuss the oxidative transformation of PE into carbon-based materials and summarize the progress in qualitative and quantitative analysis of oxidation ***,we conclude this mini-review by highlighting the challenges and opportunities in the field.

关键词： oxidation polyethylene upcycling chemical conversion plastics

Comprehensive recovery of rare earth elements and gypsum from phosphogypsum:A wastewater free process combining gravity separation and hydrometallurgy

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Journal of Rare Earths 2025年第2期43卷 362-370,I0005页

作者： Jialin Qing Dapeng Zhao Li Zeng Guiqing Zhang Liang Zhou Jiawei Du Qinggang Li Zuoying Cao Shengxi Wu School of Metallurgy and Environment Central South UniversityChangsha410083China Key Laboratory of Metallurgical Separation science and Engineering of Non-ferrous Metals Industry Central South UniversityChangsha410083China national Engineering Laboratory for Efficient Utilization of Refractory Non-ferrous Metals Resources Central South UniversityChangsha410083China

Comprehensive utilization of phosphogypsum(PG)has attracted much attention,especially for the recovery of rare earth elements(REEs)and gypsum due to the issues of stockpile,environmental pollution,and waste of associated *** utilization methods suffered the issues of low REEs leaching efficiency,huge amount of CaSO_(4)saturated wastewater and high recovery *** solve these issues,this study investigated the occurrence of REEs in PG and the leaching of *** results show that REEs in PG are in the forms of(1)REEs mineral inclusions,(2)REEs isomorphous substitution of Ca^(2+)in gypsum lattice,(3)dispersed soluble REEs *** leaching results demonstrate that(1)the dissolution of gypsum matrix is the control factor of REEs leaching;(2)H_(2)SO_(4)is a promising leachant considering the recycle of leachate;(3)the gypsum matrix suffers a recrystallization during the acid leaching and releases the soluble REEs from PG to aqueous *** the recovery of the undissolved REEs mineral inclusions,wet sieving concentrated 37.1 wt%of the REEs in a 10.7 wt%mass,increasing REEs content from 309 to 1071 ***,a green process combining gravity separation and hydrometallurgy is *** process owns the merits of wastewater free,considerable REEs recovery(about 10%increase compared with traditional processes),excellent gypsum purification(>95 wt%CaSO_(4)·2H_(2)O,with<0.06 wt%of soluble P_(2)O_(5) and<0.015 wt%of soluble F)and reagent saving(about 2/3less reagent consumption than non-cyclical leaching).

关键词： Phosphogypsum Rare earths Wastewater free Recrystallization reinforcement Gravity separation

Direct and rapid detection of serum amino acid and monoamine neurotransmitters to assist the diagnosis of panic disorder

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science china Chemistry 2025年第1期68卷 377-384页

作者： Shiwen Liu Xuerui Wan Meng Zhao Jiaqi Wang Weilan Wu Linlin You Yonggui Yuan Qian Xu Rong Gao Key Laboratory of Environmental Medicine Engineering Ministry of EducationSchool of Public HealthSoutheast UniversityNanjing 210009China Key Laboratory of Modern Toxicology of Ministry of Education Department of Hygienic Analysis and DetectionSchool of Public HealthNanjing Medical UniversityNanjing 211166China Department of Psychosomatics and Psychiatry Zhongda HospitalSchool of MedicineSoutheast UniversityNanjing 210009China

The measurement of amino acid and monoamine neurotransmitters(NTs)in serum plays a central role in the identification and monitoring of clinical panic disorder(PD).However,the strong polarity and chemical heterogeneity of NTs make direct extraction and rapid detection extremely ***,we developed a strategy that integrated solid phase extraction based on magnetic Fe_(3)O_(4)coated with polydopamine(Fe_(3)O_(4)@PDA)and direct analysis of mass spectrometry in real time(DART-MS)for quantification of 10 *** systematically investigated the optimal conditions of this strategy to achieve good accuracy and *** with existing magnetic solid phase extraction methods for NTs detection in biological samples,this strategy could adsorb more targets while having similar adsorption efficiencies,and the total process time was reduced by an average of 69.42%.We rapidly determined the metabolic abnormality of 6 types of NTs in the serum of PD patients and demonstrated their diagnostic *** addition,an outstanding feature of PD in which tryptophan was more metabolized by the KYN pathway and the 5-hydroxytryptamine pathway was inhibited could be elucidated by this *** results highlighted the potential ability of Fe_(3)O_(4)@PDA coupled with DART-MS to assist in the clinical diagnosis of PD.

关键词： neurotransmitters panic disorder magnetic solid phase extraction direct analysis of mass spectrometry in real time

Controlled cationic ring-opening polymerization of L-lactide by organic ion pair:novel approach to isotactic-rich and crystalline polylactide

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science china Chemistry 2025年第1期68卷 394-402页

作者： Zhiqiang Ding Mingqian Wang Zijing Zhou Bin Wang Yuesheng Li Tianjin Key Laboratory of Composite&Functional Materials School of Materials Science and EngineeringTianjin UniversityTianjin 300350China

Living/controlled cationic ring-opening polymerization(ROP)of L-lactide is a promising approach to isotactic-rich and crystalline poly(L-lactide).In contrast with the unsubstituted lactones,L-LA can not be polymerized by organic Lewis acids or carbenium ions,and the state of the art in this field is the cationic ROP of L-LA catalyzed by BrФnsted acid/alcohol system via activated monomer ***,we reported the first example of controlled cationic ROP of L-LA by using Meerweintype ion pair[Me_(3)O]^(+)[B(C_(6)F_(5))_(4)]^(-)as the catalyst.[Me_(3)O]^(+)[B(C_(6)F_(5))_(4)]^(-)promoted rapid L-LA cationic polymerization in the absence of alcohol,producing isotactic-rich and crystalline PLLA without transesterification and epimerization side *** activated chain end mechanism,involving twice S_(N)2 substitution and configuration-inversion(S→R→S)with the assistance of released Me_(2)O,was proposed and further verified by density functional theory and control *** work expands the catalytic toolbox of isotactic-rich and crystalline polylactide *** represents a unique example of cationic-controlled polymerization of L-LA catalyzed by an organic ion pair.

关键词： organic ion pair controlled cationic ring-opening polymerization activated chain end mechanism isotactic-rich poly-lactide