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Asymmetric Zn-N4 atomic sites embedded hollow fibers as stable Zn anode for high-performance Zn-ion hybrid capacitor

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Journal of Energy Chemistry 2024年第10期97卷 460-469页

作者： Yukun Liu Bing Li Jin Wang Caiyun Li Hongrui Yang Yang Song Sen Zhang Chao Deng Key Laboratory for Photonic and Electronic Bandgap Materials Ministry of Education College of Physics and Electronic Engineering Harbin Normal University College of Material Science and Chemical Engineering Harbin Engineering University

Zn based electrochemical energy storage systems（EES） have attracted tremendous interests owing to their low cost and high intrinsic ***,the uncontrolled growth of Zn dendrites and the side reactions of Zn metal anodes（ZMAs） severely restrict their *** address these issues,we design the asymmetric Zn-N4atomic sites embedded hollow fibers（AS-IHF） as the flexible host for stable *** introducing different nitrogen resources in the synthesis,two kinds of coordination,i,***-N（pyridinic） and Zn-N（pyrrolic）,are introduced in the Zn-N4atomic module *** asymmetric Zn-N4module with regulated micro-environment facilitates the superior zincophilic features and promotes the Zn ***,the highly porous structure of the hollow fiber effectively reduces local current density,homogenize Zn ion flux,and alleviate structure *** the advantages endow the high efficiency and good stability for Zn plating/*** theoretical and experimental results demonstrate the high reversibility,low nucleation overpotential,and dendritefree behavior of the AS-IHF@Zn anode,which afford the high stability in high-rate and long-term ***,the solid-state Zn-ion hybrid capacitor（ZIHC） based on AS-IHF@Zn anode shows the high flexibility,reliability,and superior long-term cycling capability in a wide-range of temperatures（-20-25℃）.Therefore,the present work not only gives a new strategy for modulating local environments of single atomic sites,but also propels the development of flexible power sources for diverse electronics.

关键词： Asymmetric coordination Dendrite free behavior Single atomic sites Zincophilic sites Zn-ion hybrid capacitor

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Transition metal clusters with precise numbers of atoms anchored on graphdiyne as multifunctional electrocatalysts for OER/ORR/HER:a computational study

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Rare Metals 2024年第7期43卷 3107-3117页

作者： Xin-Yang Liu Jing-Wei Liu Gang Li Jing-Xiang Zhao College of Chemistry and Chemical Engineering Harbin Normal UniversityHarbin 150025China

Subnanometer metal clusters play an increasingly important role in heterogeneous catalysis due to their high catalytic activity and *** this work,by means of the density functional theory(DFT) calculations,the catalytic activities of transition metal clusters with precise numbers of atoms supported on graphdiyne(TM_(1-4)@GDY,TM=V,Cr,Mn,Fe,Co,Ni,Cu,Ru,Rh,Pd,Ir,Pt) were investigated for oxygen evolution reactions(OER),oxygen reduction reactions(ORR) and hydrogen evolution reactions(HER).The computed results reveal that the Pd_(2),Pd_(4) and Pt_(1) anchored graphdiyne can serve as trifunctional catalysts for OER/ORR/HER with the overpotentials of 0.49/0.37/0.06,0.45/0.33/0.12 and 0.37/0.43/0.01 V,respectively,while Pd_(1) and Pt_(2)@graphdiyne can exhibit excellent catalytic performance for water splitting(OER/HER) with the overpotentials of 0.55/0.17 and 0.43/0.03 *** addition,Ni_(1) and Pd_(3) anchored GDY can perform as bifunctional catalysts for metal-air cells(OER/ORR) and fuels cells(ORR/HER) with the overpotentials of 0.34/0.32 and 0.42/0.04 V,***,by precisely controlling the numbers of atoms in clusters,the TM_(1-4) anchored graphdiyne can serve as promising multifunctional electrocatalysts for OER/ORR/HER,which may provide an instructive strategy to design catalysts for the energy conversation and storage devices.

关键词： Density functional theory Graphdiyne Single-cluster catalysts Multifunctional electrocatalysts Overpotential

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N-doped hollow carbon nanospheres embedded in N-doped graphene forming a three-dimensional interconnected layered porous support loaded with palladium nanoparticles as an efficient electrocatalyst for formic acid oxidation

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新型炭材料(中英文) 2024年

作者： FANG Yue YANG Fu-kai QU Wei-li DENG Chao WANG Zhen-bo Key Laboratory of Photochemical Biomaterials and Energy Storage Materials Shenzhen Key Laboratory of Special Functional Materials Shenzhen Engineering Laboratory for Advance Technology of Ceramics Guangdong Research Center for Interfacial Engineering of Functional Materials College of Materials Science and Engineering Shenzhen University MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage School of Chemistry and Chemical Engineering State Key Lab of Urban Water Resource and Environment Harbin Institute of Technology College of Chemistry and Chemical Engineering Harbin Normal University No.1 Normal University South Road

The efficient electrocatalysts with low cost, high activity and good durability plays a crucial role in the application of direct formic acid fuel cells. Herein, Pd nanoparticles supported on N-doped hollow carbon nanospheres (NHCN) embedded in Ndoped graphene (NG) with three-dimensional (3D) layered porous configuration by a simple and economical method were investigated as direct formic acid fuel cell catalysts. Owing to the unique 3D interconnected layered porous configuration doped with nitrogen atoms, Pd/NHCN@NG catalyst with smaller Pd nanoparticle size shows large catalytic active surface area, superior electrocatalyticactivity,highsteady-statecurrentdensity,strongabilitytoresistCOpoisoning,farsurpassingthoseofconventionalPd/C,Pd/NG,andPd/***/GOratio,itisfoundthatwhenthe HCN/GO mass ratio is 1∶1, Pd/NHCN@NG catalyst has the most outstanding performance in catalytic oxidation of formic acid,with an activity 4.21 times that of Pd/C. This work has developed a superior carbon-based support material for electrocatalysts, which brings broad application prospects for the development of fuel cells.

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Giant and controllable Goos–H?nchen shift of a reflective beam off a hyperbolic metasurface of polar crystals

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Chinese Physics B 2024年第1期 300-307页

作者：薛天李宇博宋浩元王相光张强付淑芳周胜王选章 Key Laboratory for Photonic and Electronic Bandgap Materials Ministry of Educationand School of Physics and Electronic EngineeringHarbin Normal University Department of Basic Courses Guangzhou Maritime University

We conduct a theoretical analysis of the massive and tunable Goos–H¨anchen(GH) shift on a polar crystal covered with periodical black phosphorus(BP)-patches in the THz range. The surface plasmon phonon polaritons(SPPPs), which are coupled by the surface phonon polaritons(SPh Ps) and surface plasmon polaritons(SPPs), can greatly increase GH *** on the in-plane anisotropy of BP, two typical metasurface models are designed and investigated. An enormous GH shift of about-7565.58 λ0is achieved by adjusting the physical parameters of the BP-patches. In the designed metasurface structure, the maximum sensitivity accompanying large GH shifts can reach about 6.43 × 108λ0/RIU, which is extremely sensitive to the size, carrier density, and layer number of BP. Compared with a traditional surface plasmon resonance sensor, the sensitivity is increased by at least two orders of magnitude. We believe that investigating metasurface-based SPPPs sensors could lead to high-sensitivity biochemical detection applications.

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Giant and controllable Goos—Hänchen shift of a reflective beam off a hyperbolic metasurface of polar crystals

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Chinese Physics B 2024年第1期33卷 428-435页

作者：薛天李宇博宋浩元王相光张强付淑芳周胜王选章 Key Laboratory for Photonic and Electronic Bandgap Materials Ministry of Educationand School of Physics and Electronic EngineeringHarbin Normal UniversityHarbin 150025China Department of Basic Courses Guangzhou Maritime UniversityGuangzhou 510725China

We conduct a theoretical analysis of the massive and tunable Goos–Hänchen(GH) shift on a polar crystal covered with periodical black phosphorus(BP)-patches in the THz range. The surface plasmon phonon polaritons(SPPPs), which are coupled by the surface phonon polaritons(SPh Ps) and surface plasmon polaritons(SPPs), can greatly increase GH *** on the in-plane anisotropy of BP, two typical metasurface models are designed and investigated. An enormous GH shift of about-7565.58 λ_(0) is achieved by adjusting the physical parameters of the BP-patches. In the designed metasurface structure, the maximum sensitivity accompanying large GH shifts can reach about 6.43 × 10^(8) λ_(0)/RIU, which is extremely sensitive to the size, carrier density, and layer number of BP. Compared with a traditional surface plasmon resonance sensor, the sensitivity is increased by at least two orders of magnitude. We believe that investigating metasurface-based SPPPs sensors could lead to high-sensitivity biochemical detection applications.

关键词： Goos–H?nchen shift black phosphorus surface plasmon phonon polaritons sensitivity metasurfaces

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On the Characterization of Maximal Planar Graphs with a Given Signed Cycle Domination Number

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Acta Mathematica Sinica,English Series 2018年第5期34卷 911-920页

作者： Xiao Ming PI Department of Mathematics Harbin Normal University

Let G = （V, E） be a simple graph. A function f ： E → {＋1,-1} is called a signed cycle domination function （SCDF） of G if ∑e∈E（C） f（e） ≥ 1 for every induced cycle C of G. The signed cycle domination number of G is defined as γ′sc（G） = min{∑e∈E f（e）｜ f is an SCDF of G}. This paper will characterize all maxima] planar graphs G with order n ≥ 6 and γ′sc（G） =n.

关键词： Domination number signed cycle domination function signed cycle domination number planar graph maximal planar graph

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Infinite-Dimensional Lie Superalgebras SHO' over a Field of Prime Characteristic

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Journal of Beijing Institute of Technology 2008年第2期17卷 241-243页

作者：何英华杨西更李玉霞 Department of Mathematics Harbin Normal University Niu Lan Shan No.1 High School

The natural filtrations of the infinite-dimensional modular Lie superalgebra SHO＇ are proved to be invariant under automorphisms of SHO＇. The proof involves the investigation of the ad-nilpotent elements of the even part, and the determination of the subalgebras generated by certain ad-nilpotent elements. A property of automorphisms of these Lie superalgebras can be established, and an intrinsic characterization of SHO＇ can be obtained.

关键词： modular Lie superalgebras ad-nilpotent elements filtrations

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Theoretical Studies on the Reaction Mechanism of 1-Chloroethane with Hydroxyl Radical

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Chinese Journal of Structural Chemistry 2007年第6期26卷 695-702页

作者：王丙星王利 State Key Laboratory of Molecular Reaction Dynamics Dalian Institute of Chemical Physics Chinese Academy of Sciences Graduate School of the Chinese Academy of Sciences Beijing 100039 China

The reaction mechanism of 1-chloroethane with hydroxyl radical has been investigated by using density functional theory （DFT） B3LYP/6-31G （d, p） method. All bond dissociation enthalpies were computed at the same theoretical level. It was found that hydrogen abstraction pathway is the most favorable. There are two hydrogen abstraction pathways with activation barriers of 0.630 and 4.988 kJ/mol, respectively, while chlorine abstraction pathway was not found. It was observed that activation energies have a more reasonable correlation with the reaction enthalpy changes （ΔHr） than with bond dissociation enthalpies （BDE）.

关键词： bond dissociation enthalpies B3LYP 1-chloroethane hydroxyl radical reaction mechanism

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Derivations for even part of finite-dimensional modular Lie superalgebra Ω

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Frontiers of Mathematics in China 2012年第6期7卷 1169-1194页

作者： Zhu WEI Yongzheng ZHANG School of Mathematics and Statistics Northeast Normal University Changchun 130024 China

Y. Z. Zhang and Q. C. Zhang [J. Algebra, 2009, 321： 3601-3619] constructed a new family of finite-dimensional modular Lie superalgebra Ω. Let Ω denote the even part of the Lie superalgebra Ω. We first give the generator sets of the Lie algebra Ω. Then, we reduce the derivation of Ω to a certain form. With the reduced derivation and a torus of Ω, we determine the derivation algebra of Ω.

关键词： Modular Lie superalgebra derivation algebra torus

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A PROJECT OF SUSTAINABLE UTILIZATION OF FOREST RESOURCES SUPPORTED BY GIS

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Chinese Geographical Science 2000年第2期10卷 188-192页

作者： ZANG Shu-ying(Derartment of Geography, harbin normal university, harbin 150040, P. R. China) Department of Geography Harbin Normal University Harbin P. R. China

This paper, with the help of GIS, analyzes the structure characteristics, dynamic process and factors which result in failure of forest resources sustainable development in Tayuan Forest Farm, Da Hinggan Mountains, finds that there are big problems either in quantity or in Planning for forest resource development, and puts forward a project for its forest resources sustainable utilization. From the analysis, this paper is going to find an available develoment project for forest resourees sustainabe utlization for the forest farm, and also provides the proection and management of forest resources and the strategy of sustainable forestry development with scienndc foundation.

关键词： forest resources sustainable utilization project GIS

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