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Mesoporous titanium-aluminosilicate as an efficient catalyst for selective oxidation of cyclohexene at mild reaction conditions

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Chinese Journal of Chemical Engineering 2023年第3期55卷 257-265页

作者： Jitendra Diwakar Selvamani Arumugam Bhavna Saini Anup Prakash Tathod Nagabhatla Viswanadham Academy of scientific and Innovative research(AcSIR) at CSIR-Indian Institute of PetroleumDehradun 248005India Light Stock Processing Division Council of Scientific&Industrial Research-Indian Institute of PetroleumCouncil of Scientific and Industrial ResearchDehradun 248005India

Mesoporous titanium containing alumino-silicate materials with various titanium/silicon(Ti/Si) ratio(AlSi-Ti(n);n = Ti/Si mole ratio) have been successfully synthesized by a novel single-step sodium(Na)-free method, for the first time. The obtained characterization results of the prepared materials reveal that in-situ addition of Ti into AlSi shows ordered mesoporous structure along with uniformly dispersed Ti species in +4 and +3 oxidation states suitable for selective oxidation of allylic C—H bond. The prepared mesoporouse Ti-AlSi(n) samples exhibited excellent activity in the oxidation of cyclohexene with 100%conversion and 100% selectivity to ketone-alcohol(KA) oil(cyclohex-2-en-1-ol and 2-cyclohexen-1-one) at low temperature and reaction time(35℃ and 30 min reaction time). This study suggests that AlSi-Ti(0.05) material can be a promising catalyst for the selective oxidation of cyclohexene under mild reaction conditions.

关键词： Cyclohexene Allylic oxidation KA oil Mesoporous AlSi Mild conditions

Incense smoke(IS)inhalation exposure system:Physicochemical characterization,IS particle deposition and clearance in human airway using MPPD model

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Particuology 2024年第4期87卷 271-285页

作者： Vyas Kumar Hafsa Hashmi Anshita Nasreen Ghazi Ansari Jyotsna Singh Inhalation Toxicology Facility Regulatory Toxicology GroupCSR-Indian Institute of Toxicology ResearchLucknow22001UPIndi Academy of scientific and Innovative research(AcsSIR) Ghaziabad201002UPIndia Analytical Chemistry Regulatory Toxicology GroupCSIR-Indian Institute of Toxicology ResearchLucknow226001UPIndia

Incense smoke(IS)is source of indoor air pollution and key risk for diverse human *** in-formation is available regarding controlled IS rodent inhalation exposure system and IS particulate matter(PM)deposition in human *** aimed to demonstrate stable ISPM physicochemical parameters of 10 incense products inside the customized whole body inhalation exposure chamber(without animal)connected to smoke generation unit via aerosol mixing *** analyzed for size segregated PM emission,ISPM in vitro aerodynamics(MMAD and GSD determination),fine and ultrafine particle's SEM,SEM-EDX and PAH *** real life exposure scenario by utilizing MMAD,GSD and PM concentration after Tier 1 exposure assessment as key input parameters,ISPM dosimetry in infant(3 months)and adult(21 years male and female)human airways was calculated using multiple-path particle dosimetry(MPPD 3.04)*** median aerodynamic diameter(MMAD)and geo-metric standard deviation(GSD)ranged between 0.55 and 2.10μm and 1.22 to 1.77(polydisperse)***1.0 and PM0.1 showed multiple morphology and presence of heavy and trace *** like acenaphthylene,anthracene,fluorene,naphthalene and phenanthrene were detected(0.84-143.17μg/g).MPPD results showed higher ISPM deposition in pulmonary region and lowest in trachea bronchial *** deposition in tissue was higher in lower,peripheral lung as compared to upper and central lung *** body inhalation exposure system showed stable IS atmosphere(physi-cochemical parameters)indicating the device suitability in future inhalation *** ISPM deposition fraction and clearance data showed deep lung penetrating and retention behavior with higher risk in infant followed by female and then *** modeled particle deposition and clearance data may be useful in risk assessment analysis of IS.

关键词： Inhalation Incense smoke Multiple-path particle dosimetry(MPPD) Particle deposition Particulate matter(PM) Mass median aerodynamic diameter (MMAD) Human airway

Load shedding strategy coordinated with storage device and D-STATCOM to enhance the microgrid stability

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Protection and Control of Modern Power Systems 2019年第1期4卷 262-280页

作者： Sheetal Chandak Pritam Bhowmik Pravat Kumar Rout Electrical Engineering Department Siksha‘O’Anusandhan UniversityBhubaneswar751030India Electrical and Electronics Engineering Department Siksha‘O’Anusandhan UniversityBhubaneswar751030India

Recently microgrids have drawn a potential attraction by fulfilling the environmental demands and the increasing energy demands of the end-users. It is necessary to focus on various protection and control aspects of a microgrid. During the transition between the grid-following and grid-forming modes, the voltage and the frequency instability due to the power mismatch condition becomes the major point of concern. Therefore, the paper executes a frequency-active power and voltage-reactive power drooping control strategy for the precise power-sharing among the distributed power generators. Furthermore, to handle the power deficit scenarios and to maintain the system stability, a system independent and priority-based adaptive three-stage load shedding strategy is proposed. The sensitivity of the strategy depends on the system inertia and is computed according to the varying absolute rate-of-change-of-frequency. The strategy incorporates the operation of battery storage system and distributed static compensator (D-STATCOM) in the microgrid, to provide a reliable power supply to the customers for a considerable time instead of a sudden load shedding. The effectiveness of the proposed strategies is investigated on a scaled-down modified IEEE 13-bus microgrid system on the podium of MATLAB 2015b through the time-domain simulation.

关键词： Microgrid Power-sharing Load shedding High inertia distributed generators Inertia-less distributed generators Battery storage system D-STATCOM

Coating processes towards selective laser sintering of energetic material composites

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Defence Technology（防务技术） 2020年第2期16卷 316-324页

作者： Zetu Jiba Walter W.Focke Lonji Kalombo Moshawe J.Madito council for scientific and industrial research(CSIR) Defence Peace Safety and SecurityP.O Box 395Pretoria 0001South Africa University of Pretoria South Africa CSIR Chemical ClusterSouth Africa

This research aims to contribute to the safe methodology for additive manufacturing(AM)of energetic *** formulation processes were investigated and evaluated to find a suitable method that may enable selective laser sintering(SLS)as the safe method for fabrication of high explosive(HE)*** safety and co nvenie nce reasons,the co ncept demonstration was conducted using inert explosive simulants with properties quasi-similar to the real *** processes for simulant RDXbased microparticles by means of PCL and 3,4,5-trimethoxybenzaldehyde(as TNT simulant)are *** processes were evaluated for uniformity of coating the HE inert simulant particles with binder materials to facilitate the SLS as the adequate binding and fabrication *** system and single emulsion methods gave required particle near spherical morphology,size and uniform *** suspension process appears to be suitable for the SLS of HE mocks and potential formulation methods for active HE *** density is estimated to be comparable with the current HE compositions and plastic bonded explosives(PBXs)such as C4 and PE4,produced from traditional *** formulation method developed and understanding of the science behind the processes paves the way toward safe SLS of the active HE compositions and may open avenues for further research and development of munitions of the future.

关键词： Coating processes Energetic materials Simulants Mock explosives Additive manufacturing Selective laser sintering

Magnetic and flotation studies of banded hematite quartzite (BHQ) ore for the production of pellet grade concentrate

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International Journal of Minerals,Metallurgy and Materials 2010年第6期17卷 675-682页

作者： B. Das B.K.Mishra S. Prakash S.K.Das P.S.R.Reddy S.I.Angadi Institute of Minerals and Materials Technology Council of Scientific & Industrial Research (CSIR)

To identify and establish beneficiation techniques for banded hematite quartzite （BHQ） iron ore, a comprehensive research on BHQ ore treatment was carried out. The BHQ ore was assayed as 38.9wt% Fe, 42.5wt% SiO2, and 1.0wt% Al2O3. In this ore, hematite and quartz are present as the major mineral phases where goethite, martite, and magnetite are present in small amounts. The liberation of hematite particles can be enhanced to about 82% by reducing the particle size to below 63 μm. The rejection of silica particles can be obtained by magnetic and flotation separation techniques. Overall, the BHQ ore can be enriched to 65.3wt% Fe at 61.9% iron recovery. A flowsheet has been suggested for the commercial exploitation of the BHQ ore.

关键词： hematite beneficiation magnetic separation flotation pelletizing

Developments in Processing of Functionally Gradient Metals and Metal–Ceramic Composites:A Review

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Acta Metallurgica Sinica(English Letters) 2014年第5期27卷 825-838页

作者： T.P.D.Rajan B.C.Pai Materials Science and Technology Division CSIR-National Institute for Interdisciplinary Science and TechnologyIndustrial Estate PO

Functionally gradient/graded materials （FGMs）, an emerging new class of materials, are the outcome of the recent innovative concepts in materials technology. FGMs are in their early stages of evolution and expected to have a strong impact on the design and development of new components and structures with better performance. FGMs exhibit gradual transitions in the microstructure and/or the composition in a specific direction, the presence of which leads to variation in the functional performance within a part. The presence of gradual transitions in material composition in FGMs can reduce or eliminate the deleterious stress concentrations and result in a wide gradation of physical and/or chemical properties within the material. Functionally graded metal-ceramic composites are also getting the attention of the researchers. Among the fabrication routes for FGMs such as chemical vapour deposition, physical vapour deposition, the sol-gel technique, plasma spraying, molten metal infiltration, self propagating high temperature synthesis, spray forming, centrifugal casting, etc., the ones based on solidification route are preferred for FGMs because of their economics and capability to make large size products. The present paper discusses and compares various solidification processing tech- niques available for the fabrication of functionally gradient metals and metal-ceramic composites and lists their properties and possible applications. The other processing methods are briefly described.

关键词： Functionally gradient materials Solidification Aluminium Centrifugal casting Infiltration

Uniqueness,reciprocity theorem,and plane waves in thermoelastic diffusion with a fractional order derivative

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Chinese Physics B 2013年第7期22卷 286-297页

作者： Rajneesh Kumar Vandana Gupta Department of Mathematics Kurukshetra University

In this work, a theory of thermoelasticity with diffusion is taken into consideration by using the methodology of fractional calculus. The governing equations for particle motion in a homogeneous anisotropic fractional order generalized thermoelastic diffusive medium are presented. Uniqueness and reciprocity theorems are proved. The plane wave propagation in the homogeneous transversely isotropic thermoelastic diffusive medium with fractional order derivative is studied. For the two-dimensional problem, there exist a quasi-longitudinal wave, a quasi-transverse wave, a quasi-mass diffusion wave, and a quasi-thermal wave. From the obtained results, the different characteristics of waves, like phase velocity, attenuation coefficient, specific loss, and penetration depth, are computed numerically and presented graphically. Some special cases are also discussed.

关键词： thermoelastic diffusion fractional calculus uniqueness theorem reciprocity theorem

Solid-liquid extraction of Gd(Ⅲ) and separation possibilities of rare earths from phosphoric acid solutions using Tulsion CH-93 and Tulsion CH-90 resins

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Journal of Rare Earths 2012年第12期30卷 1270-1275页

作者： S.Radhika V.Nagaraju B.Nagaphani Kumar M.Lakshmi Kantam B.Ramachandra Reddy Inorganic Chemistry Division Indian Institute of Chemical Technology(IICT) Rubamin Limited Halol-389 350India

Solid-liquid extraction of gadolinium was investigated from phosphoric acid medium using commercial amino phosphonic acid resin, Tulsion CH-93. The experimental conditions studied included equilibration time, acid concentration, mass of the resin, metal concentration, loading and elution. The percent extraction of Gd（Ⅲ） was studied as a function of phosphoric acid （0.05-3 mol/L） using Tulsion CH-93 resin. The corresponding lgD vs. equilibrium pH plot gave straight line with a slope of 1.8. The percent extraction decreased with acid co centration increasing, conforming ion exchange mechanism. Under observed experimental conditions the loading capacity of Tulsion CH-93 for gadolinium was 10.6 mg/g. Among several eluants screened, the quantitative elution of Gd（III） from loaded Tulsion CH-93 was obtained with ammonium oxalate （0.15 mol/L）. The extraction behavior of commonly associated metals with gadolinium was studied as a function of phosphoric acid concentration. Tulsion CH-93 resin showed selective extraction towards heavy rare earths （Lu and Yb） which could be separated from other rare earths at 3 mol/L H3PO4, similar to wet phosphoric acid （3-5 mol/L）. On the other hand Gd（Ⅲ） and other rare earths were studied with chelating resin Tulsion CH-90. Light rare earths were highly extracted and these could be separated from heavy rare earths and Gd.

关键词： gadolinium phosphoric acid Tulsion CH-93 Tulsion CH-90 separation factors rare earths

Facet selective etching of Au microcrystallites

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Nano research 2015年第9期8卷 2925-2934页

作者： Gangaiah Mettela and Giridhar U. Kulkarni Thematic Unit of Excellence on Nanochemistry and Chemistry and Physics of Materials Unit Jawaharlal Nehru Centre for AdvancedScientific Research (JNCASR) Jakkur P.O. Bangalore 560 064 India

High-symmetry crystals exhibit isotropic properties. Inducing anisotropy, e.g., by facet selective etching, is considered implausible in face-centered cubic （FCC） metals, particularly gold, which, in addition to being an FCC, is noble. We report for the first time the facet selective etching of Au microcrystals obtained in the form of cuboctahedra and pentagonal rods from the thermolysis of a gold- organic precursor. The selective etching of {111} and {100} facets was achieved using a capping method in which tetraoctylammonium cations selectively cap the {111} facets while Br- ions protect the {100} facets. The exposed facets are oxidized by O2/C1-, yielding a variety of interesting geometries. The facet selective etching of the Au microcrystallites is governed only by the nature of the facets; the geometry of the microcystallite does not appear to play a significant role. The etched surfaces appear rough, but a closer examination reveals well-defined corrugations that are indexable to high hkl values. Such surfaces exhibit enhanced Raman activity.

关键词： gold,microcrystallites,facet selective eapping