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Production of Functional Materials Derived from Regenerated Silk Fibroin by Utilizing 3D Printing and Biomimetic Enzyme-induced Mineralization

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Chinese Journal of Polymer science 2024年第3期42卷 299-310,I0005页

作者： Ni Chen Fei-Yu Luo Gong-Wen Yang Jin-Rong Yao Xin Chen Zheng-Zhong Shao State Key Laboratory of Molecular Engineering of Polymers Laboratory of Advanced Materials and Department of Macromolecular ScienceFudan UniversityShanghai 200433China

Critical-sized bone defects, commonly encountered in clinical orthopedic surgery, present a significant challenge. One of the promising solutions is to prepare synthetic bone substitute materials with precise structural control, mechanical compatibility, and enhanced osteogenic induction performance, nevertheless the successful preparation of such materials remains difficult. In this study, a two-step technique,integrating an extrusion-based printing process with biomimetic mineralization induced by alkaline phosphatase(ALP), was developed. Initially,a pre-cured hydrogel of regenerated silk fibroin(RSF) with a small quantity of hydroxypropyl cellulose(HPC) and ALP was prepared through heating the mixed aqueous solution. This pre-cured hydrogel demonstrated thixotropic property and could be directly extruded into predetermined structures through a 3D-printer. Subsequently, the 3D-printed RSF-based materials with ALP underwent biomimetic in situ mineralization in calcium glycerophosphate(Ca-GP) mineralizing solution, utilizing the polymer chains of RSF as templates and ALP as a trigger for cleaving phosphate bonds of Ca-GP. The resulting 3D-printed RSF-mineral composites including hydrogel and sponge possessed adjustable compression modulus of megapascal grade and variable hydroxyapatite content, which could be controlled by manipulating the duration of the mineralization ***, these 3D-printed RSF-mineral composites demonstrated non-cytotoxicity towards rat bone marrow mesenchymal stem cells. Therefore, they may hold great potential for applications involving the replacement of tissues characterized by osteoinductivity and intricate structures.

关键词： Silk protein Alkaline phosphatase Extrusion-based printing Biomineralization

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Uncertainty and disturbance estimator-based model predictive control for wet flue gas desulphurization system

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Chinese Journal of Chemical Engineering 2024年第3期67卷 182-194页

作者： Shan Liu Wenqi Zhong Li Sun Xi Chen Rafal Madonski School of Energy and Environment Key Laboratory of Energy Thermal Conversion and Control of Ministry of EducationSoutheast UniversityNanjing 210096China Faculty of Automatic Control Electronics and Computer ScienceSilesian University of TechnologyGliwise 44-100Poland

Wet flue gas desulphurization technology is widely used in the industrial process for its capability of efficient pollution *** desulphurization control system,however,is subjected to complex reaction mechanisms and severe disturbances,which make for it difficult to achieve certain practically relevant control goals including emission and economic performances as well as system *** address these challenges,a new robust control scheme based on uncertainty and disturbance estimator(UDE)and model predictive control(MPC)is proposed in this *** UDE is used to estimate and dynamically compensate acting disturbances,whereas MPC is deployed for optimal feedback regulation of the resultant *** viewing the system nonlinearities and unknown dynamics as disturbances,the proposed control framework allows to locally treat the considered nonlinear plant as a linear *** obtained simulation results confirm that the utilization of UDE makes the tracking error negligibly small,even in the presence of unmodeled *** the conducted comparison study,the introduced control scheme outperforms both the standard MPC and PID(proportional-integral-derivative)control strategies in terms of transient performance and ***,the results reveal that a lowpass-filter time constant has a significant effect on the robustness and the convergence range of the tracking error.

关键词： Desulphurization system Disturbance rejection Model predictive control Uncertainty and disturbance estimator Nonlinear system

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Distributed Stochastic Scheduling of Massive Backup Batteries in Cellular Networks for Operational Reserve and Frequency Support Ancillary Services

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Journal of Modern Power Systems and Clean Energy 2024年第2期12卷 393-404页

作者： Kun Li Jiakun Fang Xiaomeng Ai Shichang Cui Rongkang Zhao Jinyu Wen State Key Laboratory of Advanced Electromagnetic Engineering and Technology School of Electrical and Electronic EngineeringHuazhong University of Science and TechnologyWuhan 430074China IEEE

Base station(BS)backup batteries(BSBBs),with their dispatchable capacity,are potential demand-side resources for future power *** enhance the power supply reliability and post-contingency frequency security of power systems,we propose a two-stage stochastic unit commitment(UC)model incorporating operational reserve and post-contingency frequency support provisions from massive BSBBs in cellular networks,in which the minimum backup energy demand is considered to ensure BS power supply *** energy,operational reserve,and frequency support ancillary services are co-optimized to handle the power balance and post-contingency frequency security in both forecasted and stochastic variable renewable energy(VRE)***,we propose a dedicated and scalable distributed optimization framework to enable autonomous optimizations for both dispatching center(DC)and *** BS model parameters are stored and processed locally,while only the values of BS decision variables are required to upload to DC under the proposed distributed optimization framework,which safeguards BS privacy *** studies on a modified IEEE 14-bus system demonstrate the effectiveness of the proposed method in promoting VRE accommodation,ensuring post-contingency frequency security,enhancing operational economics,and fully utilizing BSBBs'energy and power ***,the proposed distributed optimization framework has been validated to converge to a feasible solution with near-optimal performance within limited ***,numerical results on the Guangdong 500 kV provincial power system in China verify the scalability and practicality of the proposed distributed optimization framework.

关键词： Base station backup battery operational reserve frequency security distributed optimization privacy

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Study of the multi-physics field-coupled model of the two-stage electrostatic precipitator

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Building Simulation 2024年第3期17卷 387-398页

作者： Wenjia Hao Yu Guo Yukun Wang Tao Yu Hao Gao Zhengwei Long Tianjin Key Laboratory of Indoor Air Environmental Quality Control School of Environmental Science and EngineeringTianjin UniversityWeijin Road 92Tianjin300072China Wuhan Second Ship Design and Research Institute WuhanChin

The two-stage electrostatic precipitator is widely used to purify oil mist ***,there is limited research on the influences of relative humidity,particle deposition characteristics,and the generation of gaseous ***,this paper established a numerical model of the electrostatic oil mist purifier and applied it to a two-stage electrostatic *** the model was used to investigate the corona discharge characteristics under different relative humidity conditions in the charged zone,the particle deposition characteristics,the purification efficiency,the ozone concentration distribution,and the oil vapor concentration distribution in the collection *** results indicate that,with a constant temperature,the corona current decreases as relative humidity increase,and there is a quadratic relationship between relative humidity and *** variation in relative humidity has little impact on the purification *** maximum ozone concentration occurs near the electrode line,and its concentration is influenced by the discharge current and inlet airflow *** oil vapor concentration reaches its maximum value at the side plates,with a value of 19 ppb,while it reaches the minimum value at the collecting zone electrode plate,with a value of 2 *** temperature is the main factor affecting the volatilization of the oil film,with higher temperatures resulting in higher oil vapor.

关键词： two-stage ESPs particle deposition corona discharge oil vapor

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Sulfur vacancies and heterogeneous interfaces promote high performance sodium storage of bimetallic chalcogenide hollow nanospheres

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Journal of Energy Chemistry 2024年第8期95卷 596-610,I0013页

作者： Shiyue Cao Xiaoting Xu Qiming Liu Huijuan Zhu Ting Hu Key Laboratory of Artificial Micro-and Nano-structures of Ministry of Education School of Physics and TechnologyWuhan UniversityWuhan 430072HubeiChina

Transition metal sulfides have high theoretical capacities and are considered as potential anode materials for sodium-ion ***,due to low inherent conductivity and significant volume expansion,the electrochemical performance is greatly *** this study,a nickel/manganese sulfide material(Ni_(0.96)S_(x)/MnS_(y)-NC)with adjustable sulfur vacancies and heterogeneous hollow spheres was prepared using a simple *** introduction of a concentration-adjustable sulfur vacancy enables the generation of a heterogeneous interface between bimetallic sulfide and sulfur *** interface collectively creates an internal electric field,improving the mobility of electrons and ions,increasing the number of electrochemically active sites,and further optimizing the performance of Na~+*** direction of electron flow is confirmed by Density functional theory(DFT)*** hollow nano-spherical material provides a buffer for expansion,facilitating rapid transfer *** innovative discovery involves the interaction between the ether-based electrolyte and copper foil,leading to the formation of Cu_9S_5,which grafts the active material and copper current collector,reinforcing mechanical *** results in a new heterostructure of Cu_9S_5 with Ni_(0.96)S_(x)/MnS_(y),contributing to the stabilization of structural integrity for long-cycle ***,Ni_(0.96)S_(x)/MnS_(y)-NC exhibits excellent electrochemical properties following our modification *** stability performance,Ni0_(.96)S_(x)/MnS_(y)-NC demonstrates an average decay rate of 0.00944%after 10,000 cycles at an extremely high current density of 10000 mA g^(-1),A full cell with a high capacity of 304.2 mA h g^(-1)was also successfully assembled by using Na_(3)V_(2)(PO_(4))_(3)/C as the *** study explores a novel strategy for interface/vacancy co-modification in the fabrication of high-performance sodium-ion batteries electrode.

关键词： Sulfur vacancies Heterogeneous interface Interactions Sodium ion batteries

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Numerical study of the influence of the atmospheric pressure on the thermal environment in the passenger cabin

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Building Simulation 2024年第2期17卷 253-265页

作者： Xin Su Yu Guo Zhengwei Long Yi Cao Tianjin Key Lab.of Indoor Air Environmental Quality Control School of Environmental Science and EngineeringTianjin UniversityTianjin300072China Shanghai Aircraft Design and Research Institute Jinke RoadPudong DistrictShanghai201210China

The cabin air pressure remains lower than the horizontal atmospheric pressure when the airplane is in *** pressure is one of the parameters that must be taken into consideration while studying the thermal environment of an airplane *** are still no reference values for aircraft cabins despite the fact that numerous studies on low pressure heat transfer have demonstrated the connection between convective heat transfer coefficient(CHTC)and air *** this paper,a correction method for CHTC under low pressure conditions was established by using the dummy heat dissipation in the low-pressure cabin *** this basis,a thermal environment simulation model was developed,then was applied to the simulation of a seven-row aircraft cabin containing 42 passengers,and the CHTC and heat loss of dummy surface in the cabin were ***,the results of PMV calculated by using heat dissipation and air parameters at sampling points were *** results show that the modified CHTC can accurately reflect the cabin thermal environment under low pressure conditions,and the correction of CHTC can be realized by adjusting the turbulent Prandtl number,which is nonlinear correlated with the *** simulation results of the thermal environment in the seven-row cabin show that the CHTC changes by about 42%before and after *** air pressure decreases during take-off,which reduces the average CHTC of the crew surface from 5.09 W/(m^(2)·K)to 4.56 W/(m^(2)·K),but the air temperature rises by about 0.2°C as a *** deviation of PMV results calculated by using simulated heat loss data and using air parameters of measuring points in space is up to 0.5,but the latter is representative for calculating the thermal comfort level of the whole cabin.

关键词： low pressure aircraft cabin simulation heat dissipation convective heat transfer coefficient

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Reynolds-number scaling analysis on lift generation of a flapping and passive rotating wing with an inhomogeneous mass distribution

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Chinese Journal of Aeronautics 2024年第2期37卷 259-269页

作者： Suyang QIN Haotian HANG Yang XIANG Hong LIU J.C.Wu center for aerodynamics school of aeronautics and astronauticsshanghai jiao tong universityshanghai 200240china

Insects usually fly by passively rotating wings,which has been applied to the design of flapping-wing Micro-Air Vehicles(MAVs)to reduce mechanical *** this paper,a robotic passive rotating-wing model is designed to investigate wing kinematics and lift generation,which are measured by a high-speed camera and a force transducer,*** addition,flow fields are measured using the Particle Image Velocimetry(PIV).Experimental results demonstrate that passive rotating motion has a coordinative relationship with actively stroking *** the stroke amplitude or frequency increases,the rotating amplitude is *** characterize the active stroking motion,a driving Reynolds number Redrivingis defined,which varies from 68 to 366 in this *** the gravity center of the wing towards trailing ed ge induces the increase of additional torque M,which decreases the wing rotating amplitude and promotes the advance of wing *** find that the timing of wing rotation is gradually delayed and the mean lift coefficient C^(-)_(L)monotonously decreases as *** increasing the additional torque M,C^(-)_(L)is slightly improved and approaches to the lift coefficient of a real fruit fly at driving Re approximately equal to *** instantaneous lifts combined with the vortical structures further demonstrate that the lift generation associated with wing rotation is mainly attributed to the growth of the LeadingEdge Vortex(LEV)and the passive wake capture *** wake capture is influenced by LEV,reversal stroke motion and wing additional torque together,which can only maintain the lift at a high level for a considerable *** high-lift generation mechanisms of flapping and passive rotating flight could shed light on the simplified design of MAVs and the improvement of their aerodynamic performance.

关键词： Flapping flight Unsteady lift Passive rotation Vortex flow Leading-edge vortex

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Epidermal visualized health monitoring system based on stretchable and washable TPU hybrid conductive microtextiles

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Rare Metals 2024年第7期43卷 3185-3193页

作者： Jing-Bo Yuan Zhi-Hong Feng Dong-Chan Li Yang Luo Yun-Lei Zhou School of Chemical Engineering Hebei University of Technology Engineering Research Center of Chemical Technology for Efficient Utilization of Seawater ResourcesMinistry of EducationTianjin 300401China national Key Laboratory of Application Specific Integrated Circuit Shijiazhuang050000China Department of Materials ETH Zürich8093 ZurichSwitzerland Hangzhou Institute of Technology Xidian UniversityHangzhou 311231China

Electronic textiles,an emerging class of electronic technology,offer exciting opportunities for seamless integration with the human *** applications have been developed based on electronic ***,researches on integrating multiple electronic textilebased devices are still *** this study,we present a system integrated with an electrocardiogram monitoring sensor and an electroluminescence device based on stretchable and washable conductive micro *** signal is acquired by an electrocardiograph amplifier and displayed by a dual-color electroluminescence device based on the processed *** integrated electronic device has excellent moisture permeability and comfort for long-term *** system reported in this study opens a new avenue for the application of electronic textiles in health monitoring,robotic prosthetics,and competitive sports.

关键词： Conductive microtextile Textile composite Electronic textile Electroluminescent displays

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Thermodynamic and Economic Analysis of a Conceptual System Combining Sludge Gasification,SOFC,Supercritical CO_(2)Cycle,and Organic Rankine Cycle

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Journal of Thermal science 2024年第4期33卷 1491-1508页

作者： LV Jiayang WANG Chizhong CHEN Heng PAN Peiyuan XU Gang ZHANG Guoqiang School of Energy Power and Mechanical EngineeringNorth China Electric Power UniversityBeijing102206China

In order to reduce the environmental impact of conventional sludge treatment methods and to utilize the energy in sludge more effectively,a coupled system based on sewage sludge gasifier(SSG),solid oxide fuel cells(SOFC),supercritical CO_(2)cycle(S-CO_(2)),and organic Rankine cycle(ORC)is *** clean syngas obtained from sludge gasification is mixed with CH4 and then first utilized by the fuel *** exhaust gas from the fuel cell is fully combusted in the afterburning chamber and then enters the bottom cycle system consisting of S-CO_(2)&ORC to generate *** understand the performance of the system,thermodynamic and economic analyses were conducted to examine the project's *** thermodynamics as well as the economics of the coupled system were analyzed to arrive at the following conclusions,the power production of the system is 37.34 MW;the exergy efficiency is 55.62%,and the net electrical efficiency is 61.48%.The main exergy destruction is the gasifier and SOFC,accounting for 62.45%of the total exergy *** takes only6.13 years to repay the construction investment in the novel system,and the project obtains a NPV of 17723820USD during 20 years *** above findings indicate that the new coupled system has a better performance in terms of energy utilization and economy.

关键词： sewage sludge gasifier SOFC supercritical CO_(2)cycle organic Rankine cycle multi-system coupling

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A Deepfake Detection Algorithm Based on Fourier Transform of Biological Signal

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Computers, Materials & Continua 2024年第6期79卷 5295-5312页

作者： Yin Ni Wu Zeng Peng Xia Guang Stanley Yang Ruochen Tan School of Electrical and Electronic Engineering Wuhan Polytechnic UniversityWuhan430023China School of Mathematics and Computer science Wuhan Polytechnic UniversityWuhan430048China Paul G.Allen School of Computer science and Engineering University ofWashingtonSeattleWA98195USA School of Computer science and Engineering University of CaliforniaSanDiegoCA92093USA

Deepfake-generated fake faces,commonly utilized in identity-related activities such as political propaganda,celebrity impersonations,evidence forgery,and familiar fraud,pose new societal *** current deepfake generators strive for high realism in visual effects,they do not replicate biometric signals indicative of cardiac *** this gap,many researchers have developed detection methods focusing on biometric *** methods utilize classification networks to analyze both temporal and spectral domain features of the remote photoplethysmography(rPPG)signal,resulting in high detection ***,in the spectral analysis,existing approaches often only consider the power spectral density and neglect the amplitude spectrum—both crucial for assessing cardiac *** introduce a novel method that extracts rPPG signals from multiple regions of interest through remote photoplethysmography and processes them using Fast Fourier Transform(FFT).The resultant time-frequency domain signal samples are organized into matrices to create Matrix Visualization Heatmaps(MVHM),which are then utilized to train an image classification ***,we explored various combinations of time-frequency domain representations of rPPG signals and the impact of attention *** experimental results show that our algorithm achieves a remarkable detection accuracy of 99.22%in identifying fake videos,significantly outperforming mainstream algorithms and demonstrating the effectiveness of Fourier Transform and attention mechanisms in detecting fake faces.

关键词： Deepfake detector remote photoplethysmography fast fourier transform spatial attention mechanism

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