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An effective strategy for dendrite free Li metal anodes:Nickel foam decorated with high lattice-matching CoN and CoF_(2) nanosheets for dense deposition

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Nano research 2024年第5期17卷 4069-4078页

作者： Wenlong Liu Jianzong Man Xiaodong Sun Ning Zhang Yehong Du Kun Liu Zhongsheng Wen Song Li Juncai Sun Institute of Materials and Technology Dalian Maritime UniversityDalian 116026China Shandong Provinvial Key Laboratory of Chemical Energy Storage and Novel Cell Technology and School of Chemistry and Chemical enginneringLiaocheng UniversityLiaocheng 252000China Department of Public Security Management Liaoning Police CollegeDalian 116036China

The notorious dendrite and infinite volume change seriously restrict the advancement of lithium metal anodes(LMAs),during the long-term process of stripping/***,the nanosheets of metal fluoride(CoF_(2))and metal nitride(CoN)with magnificent lithiophilicity on the nickel(Ni)foam are designed as the“regulator”to uniform the Li plating and build stronger solid electrolyte interface(SEI)layer for dendrite free *** Ni foam offers abundant space to receive deposited Li *** CoN nanosheets can guarantee the fast transfer of electrons,which provides a stable interface of Li^(+)***,the nanosheet structure with lithiophilicity would accelerate the move of Li+and decrease the nucleation barrier,due to the high lattice-matching of Li and ***,the CoF_(2) could increase the content of F(LiF)in the SEI layer,which enhances the strength and avoids the destruction of SEI *** the cooperation of CoN and CoF_(2),the composited anode(Li/NF@CNCF)exhibits ultra-long cycle performance(more than 1200 h)and fantastic structure stability at 1 mA·cm^(-2) with 1 mAh·cm^(-2).Based on the LiFePO_(4) and Li/NF@CNCF,the full cells deliver excellent specifical capacity and steady coulombic *** strategy contributes an effective approach to alleviate the issues of lithium metal anodes in the field of LMAs.

关键词： CoN and CoF_(2) lattice-matching nanosheet lithiophilicity lithium metal anodes

Cu-based materials for electrocatalytic CO2 to alcohols:Reaction mechanism,catalyst categories, and regulation strategies

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Journal of Energy Chemistry 2024年第10期97卷 593-611页

作者： Yaru Lei Yaxin Niu Xiaolong Tang Xiangtao Yu Xiubing Huang Xiaoqiu Lin Honghong Yi Shunzheng Zhao Jiaying Jiang Jiyue Zhang Fengyu Gao Beijing Key Laboratory of Resource-oriented Treatment of Industrial Pollutants School of Energy and Environmental Engineering University of Science and Technology Beijing Collaborative Innovation Center for Steel Technology University of Science and Technology Beijing Beijing Key Laboratory of Function Materials for Molecule & Structure Construction School of Materials Science and Engineering University of Science and Technology Beijing

Electrocatalytic CO2reduction reaction（CO2RR） technology,which enables carbon capture storage and resource utilization by reducing CO2to valuable chemicals or fuels,has become a global research hotspot in recent *** the many products of CO2RR（carbon monoxide,acids,aldehydes and alcohols,olefins,etc.）,alcohols（methanol,ethanol,propanol,etc.） have a higher market value and energy density,but it is also more difficult to *** is known to be effective in catalyzing CO2to high valueadded alcohols,but with poor *** progress of Cu-based catalysts for the selective generation of alcohols,including copper oxides,bimetals,single atoms and composites is ***,to improve Cu-based catalyst activity and modulate product selectivity,the modulation strategies are straighten out,including morphological regulation,crystalline surface,oxidation state,as well as elemental doping and defect *** on the research progress of electrocatalytic CO2reduction for alcohol production on Cu-based materials,the reaction pathways and the key intermediates of the electrocatalytic CO2RR to methanol,ethanol and propanol are ***,the problems of traditional electrocatalytic CO2RR are introduced,and the future applications of machine learning and theoretical calculations are *** in-depth discussion and a comprehensive review of the reaction mechanism,catalyst types and regulation strategies were carried out with a view to promoting the development of electrocatalytic CO2RR to alcohols.

关键词： Alcohols Cu-based catalyst Electrocatalytic CO2RR Reaction mechanism Regulation strategies

A robust indium-organic framework with open tubular channels for efficient separation of acetylene

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Nano research 2024年第4期17卷 3139-3146页

作者： Yong-Zhi Li Gang-Ding Wang Fan Xu Qing Yin Danyang Zhao Jiqiu Qi Yanwei Sui Lei Hou Yao-Yu Wang School of Materials and Physics China University of Mining and TechnologyXuzhou 221116China Key Laboratory of Synthetic and Natural Functional Molecule of the Ministry of Education Shaanxi Key Laboratory of Physico-Inorganic ChemistryCollege of Chemistry&Materials ScienceNorthwest UniversityXi’an 710069China

Considering the tremendous applications and purification requirement of acetylene(C_(2)H_(2)),seeking appropriate adsorbents with high capacity and selectivity is a vital task and remains an enduring ***,we designed and synthesized a robust three-dimensional(3D)indium-organic framework([(Me)_(2)NH_(2)][In(L6)_(0.5)(IPA)_(0.5)]·DMA·2H_(2)O(In-L6-IPA,DMA=dimethylammonium,IPA=isopropyl alcohol))featuring two types of one-dimensional(1D)tubular *** activated In-L6-IPA displayed high loading for C_(2)H_(2)(104.4 cm^(3)·g^(-1),the second highest value among all reported indium-based metal-organic frameworks(MOFs))and simultaneously selective adsorption for C_(2)H_(2) over CO_(2),C_(2)H_(6),and ethylene(C_(2)H_(4))at 298 K under 100 *** modelling revealed that the porous wall of In-L6-IPA provides more and stronger multiple interactions for C_(2)H_(2) than CO_(2),C_(2)H_(6),and C_(2)H_(4) containing C–H···π,C–H···O,and O···π*** experiments validated the actual separation ability for various ratios of binary C_(2)H_(2)/C_(2)H_(4) and C_(2)H_(2)/CO_(2) mixtures as well as equimolar ternary C_(2)H_(2)/C_(2)H_(4)/CO_(2) and C_(2)H_(2)/C_(2)H_(4)/C_(2)H_(6) mixtures with excellent reusability.

关键词： indium-organic framework crystal structure gas adsorption acetylene(C_(2)H_(2))separation

Ultrathin two-dimensional medium-entropy oxide as a highly efficient and stable electrocatalyst for oxygen evolution reaction

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Nano research 2024年第4期17卷 2555-2562页

作者： Guangyuan Yan Tianlu Wang Biwei Zhao Wenjing Gao Tong Wu Liming Ou School of Mechanical Electronic and Control EngineeringBeijing Jiaotong UniversityBeijing 100044China

Medium-entropy oxides(MEOs)with broad compositional tunability and entropy-driven structural stability,are receiving booming attention as a promising candidate for oxygen evolution reaction(OER)***,ultrathin two-dimensional(2D)nanostructure offers extremely large specific surface area and is therefore considered to be an ideal catalyst ***,it remains a grant challenge to synthesize ultrathin 2D MEOs due to distinct nucleation and growth kinetics of constituent multimetallic elements in 2D anisotropic *** this work,an ultrathin 2D MEO(MnFeCoNi)O was successfully synthesized by a facile and low-temperature ionic layer epitaxy *** from multi-metal synergistic effects within ultrathin 2D nanostructure,this 2D MEO(MnFeCoNi)O revealed excellent OER electrocatalytic performance with a quite low overpotential of 117 mV at 10 mA·cm^(-2) and an impressive stability for 120 h continuous operation with only 6.9%***,the extremely high mass activity(5584.3 A·g^(-1))was three orders of magnitude higher than benchmark RuO_(2)(3.4 A·g^(-1))at the same overpotential of 117 *** work opens up a new avenue for developing highly efficient and stable electrocatalysts by creating 2D nanostructured MEOs.

关键词： medium-entropy oxide two-dimensional nanomaterials ionic layer epitaxy oxygen evolution reaction electrocatalysis

Index-free triangle-based graph local clustering

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Frontiers of Computer Science 2024年第3期18卷 143-153页

作者： Zhe YUAN Zhewei WEI Fangrui LV Ji-Rong WEN The Country and Area Studies Academy Beijing Foreign Studies UniversityBeijing 100089China Gaoling School of Artificial Intelligence Renmin University of ChinaBeijing 100872China

Motif-based graph local clustering(MGLC)is a popular method for graph mining tasks due to its various ***,the traditional two-phase approach of precomputing motif weights before performing local clustering loses locality and is impractical for large *** some attempts have been made to address the efficiency bottleneck,there is still no applicable algorithm for large scale graphs with billions of *** this paper,we propose a purely local and index-free method called Index-free Triangle-based Graph Local Clustering(TGLC^(*))to solve the MGLC problem w.r.t.a ***^(*)directly estimates the Personalized PageRank(PPR)vector using random walks with the desired triangleweighted distribution and proposes the clustering result using a standard sweep *** demonstrate TGLC^(*)’s scalability through theoretical analysis and its practical benefits through a novel visualization ***^(*)is the first algorithm to solve the MGLC problem without precomputing the motif *** experiments on seven real-world large-scale datasets show that TGLC^(*)is applicable and scalable for large graphs.

关键词： graph local clustering triangle motif index-free sampling method visualization

Effects of the nozzle structure and fluidized gas composition on the gas-particle two-phase jet characteristic in a powder fuel scramjet

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颗粒学报（英文版） 2024年第9期92卷 166-179页

作者： Changfei Zhuo Hongming Ding Xiaobin Ren Hanyu Deng Xiong Chen School of Mechanical and Engineering Key Laboratory of Special Engine TechnologyMinistry of EducationNanjing University of Science and TechnologyNanjing210094China School of Mechanical and Engineering Key Laboratory of Special Engine TechnologyMinistry of EducationNanjing University of Science and TechnologyNanjing210094China Department of Mechanical Engineering National University of Singapore9 Engineering Drive 1Singapore117576 Shanxi North Xing'an Chemical Industry Co. Ltd.Taiyuan030008China

The interaction between nozzle design and fluidization gas composition significantly influences the dynamics within a powder fuel scramjet's combustion *** investigate this relationship,an experimental study utilized high-speed shadow imaging technology to explore the macroscopic aspects of powder fuel *** investigation examined various convergence angles,nozzle throat lengths,and fluidized gas *** findings include:During jet development,powder fuel initially concentrates near the axis,with non-convergence angle nozzles exhibiting longer concentrated distri-bution periods than convergence angle *** nozzle convergence angles lead to increased penetration distance,frontal velocity,and radial diffusion distance during the initial stages of jet ***,stable jet shapes show larger divergence angles as nozzle convergence angle decreases,with the largest divergence angle observed at α=60°.In the initial 0-7 ms of jet development,the powder fuel jet demonstrates greater penetration distance and frontal velocity under certain ***,penetration distance and frontal velocity increase with throat length from 7 to 20 ms,accompanied by changes in divergence ***,at a throat length(l)of 2 mm,the near-field divergence angle measures 46.50°,and the far-field divergence angle is 22.25°.Conversely,at I=8 mm,the near-field divergence angle is 33.49°,and the far-field divergence angle is 23.21°.The fluidization gas composition minimally affects jet penetration distance and frontal velocity during the initial 0-3 ***,due to hydrogen's low density,hydrogen/powder fuel jets exhibit shorter distances and velocities compared to nitrogen/powder fuel *** fluidization also results in larger divergence angles,particularly in the near *** findings underscore the importance of nozzle design and fluidization gas composition in optimizing scramjet performance and efficiency.

关键词： Gas-particle two-phase jet Multiphase flows Nozzle contraction angle Powder fuel scramjet

BACNN: Multi-scale feature fusion-based bilinear attention convolutional neural network for wood NIR classification

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Journal of Forestry research 2024年第4期35卷 202-214页

作者： Zihao Wan Hong Yang Jipan Xu Hongbo Mu Dawei Qi College of Science Northeast Forestry UniversityHarbin 150040People’s Republic of China

Effective development and utilization of wood resources is *** modification research has become an integral dimension of wood science research,however,the similarities between modified wood and original wood render it challenging for accurate identification and classification using conventional image classification ***,the development of efficient and accurate wood classification techniques is *** paper presents a one-dimensional,convolutional neural network(i.e.,BACNN)that combines near-infrared spectroscopy and deep learning techniques to classify poplar,tung,and balsa woods,and PVA,nano-silica-sol and PVA-nano silica sol modified woods of *** results show that BACNN achieves an accuracy of 99.3%on the test set,higher than the 52.9%of the BP neural network and 98.7%of Support Vector Machine compared with traditional machine learning methods and deep learning based methods;it is also higher than the 97.6%of LeNet,98.7%of AlexNet and 99.1%of ***,the classification method proposed offers potential applications in wood classification,especially with homogeneous modified wood,and it also provides a basis for subsequent wood properties studies.

关键词： Wood classification Near infrared spectroscopy Bilinear network SE module Anti-noise algorithm

Particle Distribution Informed by Chain Rigidity in Diblock Copolymer Melts: The Effect of Entropy

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Chinese Journal of Polymer Science 2024年第3期42卷 388-399,I0009页

作者： Yuguo Chen Shuanhu Qi Ying Jiang School of Chemistry Beihang UniversityBeijing 100191China

We study the effect of chain rigidity on tailoring the nanoparticle locations for neutral and selective particles embedded in the lamellar morphology formed by semiflexible diblock copolymer chains using self-consistent field calculations. The nanoparticles are modeled through a cavity function, and the semiflexible chains are represented by the continuous Kratsky-Porod chain model. In general situation, the nanoparticles prefer to stay at the interface in order to reduce the interface areas and thus the system free energy. However, the particle distribution at the domain center is subtle, and the underlying physics is intrinsically different depending on the polymer flexibility. In the case of flexible chains, the entropy just contributes a constant shift to the free energy when the nanoparticles move around the domain center indicating that the local metastable state if appears at the domain center is wholly attributed to the local minimum in the enthalpy. If the polymers are rigid, the variation of the particle distribution at the domain center has a close relation with the polymer rigidity and nanoparticle size. In the case of strongly rigid polymers with small nanoparticles, a nearly uniform particle distribution at the domain center is observed, while in other cases, a local enhancement of particle distribution there is found. In contrast to the case of flexible chains, further analysis reveals the crucial role of entropy in controlling the shape of particle distributions at the phase domain. Specifically, the local metastable state appears in the domain center is determined by the large entropy there which arises from the weak coupling of bond orientations that allows the polymer chains to be relatively relaxed. When the particle becomes selective, its distribution in the phase domain exhibits a shift almost uniformly rather than changes its profile, and the underlying physics still holds. In all, our study establishes a strong coupling between the chain rigi

关键词： Semiflexible diblock copolymer Nanoparticle distribution Self-consistent field theory Entropic effect

On the global smooth solutions of 3D incompressible Hall-MHD equations

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Applied Mathematics(A Journal of Chinese universities) 2024年第2期39卷 319-327页

作者： YUE Gao-cheng SUN Wen-da School of Mathematics Nanjing University of Aeronautics and AstronauticsNanjing 211106China

The present paper is devoted to the well-posedness issue for the 3D incompressible Hall-MHD system obtained from kinetic models. Our analysis strongly relies on the use of the Fourier analysis. We establish the global existence of smooth solutions for a class of large initial data, this result implies the initial velocity and magnetic field can be arbitrarily large.

关键词： 3D Hall-MHD well-posedness Fourier analysis