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A Tri-Salt Composite Electrolyte with Temperature Switch Function for Intelligently Temperature-Controlled Lithium Batteries

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Energy & Environmental Materials 2024年第6期7卷 84-93页

作者： Ende Fu Huimin Wang Yating Zhang Zhenxue Xiao Xiu Zheng Shuai Hao Xueping Gao Institute of New Energy Material Chemistry School of Materials Science and EngineeringNankai UniversityTianjin300350 China

The intense research of lithium-ion batteries has been motivated by their successful applications in mobile devices and electronic *** emerging of intelligent control in kinds of devices brings new requirements for battery *** high-energy lithium batteries are expected to respond or react under different environmental *** this work,a tri-salt composite electrolyte is designed with a temperature switch function for intelligently temperature-controlled lithium ***,the halide Li_(3)YBr_(6)together with LiTFSI and LiNO_(3)works as active fillers in a low-melting-point polymer matrix(polyethyleneglycol dimethyl ether(PEGDME)and polyethylene oxide(PEO)),which is further filled into the pre-lithiated alumina fiber *** 60°C,the composite electrolyte exists in the liquid state and fully contacts with the working electrodes on the liquid–solid interface,effectively minimizing the interfacial resistance and leading to high discharge capacity in the *** electrolyte is changed into a solid state below 30°C so that the ionic conductivity is significantly reduced and the interface resistance is increased dramatically on the solid–solid ***,by simply adjusting the temperature,the cell can be turned“ON”or“OFF”*** novel function of the composite electrolyte has enlightening significance in developing intelligently temperature-controlled lithium batteries.

关键词： composite electrolyte halide electrolyte low melting point solid-state battery temperature switch function

Synthesis of core-shell nanostructured SiO_(2)/TiO_(2)photocatalysts via atomic layer deposition in a fluidized bed with central tube

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Particuology 2024年第8期91卷 19-28页

作者： Wei Liu Daoyin Liu Zuyang Zhang Zhenkun Sun Key Laboratory of Energy Thermal Conversion and Control of Ministry of Education School of Energy&EnvironmentSoutheast UniversityNanjing 210096China

Fluidized bed atomic layer deposition is an efficient technique for particle coating with precise control over the film thickness and uniformity at the *** this study,a fluidized bed with a central tube is designed,where the central tube has two roles:improve fluidization and deliver precursors *** synthesis of core-shell structured SiO_(2)/TiO_(2)nanoparticle catalysts for photodegradation of tetracycline hydrochloride(TC)is carried out using TiCl_(4)and H_(2)O as precursors at 180℃under atmospheric *** the combination of vibration and central tube,the segregation of agglomerate size along the bed height is weakened,and the prepared SiO_(2)/TiO_(2)nanoparticles show excellent photocatalytic degradation performance:the degradation efficiency on TC is 96%under 300 W xenon lamp irradiation for 60 *** mechanism of enhanced photocatalytic activity is due to the Ti-O-Si bonds generated at the interface,which increase the ability to absorb sunlight and accelerate the separation of holes and electrons.

关键词： SiO_(2)/TiO_(2)nanoparticles Fluidization Atomic layer deposition Photocatalysts Photocatalytic mechanism

Analysis of cohesive particles mixing behavior in a twin-paddle blender:DEM and machine learning applications

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Particuology 2024年第7期90卷 350-363页

作者： Behrooz Jadidi Mohammadreza Ebrahimi Farhad Ein-Mozaffari Ali Lohi Department of Chemical Engineering Toronto Metropolitan University350 Victoria StreetToronto M5B 2K3Canada

This research paper presents a comprehensive discrete element method(DEM)examination of the mixing behaviors exhibited by cohesive particles within a twin-paddle blender.A comparative analysis between the simulation and experimental results revealed a relative error of 3.47%,demonstrating a strong agreement between the results from the experimental tests and the DEM *** main focus centers on systematically exploring how operational parameters,such as impeller rotational speed,blender's fill level,and particle mass ratio,influence the *** investigation also illustrates the significant influence of the mixing time on the mixing *** gain a deeper understanding of the DEM simulation findings,an analytical tool called multivariate polynomial regression in machine learning is *** method uncovers significant connections between the DEM results and the operational parameters,providing a more comprehensive insight into their *** multivariate polynomial regression model exhibited robust predictive performance,with a mean absolute percentage error of less than 3%for both the training and validation sets,indicating a slight deviation from actual *** model's precision was confirmed by low mean absolute error values of 0.0144(80%of the dataset in the training set)and 0.0183(20%of the dataset in the validation set).The study offers valuable insights into granular mixing behaviors,with implications for enhancing the efficiency and predictability of the mixing processes in various industrial applications.

关键词： Machine learning Granular mixing Discrete element method Mixing kinetics and mechanism Cohesive particles

Critical approaches in the catalytic transformation of sugar isomerization and epimerization after Fischer-History,challenges,and prospects

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Green Energy & Environment 2024年第3期9卷 435-453页

作者： Da-Ming Gao Xun Zhang Haichao Liu Hidemi Fujino Tingzhou Lei Fuan Sun Jie Zhu Taoli Huhe National-local Joint Engineering Research Center of Biomass Refine and High-Quality Utilization Changzhou UniversityChangzhou213164China Institute of Urban and Rural Mining Research Changzhou UniversityChangzhou213164China Changzhou Key Laboratory of Biomass Green Safe&High Value UtilizationChangzhou UniversityChangzhou213164China Beijing National Laboratory for Molecular Science College of Chemistry and Molecular EngineeringPeking UniversityBeijing100871China Department of Rehabilitation Science Kobe University Graduate School of Health SciencesKobe654-0142Japan

The transformation of aldose to ketose or common sugars into rare saccharides,including rare ketoses and aldoses,is of great value and interest to the food industry and for saccharidic biomass utilization,medicine,and the synthesis of ***,high-fructose corn syrup(HFCS)is industrially produced in more than 10 million tons annually using immobilized glucose *** low-calorie saccharides such as tagatose and psicose,which are becoming popular sweeteners,have also been produced on a pilot scale in order to replace sucrose and ***,current catalysts and catalytic processes are still difficult to utilize in biomass conversion and also have strong substrate dependence in producing high-value,rare *** the specific reaction properties of saccharides and catalysts,since the pioneering discovery by Fischer,various catalysts and catalytic systems have been discovered or developed in attempts to extend the reaction pathways,improve the reaction efficiency,and to potentially produce commercial *** this review,we trace the history of sugar isomerization/epimerization reactions and summarize the important breakthroughs for each reaction as well as the difficulties that remain unresolved to date.

关键词： Rare sugars Isomerization Ketonization Epimerization Catalytic transformation

Investigation on the influence of vortex generator on particle resuspension

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Particuology 2024年第3期86卷 126-136页

作者： Dongchi Yu Jun-Li Lin Jin-Han Xie ASML 80W Tasman DrSan Jose95134CaliforniaUSA Department of Mechanics and Engineering Science at College of Engineering and State Key Laboratory for Turbulence and Complex Systems Peking UniversityBeijing100081China

The vortex generator(VG)and its well-known effect in flow optimization are widely studied and employed across different engineering ***,while the same working principles of VG may be well suited for the applications on surface-cleaning technologies,such promising potential is hardly,if any,explored in the published ***,in the present study,the influence on flow-induced particle resuspension brought by a rectangular vG in a channel flow is investigated with the help of highfidelity computational fluid dynamics *** increases of particle removal forces and resuspension rates are discovered in long,strip-like regions with reduced boundary-layer thickness resulted from the vG-induced vortices,and the enhancement effect is especially significant for configurations with the VG installed at a greater angle of *** is also shown that while the resuspension enhancements on the lower and the upper surfaces of the channel exhibit distinct statistical characteristics,having a VG in the channel improves the overall particle-removing capability of the channel flow by introducing higher surface-averaged removal forces and particle resuspension *** but not least,the increase of resuspension rate is especially significant for the smaller,micron-scale particles which are otherwise hardly disturbed by a VG-less channel flow,and such resuspension-enhancement effectgenerally subsides with increasing particle size.

关键词： Particle resuspension Vortexgenerator CFD Surface cleaning

Flexural behavior of textile reinforced mortar-autoclaved lightweight aerated concrete composite panels

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Frontiers of Structural and Civil Engineering 2024年第5期18卷 776-787页

作者： Liying GUO Mingke DENG Wei ZHANG Tong LI Yangxi ZHANG Mengyu CAO Xian HU Department of Civil Engineering Xi’an University of Architecture and TechnologyXi’an 710055China Key Lab of Structural Engineering and Earthquake Resistance Ministry of Education(XAUAT)Xi’an 710055China Scene engineering design institute Xi’an 710016China Dahua Group Shang hai 200062China

To improve the deficiencies of prefabricated autoclaved lightweight aerated concrete(ALC)panel such as susceptibility to cracking and low load-bearing capacity,a textile-reinforced mortar-autoclaved lightweight aerated concrete(TRM-ALC)composite panel was developed in this *** group of reference ALC panels and five groups of TRM-ALC panels were fabricated and subjected to four-point flexural *** was applied on the tensile side of the ALC panels to create *** variable parameters were the plies of textile(one or two),type of textile(basalt or carbon),and whether the matrix(without textile)was applied on the compression side of *** results showed that a bonding only 8-mm-thick TRM layer on the surface of the ALC panel could increase the cracking load by 180%−520%.The flexural capacity of the TRM-ALC panel increased as the number of textile layers *** reinforcement of the matrix on the compressive side could further enhance the stiffness and ultimate loadbearing capacity of the TRM-ALC *** panels with basalt textile failed in flexural mode,with the rupture of fabric *** with carbon textile failed in shear mode due to the ultra-high tensile strength of *** addition,analytical models related to the different failure modes were presented to estimate the ultimate load-carrying capacity of the TRM-ALC panels.

关键词： prefabricated autoclaved lightweight aerated concrete panel textile-reinforced mortar cracking load flexural capacity stiffness

Photo-induced 1,2-aryl migration of 2-chloro-1-arylpropanone under batch and flow conditions:Rapid,scalable and sustainable approach to 2-arylpropionic acids

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Chinese Chemical Letters 2024年第2期35卷 366-369页

作者： Qiao Li Minjie Liu Meifen Jiang Li Wan Yingtang Ning Fen-Er Chen College of Chemical Engineering Zhejiang University of TechnologyHangzhou 310014China Engineering Center of Catalysis and Synthesis for Chiral Molecules Fudan UniversityShanghai 200433China Shanghai Engineering Center of Industrial Catalysis for Chiral Drugs Shanghai 200433China Institute of Pharmaceutical Science and Technology Zhejiang University of TechnologyHangzhou 310014China

We report the photo-mediated 1,2-aryl migration of 2‑chloro-1-arylpropanones to 2-arylpropionic acids using HCOONa as an acid *** pragmatically focused study obviates the multiple-step sequence in the industrially employed,ZnO-promoted rearrangement strategy,and offers rapid access to various 2-arylpropionic acids under environmentally friendly ***,the successful transfer of this batch photochemistry to a continuous flow platform led to improved scalability and enabled the gram-scale synthesis of loxoprofen.

关键词： Green chemistry Flow chemistry 2-Arylpropionic acids Photo-Favorskii reaction

Nonlinear uncertainty impact of geometric variations on aerodynamic performance of low-pressure turbine blades with ultra-high loading under extreme operational conditions

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Chinese Journal of Aeronautics 2024年第5期37卷 281-300页

作者： Xiaojing WANG Zhengping ZOU Chao FU Pengcheng DU School of Energy and Power Engineering Beihang UniversityBeijing 100191China National Key Laboratory of Science and Technology on Aero-Engine Aero-Thermodynamics Beihang UniversityBeijing 100191China Research Institute of Aero-Engine Beihang UniversityBeijing 100191China

Uncertainty impact of random geometric variations on the aerodynamic performance of low-pressure turbine blades is considerable,which is further amplified by the current ultra-high-lift design trend for weight ***,this uncertainty impact on ultra-highly loaded blades under extreme operational conditions near the margins with potential large-scale open separation is focused on in this *** is demonstrated that this impact is significant,unfavourable,and nonlinear,which is clearly severer under extreme *** addition to the overall attenuation and notable scattering of specific performance,the operational margins with open separation are also notably scattered with great risk of significant *** scattering and nonlinearity are dominated by the variations in leading-edge *** thinning of leading edge triggers local transition,enhancing downstream friction and reducing resistance to open separation,which is further exacerbated by operational ***,the opposite thickening yields less benefit,implying *** unfavourable impact highlights the need for robust aerodynamic design,where both a safer operational condition and a more robust blade are indispensable,i.e.,a compromise among performance,weight,and *** the necessary limitation of loading levels,a mid-loaded design is recommended to reduce adverse pressure gradients in both the leading edge and rear region of the suction side,which helps to decrease the susceptibility of the transition and open separation to random *** improvements can also be achieved by appropriately thickening the leading edge.

关键词： Ultra-highly loaded turbine blade Geometric variations Uncertainty analysis Operational margins Robust aerodynamic design Nonlinearity

Solvent-free carbon sphere nanofluids towards intelligent lubrication regulation

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Friction 2024年第1期12卷 95-109页

作者： Sheng ZHANG Wen LI Xiaoliang MA Xiaoqiang FAN Minhao ZHU Tribology Research Institute School of Mechanical EngineeringSouthwest Jiaotong UniversityChengdu 610031China Key Laboratory of Advanced Technologies of Materials Ministry of EducationSchool of Materials Science and EngineeringSouthwest Jiaotong UniversityChengdu 610031China

By simply switching the electrical circuit installed on steel/steel contact,the tribological behaviors of nanofluids(NFs)can be regulated in real time,thereby achieving the desired performance of friction reduction and wear ***,solvent-free carbon spherical nanofluids(C-NFs)were successfully prepared for intelligent lubrication regulation.C-NFs with excellent lubrication performance can immediately reduce the coefficient of friction(COF)despite applying a weak electric potential(1.5 V).Moreover,polyethylene glycol 400(PEG400)containing 5.0 wt%C-NFs remained responsive to electrical stimulation under the intermittent voltage application with an average coefficient of friction(ACOF)reduction of 20.8%over *** intelligent lubrication regulation of C-NFs under an external electric field(EEF)mainly depends on the orderly arranged double-electric adsorption film of ion canopy-adsorbed carbon spheres(CSs).The intermittent electrical application can continuously reinforce the adsorption film and its durability for real-time controlling the sliding ***-stimulation-responsive intelligent lubricants provide a new technical support for realizing intelligent stepless control of devices.

关键词： solvent-free carbon spherical nanofluids(C-NFs) intelligent lubrication regulation lubrication performance adsorption film