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Rare Metals 2024年第10期43卷 5070-5081页

作者： Zhao-Meng Liu Da Wang Shang-Zhuo Li Qing-Song Lai Dong-Run Yang Lu-Kang Zhao Jian-Jia Mu Xuan-Chen Wang Xuan-Wen Gao Wen-Bin Luo Institute for Energy Electrochemistry and Urban Mines Metallurgy School of MetallurgyNortheastern University Key Laboratory of Advanced Energy Materials Chemistry(Ministry of Education) Nankai University

Ultrafast rechargeable hybrid potassium dualion capacitors （HPDICs） were designed by employing carbon quantum dot@ultrathin carbon film （CQD@CF） as the cathode *** designed CQD@CF is selfassembled by a simple catalytic graphitization route followed by an acid leaching *** special composite features a large adsorption interface,a remarkable anion hybrid storage capability and outstanding structure *** electrochemical performance of CQD@CF composite is fully tapped in a half-cell system at the operating voltage between 1.4 and 4.5 V,achieving an admirable specific discharge capacity of 128.5 mAh·g-1a 50 mA·g-1,an ultra-high capacity retention ratio of 97.97% after cycling 5000 times at 1000 mA·g-1and a 96.10%high capacity retention ratio after cycling 40,000 times at 5000 mA·g-1,***,with the support of ex situ TEM and XPS,the structural stability principle and anionic hybrid storage mechanism of CQD@CF electrode are investigated *** the full-cell system,HPDICs with the CQD@CF as cathode and nanographite powder as anode also present a 141.5 Wh·kg-1high energy density,a 5850 W·kg-1power density and a super-long cycle stability (90.2% capacity retention ratio after cycling 30,000 times at 5000 mA·g-1).

关键词： Anion hybrid storage mechanism Carbon quantum dots Potassium dual ion capacitor Ultrafast rechargeable Ultrathin carbon film

Constructing extrinsic oxygen vacancy on the surface of photocatalyst as CO_(2)and electrons reservoirs to improve photocatalytic CO_(2)reduction activity

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Journal of Environmental sciences 2024年第6期140卷 37-45页

作者： Zaiyong Jiang Hao Li Zhimin Yuan Zheng Wang Maohong Fan Wenkang Miao Hong He State Key Joint Laboratory of Environment Simulation and Pollution Control Research Center for Eco-Environmental SciencesChinese Academy of SciencesBeijing 100085China School of Chemistry&Chemical Engineering and Environmental Engineering Weifang UniversityWeifangShandong 261061China Departments of Chemical and Petroleum Engineering University of WyomingLaramieWY 82071USA Materials Genome Institute Shanghai UniversityShanghai 200444China

Constructing own oxygen vacancies in the photocatalysts is a very promising method to improve their photocatalytic CO_(2)reduction ***,some catalysts have excellent stabilities,making it difficult for them to construct their own oxygen *** simplify the above difficulty of stable photocatalysts,constructing extrinsic oxygen vacancies on their surface as a novel idea is ***,a stable TiO_(2)nanosheet is chosen as a research object,we uniformly deposited BiOCl quantum dots on their surface via a simple adsorption-deposition *** is found that BiOCl quantum dots are able to simultaneously self-transform into defective BiOCl with many oxygen vacancies when the photocatalyst is performed photocatalytic CO_(2)*** extrinsic oxygen vacancies can act as“CO_(2)and photo-generated electrons reservoirs”to improve CO_(2)capture and accelerate the separation of photogenerated electrons and *** the above reasons,the modified TiO_(2)showed obvious enhancement of photocatalytic CO_(2)reduction compared to pristine TiO_(2)and *** work may open a new avenue to broaden the use of oxygen vacancies in the process of photocatalytic CO_(2)reduction.

关键词： Oxygen vacancy BiOCl Photocatalyst CO_(2)reduction TiO_(2)

Charge regulation by ferromagnetic metal/LiF spin-polarized interface for high-performance Li metal anodes

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Rare Metals 2024年第3期43卷 995-1005页

作者： Ming-Yang Feng Shuang Zhou Yi-Fang Zhang Ya-Ping Wang Chun-Yan Fu Jian-Wen Li Yuan-Lang Wan Zhi-Jia Zhang Yong Jiang An-Qiang Pan State Key Laboratory of Powder Metallurgy School of Materials Science and EngineeringCentral South UniversityChangsha410083China State Key Laboratory of Separation Membranes and Membrane Processes Tianjin Key Laboratory of Advanced Fibers and Energy StorageSchool of Material Science and EngineeringTiangong UniversityTianjin300387China School of Materials science and Engineering Hebei University of TechnologyTianjin300130China

The interfacial characteristics of the Li metal anode(LMA)play a crucial role in its overall *** various materials being applied to modify the interface,a comprehensive understanding of their specific mechanisms remains to be ***,we have prepared carbon cloth(CC)frameworks with their surfaces modified using ferromagnetic metal/LiF heterogeneous films(T^(M)-LiF-CC)as the substrate for LMA,which exhibit superior electrochemical *** ferromagnetic Co as a representative example,our study demonstrates that the enhanced performance of Co-LiF-CC,compared to bare CC,is attributed to the spinpolarized interface contributed by the Co/LiF *** and LiF play individual roles in redistributing electrons and Li^(+)to promote homogeneous Li *** nanoparticles play a crucial role in generating strong surface capacitance by storing electrons in spin-split bands,while LiF,with low surface diffusion barriers,ensures fast transportation of Li^(+).The Co-LiF-CC@Li electrodes deliver long lives of 7400 and 3600 h at 1 and 2 mA·cm^(-2)in symmetric cells,respectively;moreover,they enable full batteries with high and durable capacities,particularly when the N/P ratios are low(3.3 or even 1.7).

关键词： Lithium metal anode Interfacial charge Ferromagnetic metal Lithium fluoride Spin polarization

Machine learning for carbonate formation drilling: Mud loss prediction using seismic attributes and mud loss records

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Petroleum science 2024年第2期21卷 1241-1256页

作者： Hui-Wen Pang Han-Qing Wang Yi-Tian Xiao Yan Jin Yun-Hu Lu Yong-Dong Fan Zhen Nie National Key Laboratory of Petroleum Resources and Engineering China University of Petroleum(Beijing)Beijing102249China College of science China University of Petroleum-BeijingBeijing102249China Petroleum Exploration and Production Research Institute SINOPECBeijing102206China College of Petroleum Engineering China University of Petroleum-BeijingBeijing102249China Research Institute of Petroleum Exploration and Development CNPCBeijing100083China

Due to the complexity and variability of carbonate formation leakage zones, lost circulation prediction and control is one of the major challenges of carbonate drilling. It raises well-control risks and production expenses. This research utilizes the H oilfield as an example, employs seismic features to analyze mud loss prediction, and produces a complete set of pre-drilling mud loss prediction solutions. Firstly, 16seismic attributes are calculated based on the post-stack seismic data, and the mud loss rate per unit footage is specified. The sample set is constructed by extracting each attribute from the seismic trace surrounding 15 typical wells, with a ratio of 8:2 between the training set and the test set. With the calibration results for mud loss rate per unit footage, the nonlinear mapping relationship between seismic attributes and mud loss rate per unit size is established using the mixed density network ***, the influence of the number of sub-Gausses and the uncertainty coefficient on the model's prediction is evaluated. Finally, the model is used in conjunction with downhole drilling conditions to assess the risk of mud loss in various layers and along the wellbore trajectory. The study demonstrates that the mean relative errors of the model for training data and test data are 6.9% and 7.5%, respectively, and that R2is 90% and 88%, respectively, for training data and test data. The accuracy and efficacy of mud loss prediction may be greatly enhanced by combining 16 seismic attributes with the mud loss rate per unit footage and applying machine learning methods. The mud loss prediction model based on the MDN model can not only predict the mud loss rate but also objectively evaluate the prediction based on the quality of the data and the model.

关键词： Lost circulation Risk prediction Machine learning Seismic attributes Mud loss records

Crystalline-amorphous M@MN_x(M=Co,Fe,Ni)encapsulated in nitrogen-doped carbon for enhanced efficient and durable hydrogen evolution reaction

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Rare Metals 2024年第4期43卷 1547-1556页

作者： Yang Yang Xiao-Chuan Duan Shao-Hui Guo Xian-Ming Zhang College of Materials science and Engineering College of ChemistryKey Laboratory of Interface Science and Engineering in Advanced MaterialsTaiyuan University of TechnologyYuci030600China

Developing earth-abundant electrocatalysts for hydrogen evolution reaction(HER)is important for the sustainable energy ***,efficient and stable heterocatalysts consisting of crystalline-amorphous M@MN_(x)(M=Co,Fe,Ni)encapsulated in N-doped carbon layers supported with N-doped graphene sheets(denoted as M@MN_(x)@NC-NG)are synthesized by facile hydrothermal reaction and nitridation *** the nitriding process,metal ions in M(tzbc)_2(H_(2)O)_4(tzbc=4-(1H-1,2,4-triazol-1-yl)benzoic acid)complexes are reduced to crystalline M cores,accompanied by the formation of amorphous MN_(x)shells;the tzbc ligands are insitu carbonized to form outermost N-doped carbon(NC)layers that connect with inner MN_(x)via M-N-C motifs inherited from the complex precursors and inhibit the transition of MN_(x)from amorphous to crystalline *** Co@CoN_(x)@NC-NG catalyst exhibits excellent HER activity with small overpotentials of 45 and 64 mV at a cathode current density of 10 mA·cm^(-2)and low Tafel slopes of 40 and 85 mV·dec^(-1)in 0.5 mol·L^(-1)H_(2)SO_4 and1.0 mol·L^(-1)KOH electrolytes,*** Co@CoN_(x)@NC-NG retains 97%of the initial overpotential after 100,000 s in both acidic and alkaline *** outstanding HER performance originates from the crystalline-amorphous Co@CoN_(x)that redistributes electrons around the heterointerfaces,facilitating the conversion process of H^(+)/H_(2)O to hydrogen and thereby promoting HER *** outermost NC layers serve as the armor of Co@CoN_(x),and graphene nanosheets act as carriers of egg-like Co@CoN_(x)@NC and conduction paths for electron shuttles,ensuring stable and continuous electrocatalytic hydrogen production.

关键词： Hydrogen evolution reaction Electrocatalysts Iron group metals Heterojunction Crystalline-amorphous structure

Intelligent geochemical interpretation of mass chromatograms:Based on convolution neural network

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Petroleum science 2024年第2期21卷 752-764页

作者： Kai-Ming Su Jun-Gang Lu Jian Yu Zi-Xing Lu Shi-Jia Chen Hubei Key Laboratory of Petroleum Geochemistry and Environment Wuhan430100HubeiChina College of Resources and Environment Yangtze UniversityWuhan430100HubeiChina School of Geoscience and Technology Southwest Petroleum UniversityChengdu610500SichuanChina Changqing Oilfield Company PetroChinaXi'an710021ShaanxiChina

Gas chromatography-mass spectrometry(GC-MS)is an extremely important analytical technique that is widely used in organic *** is the only approach to capture biomarker features of organic matter and provides the key evidence for oil-source correlation and thermal maturity ***,the conventional way of processing and interpreting the mass chromatogram is both timeconsuming and labor-intensive,which increases the research cost and restrains extensive applications of this *** overcome this limitation,a correlation model is developed based on the convolution neural network(CNN)to link the mass chromatogram and biomarker features of samples from the Triassic Yanchang Formation,Ordos Basin,*** this way,the mass chromatogram can be automatically *** research first performs dimensionality reduction for 15 biomarker parameters via the factor analysis and then quantifies the biomarker features using two indexes(*** and PMI)that represent the organic matter thermal maturity and parent material type,***,training,interpretation,and validation are performed multiple times using different CNN models to optimize the model structure and hyper-parameter setting,with the mass chromatogram used as the input and the obtained MI and PMI values for supervision(label).The optimized model presents high accuracy in automatically interpreting the mass chromatogram,with R2values typically above 0.85 and0.80 for the thermal maturity and parent material interpretation results,*** significance of this research is twofold:(i)developing an efficient technique for geochemical research;(ii)more importantly,demonstrating the potential of artificial intelligence in organic geochemistry and providing vital references for future related studies.

关键词： Organic geochemistry Biomarker Mass chromatographic analysis Automated interpretation Convolution neural network Machine learning

Fe-N_(x) sites coupled with core-shell FeS@C nanoparticles to boost the oxygen catalysis for rechargeable Zn-air batteries

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Journal of Energy Chemistry 2024年第3期90卷 565-577,I0013页

作者： Katam Srinivas Zhuo Chen Anran Chen Fei Ma Ming-qiang Zhu Yuanfu Chen School of Integrated Circuit science and Engineering and State Key Laboratory of Electronic Thin Films and Integrated DevicesUniversity of Electronic Science and Technology of ChinaChengdu 610054SichuanChina College of Mechanical and Electronic Engineering Northwest A&F UniversityYangling 712100ShaanxiChina School of Materials and Energy Yunnan UniversityKunming 650091YunnanChina

The development of efficient single-atom catalysts(SACs) for the oxygen reduction reaction(ORR)remains a formidable challenge,primarily due to the symmetric charge distribution of metal singleatom sites(M-N_(4)).To address such issue,herein,Fe-N_(x) sites coupled synergistic catalysts fabrication strategy is presented to break the uniform electronic distribution,thus enhancing the intrinsic catalytic ***,atomically dispersed Fe-N_(x) sites supported on N/S-doped mesoporous carbon(NSC)coupled with FeS@C core-shell nanoparticles(FAS-NSC@950) is synthesized by a facile hydrothermal reaction and subsequent *** to the presence of an in situ-grown conductive graphitic layer(shell),the FeS nanoparticles(core) effectively adjust the electronic structure of single-atom Fe sites and facilitate the ORR kinetics via short/long-range coupling ***,FAS-NSC@950displays a more positive half-wave potential(E_(1/2)) of 0.871 V with a significantly boosted ORR kinetics(Tafel slope=52.2 mV dec^(-1)),outpacing the commercial Pt/C(E_(1/2)=0.84 V and Tafel slope=54.6 mV dec^(-1)).As a bifunctional electrocatalyst,it displays a smaller bifunctional activity parameter(ΔE) of 0.673 V,surpassing the Pt/C-RuO_(2) combination(ΔE=0.724 V).Besides,the FAS-NSC@950-based zincair battery(ZAB) displays superior power density,specific capacity,and long-term cycling performance to the Pt/C-Ir/C-based *** work significantly contributes to the field by offering a promising strategy to enhance the catalytic activity of SACs for ORR,with potential implications for energy conversion and storage technologies.

关键词： Fe-N_(x)sites Core-shell FeS@C Synergistic interactions Oxygen reduction reaction Zn-air battery

Protective benefits of HDPE board sand fences in an environment with variable wind directions on Gobi surfaces:wind tunnel study

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Journal of Mountain science 2024年第10期21卷 3353-3367页

作者： ZHANG Kai TIAN Jianjin LIU Benli ZHAO Yanhua ZHANG Hailong WANG Zhenghui DENG Yuhui College of Civil Engineering Lanzhou Jiaotong UniversityLanzhou 730000China Key Laboratory of Ecological Safety and Sustainable Development in Arid Lands Northwest Institute of Eco-Environment and ResourcesChinese Academy of SciencesLanzhou 730000China

The Golmud-Korla Railway in the Gobi area faces operational challenges due to sand hazards,caused by strong and variable *** study addresses these challenges by conducting wind tunnel tests to evaluate the protective benefits of High Density Polyethylene(HDPE)board sand fences,focusing on their orientation relative to various wind directions(referred to as'wind angle').This study found that the size of the low-velocity zone on the leeward side of the sand fences(LSF)expanded with an increase in the wind angle(WA).At 1H(the height of the sand fence)and 2H positions on the LSF,the wind speed profiles(WSP)exhibited a segmented logarithmic growth,constrained by Z=H at varying *** efficacy of the sand fence in obstructing airflow escalated as WA *** size of the WA has a significant impact on the protective efficiency of HDPE board sand ***,compared to typical sandy surfaces,the rate of sand transport across the Gobi surface diminishes more slowly with height,attributed to the gravel's rebound *** phenomenon allows some sand particles to bypass the fences,rendering them less effective at blocking wind and trapping sand than in sandy *** paper offers scientific evidence supporting the practical use and enhancement of HDPE board sand fences in varied wind conditions.

关键词： Variable wind directions Blown sand control Wind tunnel tests HDPE board sand fences

Reinforcing effects of polypropylene on energy absorption and fracturing of cement-based tailings backfill under impact loading

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International Journal of Minerals,Metallurgy and Materials 2024年第4期31卷 650-664页

作者： Jiajian Li Shuai Cao Erol Yilmaz School of Civil and Resources Engineering University of Science and Technology BeijingBeijing 100083China State Key Laboratory of High-Efficient Mining and Safety of Metal Mines of Ministry of Education University of Science and Technology BeijingBeijing 100083China Department of Civil Engineering Geotechnical DivisionRecep Tayyip Erdogan UniversityFenerRize TR53100Turkey

Polypropylene(PP)fiber-reinforced cement-based tailings backfill(FRCTB)is a green compound material with superior crack resistance and has good prospects for application in underground ***,FRCTB exhibits susceptibility to dynamic events,such as impact ground pressure and blast *** paper investigates the energy and crack distribution behavior of FRCTB under dynamic impact,considering the height/diameter(H/D)*** Hopkinson pressure bar,industrial computed tomography scan,and scanning electron microscopy(SEM)experiments were carried out on six types of *** outcomes confirmed fiber aggregation at the bottom of *** H/D was less than 0.8,the proportion of PP fibers distributed along theθangle direction of80°-90°*** the total energy,all samples presented similar energy absorption,reflectance,and ***,a rise in H/D may cause a rise in the energy absorption rate of FRCTB during the peak phase.A positive correlation existed between the average strain rate and absorbed energy per unit *** increase in H/D resulted in a decreased crack volume fraction of *** the H/D was greater than or equal to 0.7,the maximum crack volume fraction of FRCTB was observed close to the incidence *** cracks were present only in the FRCTB with an H/D ratio of *** with H/D ratios of 0.5 and 0.6 showed similar distributions of weakly and heavily damaged *** fibers can limit the emergence and expansion of cracks by influencing their *** observations revealed considerable differences in the bonding strengths between fibers and the *** that adhered particularly well to the substrate were attracted together with the hydration products adhering to *** results show that FRCTB is promising as a sustainable and green backfill for determining the design properties of mining with backfill.

关键词： cement-based tailings fiber-reinforced backfills fracture energy absorption impact loading

Time-dependent behavior and permeability evolution of limestone under hydro-mechanical coupling

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Journal of Mountain science 2024年第5期21卷 1697-1714页

作者： WANG Zhilong ZENG Zhengqiang LYU Cheng WANG Mingnian HU Xiongyu DONG Yucang School of Civil Engineering Southwest Jiaotong UniversityChengdu 61003China College of Civil Engineering Tongji UniversityShanghai 200092China College of Water Resource and Hydropower Sichuan UniversityChengdu 610065China Hebei GEO University Shijiazhuang 050031China

Excessively high pore water pressure presents unpredictable risks to the safety of rock tunnels in mountainous regions that are predominantly composed of limestone. Investigating the creep characteristics and permeability evolution of limestone under varying hydrated conditions is crucial for a better understanding of the delayed deformation mechanisms of limestone rock tunnels. To this end, this paper initially conducts a series of multi-stage triaxial creep tests on limestone samples under varying pore water pressures. The experiment examines how pore water pressure affects limestone’s creep strain, strain rate, long-term strength, lifespan, and permeability, all within the context of hydraulicmechanical(HM) coupling. To better describe the creep behavior associated with pore water pressure, this paper proposes a new nonlinear fractional creep constitutive model. This constitutive model depicts the initial, steady-state, and accelerated phases of limestone’s creep behavior. Finally, the proposed model is applied to the numerical realization of deformation in limestone tunnel, validating the effectiveness of the proposed constitutive model in predicting tunnel’s creep deformation. This research enhances our understanding of limestone’s creep characteristics and permeability evolution under HM coupling, laying a foundation for assessing the longterm stability of mountain tunnels.

关键词： Creep test Hydraulic-mechanical coupling Creep constitutive model Fractional derivatives Pore pressure