检索结果-南通市图书馆

Nano Research 2024年第4期17卷 3130-3138页

作者： Zedong Hu Juanjuan Lu Hongyi Dou Jianan shen James PBarnard Juncheng Liu Xinghang Zhang Haiyan Wang school of Electrical and Computer Engineering Purdue UniversityWest LafayetteIN 47906USA school of Materials Engineering Purdue UniversityWest LafayetteIN 47906USA

Oxide-metal based nanocomposite thin films have attracted great interests owing to their unique anisotropic structure and physical properties.A wide range of Au-based oxide-metal nanocomposites have been demonstrated,while other metal systems are scarce due to the challenges in the initial nucleation and growth as well as possible interdiffusions of the metallic *** this work,a unique anodic aluminum oxide(AAO)template was used to grow a thin Co seed layer and the following self-assembled metal-oxide(Co-BaTiO_(3))vertically aligned nanocomposite thin film *** AAO template allows the uniform growth of Co-seeds and successfully deposition of highly ordered Co pillars(with diametersside the oxide *** magnetic anisotropy and strong magneto-optical coupling properties have been observed.A thin Au-BaTiO_(3) template was also later introduced for further enhanced nucleation and ordered growth of the *** the advantage of such a unique nanostructure,a large out-of-plane(OP)coercive field(Hc)of~5000 Oe has been achieved,making the nanocomposite an ideal candidate for high density perpendicular magnetic tunneling junction(p-MTJ).A strong polar magneto-optical Kerr effect(MOKE)has also been observed which inspires a novel optical-based reading method of the MTJ states.

关键词： vertically aligned nanocomposite(VAN) Co BaTiO_(3) thin film magneto-optical coupling magnetic anisotropy

Construction of conjugated scaffolds driven by mechanochemistry towards energy storage applications

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Green Chemical Engineering 2024年第2期5卷 155-172页

作者： Juntian Fan Zhenzhen Yang sheng Dai department of Chemistry Institute for Advanced Materials and ManufacturingUniversity of TennesseeKnoxvilleTN37996USA Chemical sciences Division Oak Ridge National LaboratoryOak RidgeTN37831USA

Mechanochemistry has been recognized as an efficient and sustainable methodology to provide a unique driven force and reaction environments under ambient and neat conditions for the construction of functionalized materials possessing promising *** them,highly porous conjugated scaffolds with attractive electronic conductivities and high surface areas are one of the representative categories exhibiting diverse taskspecific applications,especially in electrochemical energy *** recent years,the mechanochemistry-driven procedures have been deployed to construct conjugated scaffolds with engineered structures and properties leveraging the tunability in chemical structures of building blocks and polymerization capability of diverse ***,a thorough review of related works is required to gain an in-depth understanding of the mechanochemical synthesis procedure and property-performance relationship of the as-produced conjugated ***,the mechanochemistry-driven construction of conjugated porous networks(CPNs),the carbon-based materials(e.g.,graphite and graphyne),and carbon supported single atom catalysts(Cs-sACs)are discussed and *** electrochemical performance of the afforded conductive scaffolds as electrode materials in supercapacitors and alkali-ion batteries is ***,the challenges and potential opportunities related to the construction of conjugated scaffolds driven by mechanochemistry are also discussed and concluded.

关键词： Mechanochemistry Conjugated scaffolds Porous organic networks Alkali-ion battery supercapacitor

Nano-enhanced solid-state hydrogen storage:Balancing discovery and pragmatism for future energy solutions

在线全文

学校读者我要写书评

暂无评论

Nano Research 2024年第10期17卷 8729-8753页

作者： Chaochao Dun Xinyi Wang Linfeng Chen sichi Li Hanna M.Breunig Jeffrey J.urban The Molecular Foundry Lawrence Berkeley National Laboratory BerkeleyBerkeleyCA 94720USA energy Analysis and Environmental Impacts Division Lawrence Berkeley National LaboratoryBerkeleyCA 94720USA Lawrence Livermore National laboratory LivermoreCA 94550USA

Nanomaterials have revolutionized the battery industry by enhancing energy storage capacities and charging speeds,and their application in hydrogen(H_(2))storage likewise holds strong potential,though with distinct challenges and mechanisms.H_(2) is a crucial future zero-carbon energy vector given its high gravimetric energy density,which far exceeds that of liquid ***,its low volumetric energy density in gaseous form currently requires storage under high pressure or at low *** review critically examines the current and prospective landscapes of solid-state H_(2) storage technologies,with a focus on pragmatic integration of advanced materials such as metal-organic frameworks(MOFs),magnesium-based hybrids,and novel sorbents into future energy *** materials,enhanced by nanotechnology,could significantly improve the efficiency and capacity of H_(2) storage systems by optimizing H_(2) adsorption at the nanoscale and improving the kinetics of H_(2) uptake and *** discuss various H_(2) storage mechanisms—physisorption,chemisorption,and the Kubas interaction—analyzing their impact on the energy efficiency and scalability of storage *** review also addresses the potential of“smart MOFs”,single-atom catalyst-doped metal hydrides,MXenes and entropy-driven alloys to enhance the performance and broaden the application range of H_(2) storage systems,stressing the need for innovative materials and system integration to satisfy future energy ***-throughput screening,combined with machine learning algorithms,is noted as a promising approach to identify patterns and predict the behavior of novel materials under various conditions,significantly reducing the time and cost associated with experimental *** closing,we discuss the increasing involvement of various companies in solid-state H_(2) storage,particularly in prototype vehicles,from a techno-economic *** forward-looking perspective underscores t

关键词： nanomaterials nanotechnology solid-state H_(2)storage techno-economic analysis model-driven material development processes

Indispensable gutter layers in thin-film composite membranes for carbon capture

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Green energy & Environment 2024年第8期9卷 1220-1238页

作者： Gengyi Zhang Haiqing Lin department of Chemical and Biological Engineering University at Buffalo The State University at New York

Industrial thin-film composite(TFC) membranes achieve superior gas separation properties from high-performance selective layer materials,while the success of membrane technology relies on high-performance gutter layers to achieve production scalability and low-cost manufacturing. However, the current literature predominantly focuses on the design of polymer architectures to obtain high permeability and selectivity, while the art of fabricating gutter layers is usually safeguarded by industrial manufacturers and appears lackluster to academic researchers. This is the first report aiming to provide a comprehensive and critical review of state-of-the-art gutter layer materials and their design and modification to enable TFC membranes with superior separation performance. We first elucidate the importance of the gutter layer on membrane performance through modeling and experimental results. Then various gutter layer materials used to obtain high-performance composite membranes are critically reviewed, and the strategies to improve their compatibility with the selective layer are highlighted, such as oxygen plasma treatment, polydopamine deposition, and surface grafting. Finally, we present the opportunities of the gutter layer design for practical applications.

关键词： Thin-film composite membranes Gutter layer Gas separation Carbon capture

Tuning structural and Electronic Configuration of FeN_(4) via External s for Enhanced Oxygen Reduction Reaction

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

energy & Environmental Materials 2024年第2期7卷 93-101页

作者： shidong Li Lixue Xia Jiantao Li Zhuo Chen Wei Zhang Jiexin Zhu Ruohan Yu Fang Liu sungsik Lee Yan Zhao Liang Zhou Liqiang Mai state Key laboratory of Advanced Technology for Materials synthesis and Processing Wuhan University of TechnologyWuhan 430070China Foshan Xianhu laboratory of the Advanced energy science and Technology Guangdong laboratory Foshan 528200China Chemical sciences and Engineering Division Argonne National Laboratory9700 South Cass AvenueLemontIL 60439USA NRC(Nanostructure Research Centre) Wuhan University of TechnologyWuhan 430070China X-ray science Division Advanced Photon SourcesArgonne National Laboratory9700 South CassAvenueLemontIL 60439USA state Key laboratory of silicate Materials for Architectures International School of Materials Science and EngineeringWuhan University of TechnologyWuhan 430070China The Institute of Technological sciences Wuhan UniversityWuhan 430072China Hubei Longzhong laboratory Xiangyang 441000China

The Fe-N-C material represents an attractive oxygen reduction reaction electrocatalyst,and the FeN_(4)moiety has been identified as a very competitive catalytic active *** tuning of the coordination structure of FeN_(4)has an essential impact on the catalytic ***,we construct a sulfur-modified Fe-N-C catalyst with controllable local coordination environment,where the Fe is coordinated with four in-plane N and an axial external *** external s atom affects not only the electron distribution but also the spin state of Fe in the FeN_(4)active *** appearance of higher valence states and spin states for Fe demonstrates the increase in unpaired *** the above characteristics,the adsorption and desorption of the reactants at FeN_(4)active sites are optimized,thus promoting the oxygen reduction reaction *** work explores the key point in electronic configuration and coordination environment tuning of FeN_(4)through s doping and provides new insight into the construction of M-N-C-based oxygen reduction reaction catalysts.

关键词： coordination structure electronic configuration FeN_(4)moiety oxygen reduction reaction sulfur doping

Multidimensional images and aberrations in sTEM

在线全文

学校读者我要写书评

暂无评论

Chinese Physics B 2024年第9期33卷 68-74页

作者： Eric R.Hoglund Andrew R.Lupini Center for Nanophase Materials sciences Oak Ridge National LaboratoryOak RidgeTN 37831United States

Recent advances in scanning transmission electron microscopy(sTEM)have led to increased development of multidimensional sTEM imaging modalities and novel image reconstruction *** interest arises because the main electron lens in a modern transmission electron microscope usually has a diffraction-space information limit that is significantly better than the real-space resolution of the same *** state-of-affairs is sometimes shared by other scattering methods in modern physics and contributes to a broader excitement surrounding multidimensional techniques that scan a probe while recording diffraction-space images,such as ptychography and scanning nano-beam ***,the contrasting resolution in the two spaces raises the question as to what is limiting their effective ***,we examine this paradox by considering the effects of aberrations in both image and diffraction planes,and likewise separate the contributions of pre-and post-sample *** consideration provides insight into aberration-measurement techniques and might also indicate improvements for super-resolution techniques.

关键词： scanning transmission electron microscopy (sTEM) aberrations

Nanoscale materials transformations revealed by liquid phase TEM

在线全文

学校读者我要写书评

暂无评论

Nano Research 2024年第10期17卷 9152-9165页

作者： Qiubo Zhang Daewon Lee Haimei Zheng Materials sciences Division Lawrence Berkeley National LaboratoryBerkeleyCalifornia 94720USA department of Materials science and Engineering University of CaliforniaBerkeleyCalifornia 94720USA

Nanoscale materials often undergo structural,morphological,or chemical changes,especially in solution processes,where heterogeneity and defects may significantly impact the transformation *** phase transmission electron microscopy(TEM),allowing us to track dynamic transformations of individual nanoparticles,has become a powerful platform to reveal nanoscale materials transformation pathways and address challenging issues that are hard to approach by other *** the development of modern liquid cells,implementing advanced imaging and image analysis methods,and strategically exploring diverse systems,significant advances have been made in liquid phase TEM,including improved high-resolution imaging through liquids at the atomic level and remarkable capabilities in handling complex systems and *** the past more than a decade,we spent much effort in developing and applying liquid phase TEM to elucidate how atomic level heterogeneity and defects impact various physicochemical processes in liquids,such as growth,self-assembly of nanoparticles,etching/corrosion,electrodeposition of alkali metals,catalyst restructuring during reactions,and so *** article provides a brief review of the liquid phase TEM study of nanoscale materials transformations,focusing on the growth of nanomaterials with distinct shape/hierarchical structures,such as one-dimensional(1D)growth by nanoparticle attachment,two-dimensional(2D)growth with nanoparticles as intermediates,core-shell structure ripening,solid-liquid interfaces including those in batteries and electrocatalysis,highlighting the impacts of heterogeneity and defects on broad nanoscale transformation pathways.

关键词： liquid phase transmission electron microscopy(TEM) liquid cells nanomaterials growth transformations pathways solid-liquid interface heterogeneity and fluctuations

Quantification of grain boundary effects on the geometrically necessary dislocation density evolution and strain hardening of polycrystalline Mg-4Al using in situ tensile testing in scanning electron microscope and HR-EBsD

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Journal of Magnesium and Alloys 2024年第5期12卷 1815-1829页

作者： Eunji song Mohsen Taheri Andani Amit Misra department of Materials science and Engineering University of MichiganAnn ArborMI 48109USA department of Mechanical Engineering University of MichiganAnn ArborMI 48109USA department of Mechanical Engineering Texas A&M UniversityCollege StationTX 77843USA

In situ tensile testing in a scanning electron microscope(sEM)in conjunction with high-resolution electron backscatter diffraction(HR-EBsD)under load was used to characterize the evolution of geometrically necessary dislocation(GND)densities at individual grain boundaries as a function of applied strain in a polycrystalline Mg-4Al *** increase in GND density was investigated at plastic strains of 0%,0.6%,2.2%,3.3% from the area including 76 grains and correlated with(i)geometric compatibility between slip systems across grain boundaries,and(ii)plastic *** develop expressions for the grain boundary GND density evolution as a function of plastic strain and plastic incompatibility,from which uniaxial tensile stress-strain response of polycrystalline Mg-4Al are computed and compared with experimental *** findings in this study contribute to understanding the mechanisms governing the strain hardening response of single-phase polycrystalline alloys and more reliable prediction of mechanical behaviors in diverse microstructures.

关键词： Mg-Al alloys Grain boundaries Geometrically necessary dislocations strain gradient plasticity HR-EBsD

Transforming nanoscale VO_(2)(B) into a scalable sodium-ion electrode

在线全文

学校读者我要写书评

暂无评论

Nano Research 2024年第10期17卷 8809-8818页

作者： Yunkai Luo swetha Chandrasekaran Bintao Hu Randy Chen Marcus Worsley Bruce Dunn department of Materials science and Engineering University of CaliforniaLos AngelesCA 90095USA Lawrence Livermore National laboratory CA 94550USA

The intermittent nature of renewable energies requires highly reliable grid-level energy storage approaches.A critical consideration in developing this technology is the areal capacity which determines battery performance and influences the cost of battery *** related importance is finding new ways of developing scalable *** recent years,threedimensional(3D)printing of conductive scaffolds has emerged as an alternative to overcome the scalability limitations of commercial tape cast *** research carried out in the current study demonstrates a successful scalability pathway for nanoscale VO_(2)(B),a desirable cathode for sodium-ion batteries which has a nano-flower morphology with a crystallite sizesiting VO_(2)(B)onto a graphene aerogel scaffold,we were able to achieve mass loading of over 100 mg·cm^(-2) and still possess an areal capacity of 10 mAh·cm^(-2) at a current density of 5 mA·cm^(-2).Moreover,after 1000 cycles,these electrodes retained 75% to 80% of their initial *** at high loading levels,the electrodeposited VO_(2)(B)exhibits pseudocapacitive material signatures such as a box-like voltammetry response,linear galvanostatic response,and no phase change upon *** scalability of the VO_(2)(B)electrode is demonstrated in a series of experiments which show the areal capacity to scale upon increase in both mass loading and electrode thickness,with only small changes in specific *** study establishes that nanoscale materials can be scaled up to achieve thick electrodes without compromising their electrochemical properties.

关键词： nano VO_(2)(B) sodium-ion battery scalable electrodes three-dimensional(3D)printed scaffold additive manufacturing

Volumetric lattice Boltzmann method for pore-scale mass diffusionadvection process in geopolymer porous structures

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Journal of Rock Mechanics and Geotechnical Engineering 2024年第6期16卷 2126-2136页

作者： Xiaoyu Zhang Zirui Mao Floyd W.Hilty Yulan Li Agnes Grandjean Robert Montgomery Hans-Conrad zur Loye Huidan Yu shenyang Hu Purdue university IndianapolisIN46202USA Pacific Northwest National laboratory RichlandWA99352USA CEA DESISECDMRCUniv.MontpellierMarcouleFrance department of Chemistry and Biochemistry University of South CarolinaColumbiaSC29208USA

Porous materials present significant advantages for absorbing radioactive isotopes in nuclear waste *** improve absorption efficiency in nuclear waste treatment,a thorough understanding of the diffusion-advection process within porous structures is essential for material *** this study,we present advancements in the volumetric lattice Boltzmann method(VLBM)for modeling and simulating pore-scale diffusion-advection of radioactive isotopes within geopolymer porous *** structures are created using the phase field method(PFM)to precisely control pore *** our VLBM approach,we introduce a concentration field of an isotope seamlessly coupled with the velocity field and solve it by the time evolution of its particle population *** address the computational intensity inherent in the coupled lattice Boltzmann equations for velocity and concentration fields,we implement graphics processing unit(GPu)*** of the developed model involves examining the flow and diffusion fields in porous ***,good agreement is observed for both the velocity field from VLBM and multiphysics object-oriented simulation environment(MOOsE),and the concentration field from VLBM and the finite difference method(FDM).Furthermore,we investigate the effects of background flow,species diffusivity,and porosity on the diffusion-advection behavior by varying the background flow velocity,diffusion coefficient,and pore volume fraction,***,all three parameters exert an influence on the diffusion-advection *** background flow and diffusivity markedly accelerate the process due to increased advection intensity and enhanced diffusion capability,***,increasing the porosity has a less significant effect,causing a slight slowdown of the diffusion-advection process due to the expanded pore *** comprehensive parametric study provides valuable insights into the kinetics of isotope

关键词： Volumetric lattice Boltzmann method(VLBM) Phase field method(PFM) Pore-scale diffusion-advection Nuclear waste treatment Porous media flow Graphics processing unit(GPu) parallelization