检索结果-南通市图书馆

一种通用静电组装策略用于印刷无机纳米颗粒及其在大面积钙钛矿太阳电池中的应用

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

Science China Materials 2024年第5期67卷 1602-1611页

作者：李文杰褚昭阳李豪杰李丰邢直范宝锦孟祥川余德见梁超章少华胡笑添陈义旺 College of Chemistry and Chemical Engineering/Institute of Polymers and Energy Chemistry(IPEC)/Film Energy Chemistry for Jiangxi Provincial Key Laboratory(FEC) Nanchang University999 Xuefu AvenueNanchang330031China Key Lab of Fluorine and Silicon for Energy Materials and Chemistry of Ministry of Education Jiangxi Normal University99 Ziyang AvenueNanchang330022China Joint Key Laboratory of the Ministry of Education Institute of Applied Physics and Materials EngineeringUniversity of MacaoMacao999078China MOE Key Laboratory for Nonequilibrium Synthesis and Modulation of Condensed Matter School of PhysicsNational Innovation Platform(Center)for Industry-Education Integration of Energy Storage TechnologyXi’an Jiaotong UniversityXi’an710049China Peking University Yangtze Delta Institute of OptoelectronicsNantong226010China

无机纳米颗粒作为一种极具前景的材料,在钙钛矿太阳电池的传输层中得到了广泛应用.然而,无机纳米颗粒易于聚集的特性阻碍了其进一步的发展.在大面积制备过程中,无机纳米颗粒的聚集加剧了“咖啡环效应”,导致薄膜不均匀,使得底部界面性... 详细信息

无机纳米颗粒作为一种极具前景的材料,在钙钛矿太阳电池的传输层中得到了广泛应用.然而,无机纳米颗粒易于聚集的特性阻碍了其进一步的发展.在大面积制备过程中,无机纳米颗粒的聚集加剧了“咖啡环效应”,导致薄膜不均匀,使得底部界面性能较差,进而影响钙钛矿薄膜的结晶,最终导致整个器件性能下降.为解决这一问题,我们将一种带电聚合物一一聚乙烯亚胺引入至无机纳米颗粒溶液中.聚乙烯亚胺的带电性质对无机纳米颗粒的聚集起到了显著的抑制作用,此外,添加聚乙烯亚胺还增加了无机纳米颗粒溶液的粘度,有助于减少薄膜上的负面咖啡环效应.最终,我们在基于1-cm^(2)正式结构且使用SnO_(2)传输层的器件上实现了23.2%的光电转换效率.为进一步证明这一策略的普适性,我们还将此策略验证基于NiO_(x)传输层的1-cm^(2)反式器件,其转换效率超过20%.

关键词： perovskite solar cells inorganic nanoparticles large-area device electrostatic assembly technique

Highly elastic energy storage device based on intrinsically super-stretchable polymer lithium-ion conductor with high conductivity

在线全文

学校读者我要写书评

暂无评论

Fundamental Research 2024年第1期4卷 140-146页

作者： Shi Wang Jixin He Qiange Li Yu Wang Chongyang Liu Tao Cheng Wen-Yong Lai State Key Laboratory of Organic Electronics and Information Displays(SKLOEID) Institute of Advanced Materials(IAM)School of Chemistry and Life SciencesNanjing University of Posts&Telecommunications9 Wenyuan RoadNanjing 210023China Frontiers Science Center for Flexible Electronics(FSCFE) MIIT Key Laboratory of Flexible Electronics(KLoFE)Northwestern Polytechnical UniversityXi'an 710072China

Stretchable power sources,especially stretchable lithium-ion batteries(LIBs),have attracted increasing attention due to their enormous prospects for powering flexible/wearable *** recent advances,it is still challenging to develop ultra-stretchable LIBs that can withstand large *** particular,stretchable LIBs require an elastic electrolyte as a basic component,while the conductivity of most elastic electrolytes drops sharply during deformation,especially during large *** is why highly stretchable LIBs have not yet been realized until *** a proof of concept,a super-stretchable LIB with strain up to 1200%is created based on an intrinsically super-stretchable polymer electrolyte as the lithium-ion *** super-stretchable conductive system is constructed by an effective diblock copolymerization strategy via photocuring of vinyl functionalized 2-ureido-4-pyrimidone(VFUpy),an acrylic monomer containing succinonitrile and a lithium salt,achieving high ionic conductivity(3.5×10^(-4)mS cm^(-1)at room temperature(RT))and large deformation(the strain can reach 4560%).The acrylic elastomer containing Li-ion conductive domains can strongly increase the compatibility between the neighboring elastic networks,resulting in high ionic conductivity under ultra-large deformation,while VFUpy increases elasticity modulus(over three times)and electrochemical stability(voltage window reaches 5.3 V)of the prepared polymer *** a strain of up to 1200%,the resulting stretchable LIBs are still sufficient to power *** study sheds light on the design and development of high-performance intrinsically super-stretchable materials for the advancement of highly elastic energy storage devices for powering flexible/wearable electronics that can endure large deformation.

关键词： Stretchable electronics Flexible electronics Flexible energy storage devices Stretchable lithium-ion conductors Flexible lithium-ion batteries

Structure-regulated fluorine-containing additives to improve the performance of perovskite solar cells

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Nano Research 2024年第7期17卷 6080-6086页

作者： Peiya Chen Xiaoman Bi Hao Yan Yingjie Zhao Yihao Liu Zhuo Huang Qian Xiao Yongpeng Yang Shasha Zhang Yiqiang Zhang Yanlin Song Henan Institute of Advanced Technology College of ChemistrySchool of Materials Science and EngineeringZhengzhou UniversityZhengzhou 450001China Key Laboratory of Green Printing CAS Research/Education Center for Excellence in Molecular SciencesInstitute of ChemistryChinese Academy of Sciences(ICCAS)Beijing Engineering Research Center of Nanomaterials for Green Printing TechnologyNational Laboratory for Molecular Sciences(BNLMS)Beijing 100190China

Perovskite solar cells(PSCs)have seen remarkable progress in recent years,largely attributed to various additives that enhance both efficiency and *** these,fluorine-containing additives have garnered significant interest because of their unique hydrophobic properties,effective defect passivation,and regulation capability on the crystallization ***,a targeted structural approach to design such additives is necessary to further enhance the performance of ***,fluoroalkyl ethylene with different fluoroalkyl chain lengths(CH_(2)CH(CF_(2))nCF_(3),n=3,5,and 7)as liquid additives is used to investigate influences of fluoroalkyl chain lengths on crystallization regulation and defect *** findings indicate that optimizing the quantity of F groups plays a crucial role in regulating the electron cloud distribution within the additive *** optimization fosters strong hydrogen bonds and coordination effects with FA+and uncoordinated Pb^(2+),ultimately enhancing crystal quality and device ***,1H,1H,2H-perfluoro-1-hexene(PF_(3))with the optimal number of F presents the most effective modulation effect.A PSC utilizing PF_(3)achieves an efficiency of 24.05%,and exhibits exceptional stability against humidity and thermal *** work sheds light on the importance of tailored structure designs in additives for achieving high-performance PSCs.

关键词： perovskite solar cells fluorine number additive structure crystallization regulation defect passivation

The ALMaQUEST Survey ⅩⅤ:The dependence of the molecular-to-atomic gas ratios on resolved optical diagnostics

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Science China(Physics,Mechanics & Astronomy) 2024年第9期67卷 174-196页

作者： Niankun Yu Zheng Zheng Chao-Wei Tsai Pei Zuo Sara L.Ellison David V.Stark Di Li Jingwen Wu Karen L.Masters Ting Xiao Yinghui Zheng Zongnan Li Kai Zhang Hongying Chen Shu Liu Sihan Jiao Fanyi Meng National Astronomical Observatories Chinese Academy of SciencesBeijing 100101China Key Laboratory of Radio Astronomy and Technology Chinese Academy of SciencesBeijing 100101China Institute for Frontiers in Astronomy and Astrophysics Beijing Normal UniversityBeijing 102206China School of Astronomy and Space Science University of Chinese Academy of SciencesBeijing 100049China Department of Physics&Astronomy University of VictoriaVictoriaV8P 1A1Canada Departments of Physics and Astronomy Haverford CollegeHaverford19041USA Space Telescope Science Institute San Martin Dr.Baltimore 21218USA Zhejiang Laboratory Hangzhou 311121China New Cornerstone Science Laboratory Shenzhen 518054China School of Physics Zhejiang UniversityHangzhou 310058China

The atomic-to-molecular gas conversion is a critical step in the baryon cycle of galaxies,which sets the initial conditions for subsequent star formation and influences the multi-phase interstellar *** compiled a sample of 94 nearby galaxies with observations of multi-phase gas contents by utilizing public H_(Ⅰ),CO,and optical IFU data from the Ma NGA survey together with new FAST H_(Ⅰ)*** agreement with previous results,our sample shows that the global molecular-to-atomic gas ratio(R_(mol)≡log M_(H2)/M_(H_(Ⅰ)))is correlated with the global stellar mass surface densityμ_*with a Kendall'sτcoefficient of 0.25 and p<10^(-3),less tightly but still correlated with stellar mass and NUV-r color,and not related to the specific star formation rate(sSFR).The cold gas distribution and kinematics inferred from the H_(Ⅰ)and CO global profile asymmetry and shape do not significantly rely on R_(mol).Thanks to the availability of kpc-scale observations of MaNGA,we decompose galaxies into H_(Ⅱ),composite,and AGN-dominated regions by using the BPT *** increasing R_(mol),the fraction of H_(Ⅱ)regions within 1.5 effective radius decreases slightly;the density distribution in the spatially resolved BPT diagram also changes significantly,suggesting changes in metallicity and ionization *** with high R_(mol)tend to have high oxygen abundance,both at one effective radius with a Kendall'sτcoefficient of 0.37(p<10^(-3))and their central *** all parameters investigated here,the oxygen abundance at one effective radius has the strongest relation with global R_(mol).The dependence of gas conversion on gas distribution and galaxy ionization states is *** contrast,the observed positive relation between oxygen abundance(μ_(*))and R_(mol)indicates that the gas conversion is efficient in regions of high metallicity(density).

关键词： Galaxies baryon cycle radio lines H_(Ⅰ)21 cm atomic-to-molecular gas conversion

Toosendanin: upgrade of an old agent in cancer treatment

在线全文

学校读者我要写书评

暂无评论

Chinese Journal of Natural Medicines 2024年第10期22卷 887-899页

作者： LI Shuwei XIONG Qingyi SHEN Yiwen LIN Jiayi ZHANG Lijun WU Ye JIN Jinmei LUAN Xin Shanghai Frontiers Science Center for Chinese Medicine Chemical Biology Institute of Interdisciplinary Integrative Medicine Research and Shuguang Hospital Shanghai University of Traditional Chinese Medicine

Toosendanin(TSN), a tetracyclic triterpenoid derived from Melia toosendan and M. azedarach, demonstrates broad application prospects in cancer treatment. Although previously employed as a pesticide, recent studies have revealed its potential therapeutic value in treating various types of cancer. TSN exerts an anticancer effect via mechanisms including proliferation inhibition, apoptosis induction, migration suppression, and angiogenesis inhibition. However, TSN's toxicity, particularly its hepatotoxicity, significantly limits its therapeutic application. This review explored the dual nature of TSN, evaluating both its anticancer potential and toxicological risks, emphasizing the importance of balancing these aspects in therapeutic applications. Furthermore, we investigated the incorporation of TSN into novel therapeutic strategies, such as Proteolysis-targeting chimeras(PROTAC) technology and nanotechnology-based drug delivery systems(DDS), which enhance treatment efficacy while mitigating toxicity in normal tissues.

关键词： Cancer therapy Hepatotoxicity Nano-delivery systems PROTAC Toosendanin

Entanglement quantification via weak measurements assisted by deep learning

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

Photonics Research 2024年第4期12卷 712-719页

作者： MU YANG YA XIAO ZE-YAN HAO YU-WEI LIAO JIA-HE CAO KAI SUN EN-HUI WANG ZHENG-HAO LIU YUTAKA SHIKANO JIN-SHI XU CHUAN-FENG LI GUANG-CAN GUO CAS Key Laboratory of Quantum Information University of Science and Technology of ChinaHefei 230026China College of Physics and Optoelectronic Engineering Ocean University of ChinaQingdao 266100China CAS Center for Excellence in Quantum Information and Quantum Physics University of Science and Technology of ChinaHefei 230026China Hefei National Laboratory University of Science and Technology of ChinaHefei 230088China Electric Power Research Institute State Grid Anhui Electric Power Co.Ltd.Hefei 230601China Institute of Systems and Information Engineering University of TsukubaIbaraki 305-8573Japan Center for Artificial Intelligence Research University of TsukubaIbaraki 305-8577Japan Graduate School of Science and Technology Gunma UniversityGunma 371-8510Japan Institute for Quantum Studies Chapman UniversityOrangeCalifornia 92866USA JST PRESTO Saitama 332-0012Japan

Entanglement has been recognized as being crucial when implementing various quantum information ***, quantifying entanglement for an unknown quantum state requires nonphysical operations or post-processing measurement data. For example, evaluation methods via quantum state tomography require vast amounts of measurement data and likely estimation.

关键词： estimation quantum angle

Large-scale interplant exchange of macromolecules between soybean and dodder under nutrient stresses

在线全文

学校读者我要写书评

暂无评论

Plant Diversity 2024年第1期46卷 116-125页

作者： Jingxiong Zhang Shalan Li Wenxing Li Zerui Feng Shuhan Zhang Xijie Zheng Yuxing Xu Guojing Shen Man Zhao Guoyan Cao Xuna Wu Jianqiang Wu Department of Economic Plants and Biotechnology Yunnan Key Laboratory for Wild Plant ResourcesKunming Institute of BotanyChinese Academy of SciencesKunming 650201China CAS Center for Excellence in Biotic Interactions University of Chinese Academy of SciencesBeijing 100049China State Key Laboratory of Conservation and Utilization of Bio-Resources in Yunnan and Center for Life Science School of Life SciencesYunnan UniversityKunming 650500China

Parasitic plants and their hosts communicate through haustorial *** deficiency is a common stress for plants,yet little is known about whether and how host plants and parasites communicate during adaptation to such nutrient *** this study,we used transcriptomics and proteomics to analyze how soybean(Glycine max)and its parasitizing dodder(Cuscuta australis)respond to nitrate and phosphate deficiency(-N and-P).After-N and-P treatment,the soybean and dodder plants exhibited substantial changes of transcriptome and proteome,although soybean plants showed very few transcriptional responses to-P and dodder did not show any transcriptional changes to either-N ***,large-scale interplant transport of mRNAs and proteins was *** the mobile mRNAs only comprised at most 0.2%of the transcriptomes,the foreign mobile proteins could reach 6.8%of the total proteins,suggesting that proteins may be the major forms of interplant ***,the interplant mobility of macromolecules was specifically affected by the nutrient regimes and the transport of these macromolecules was very likely independently *** study provides new insight into the communication between host plants and parasites under stress conditions.

关键词： Cuscuta Mobile molecules Nutrient deficiency Host plant-parasitic plant interaction Interplant transport Systemic signaling

利用过渡金属氧化物调控金属铋纳米片的p轨道从而实现CO_(2)的高效电还原

在线全文

学校读者我要写书评

暂无评论

Science China Materials 2024年第6期67卷 1965-1974页

作者：尹伟勃刘博文王晓蕾王文倩宋子辰任志宇付宏刚 Key Laboratory of Functional Inorganic Material Chemistry Ministry of Education of ChinaSchool of Chemistry and Materials ScienceHeilongjiang UniversityHarbin 150080China Key Laboratory of Superlight Materials and Surface Technology of Ministry of Education College of Materials Science and Chemical EngineeringHarbin Engineering UniversityHarbin 150001China

p-d轨道之间的相互作用是一种提升电催化性能的有效方法.然而,其对主族金属的电催化CO_(2)还原(eCO_(2)RR)的增强机制尚不清晰.因此,我们向金属Bi纳米片中引入了一系列过渡金属氧化物(TMO:Fe_(2)O_(3)、Co_(3)O_(4)、NiO),并以此研究引... 详细信息

p-d轨道之间的相互作用是一种提升电催化性能的有效方法.然而,其对主族金属的电催化CO_(2)还原(eCO_(2)RR)的增强机制尚不清晰.因此,我们向金属Bi纳米片中引入了一系列过渡金属氧化物(TMO:Fe_(2)O_(3)、Co_(3)O_(4)、NiO),并以此研究引入TMO对Bi物种eCO_(2)RR性能的影响.根据原位傅里叶变换红外光谱(FTIR)和CO_(2)-程序升温脱附(TPD)的结果,Bi/TMO中的TMO可以增强CO_(2)的吸附和活化能力.密度泛函理论(DFT)计算结果表明,Bi活性位点^(*)OCHO吸附能及p轨道的优化可以降低CO_(2)到^(*)OCHO过程和^(*)OCHO到HCOOH过程的理论过电位.同时,由于Bi与TMO之间因复合而发生的电子重排也促进了催化剂与反应物之间的电子传输.因此,在热力学和动力学的双重作用下,Bi/TMO中的Bi活性位点表现出最佳的催化能力,在更宽的电位区间内实现了更高的催化活性和甲酸选择性.其中,Bi/Fe_(2)O_(3)的增强效果最为显著.在500 mV的宽电位区间内达到较高的甲酸的法拉第效率(>90%),在-0.8 VRHE时,甲酸的法拉第效率达到最大值99.7%(Bi的1.11倍),甲酸局部电流密度达到12.65 mA cm^(-2)(Bi的1.86倍).这一研究不仅建立了eCO_(2)RR性能增强与引入TMO之间的关系,也为理性设计高性能电催化剂提供了一条实用的、可扩展的途径.

关键词： transition metal oxides Bi/Fe_(2)O_(3)nanosheets elec-trocatalytic CO_(2)reduction HCOOH p-orbital regulation

2.4 V ultrahigh-voltage aqueous MXene-based asymmetric micro-supercapacitors with high volumetric energy density toward a self-sufficient integrated microsystem

在线全文

学校读者我要写书评

暂无评论

Fundamental Research 2024年第2期4卷 307-314页

作者： Yuanyuan Zhu Shuanghao Zheng Jieqiong Qin Jiaxin Ma Pratteek Das Feng Zhou Zhong-Shuai Wu State Key Laboratory of Catalysis Dalian Institute of Chemical PhysicsChinese Academy of SciencesDalian 116023China University of Chinese Academy of Sciences Shijingshan DistrictBeijing 100049China College of Science Henan Agricultural UniversityZhengzhou 450002China Dalian National Laboratory for Clean Energy Chinese Academy of SciencesDalian 116023China Key Laboratory of Spin Electron and Nanomaterials of Anhui Higher Education Institutes Suzhou UniversitySuzhou 234000China

Two-dimensional MXenes are key high-capacitance electrode materials for micro-supercapacitors(MSCs)catering to integrated ***,the narrow electrochemical voltage windows of conventional aqueous electrolytes(≤1.23 V)and symmetric MXene MSCs(typically≤0.6 V)substantially limit their output voltage and energy *** concentrated aqueous electrolytes exhibit lower water molecule activity,which inhibits water splitting and consequently widens the operating voltage ***,we report ultrahigh-voltage aqueous planar asymmetric MSCs(AMSCs)based on a highly concentrated LiCl-gel quasi-solid-state electrolyte with MXene(Ti3C2Tx)as the negative electrode and MnO_(2) nanosheets as the positive electrode(MXene//MnO_(2)-AMSCs).The MXene//MnO_(2)-AMSCs exhibit a high voltage of up to 2.4 V,attaining an ultrahigh volumetric energy density of 53 mWh cm−***,the in-plane geometry and the quasi-solid-state electrolyte enabled excellent mechanical flexibility and performance uniformity in the serially/parallel connected packs of our ***,the MXene//MnO_(2)-AMSC-based integrated microsystem,in conjunction with solar cells and consumer electronics,could efficiently realize simultaneous energy harvesting,storage,and *** findings of this study provide insights for constructing high-voltage aqueous MXene-based AMSCs as safe and self-sufficient micropower sources in smart integrated microsystems.

关键词： Asymmetric micro-supercapacitors MXene MnO_(2) Aqueous electrolyte High voltage Integrated microsystem