检索结果-南通市图书馆

Effects of water molecules on luminescence in europium and terbium coordination polymers with p-fluorobenzoic acid as ligand

引用

Journal of Rare Earths 2024年第7期42卷 1258-1264,I0003页

作者： Xiaoqi Zhao Puyan Hao Yami Ling Mengzhen Jia Rui Zhu Jiawen Liu Qiang Xu Jianhong Zhou Collaborative Innovation Center of Rare-Earth Optical Functional Materials and Devices Development Baoji Key Laboratory of Micro-Nano Optoelectronics and Terahertz TechnologySchool of Physics and Opto-Electronic TechnologyBaoji University of Arts and SciencesBaoji721016China

Our previous experimental observations show that the crystal structure of lanthanide luminescent complexes synthesized in aqueous solution usually contains a large number of coordination water molecules or free water *** order to probe the influence of water molecules on luminescent processes of lanthanide complexes,the photoluminescence properties of Ln-FBA(Ln=Eu and Tb,FBA=p-fluorobenzoic acid)coordination polymers at different ambient temperatures,in different solvents and aqueous DMSO solutions with different volume concentrations were systematically *** experiment results show that the presence of water molecules can promote the energy transfer from FBA ligand to Ln3+,at the same time,can cause luminescent non-radiation quenching of lanthanide *** addition,the variation of emission intensity ratio of 615 nm/591 nm peaks of Eu^(3+)with increasing the volume concentration of H_(2)O can be potentially used for the quantitatively detection of water traces in organic *** order to suppress the non-radiation quenching caused by the water molecules,Ln-FBA(Ln=Eu and Tb)coordination polymers were embedded into the PVP matrix to prepare Ln-FBA@PVP hybrid *** photoluminescence investigation indicates that PVP can not only block the quenching effect of water molecules on luminescence,but also effectively sensitize Eu^(3+)and Tb^(3+)*** experimental conclusions are useful for probing the influence of water molecules on luminescent processes of lanthanide complexes,quantitatively detecting water traces in organic solvents and enhancing the photoluminescence intensity in lanthanide complexes.

关键词： Lanthanide complexes Photoluminescence Luminescent quenching Rare earths

来源：

维普期刊数据库

同方期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Preparation and Swelling Kinetic Analysis of Poly (HPMC-co-AA-co-AM) Super Absorbent Resin

引用

Journal of Wuhan University of Technology(Materials science) 2024年第3期39卷 790-799页

作者：马砺 WANG Xin LIU Xixi WEI Gaoming GUO Ying School of Safety science and Engineering Xi’an University of Science and TechnologyXi'an 710054China Key Laboratory of Coal Fire Disaster Prevention Xi’an University of Science and TechnologyXi'an 710054China School of Energy Engineering Xi’an Uni-versity of Science and TechnologyXi'an 710054China Yanzhou Coal Mining Co. Ltd.Zoucheng 237500China

Super absorbent resin(SAR)is prepared by aqueous high temperature polymerization using hydroxypropyl methylcellulose(HPMC)as monomer backbone material,acrylic acid(AA)and acrylamide(AM)as the graft copolymer monomer,potassium persulfate(KPS)as the initiator to generate free radicals,and N,N`-methylenebisacrylamide(MBA)as cross-linking agent for cross-linking ***,the influence of individual factors on the water absorption is investigated,and these factors are mainly AA,AM,KPS,MBA,HPMC,and reaction *** optimized conditions are obtained by the experiment repeating for several *** water absorption multiplicity and salt absorption multiplicity under the conditions are 782.4 and 132.5 g/g,***,the effects of different temperatures and salt concentrations on its water absorption,as well as the swelling kinetics of SAR are *** is indicated the water-absorbing swelling process is mainly caused by the difference in water osmotic pressure and Na+concentration inside and outside the cross-linked molecular structure of the resin,which is not only consistent with the quasi-secondary kinetic model,but also with the Fick diffusion model.

关键词： super absorbent resin swelling kinetics water absorption graft copolymerization hydroxypropyl methyl cellulose

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

The response and anti-stress mechanisms of nitrifying sludge under long-term exposure to Cd Se quantum dots

引用

Journal of Environmental sciences 2024年第1期135卷 174-184页

作者： Linkai Guo Lei Yang Yongxiang Ren Shen Cui Xiaotong Li Jia Wang Jun Lan Haoqi Lu Yuchao Wang shaanxi Key Laboratory of Environmental Engineering Xi’an University of Architecture and TechnologyXi’an 710055China Key Lab of Northwest Water Resource Environment and EcologyMinistry of EducationXi’an University of Architecture and TechnologyXi’an 710055China

The wide application of CdSe quantum dots(QDs)increases its stress risk to sewage treatment *** study evaluated the response of nitrification performance,floc characteristics and microbial community of nitrifying sludge under long-term exposure to CdSe *** showed CdSe QDs(≥1 mg/L)would decrease the activity of ammonia monooxygenase(AMO).Under the stress of 30 mg/L CdSe QDs,the activity of AMO was reduced by 66%,while the activities of hydroxylamine oxidase and nitrite oxidoreductase were enhanced by 19.1%and 26%,***,the final nitrification effects were not adversely affected,and the production rates of NO_(2)^(-)-N and NO_(3)^(-)-N were ***,CdSe QDs improved biomass concentration in sludge and maintained the stability of sludge *** throughput sequencing analysis showed that CdSe QDs evidently reduced the abundance and diversity of microbial community in nitrifying *** abundances of amino acid metabolism and lipid metabolism were ***,CdSe QDs decreased the fluorescence intensity of tryptophan-like protein from 2,326 to 1,179 *** loosely bound extracellular polymeric substances(EPSs)and from 3,792 to 3,117 *** tightly bound *** relieve CdSe QD stress,the polysaccharide content increased from0.31 to 0.61 mg/g MLSS and intracellular antioxidant defense was *** CdSe QD level increasing to 30 mg/L,the total antioxygenic capacity and the activities of catalase were enhanced up to 411%and 143.2%,***,CdSe QDs had little adverse effects on cell membrane integrity,microbial metabolism and the abundance of Nitrospirae.

关键词： Quantum dots Activated sludge Extracellular polymeric substances Microbial community Antioxidant effect

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Recent progress in CdS-based S-scheme photocatalysts

引用

Journal of Materials science & Technology 2024年第4期171卷 162-184页

作者： Yajing Ren Yunfeng Li Guixu Pan Ning Wang Yan Xing Zhenyi Zhang College of Environmental and Chemical Engineering Xi’an Polytechnic UniversityXi’an 710048China Jilin provincial Key Laboratory of Advanced Energy Materials Department of ChemistryNortheast Normal UniversityChangchun 130024China Key Laboratory of New Energy and Rare Earth Resource Utilization of State Ethnic Affairs Commission Key Laboratory of Photosensitive Materials and Devices of Liaoning ProvinceSchool of Physics and Materials EngineeringDalian Minzu UniversityDalian 116600China

Photocatalytic technology with sunlight as driving force can convert solar energy into other energy sources for storage and further *** sulfide(CdS),as a typical reducing semiconductor of metal sulfides,represents an interesting research hotspot in photocatalysis due to its suitable bandgap(2.4 eV)for utilizing visible light and strong reducing ability for inducing surface catalytic ***,the photocatalytic performance of CdS is still limited by its fast carrier recombination and serious *** far,CdS semiconductor has been widely developed as a typical reducing photocatalyst in constructing novel S-scheme heterojunction to overcome the above *** this review,the de-sign concepts,basic principles,and charge transfer characteristics of CdS-based S-scheme heterojunction photocatalysts have been comprehensively *** advanced and effective characterization methods for studying the mechanism of CdS-based S-scheme heterojunction are analyzed in ***-thermore,we also summarize the typical applications of CdS-based S-scheme heterojunctions for water splitting,CO_(2) reduction,pollutant degradation,***,according to the current investigation sta-tus,some drawbacks in the current synthetic strategy,mechanism exploration,and application prospect of CdS-based S-scheme heterojunction are proposed,which need to be addressed by further expansion and innovative research.

关键词： Photocatalysis CdS semiconductor Heterojunction S-scheme Metal sulfide

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Preparation of a Novel Green Fluorescent Carbon Quantum Dots and Application in Fe^(3+)-Specific Detection in Biological System

引用

Journal of Analysis and Testing 2024年第1期8卷 40-51页

作者： Xianfen Zhang Wenxian Wang Lijiao Guan Huajie Chen Dai Li Lipeng Zhang Saipeng Huang School of Chemical Engineering Northwest UniversityXi'an 710069China Chemical Technology Academy of Shandong Province Qingdao University of Science and TechnologyJinan250014China

Trace ferric ion(Fe^(3+))detection has attracted increasing attention as an essential and indispensable role in many physiological and pathological *** green-emitting carbon quantum dots(Green-CQDs)were obtained through a green and facile one-step hydrothermal method for the specific recognition and trace detection of Fe^(3+)in this *** optimal excitation and emission wavelengths of the CQDs were 395 nm and 490 nm,*** stokes shift was up to 95 nm,which can effectively reduce the background fluorescence *** addition,it also exhibited good water solubility,stability,and high *** fluorescence intensity of Green-CQDs was linearly related to the concentration of Fe^(3+)(range of 0-80μmol/L),and the detection limit was as low as 59 nmol/*** good properties were favorable and successful for Fe^(3+)detection in tap water,human serum samples and living *** addition,a fluorescence visual test paper(FP@CQDs)was prepared utilizing filter paper as carrier,which can quickly identify Fe^(3+)in real time,and is suitable for the visualization analysis of Fe^(3+)in *** an efficient nanoprobe,the Green-CQDs held great promise and bright prospects in practical application in prevention and early clinical diagnosis of Fe^(3+)-associated diseases.

关键词： Carbon quantum dots Fluorescent Hydrothermal Fe^(3+)-specific detection Cell imaging

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Electrostatic Encapsulation of Cobalt Ions into Crystalline Framework Derived Polymer Aerogel:Ultra-light,Pressure Resistant,Hydrophobic,Photothermal Conversion,Heat Insulation and Infrared Stealth

引用

Chinese Journal of Polymer science 2024年第7期42卷 946-957,I0007页

作者： Yi-Fan Kang Jin-Lu Tang Ming Song Wei Wang Jia-Cheng Ma Zhan-You Ji Tong Liu Wen-Huan Huang China Key Laboratory of Chemical Additives for China National Light Industry College of Chemistry and Chemical EngineeringShaanxi University of Science and TechnologyXi’an710021China College of New Energy Xi’an Shiyou UniversityXi’an710065China Xi’an Key Laboratory of Functional Supramolecular Structure and Materials College of Chemistry and Materials ScienceNorthwest UniversityXi’an710127China

A variety of electromagnetic wave absorption materials(EMWAs)have been reported,but the integration of powder materials and multifunctional devices should be investigated in-depth to adapt to practical ***,carbon-coated cobalt composites were prepared by adsorbing magnetic metal cations into an anionic crystalline framework through an electrostatic encapsulate *** reflection loss(RL_(min))of-40.49 d B and effective absorption bandwidth(EAB)of 5.36 GHz(RL<-10 d B,10.4-15.76 GHz)was achieved with an optimal radar cross section(RCS)reduction of 34.9 dB·m^(2) for the sample *** commercial applications,Co@CN-4 was integrated into sodium carboxymethyl cellulose(CMC)aerogel to create an ultra-lightweight composite aerogel that is compressive resistant and heat-holding while also having photothermal conversion *** hydrophobic modification makes it more widely *** study provides a new strategy for EWAMs to integrate versatility and improve their application prospects.

关键词： Electrostatic incorporation Magnetic nanoparticle Co@CN composites Electromagnetic wave absorbing Metal-organic framework

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Numerical simulation of water-slag elbow erosion-inhibiting by regulating the slag injection position with a novel preceding rotating sheet structure

引用

Particuology 2024年第7期90卷 323-339页

作者： Fopeng Wen Liuyun Xu Yixiang Chen Zhaofu Deng Shen Zhang Wenming Song Yuge Li Liping Wei School of Chemical Engineering Northwest UniversityXi’an710069China School of Chemistry and Chemical Engineering Yan'an UniversityYan'an716000China Machinery Industry Shanghai Lanya Petrochemical Equipment Inspection Institute Co. Ltd.Shanghai201518China The Research Center of Chemical Engineering Applying Technology for Resource of shaanxi Xi’an710069China

The elbow erosion seriously jeopardizes the safe and stable operation of water–slag discharge pipeline of the coal gasification *** work simulated water–slag elbow characteristics with various slag injection positions by simulating five simplified and representative erosion categories,including A-type horizontal-vertical elbow with an upstream flow,B-type horizontal-vertical elbow with a downstream flow,C-type vertical-horizontal elbow with an upstream flow,D-type vertical-horizontal elbow with a downstream flow and E-type horizontal-horizontal *** with the C/D-type elbow,where particles were injected uniformly,the A-type elbow and E-type elbow were found to increase erosion rate,while the B-type elbow decreases erosion *** interesting discovery is that the elbow erosion rate is relatively low for small particles when particles are injected from the middle and bottom positions of the inlet section of the *** on the observation,a novel preceding rotating sheet structure was developed to regulate the particle injection *** shows an excellent anti-erosion performance by reducing the maximum erosion rate of particles with diameters of 50,100,and 200μm by 23%,35%,and 43%,respectively.

关键词： Erosion Slag-water Uneven particles Elbow pipe Erosion inhibition Preceding rotating sheet structure

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Reconstruction of aether scalar tensor theory for variouscosmological scenarios

引用

Chinese Physics C 2024年第4期48卷 202-208页

作者：付启铭何梦慈眭陶陶张鑫 Institute of Physics Shaanxi University of TechnologyHanzhong 723000China College of Physics Nanjing University of Aeronautics and AstronauticsNanjing 211106China Key Laboratory of Cosmology and Astrophysics(Liaoning)&College of sciences Northeastern UniversityShenyang 110819China Key Laboratory of Data Analytics and Optimization for Smart Industry(Ministry of education) Northeastern UniversityShenyang 110819China National Frontiers science Center for Industrial Intelligence and Systems Optimization Northeastern UniversityShenyang 110819China

In this paper,we present several explicit reconstructions for the aether scalar tensor(AeST)theory derived from the background of the Friedmann-Lemaître-Robertson-Walker cosmological *** is shown that the Einstein-Hilbert Lagrangian with a positive cosmological constant is the only Lagrangian capable of accurately replicating the exact expansion history of theΛcold dark matter(ΛCDM)universe filled solely with dust-like ***,theΛCDM-era can be produced within the framework of the AeST theory for some other fluids,including a perfect fluid with p=−(1/3)ρ,multifluids,and nonisentropic perfect ***,we demonstrate that theΛCDM-era can be replicated with no real matter field for the AeST *** cosmic evolution resulting from both the power-law and de-Sitter solutions can also be obtained.

关键词： reconstruction modified gravity cosmology

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Difference in microstructural characteristics of stamp-charged coke and gravity-charged coke with approximate macroscopic performance

引用

Journal of Iron and Steel Research International 2024年第5期31卷 1050-1062页

作者： Chong Zou Zheng-yan Huang Jian-yun Li Bin Li Shi-wei Liu Yuan She School of Metallurgical Engineering Xi’an University of Architecture and TechnologyXi’an710311ShaanxiChina Technical Center of Shandong Iron and Steel Co. Ltd.(Laiwu Branch)Jinan271104ShandongChina

The microstructural characteristics including optical texture,porosity and pore structure and chemical structure of stamp-charged coke(SCC)and gravity-charged coke(GCC)with similar conventional macro-indicators were investigated,and the properties including micro-strength,reactivity of coke matrix and that after alkali enrichment were comparatively studied by various characterization *** anisotropic structure of SCC is composed of high content of fine mosaic texture,while the content of medium mosaic texture,coarse texture and fibrous texture is *** statistical average shows that the fine mosaic average of SCC(24.89%)is 3.78 times the GCC average(6.58%),and the coarse mosaic average(1.24%)is only about 1/3 of the GCC average(3.43%).The porosity of SCC is lower than that of GCC,but tamping process does not lead to the fact that the number of closed pores of SCC is significantly lower than that of *** the structure of SCC is compact,its pore number is large and the pore wall is *** of coke with diameter less than 150 nm seem unaffected by tamping *** aromatic structure of SCC was less ordered than that of GCC,which was speculated to be related to the addition of more low metamorphic coal in *** microscopic strength and structural strength of SCC are lower than those of *** reactivity of coke matrix is affected by the specific surface area,but it is not the determining factor of its *** improvement in dissolution reactivity of coke after potassium enrichment is independent of coke type.

关键词： Stamp-charged coke Optical texture Porosity Microstructure Reactivity

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Simultaneous measurement of temperature and liquid refractive index based on fiber open Fabry-Pérot cavity and Bragg grating

引用

Optoelectronics Letters 2024年第8期20卷 477-482页

作者： LIU Qinpeng WANG Danyang LI Xingrui GAO Hong YU Dakuang College of science Xi'an Shiyou UniversityXi'an 710065China

A temperature and refractive index sensor based on fiber Bragg grating(FBG)end surface cascade open Fabry-Pérot(FP)cavity has been designed and demonstrated *** open FP cavity has been fabricated on the end face of an FBG by dislocation fusion in this work,the open FP cavity could be used for refractive index sensing,and the temperature is measured by the *** working principle of the sensor and the method of improving the sensitivity are analyzed by theoretical *** refractive index sensitivity of the sensor is 1108.4 nm/RIU,while the maximum fluctuation of the sensor stability experiment detection is 0.005 *** results show that it has satisfactory *** sensor is a compact all-fiber structure,so it has potential applications in the field of temperature refractive index sensing,such as biomedical and capacitor electrolyte detection.

关键词： fiber refractive cavity

来源：

维普期刊数据库

同方期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

欢迎您,

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案：

请选择收藏分类：

通借通还

欢迎您,

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：