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International Journal of Minerals,Metallurgy and Materials 2025年第3期32卷 657-667页

作者： Changtian Zhu Pei Liu Jin Chen Zixuan Ding Guohui Tang Qingqing Gao Yinxu Ni Kai Xu Zhilei Hao Gaojie Xu Fenghua Liu School of Materials Science and Chemical Engineering Ningbo UniversityNingbo 315211China Ningbo Institute of Materials Technology&Engineering Chinese Academy of SciencesNingbo 315201China

As a novel 2D material,Ti_(3)C_(2)T_(x)-MXene has become a major area of interest in the field of microwave absorption(MA).However,the MA effect of common Ti_(3)C_(2)T_(x)-MXene is not prominent and often requires complex processes or combinations of other ma-terials to achieve enhanced *** this context,a kind of gradient woodpile structure using common Ti_(3)C_(2)T_(x)-MXene as MA ma-terial was designed and manufactured through direct ink writing(DIW)3D *** minimum reflection loss(RL_(min))of the Ti_(3)C_(2)T_(x)-MXene-based gradient woodpile structures with a thickness of less than 3 mm can reach-70 dB,showing considerable improve-ment compared with that of a completely filled *** addition,the effective absorption bandwidth(EAB)reaches 7.73 *** study demonstrates that a Ti_(3)C_(2)T_(x)-MXene material with excellent MA performance and tunable frequency band can be successfully fab-ricated with a macroscopic structural design and through DIW 3D printing without complex material hybridization and modification,of-fering broad application prospects by reducing electromagnetic wave radiation and interference.

关键词： Ti_(3)C_(2)T_(x)-MXene electromagnetic wave absorption macro-design impedance matching 3D printing ink

Predicting the efficiency of arsenic immobilization in soils by biochar using machine learning

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Journal of Environmental Sciences 2025年第1期147卷 259-267页

作者： Jin-Man Cao Yu-Qian Liu Yan-Qing Liu Shu-Dan Xue Hai-Hong Xiong Chong-Lin Xu Qi Xu Gui-Lan Duan State key Lab of Urban and Regional Ecology Research Center for Eco-Environmental SciencesChinese Academy of SciencesBeijing 100085China Henan Institute of Advanced Technology Zhengzhou UniversityZhengzhou 450052China University of Chinese Academy of Sciences Beijing 100049China

Arsenic(As)pollution in soils is a pervasive environmental *** immobilization offers a promising solution for addressing soil As *** efficiency of biochar in immobilizing As in soils primarily hinges on the characteristics of both the soil and the ***,the influence of a specific property on As immobilization varies among different studies,and the development and application of arsenic passivation materials based on biochar often rely on empirical *** enhance immobilization efficiency and reduce labor and time costs,a machine learning(ML)model was employed to predict As immobilization efficiency before biochar *** this study,we collected a dataset comprising 182 data points on As immobilization efficiency from 17 publications to construct three ML *** results demonstrated that the random forest(RF)model outperformed gradient boost regression tree and support vector regression models in predictive *** importance analysis and partial dependence plots based on the RF model were conducted to identify the most crucial factors influencing As *** findings highlighted the significant roles of biochar application time and biochar pH in As immobilization efficiency in ***,the study revealed that Fe-modified biochar exhibited a substantial improvement in As *** insights can facilitate targeted biochar property design and optimization of biochar application conditions to enhance As immobilization efficiency.

关键词： Biochar Arsenic immobilization Soil Machine learning

Synthesis ofδ-MnO_(2)via ozonation routine for low temperature formaldehyde removal

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Journal of Environmental Sciences 2025年第1期147卷 642-651页

作者： Guijun Fan Yacong Guo Shaohua Chai Le Zhang Jian Guan Guojun Ma Ning Han Yunfa Chen State key Laboratory of Multiphase Complex Systems Institute of Process EngineeringChinese Academy of SciencesBeijing 100190China College of Chemical Engineering University of Chinese Academy of SciencesBeijing 100049China key Laboratory of Science and Technology on Particle Materials Institute of Process EngineeringChinese Academy of SciencesBeijing 361021China key Laboratory for Mechanics in Fluid Solid Coupling Systems Institute of MechanicsChinese Academy of SciencesBeijing 100190China School of Petrochemical Engineering&Environment Zhejiang Ocean UniversityZhoushan 316022China

Nowadays,it is still a challenge to prepared high efficiency and low cost formaldehyde(HCHO)removal catalysts in order to tackle the long-living indoor air ***,δ-MnO_(2)is successfully synthesized by a facile ozonation strategy,where Mn^(2+)is oxidized by ozone(O_(3))bubble in an alkaline *** presents one of the best catalytic properties with a low 100%conversion temperature of 85℃for 50 ppm of HCHO under a GHSV of 48,000 mL/(g·hr).As a comparison,more than 6 times far longer oxidation time is needed if O3 is replaced by O_(2).Characterizations show that ozonation process generates a different intermediate of tetragonalβ-HMnO_(2),which would favor the quick transformation into the final productδ-MnO_(2),as compared with the relatively more thermodynamically stable monoclinicγ-HMnO_(2)in the O_(2)***,HCHO is found to be decomposed into CO_(2)via formate,dioxymethylene and carbonate species as identified by room temperature insitu diffuse reflectance infrared fourier transform *** these results show great potency of this facile ozonation routine for the highly activeδ-MnO_(2)synthesis in order to remove the HCHO contamination.

关键词： δ-MnO_(2) Ozone oxidation HCHO oxidation In-situ DRIFTS

Si-C Foam Porous-Medium Combustion Power-Generation System for Low-Calorific-Value Biomass Syngas

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Journal of Thermal Science 2025年第1期34卷 206-222页

作者： YANG Jianwen CHEN Wei CAO Bingwei LIU Xinhui LI Hang College of Mechanical and Aerospace Engineering Jilin UniversityChangchun 130025China School of Mechanical and Vehicle Engineering Changchun UniversityChangchun 130022China

Syngas produced from the gasification of organic feedstocks from biomass is one of the clean and sustainable sources of *** advantages of simple access and renewability of biomass energy can meet the energy needs of temporary power *** study presents a biomass power-generation system for vehicular *** biomass and a free-piston Stirling engine generator(FPSEG)as the primary material and prime mover,respectively,biomass energy is converted into electricity by combusting the syngas to heat the *** and key parameter design for biomass gasification and thermoelectric conversion systems within a power generation system were performed.A porous medium area was constructed using Si-C foam ceramics to obtain an energy-conversion experimental *** effects of bed height,porosity,porous-region diameter,and air-intake conditions on the power-generation performance were investigated,and optimisations were performed for the thermoelectric conversion *** rate of increase during FPSEG power generation first increased and then decreased with increasing bed height,peaking at a bed height of 40 *** increasing porous-region diameter accelerated FPSEG power generation,whereas porosity changes in the porous media did not significantly affect the rate of change during FPSEG power *** increasing air intake,the rate of increase during power generation first increased and then *** maximum change rate and the highest thermoelectric conversion efficiency of the power-generation system occurred at 9.5 m^(3)/h and 6.5 m^(3)/h(~45.1%)air intakes,*** the thermal inertia and combustion structure of the thermoelectric conversion system significantly increased the power-generation rate of the system,with 1.8 W/s being observed at a 9.7 m^(3)/h air intake.

关键词： biomass gasification combined heat and power(CHP) porous media combustion power generation

The mechanisms of pH regulation on promoting volatile fatty acids production from kitchen waste

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Journal of Environmental Sciences 2025年第1期147卷 414-423页

作者： Feng Liu Tingting Wang Leiyu Feng Yinguang Chen College of Environmental Science and Engineering Tongji UniversityShanghai 200092China TUS-Environmental Science and Technology development Co. Ltd.Beijing 100084China

The anaerobic acid production experiments were conducted with the pretreated kitchen waste under pH *** results showed that pH 8 was considered to be the most suitable condition for acid production,especially for the formation of acetic acid and propionic *** average value of total volatile fatty acid at pH 8 was 8814 mg COD/L,1.5 times of that under blank *** average yield of acetic acid and propionic acid was 3302 mg COD/L and 2891 mg COD/L,*** activities of key functional enzymes such as phosphotransacetylase,acetokinase,oxaloacetate transcarboxylase and succinylcoA transferase were all *** further explore the regulatory mechanisms within the system,the distribution of microorganisms at different levels in the fermentation system was obtained by microbial sequencing,results indicating that the relative abundances of Clostridiales,Bacteroidales,Chloroflexi,Clostridium,Bacteroidetes and Propionibacteriales,which were great contributors for the hydrolysis and acidification,increased rapidly at pH 8 compared with the blank ***,the proportion of genes encoding key enzymes was generally increased,which further verified the mechanism of hydrolytic acidification and acetic acid production of organic matter under pH regulation.

关键词： Kitchen waste Acid fermentation Volatile fatty acids pH regulation Functional genes

Removal of arsenic from water by silver nanoparticles and Fe-Ce mixed oxide supported on polymeric anion exchanger

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Journal of Environmental Sciences 2025年第5期151卷 540-549页

作者： Li Li Su-juan Yu Rong-gang Zheng Qing-cun Li Rui Liu Jing-fu Liu State key Laboratory of Environmental Chemistry and Ecotoxicology Research Center for Eco-Environmental SciencesChinese Academy of SciencesBeijing 100085China Hubei key Laboratory of Environmental and Health Effects of Persistent Toxic Substances Institute of Environment and HealthJianghan UniversityWuhan 430056China University of Chinese Academy of Sciences Beijing 100049China Department of Ecology and Resources Engineering He Tao CollegeInner Mongolia 015000China

By encapsulating nanoscale particles of goethite(α-FeO(OH)),hydrous ceric oxide(CeO_(2)·H_(2)O,HCO)and silver nanoparticles(AgNPs)in the pores of polystyrene anion exchanger D201,a novel nanocomposite FeO(OH)-HCO-Ag-D201 was prepared for the effective removal of arsenic from *** isotherm study shows that FeO(OH)-HCO-Ag-D201 has excellent adsorption performance for As(III)and As(V),with an increased adsorption capacity of As(III)to 40.12 mg/g compared to that of 22.03 mg/g by the composite adsorbent without AgNPs(FeO(OH)-HCO-D201).The adsorption kinetics data showed that the sorption rate of FeO(OH)-HCO-Ag-D201 for As(III)is less than that for As(V),and the adsorption of As(III)and As(V)were consistent with the pseudo-second-order model and the pseudofirst-order model,*** or basic conditions are favored for the adsorption of As(III/V)by FeO(OH)-*** with nitrate/chloride/bicarbonate,sulfate/silicate/phosphate showed more remarkable inhibition of arsenic removal by FeO(OH)-HCO-Ag-D201,whereas natural organic matter showed no interference to the arsenic *** As(V)adsorption involved different interactions such as electrostatic attraction and surface complexation,while the adsorption of As(III)involved the part oxidization of As(III)to As(V)and the simultaneous adsorption of As(III)and As(V).In addition to the Ce(IV)in CeO_(2)·H_(2)O acted as an oxidant,the synergistic effect ofα-FeO(OH)and AgNPs also contributed to the oxidization of As(III)to As(V).Moreover,the reusable property suggested that this FeO(OH)-HCO-Ag-D201 nanocomposite has great potential for arsenic-contaminated water purification.

关键词： FeO(OH)-HCO-Ag-D201 Arsenic removal Synergistic effect Oxidation Electrostatic attraction Surface complexation

Emission characteristics and probabilistic health risk of volatile organic compounds from leather sofa

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Journal of Environmental Sciences 2025年第2期148卷 79-87页

作者： Chuanhui Mu Yuling Tang Zhaohui Yang Jianfei Zhou Bi Shi national Engineering Laboratory for Clean Technology of Leather Manufacture Sichuan UniversityChengdu 610065China research Institute of Leather and Footwear Industry of Wenzhou Wenzhou 325088China key Laboratory of Leather Chemistry and Engineering of Ministry of Education Sichuan UniversityChengdu 610065China

Furniture is identified as a vital volatile organic compound(VOC)emission source in the indoor *** has become the most common raw and auxiliary fabric material for upholstered furniture,particularly with extensive consumption in sofas,due to its abundant resources and efficient *** being widely traded across the world,little research has been conducted on the VOCs released by leathermaterials and their health risk assessment in the indoor ***,this study investigated the VOC emissions of leather with different grades and the health risk of the inhalation *** on the ultra-fast gas phase electronic nose(EN)and GC-FID/Qtof,the substantial emissions of aliphatic aldehyde ketones(Aks),particularly hexanal,appear to be the cause of off-flavor in medium and low grade(MG and LG)sofa *** health risk assessment indicated that leather materials barely pose non-carcinogenic and carcinogenic effects to *** the abundance of VOC sources and the accumulation of health risks in the indoor environment,more stringent specifications concerning qualitative and quantitative content should be extended to provide VOC treatment basic for the manufacturing industry and obtain better indoor air quality.

关键词： Indoor environment Leather Volatile organic compounds(VOCs) Health risk assessment

Efficient magnetic capture of PE microplastic from water by PEG modified Fe_(3)O_(4)nanoparticles:Performance,kinetics,isotherms and influence factors

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Journal of Environmental Sciences 2025年第1期147卷 677-687页

作者： Yifan Zhang Jingjing Duan Ruiqian Liu Evangelos Petropoulos Yanfang Feng Lihong Xue Linzhang Yang Shiying He College of Resources and Environmental Sciences Nanjing Agricultural UniversityNanjing 210095China key Laboratory of Agro-Environment in Downstream of Yangze Plain Ministry of Agriculture and Rural AffairsInstitute of Agricultural Resources and EnvironmentJiangsu Academy of Agricultural SciencesNanjing 210014China School of Engineering Newcastle UniversityNewcastle upon Tyne NE17RUUK Stantec UK Newcastle upon Tyne NE13DYUK

Due to their resistance to degradation,wide distribution,easy diffusion and potential uptake by organisms,microplastics(MPs)pollution has become a major environmental *** this study,PEG-modified Fe_(3)O_(4)magnetic nanoparticles demonstrated superior adsorption efficiency against polyethylene(PE)microspheres compared to other adsorbents(bare Fe_(3)O_(4),PEI/Fe_(3)O_(4)and CA/Fe_(3)O_(4)).Themaximumadsorption capacity of PEwas found to be 2203 mg/g by adsorption isotherm ***/Fe_(3)O_(4)maintained a high adsorption capacity even at low temperature(5℃,2163 mg/g),while neutral pH was favorable for MP *** presence of anions(Cl^(-),SO_(4)^(2-),HCO_(3)^(-),NO_(3)^(-))and of humic acids inhibited the adsorption of *** is proposed that the adsorption process was mainly driven by intermolecular hydrogen ***,the study demonstrated that PEG/Fe_(3)O_(4)can potentially be used as an efficient control against MPs,thus improving the quality of the aquatic environment and of our water resources.

关键词： Microplastic removal Adsorption Magnetic nanoparticles Wastewater Surface modification

Exploring the diversity of dissolved organic matter(DOM)properties and sources in different functional areas of a typical macrophyte-derived lake combined with optical spectroscopy and FT-ICR MS analysis

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Journal of Environmental Sciences 2025年第1期147卷 462-473页

作者： Kun Wang Haoyu Ren Shengwu Yuan Xia Jiang Pengfei Wang College of Water Sciences Beijing Normal UniversityBeijing 100875China national Engineering Laboratory of Lake Pollution Control and Ecological Restoration Chinese Research Academy of Environmental SciencesBeijing 100012China

Lake Baiyangdian is one of China’s largest macrophyte-derived lakes,facing severe challenges related to water quality maintenance and eutrophication *** organic matter(DOM)was a huge carbon pool and its abundance,property,and transformation played important roles in the biogeochemical cycle and energy flow in lake *** this study,Lake Baiyangdian was divided into four distinct areas:Unartificial Area(UA),Village Area(VA),Tourism Area(TA),and Breeding Area(BA).We examined the diversity of DOM properties and sources across these functional *** findings reveal that DOM in this lake is predominantly composed of protein-like substances,as determined by excitation-emission matrix and parallel factor analysis(EEM-PARAFAC).Notably,the exogenous tyrosine-like component C1 showed a stronger presence in VA and BA compared to UA and ***-resolution mass spectrometry(FT-ICR MS)unveiled a similar DOM molecular composition pattern across different functional areas due to the high relative abundances of lignan compounds,suggesting that macrophytes significantly influence the material structure of *** properties exhibited specific associations with water quality indicators in various functional areas,as indicated by the Mantel *** connections between DOM properties and NO_(3)-N andNH3-Nwere more pronounced in VA and BA than in UA and *** results underscore the viability of using DOM as an indicator for more precise and scientific water quality management.

关键词： Dissolved organic matter Fluorescence property Molecular composition Source

Observation of acoustic hybrid topological phases induced by the p-d orbital interactions

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Science China(Physics,Mechanics & Astronomy) 2025年第1期68卷 128-135页

作者： Xiao Xiang Feng Gao Yu-Gui Peng Peng Wu Zong-Lin Li Xue-Feng Zhu School of Physics and Innovation Institute Huazhong University of Science and TechnologyWuhan 430074China

In spinless systems,growing attention has recently been attracted to synthetic gauge fields,which redefine the fundamental crystal symmetries by utilizing the projective algebraic ***,synthetic gauge fields have been commonly investigated in single orbital systems,and explorations on hybrid orbitals remain elusive in ***,we report the experimental observation of hybrid topological phases induced by hybrid synthetic gauge flux,which is formed by the interaction between p and d orbitals embedded in acoustic *** breaking the translation symmetries of L_(x) and/or L_(y),we unambiguously demonstrate the first-order Möbius edge states and higher-order corner *** work establishes a platform for seeking exotic topological phases induced by hybrid-orbitals interactions and initializing the framework of hybrid-orbitalsrelated topological *** applications can be anticipated in scenarios such as high-quality sensing and robust wave trapping due to the stepwise energy distribution of the hybrid topological phase.

关键词： topological insulator synthetic gauge field projective symmetry corner states