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Deep decalcification of factory-provided freezing acidolysis solution to achieveα-high-strength gypsum

Chinese Journal of Chemical Engineering 2024年第5期69卷 143-151页

作者： Wencai Ye Yulu Li Yonggang Dong Lin Yang Yun Yi Jianxin Cao School of Chemistry and Chemical Engineering Guizhou UniversityGuiyang 550025China Engineering Research Center of Efficient Utilization for Industrial Waste Guizhou UniversityGuiyang 550025China Key Laboratory of Guizhou Province for Green Chemical Industry and Clean Energy technology Guizhou UniversityGuiyang 550025China

The freezing acidolysis solution of the nitric acid-phosphate fertilizer process has a high calcium content,which makes it difficult to produce fine phosphate and high water-soluble phosphate fertilizer ***,based on the potential crystallization principle of calcium sulfate in NH_(4)NO_(3)-H_(3)PO_(4)-H_(2)O,the deep decalcification(*** removal)technology to achieveα-high-strength gypsum originated from freezing acidolysis-solutions has been firstly proposed and ***,calcium can be removed from the factory-provided freezing acidolysis-solution by neutralizing it with ammonia,followed by the addition of ammonium sulfate *** a result,the formation of calcium sulfate in the reaction system undergoes the nucleation and growth of CaSO_(4)·2H_(2)O(DH),as well as its dissolution and crystallization into short columnarα-CaSO_(4)·0.5H_(2)O(α-HH).Remarkably,with the molar ratio of SO_(4)^(2-)/Ca^(2+)at 1.8,the degree of neutralization(NH_(3)/HNO_(3) molar ratio)at 1.7,the reaction temperature of 94℃,and the reaction time of 300 min,the decalcification rate can reach 86.89%,of which the high-strengthα-CaSO_(4)·0.5H_(2)O(α-HH)will be ***,the deep decalcification product meets the standards for the production of fine phosphates and highly water-soluble phosphate ***,the 2 h flexural strength ofα-HH is 5.3 MPa and the dry compressive strength is 36.8 MPa,which is up to the standard of commercialα-HH.

关键词： Nitrophosphate Ammonia neutralization Deep decalcification High-strengthα-hemihydrate gypsum Controlled crystallization at atmospheric pressure

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Exploring a new path of green and efficient utilization of sinter return fine to produce composite pellets

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Journal of Iron and Steel Research International 2024年第7期31卷 1610-1622页

作者： Yan-biao Chen Wen-guo Liu Hao Guo Jing-song Wang Qing-guo Xue Hai-bin Zuo State Key Laboratory of Advanced Metallurgy University of Science and Technology BeijingBeijing 100083China MCC Capital Engineering and Research Incorporation Limited Beijing 100176China

Efficient utilization of sinter return fine is an important measure to reduce cost,increase efficiency,save energy and reduce emission.A new path of green and efficient utilization of return fine was proposed to produce composite *** metallurgical properties of composite pellets under the condition of hydrogen-rich blast furnace were *** experimental results indicate that the coated concentrate was consolidated for the composite pellets through normal Fe_(2)O_(3) *** the surface of core return fine,the liquid phase formed due to its low-melting point,assimilated the adjacent concentrate,and then consolidated with the temperature *** with regular pellets,the com-pressive strength and reduction swelling index of composite pellets were decreased,but the reducibility index and softening-melting properties were *** addition,the reduction degradation index of composite pellets was sig-nificantly higher than that of ***,adding composite pellets was conducive to indirect reduction in blast furnace,reducing fuel ratio and improving production *** to the effect of the roasting system on the metallurgical properties,the roasting temperature and time were determined as 1250℃and 30 min,*** composite pellets can be produced under the traditional pelletizing process.

关键词： Sinter Return fine Composite pellet Roasting system Metallurgical property Hydrogen-rich blast furnace

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Improving mathematical model of burden distribution and correcting chute angle to cope with fluctuation of stock line

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Journal of Iron and Steel Research International 2024年第2期31卷 342-356页

作者： Jian-sheng Chen Wen-guo Liu Hao Guo Wang Ding Qing-guo Xue Jing-song Wang Hai-bin Zuo State Key Laboratory of Advanced Metallurgy University of Science and Technology BeijingBeijing100083China MCC Capital Engineering&Research Incorporation Limited Beijing100176China Hunan Valin Xiangtan Iron and Steel Co. Ltd.Xiangtan411101HunanChina

Accurate evaluations of the burden distribution are of critical importance to stabilize the operation of blast *** mathematical model and discrete element method(DEM)are two attractive methods for predicting burden *** on DEM,the initial velocities of the pellet,sinter,and coke were calculated,and the velocity attenuations of the above three particles between the burden and the chute were *** initial velocity and velocity attenuation were applied to a mathematical model for improving the ***,based on the improved model,a scheme for rectifying the chute angles was proposed to address the fluctuation of the stock line and maintain a stable burden *** validity of the scheme was confirmed via a stable burden distribution under different stock *** mathematical model has been successfully applied to evaluate the online burden distribution and cope with the fluctuation of the stock line.

关键词： Burden distribution Mathematical model Discrete element method Velocity attenuation Stock line fluctuation

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Numerical Study of Water Transport and Operating Strategy for Fuel Cells with Segmented Water Management Flow Fields

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Journal of Thermal science 2024年第4期33卷 1577-1589页

作者： CHEN Chengdai WANG Changhong ZHENG Zijun School of Materials and Energy Guangdong University of TechnologyGuangzhou510006China

The effective cathode flow field design can realize the internal water balance and higher current density output of proton exchange membrane fuel cells(PEMFC).Therefore,a segmented water management flow field is proposed in this study,i.e.a half separated-half coupled cathode(HSHC)flow field which has two inlets but just one outlet.A 3D numerical PEMFC model is applied to study the effect of the HSHC flow field on PEMFC performance and its operating strategy in terms of operating *** study results are shown as follows:Compared with the two conventional cathode flow fields,the HSHC flow field improves the water balance along the channel and increases the current density by 17.1%at a cathode stoichiometry of *** is because the HSHC flow field can overcome the water loss at channels upstream and the water accumulation at channels *** draw water phenomenon(DWP)in the HSHC flow field is observed,which is mainly affected by the water vapor pressure of *** on the DWP,cooling channel inlet flow rates can be used to adjust water balance,but severe water loss should be *** addition,the inlet temperature control in HSHC flow field should be that cell temperature>cathode channel inlet temperature>cooling channel inlet temperature>ambient temperatures for better water balance.

关键词： proton exchange membrane fuel cells channel design segmented water management water balance operating strategy

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Difluoromethyl phenoxathiinium salt: A new general and versatile difluoromethylating reagent with divergent ·CF_(2)H, CF_(2)H^(+), and :CF_(2) reactivities

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science China Chemistry 2024年第3期67卷 953-962页

作者： Yuan-Qing Gu Hong-Xin Long Dan-Dan Zhang Mei-Feng Ruan Guo-Kai Liu School of Pharmacy Shenzhen University Medical SchoolShenzhen UniversityShenzhen 518055China

Development of practical and versatile electrophilic difluoromethylating reagent is still a grand challenge so far due to its inherent instability or low ***,we report the design and synthesis of difluoromethyl phenoxathiinium tetrafluoroborate(PT-CF_(2)H^(+)BF_(4)^(-)) as a novel difluoromethylating reagent,which proves to be a bench-stable,general,powerful and versatile reagent with divergent·CF_(2)H,CF_(2)H^(+),and:CF_(2) *** use of this reagent,we demonstrated a vast array of difluoromethyl radical transfer reactions via diverse pathways involving photocatalyst-free visible-light induction,visible-light photoredox catalysis and visible-light mediation single electron transfer of EDA ***,the green and highly effective CF_(2)H^(+) and:CF_(2) transfer reactions were also readily accomplished.

关键词： difluoromethyl phenoxathiinium salt versatile difluoromethylating reagent difluoromethyl radical difluoromthyl cation difluorocarbene

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Integrated multi-omics reveals the relationship between growth performance, rumen microbes and metabolic status of Hu sheep with different residual feed intakes

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ANIMAL NUTRITION 2024年第3期18卷 284-295页

作者： Zhang, Yanzhen Zhang, Xiaowei Cao, Dingren Yang, Jinyong Mao, Huiling Sun, Lingling Wang, Chong Zhejiang A&F Univ Coll Anim Sci & Technol Coll Vet Med Hangzhou 311300 Peoples R China Key Lab Appl Technol Green Ecohlth Anim Husb Zheji Hangzhou 311300 Peoples R China Shandong Vocat Anim Sci & Vet Coll Dept Anim Sci Weifang 261061 Peoples R China Zhejiang Prov Anim Husb Technol Promot & Monitorin Hangzhou 310021 Peoples R China

Residual feed intake (RFI) is a metric that provides a more accurate measure of feed efficiency. The lower the RFI, the higher the feed efficiency. The changes in the host microbiome and metabolome contribute to the greater feed efficiency of low RFI (LRFI) animals. The aim of this study was to explore the differences in rumen microorganisms, rumen metabolites and plasma metabolites of Hu sheep with differing RFI through the microbiome and metabolome. A total of 80 Hu sheep were used. The experiment consisted of a 15-d pretrial period and a 128-d experimental period. The RFI in the experimental period was calculated for all sheep, and the sheep were screened into high RFI (HRFI, n = 8) and LRFI (n = 8) groups. The HRFI and LRFI sheep did not differ in their initial and final body weights, average daily gain and body measurements, but the dry matter intake of LRFI sheep was significantly decreased (28.4%, P < 0.001). The sheep with LRFI had higher digestibility of crude protein (P = 0.010) and ether extract (P = 0.010) compared to HRFI group. The concentrations of acetate (P = 0.036), propionate (P = 0.010), valerate (P = 0.027) and total volatile fatty acids (P = 0.048) in rumen of LRFI group were higher compared to HRFI group. The results of 16S rDNA sequencing indicated that the sheep with LRFI had higher proportions of Prevotella genus in rumen liquid (P = 0.031). The rumen metabolome and plasma metabolome results showed that the citrate cycle, pyruvate metabolism and alanine, aspartate and glutamate metabolism processes were more active for sheep in LRFI group, which provided more energy substrate such as malic acid, oxoglutaric acid and citric acid. In conclusion, sheep with LRFI can utilize feed more efficiently, and the more active energy metabolism pathway and the production of energy substances may account for the higher feed efficiency.

关键词： Feed efficiency Residual feed intake Rumen microbiome and metabolome Plasma metabolome CHAIN FATTY-ACIDS GENETIC-PARAMETERS MILK-PRODUCTION BEEF-CATTLE AMINO-ACID D-LACTATE EFFICIENCY SUPPLEMENTATION FERMENTATION DIVERGENCE

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Influence of ammonium sulfate on the corrosion behavior of AZ31 magnesium alloy in chloride environment

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Journal of Magnesium and Alloys 2024年第3期12卷 1082-1101页

作者： Feng Ge Zhongyu Cui Yue Liu Li Lei Xin Wang Hongzhi Cui School of Materials science and Engineering Ocean University of ChinaQingdao 266100China Beijing national Innovation Institute of Lightweight Ltd.Beijing 101499China

Electrochemical corrosion of AZ31 magnesium alloy in the NH_(4)^(+)-SO_(4)2−-Cl−environment is *** of NH_(4)^(+)overshadows that of Cl−as the(NH_(4))_(2)SO_(4) concentration is 0.005 M or higher,yielding an evolution from localized corrosion to uniform *** effect of NH_(4)^(+)can be attributed to that(i)NH_(4)^(+)dissolves the inner MgO and hinders the precipitation of Mg(OH)_(2) and(ii)the buffering ability of NH_(4)^(+)provides H+,enhances the hydrogen evolution,and expedites the corrosion *** latter is demonstrated as the dominant factor with the results in unbuffered and buffered *** severe corrosion and hydrogen process in NH_(4)^(+)-containing solution results in a high Hads coverage and yields an inductive loop within the low ***,SO_(4)^(2−)is helpful in generating cracked but partially protective corrosion products,while Cl−could broaden the corrosion area beneath the corrosion product.

关键词： Magnesium alloy Ammonium corrosion Electrochemical kinetic parameter Anodic dissolution.

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Effect of matrix resin components on properties of the semi-conductive shielding material for high-voltage cable

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High Voltage 2024年第2期9卷 419-428页

作者： Guochang Li Tianyao Liu Xiaolong Chen Yanhui Wei Chuncheng Hao Shengtao Li Institute of Advanced Electrical Materials Qingdao University of Science and TechnologyQingdaoChina State Key Laboratory of Electrical Insulation and Power Equipment Xi'an Jiaotong UniversityXi'anChina

The semi-conductive shielding layer is an important part of the high-voltage cable,playing a role in uniform electric field and reducing the air gap at the *** overall performance of the cable is affected by the semi-conductive shielding layer with different base resin *** matrix resins of ethylene-vinyl acetate(EVA),ethylene-ethyl acrylate(EEA)and ethylene-butyl acrylate(EBA)were used to prepare the semi-conductive shielding materials of CB/EVA,CB/EEA and CB/*** influences of different matrix resins on the chemical,electrical,thermal and mechanical properties of the shielding materials were *** results show that CB has the best dispersion in EBA resin and the worst dispersion in EEA *** temperature in-flection points of CB/EVA,CB/EEA and CB/EBA shielding materials are 90°C,100°C and 110°C,respectively,and the CB/EBA shielding material has the lowest resistivity and the weakest positive temperature coefficient effect at room *** thermal conductivity of all three matrix resins is smaller than that of the shielding material,the thermal conductivity of CB/EVA and CB/EBA shielding materials show a slow increase with temperature,and the CB/EEA shielding material is the least affected by the *** mechanical properties of the three matrix resins and the three shielding materials are EBA>EVA>EEA,among them the stress of CB/EBA shielding material is 31.0 MPa and the strain is 570%.This work has important reference significance for the selection of shielding layer matrix resin and material formulation in engineering applications.

关键词： temperature. resin resins

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Versatile zeolite overlayer on ZnO film enabling high-performance bilayer NO_(2) sensoring

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Nano Research 2024年第10期17卷 9193-9201页

作者： Tianshuang Wang Yiheng Li Dan Li Peng Sun Xiaowei Song Geyu Lu Jihong Yu State Key Laboratory of Inorganic Synthesis and Preparative Chemistry College of ChemistryJilin University2699 Qianjin StreetChangchun 130012China State Key Laboratory on Integrated Optoelectronics College of Electronic Science and EngineeringJilin University2699 Qianjin StreetChangchun 130012China International Center of Future science Jilin University2699 Qianjin StreetChangchun 130012China

Bilayer structure with functional overlayer has been commonly adopted to resolve the issue of moisture poisoning in ***,the conventional overlayers always suffer from blocking access of gas molecules to sensing layer due to lacking porosity and deteriorated adsorption ***,taking advantages of the well-defined porous structure and hydrophobic nature of pure silica zeolite,we assembled an overlayer of Pd-PdO clusters-encapsulated mesoporous silicalite-1(MFI)zeolite(named M-S-1)on ZnO sensing layer,to prevent moisture poisoning,and enhance gas diffusion and adsorption *** inherent capability of MFI zeolite to incorporate monodispersed nanometric(ca.3 nm)Pd-PdO cluster in its void space is of great importance for the NO_(2) *** Pd-PdO@M-S-1 overlayer can attain negligible moisture interference to the ZnO layer without significantly altering the gas selectivity and baseline resistance,and enhance gas ***,the Pd-PdO@M-S-1/ZnO bilayer sensor can ultra-selectively(S_(nitrogen dioxide)/S_(interference gas)>4),and ultra-stably detect trace level of NO_(2)(9.5 ppb)at low temperature(370 K)under high levels of humidity(90%RH).This work exemplifies a next-generation solution to design bilayer sensors using zeolite overlayer for eliminating the humidity dependence of the gas-sensing properties.

关键词： zeolites metal clusters bilayer structure NO_(2)chemiresistor

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Adjustment mechanism of blasting dynamic-static action in the water decoupling charge

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International Journal of Mining science and technology 2024年第6期34卷 821-836页

作者： Hao Zhang Xueyang Xing Yiteng Du Tingchun Li Jianxin Yu Qingwen Zhu College of Civil Engineering and Architecture Shandong University of AeronauticsBinzhou 256600China Shandong Key Laboratory of Civil Engineering Disaster Prevention and Mitigation Shandong University of Science and TechnologyQingdao 266590China School of Civil Engineering Henan Polytechnic UniversityJiaozuo 454003China

Water decoupling charge blasting excels in rock breaking,relying on its uniform pressure transmission and low energy *** water decoupling coefficients can adjust the contributions of the stress wave and quasi-static ***,the quantitative relationship between the two contributions is unclear,and it is difficult to provide reasonable theoretical support for the design of water decoupling *** this study,a theoretical model of blasting fracturing partitioning is *** mechanical mechanism and determination method of the optimal decoupling coefficient are *** reliability is verified through model experiments and a field *** results show that with the increasing of decoupling coefficient,the rock breaking ability of blasting dynamic action decreases,while quasi-static action increases and then *** ability of quasi-static action to wedge into cracks changes due to the spatial adjustment of the blast hole and crushed *** quasi-static action plays a leading role in the fracturing range,determining an optimal decoupling *** optimal water decoupling coefficient is not a fixed value,which can be obtained by the proposed theoretical *** with the theoretical results,the maximum error in the model experiment results is 8.03%,and the error in the field test result is 3.04%.

关键词： Water decoupling blasting Blasting dynamic-static action Optimal decoupling coefficient Adjustment mechanism

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