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Chinese Chemical Letters 2024年第6期35卷 288-292页

作者： Hui-Juan Wang Wen-Wen Xing Zhen-Hai Yu Yong-Xue Li Heng-Yi Zhang Qilin Yu Hongjie Zhu Yao-Yao Wang Yu Liu College of Chemistry State Key Laboratory of Elemento-Organic ChemistryNankai UniversityTianjin 300071China Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology School of Chemistry and Chemical EngineeringLiaocheng UniversityLiaocheng 252000China Key Laboratory of Molecular Microbiology and Technology College of Life SciencesNankai UniversityTianjin 300071China

Macrocycle confinement induced guest near-infrared(NIR)luminescence was research hotspot *** in,we reported a cucurbit[7]uril(CB[7])confined 3,7-bis((E)-2-(pyridin-4-yl)vinyl)-10-Hphenothiazine bridged bis(4-(4-bromophenyl)pyridine)(G),which not only boosted its NIR luminescence but also realized detection of HClO/ClO^(-)in living cells and lysosome *** spectroscopy experiments were performed to calculate the detection ability of probe G to HClO/ClO^(-)up to 147 nmol/*** compared with G,supramolecular probe G■CB[7]formed after encapsulated by CB[7],the detection ability towards HClO/ClO^(-)was improved to 24 nmol/L which was ascribe to the macrocycle CB[7]confinement increasing the fluorescence intensity to 103 *** the excitation wavelength changing,the fluorescence red-shifted to 820 nm when excited by 570 nm light,which was used to NIR lysosome ***,the supramolecular assembly G■CB[7]was also successfully used to highly sense to exogenous HClO/ClO^(-)in RAW 264.7 cells and live animal.

关键词： Phenothiazine Supramolecular assembly Macrocycle confined Probe HClO/ClO^(-)

Rational construction of CuFe_(2)O_(4)@C/Cd_(0.9)Zn_(0.1)S S-scheme heterojunction photocatalyst for extraordinary photothermal-assisted photocatalytic H_(2) evolution

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Journal of Energy Chemistry 2024年第5期92卷 240-249页

作者： Dong Zhang Minghui Zhu Ran Qin Peixian Chen Maoye Yin Dafeng Zhang Junchang Liu Hengshuai Li Xipeng Pu Peiqing Cai School of Physics Science and Information Technology Shandong Key Laboratory of Optical Communication Science and TechnologyLiaocheng UniversityLiaocheng 252000ShandongChina School of Materials Science and Engineering Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell TechnologyLiaocheng UniversityLiaocheng 252000ShandongChina College of Optical and Electronic Technology China Jiliang UniversityHangzhou 310018ZhejiangChina

Rational design of photocatalyst to maximize the use of sunlight is one of the issues to be solved in photocatalysis *** this study,the CuFe_(2)O_(4)@C/Cd_(0.9)Zn_(0.1)S(CFO@C/CZS)S-scheme photocatalyst with photothermal effect was synthesized by ultrasonic self-assembly combined with *** dark CFO@C absorbed visible light and partly converted into heat to promote the hydrogen evolution *** presence of heterojunctions inhibited the photogenerated electron-hole *** graphite-carbon layer provided a stable channel for electron transfer,and the presence of magnetic CFO made recycle *** the action of photothermal assistance and heterojunction,the hydrogen evolution rate of the optimal CFO@C/CZS was 80.79 mmol g^(-1) h^(-1),which was 2.55 times and 260.61 times of that of pure CZS and CFO@C,***,the composite samples also exhibit excellent stability and a wide range of environmental *** experimental tests and first-principles simulation calculation methods,the plausible mechanism of photoactivity enhancement was *** work provided a feasible strategy of photothermal assistance for the development of heterojunction photocatalysts with distinctive hydrogen evolution.

关键词： Photothermal effect S-scheme heterojunction Photocatalytic hydrogen evolution First-principles calculations

Synergistically enhanced dielectric, insulating and thermally conductive performances of sandwich PMMA based dielectric films

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Progress in Natural Science:Materials International 2024年第3期34卷 591-597页

作者： Dongmei Zhang Yufan Li Yuchao Li Zhonggui Sun Hanxue Zhu Lujia Yang Yanhu Zhan Yankai Li Shi Wang Jun-Wei Zha School of Mathematical Sciences Liaocheng University School of Materials Science and Engineering Liaocheng University State Key Laboratory of Organic Electronics and Information Displays & Institute of Advanced Materials (IAM) Nanjing University of Posts & Telecommunications School of Chemistry and Biological Engineering University of Science and Technology Beijing

A tri-layered(B-G-B) dielectric films were simply prepared by alternatively spin-coating boron nitride/polymethylmethacrylate(BN/PMMA, B) and graphene nanosheets(GNS/PMMA, G) compound solutions. The structure, morphology, thermal conductivity, and particularly the dielectric and relaxation behaviors were systematically studied. Results showed that a good exfoliation and dispersion of BN and GNS can be simply achieved through intensive mechanical compounding with PMMA in the internal mixer. The dielectric constant and breakdown strength of the obtained 1-3-1(B-G-B) sandwich composite film reached 4.3(@1 kHz) and 458.6kV/mm, being 119 % and 113 % higher than that of pure PMMA, respectively. Furthermore, the overall thermal conductivity of sandwich 1-3-1 composite increased by 112 % due to the addition of thermally conductive BN and GNS. The sandwich design strategy provided an effective way of achieving good permittivity, high insulation, and improved thermal conductivity simultaneously, showing potential applications in the miniaturization and integration of electronic devices.

关键词： Breakdown strength Composites Dielectric constant Sandwich structure Thermal conductivity

Integrated Practice of Cultivating Innovative Ability and Ideological Education for Graduate Students of Materials Science Major

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Journal of Contemporary Educational Research 2024年第5期8卷 247-253页

作者： Junjie Ni Yan Li School of Materials Science and Engineering Liaocheng UniversityLiaocheng 252000Shandong ProvinceChina

Aiming at the problem of weak integration of innovation ability and ideological education of postgraduates in materials major,this paper explores postgraduates’cultivation work under the support of liaocheng *** is found that the cultivation of the innovation ability of postgraduates in materials can be the realization path and sublimation carrier of ideological education,ideological education can provide spiritual support and methodological guidance for the former,and the organic integration of the two is *** the fit relationship between innovation ability and ideological education,institutionalizing tutor guidance,establishing tutor+counselor+professional teacher communication mechanism,and taking disciplinary competitions as a handhold can achieve the integration of innovation ability cultivation and ideological education of graduate students in materials major.

关键词： Postgraduate education Innovation ability Ideological education Materials major

Photocatalytic in situ H_(2)O_(2) production and activation for enhanced ciprofloxacin degradation over CeO_(2)-Co_(3)O_(4)/g-C_(3)N_(4):key role of CeO_(2)

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Rare Metals 2024年第6期43卷 2695-2707页

作者： Hong-Jie Zhu Yi-Kai Yang Ming-Hui Li Lu-Ning Zou Hai-Tao Zhao Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology School of Chemistry and Chemical Engin College of Ecology and Environment Anhui Normal UniversityWuhu241002China liaocheng YiLu Advanced Materials Co. LtdLiaocheng 252000China

The abused ciprofloxacin antibiotics have caused significant environmental *** oxidative degradation of ciprofloxacin exhibits promising efficacy,it often entails excessive energy ***,it is necessary to explore an effective and ecologically sustainable degradation ***,we demonstrated that g-C_(3)N_(4) decorated with the coordinated CeO_(2)and Co_(3)O_(4)(CeO_(2)-Co_(3)O_(4)/CN)exhibited effective ciprofloxacin photodegradation via in situ H_(2)O_(2) production and activation *** indicate that the introduced CeO_(2) enhances the transference of photogenerated electrons to O_(2) by adjusting the oxygen vacancy of photocatalyst,thereby increasing the generation of superoxide radicals,which in turn generate H_(2)O_(2),resulting in a 22.4-fold increase in H_(2)O_(2) generation over g-C_(3)N_(4).Moreover,the in situ H_(2)O_(2)generation facilitated by CeO_(2) is confirmed to be essential for ciprofloxacin degradation via CeO_(2)-Co_(3)O_(4)/CN,as it provides enough oxidant for Co_(3)O_(4) to activate into hydroxyl radicals for the pollutants ***,CeO_(2)-Co_(3)O_(4)/CN achieves a ciprofloxacin degradation ratio of 97.7%within 80 *** study introduces a novel approach that combines H_(2)O_(2) generation and activation,offering an innovative perspective for achieving clean and efficient purification of antibiotic-contaminated water.

关键词： CeO_(2) In situ H_(2)O_(2)generation Ciprofloxacin degradation Photocatalyst

Selectively nucleotide-derived RuP on N,P-codoped carbon with engineered mesopores for energy-efficient hydrogen production assisted by hydrazine oxidation

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SusMat 2024年第1期4卷 166-177页

作者： Xiya Guan Yu Sun Simeng Zhao Haibo Li Suyuan Zeng Qingxia Yao Rui Li Hongyan Chen Konggang Qu School of Chemistry and Chemical Engineering Shandong Provincial Key Laboratory/Collaborative Innovation Center of Chemical Energy Storage&Novel Cell TechnologyLiaocheng UniversityLiaochengChina

Integrating hydrogen evolution reaction(HER)with hydrazine oxidation reaction(HzOR)has an encouraging prospect for the energy-saving hydrogen production,demanding the high-performance bifunctional HER/HzOR *** phosphide/doped carbon composites have exhibited superior activity towardmultiple electrocatalytic *** explore the decent water-soluble precursors containing bothNand P elements is highly attractive to facilely prepare metal phosphide/doped carbon ***,as one kind ecofriendly biomolecules,adenine nucleotide was first employed to selectively fabricate the highly pure RuP nanoparticles embedded into porous N,P-codoped carbons(RuP/PNPC)with a straightforward“mix-and-pyrolyze”*** newly prepared RuP/PNPC only requires 4.0 and−83.0 mV at 10 mA/cm^(2) separately in alkaline HER and HzOR,outperforming most of reported electrocatalysts,together with the outstanding neutral bifunctional ***,the two-electrode alkaline and neutral overall hydrazine splitting both exhibit significant power-efficiency superiority to the corresponding overall water splitting with the voltage difference of larger than 2 V,which can be also easily driven by the fuel cells and solar cells with considerableH2 *** report innovates the N-and P-bearing adenine nucleotide to effortlessly synthesize the high-quality RuP/doped carbon composite catalysts,highly potential as a universal platform for metal phosphide-related functional materials.

关键词： bifunctional electrocatalyst hydrazine oxidation hydrogen energy hydrogen evolution RuP

An Improved Iterated Greedy Algorithm for Solving Rescue Robot Path Planning Problem with Limited Survival Time

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Computers, Materials & Continua 2024年第7期80卷 931-947页

作者： Xiaoqing Wang Peng Duan Leilei Meng Kaidong Yang School of Computer Science Liaocheng UniversityLiaocheng252000China Shandong Key Laboratory of Optical Communication Science and Technology School of Physics Science and Information TechnologyLiaocheng UniversityLiaocheng252059China

Effective path planning is crucial for mobile robots to quickly reach rescue destination and complete rescue tasks in a post-disaster *** this study,we investigated the post-disaster rescue path planning problem and modeled this problem as a variant of the travel salesman problem(TSP)with life-strength *** address this problem,we proposed an improved iterated greedy(IIG)***,a push-forward insertion heuristic(PFIH)strategy was employed to generate a high-quality initial ***,a greedy-based insertion strategy was designed and used in the destruction-construction stage to increase the algorithm’s exploration ***,three problem-specific swap operators were developed to improve the algorithm’s exploitation ***,an improved simulated annealing(SA)strategy was used as an acceptance criterion to effectively prevent the algorithm from falling into local *** verify the effectiveness of the proposed algorithm,the Solomon dataset was extended to generate 27 instances for ***,the proposed IIG was compared with five state-of-the-art *** parameter analysiswas conducted using the design of experiments(DOE)Taguchi method,and the effectiveness analysis of each component has been verified one by *** results indicate that IIGoutperforms the compared algorithms in terms of the number of rescue survivors and convergence speed,proving the effectiveness of the proposed algorithm.

关键词： Rescue robot path planning life strength improved iterative greedy algorithm problem-specific swap operators

Novel Insight into the Preparation of Ti-6Al-4V Alloy Through Thermite Reduction Based on the Mass Action Concentration

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Journal of Wuhan university of Technology(Materials Science) 2023年第3期38卷 652-658页

作者：宋玉来 DOU Zhihe CHENG Chu 张廷安 School of Materials Science and Engineering Liaocheng UniversityLiaocheng 252059China Key Laboratory of Ecological Metallurgy of Multi-metal Intergrown Ores Ministry of EducationNortheastern UniversityShenyang 110819China School of Materials Science and Engineering Henan University of Science and TechnologyLuoyang 471003China

Based on the mass action concentration theory,a novel thermodynamic analysis for the raw material ratio in the procedure of preparing Ti-6Al-4V alloy by aluminothermic reduction process is proposed in this paper,which is originated from TiO_(2),Al particles,and V_(2)O_(5) as feedstocks,and the relevant equilibrium thermodynamics was calculated through this new *** results show that the range of aluminum addition coefficient in raw material to experiment should be controlled within 61.5%-100%,which can significantly reduce the number of experimental *** method is ready to regulate the matter of excessive aluminum content in reactants for materials preparation,especially for those reactions including elements that are effortless to combine with aluminum to form the corresponding intermetallics or *** addition,it can also be used in general metallurgy or material preparation process to effectively predict the composition and proportion of equilibrium components under certain conditions.

关键词： mass action concentration titanium alloy thermodynamics intermetallics thermite reduction

COF-derived Co nanoparticles@N-doped carbon electrocatalysts for high performance Zn-air batteries

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Chinese Journal of Chemical Engineering 2023年第11期63卷 43-50页

作者： Jie Wei Chengcai Zhao Ming Chen Fengying Liu Limin Zhao Hui Zhao Zhong-Yong Yuan School of Materials Science and Engineering Liaocheng UniversityLiaocheng 252000China College of Chemistry and Chemical Engineering Xinyang Normal UniversityXinyang 464000China Key Laboratory of Advanced Energy Materials Chemistry(Ministry of Education) School of Materials Science and EngineeringNankai UniversityTianjin 300350China

Precise modulation of the structure and composition of electrocatalysts is critical for promoting the kinetically sluggish process of oxygen reduction reaction(ORR)and oxygen evolution reaction(OER).Covalent organic frameworks(COF)offer a novel way to create highly efficient electrocatalysts due to their tunable composition,structure and surface ***,we report a high-efficiency bifunctional electrocatalyst comprising Co nanoparticles embedded within N-doped carbons(Co@NCs)for Zn-air batteries(ZABs).The Co@NC is yielded via the coordination of a triazine COF with Co-containing precursors and subsequent calcination under inert *** as-prepared Co@NC exhibits remarkable ORR/OER performance and great potential in rechargeable *** liquid ZAB constructed with Co@NC provides both high specific capacity and power ***,the ZAB exhibits a voltage gap of 0.8 V during discharge and charge cycles and high stability for 220 h compared to the Pt/C-assembled *** strategy for regulating electrocatalytic activities of COF-derived carbon materials could be expanded for creating various carbon catalysts.

关键词： COF Co@NC Composites Electrochemistry Catalysis Zn-air battery

Dependence of lithium metal battery performances on inherent separator porous structure regulation

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Journal of Energy Chemistry 2023年第9期84卷 436-447页

作者： Lei Ding Dandan Li Lingyang Liu Pengfang Zhang Fanghui Du Chao Wang Daoxin Zhang Shuo Zhang Sihang Zhang Feng Yang Shandong Key Laboratory of Chemical Energy Storage and New Battery Technology Institute of BioPharmceutical ResearchSchool of Chemistry and Chemical EngineeringLiaocheng UniversityLiaocheng 252000ShandongChina State Key Laboratory of Polymer Materials Engineering College of Polymer Science and EngineeringSichuan UniversityChengdu 610065SichuanChina College of Materials Science and Engineering Qingdao University of Science and TechnologyQingdao 266042ShandongChina School of Food Science and Engineering Hainan UniversityHaikou 570228HainanChina

Boosting of rechargeable lithium metal batteries(LMBs) holds challenges because of lithium dendrites germination and high-reactive surface *** may experience structure-determined chemical deterioration and worsen Li plating-stripping behaviors when smoothly shifting from lithium-ion batteries(LIBs) to *** study precisely regulations the crystal structure of β-polypropylene and separator porous construction to investigate the intrinsic porous structure and mechanical properties determined electrochemical performances and cycling durability of *** structure characterizations,porous structure analyses,and electrochemical cycling tests uncover appropriate annealing thermal stimulation concentrates β-lamellae thickness and enhances lamellae thermal stability by rearranging molecular chain in inferior β-lamellae,maximally homogenizing biaxial tensile deformation and resultant porous *** even pores with high connectivity lower ion migration barriers,alleviate heterogeneous Li^(+) flux dispersion,stabilize reversible Li plating-stripping behaviors,and hinder coursing and branching of Li dendrites,endowing steady cell cycling durability,especially at higher currents due to the highlighted uncontrollable cumulation of dead Li,which offers new insights for the current pursuit of high-power density battery and fast charging *** suggested separator structure-chemical nature functions in ensuring cyclic cell stability and builds reliable relationships between separator structure design and practical LMBs applications.

关键词： Lithium metal battery Polyolefin separator Porous structure design Lithium dendrite regulation Cycling stability