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Interleukin-1 receptor antagonist:From synthesis to therapeutic applications

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BIOCELL 2023年第4期47卷 809-823页

作者： KANWAL REHMAN AMMARA AFZAAL MUHAMMAD SAJID HAMID AKASH MUHAMMAD IMRAN MOHAMMED A.ASSIRI Department of Pharmacy The Women UniversityMultan60000Pakistan Department of Pharmaceutical Chemistry Government College UniversityFaisalabad38000Pakistan research center for advanced materials science(RCAMS) King Khalid UniversityAbha62413Saudi Arabia Department of Chemistry Faculty of ScienceKing Khalid UniversityAbha62413Saudi Arabia

The cytokine channel’s mechanism for self-regulation involves the application of antagonistic cytokines that are synthesized to connect to the receptors and release soluble cytokine *** very first receptor antagonist of cytokine that was naturally present was interleukin-1 receptor antagonist(IL-1Ra).The IL-1Ra protein forms are disinfected from supernatants of cultured monocytes on stacked *** family of IL-1 consists of IL-1α,IL-1βand *** monocytes regulate the production of ***-Ra takes part in normal physiological functions by using specific antibodies,and acts as an anti-inflammatory ***-Ra is synthesized in the tissues during the period of active disease and can be systematically measured and/or *** of the levels of IL-Ra and IL-1 is the main factor for host resistance in patients during diseased conditions,as IL-Ra acts as an inherent regulator of various inflammatory *** this article,we focuse on how IL-Ra is synthesized and performs its functions once the inflammatory responses are activated.

关键词： IL-Ra Synthesis Therapeutic applications Functions of IL-1Ra

Magnetically separable and visible light-active Ag/NiCo2O4 nanorods prepared by a simple route for superior photodegradation of atrazine in water

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Progress in Natural science:materials International 2020年第2期30卷 160-167页

作者： Ahmed Shawky Maha Alhaddad R.M.Mohamed Nasser S.Awwad Hala A.Ibrahium Nanomaterials and Nanotechnology Department Advanced Materials DivisionCentral Metallurgical R&D Institute(CMRDI) P.O.Box 87 Helwan Department of Mechanical Engineering School of EngineeringThe University of Tokyo Chemistry Department Faculty of ScienceKing Abdulaziz University research Centre for advanced materials science (RCAMS) King Khalid University Department of Biology Nuclear Materials Authority

Atrazine（ATZ） is a known herbicide used in agriculture and caused many concerns according to its ***,we have prepared NiCo2O4nanorods that can work as a photocatalyst under visible light exposure by Ag loading through a simple *** characterizations revealed the role of Ag for improving the structural,optical and optoelectronic properties of the produced *** Ag loading with 5 wt% confirms the minimization of the bandgap from 3.6 down to 2.57 eV with enhanced visible light absorption and sustaining the magnetic *** Ag/NiCo2O4nanorods showed a superior photodegradation of ATZ within 20 min at2.0 g L-1with excellent *** enhancement of the photocatalytic activity is referred to the local surface plasmon resonance of Ag-loaded *** reduces the electron-hole recombination and outperforms the unloaded *** work is highlighting the application of magnetically separable spinel photocatalysts for the removal of herbicides and water remediation.

关键词： Spinel photocatalyst Visible light Photodegradation Atrazine Magnetic separation

Adsorption of rare earth elements onto diatomite M45:Experimental investigations and modeling with statistical physics theory

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Journal of Rare Earths 2023年第11期41卷 1805-1811,I0006页

作者： Fatma Dhaouadi Guilherme L.Dotto Julien Vieillard Diana Pinto Luis F.O.Silva Éder C.Lima Mu Naushad Fatma Aouaini Samia Nasr Adrián Bonilla-Petriciolet Abdelmottaleb Ben Lamine Laboratory of Quantum and Statistical Physics LR18ES18Faculty of Sciences of MonastirMonastir UniversityMonastirTunisia research Group on Adsorptive and Catalytic Process Engineering(ENGEPAC) Federal University of Santa MariaAv.Roraima1000-797105–900Santa MariaRSBrazil NormandieUniversité UNIROUENINSA RouenCNRSCOBRA(UMR 6014)27000EvreuxFrance Universidad De La Costa Calle 58#55-66080002BarranquillaAtlánticoColombia advanced materials research Chair Department of ChemistryCollege of ScienceKing Saud UniversityRiyadh11451Saudi Arabia Department of Chemistry College of ScienceBuilding#5King Saud UniversityRiyadhSaudi Arabia Department of Physics College of SciencePrincess Nourah Bint Abdulrahman UniversityP.O.Box 84428Riyadh11671Saudi Arabia research center for advanced materials science(RCAMS) King Khalid UniversityAbha61413P.O.Box 9004Saudi Arabia Chemistry Department Faculty of ScienceKing Khalid UniversityP.O.Box 9004Abha61413Saudi Arabia Instituto Tecnológico de Aguascalientes 20256AguascalientesMexico

The separation of rare earth elements using diatomite M45 from aqueous solutions was *** experimental isotherms for the adsorption of trivalent lanthanum,cerium,and neodymium cations on this adsorbent were quantified under strongly acidic conditions(pH 2)at 298-328 *** adsorption equilibria of these earth elements were analyzed using two statistical physics models(homogeneous and heterogeneous monolayer models).The results show that the adsorption of these ions implies a multiionic mechanism,which is ***-containing functional groups are responsible for the adsorption of these rare-earth elements on the diatomite surface.A heterogeneous statistical physics model confirms that two Si-based functional groups participate in the separation of these *** calculated adsorption capacities at saturation follow the order:neodymium>cerium>*** interaction energies range from 28600 to 40100 J/mol,indicating physical adsorption on diatomite *** study demonstrates that diatomite M45 is a promising separation medium that can be used for the recovery of REEs dissolved in aqueous solutions via adsorption.

关键词： Lanthanum Cerium Neodymium Adsorption Diatomite M45 Statistical physics model

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Preparation of epoxy resin/rare earth doped aluminate nanocomposite toward photoluminescent and superhydrophobic transparent woods

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Journal of Rare Earths 2023年第3期41卷 397-405,I0003页

作者： Mehrez E.El-Naggar Sami Ullah S.Wageh M.A.Abu-Saied Tawfik A.Khattab Dalal Alhashmialameer Manal Abou Taleb E.A.Matter Institute of Textile research and Technology National Research CenterDokkiCairo16221Egypt research center for advanced materials science(RCAMS) King Khalid UniversityP.O.Box 9004Abha61413Saudi Arabia Department of Chemistry College of ScienceKing Khalid UniversityP.O.Box 9004Abha61413Saudi Arabia Department of Physics Faculty of ScienceKing Abdulaziz UniversityJeddah21589Saudi Arabia K.A.CARE Energy research and Innovation center King Abdulaziz UniversityJeddah21589Saudi Arabia Polymeric materials research Department Advanced Technology and New Materials Research InstituteCity of Scientific Research and Technological Applications(SRTACITY)New Borg El-Arab CityAlexandria21934Saudi Arabia Department of Chemistry College of ScienceTaif UniversityTaif21944Saudi Arabia Department of Chemistry College of Science and HumanitiesPrince Sattam Bin Abdulaziz UniversityAl-kharj11942Saudi Arabia Department of Polymer Chemistry National Center for Radiation Research and Technology(NCRRT)Egyptian Atomic Energy AuthorityNasr CityP.O.Box 7551Cairo11762Egypt Department of Chemistry Faculty of ScienceDamanhour University22111 DamanhourEgypt

A translucent wooden substrate with long-lasting phosphorescence,high photostability and durability,tough surface,ultraviolet protection,high optical transmittance,and superhydrophobicity was *** long-lasting phosphorescent wooden substrate is able to continue emitting light for extended time ***-modified wood(LMW)was immobilized with a solution of epoxy resin(ER)and rare-earth doped aluminate(REDA)phosphor nanoparticles(NPs).For an improved dispersion of pigment,REDA was synthesized in a nanoscale particle size,and characterized by transmission electron microscopy(TEM)to indicate a particle size of 8-14 *** crystal structure of REDA nanoparticles was also proved by X-ray diffraction(XRD).For an improved production of long-persistent phosphorescent colo rless woods,REDA must be well-dispersed in MAA without *** and emissio n,as well as decay and lifetime spectra were *** morphologies of the wooden substrates with different ratios of REDA were investigated by scanning electron microscopy(SEM),X-ray fluorescence(XRF)analysis,Fourier transform infrared spectra(FT-IR),elemental mapping,and energy-dispersion Xray(EDXA).The phosphorescent woods show changes in color from colorless to green under ultraviolet(UV)irradiation,and to yellowish-green in the dark,as proved by the colorimetric parameters of the CIE Lab *** afterglow wood samples display an absorbance band at 365 nm and two phosphorescent bands at 431 and 520 *** UV shielding,photostability,and hydrophobicity were *** increasing REDA ratio,both static contact and slide angles are found to improve in the ranges of147.6°-163.6°and 9°-14°,*** long-lasting photoluminescence is optimized at a REDA ratio of 8%.The present strategy shows a large-scale production approach of multiple functional woods for many potential applications,such as smart glow in the dark windows and safety signs.

关键词： Translucent wood Rare-earth doped aluminate Superhydrophobic Long-lasting light emission Ultraviolet protection

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New Decision-Making Technique Based on Hurwicz Criteria for Fuzzy Ranking

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Computers, materials & Continua 2022年第12期73卷 4595-4609页

作者： Deepak Sukheja Javaid Ahmad Shah G.Madhu K.Sandeep Kautish Fahad A.Alghamdi Ibrahim.S.Yahia El-Sayed M.El-Kenawy Ali Wagdy Mohamed Department of Computer science and Engineering VNR Vignana Jyothi Institute of Engineering and TechnologyHyderabadIndia Department of Mathematics Dr.APJ Abdul Kalam University Indore(M.P)India Department of Information Technology VNR Vignana Jyothi Institute of Engineering and TechnologyHyderabadIndia LBEF Campus Kathmandu44600Nepal Department of Management Information Systems College of Applied Studies and Community ServiceImam Abdulrahman Bin Faisal UniversityDammamSaudi Arabia Laboratory of Nano-Smart materials for science and Technology(LNSMST) Department of PhysicsFaculty of ScienceKing Khalid UniversityP.O.Box 9004Abha 61413Saudi Arabia research center for advanced materials science(RCAMS) King Khalid UniversityP.O.Box 9004Abha 61413Saudi Arabia Nanoscience Laboratory for Environmental and Biomedical Applications(NLEBA) Semiconductor Lab.Department of PhysicsFaculty of EducationAin Shams UniversityRoxyCairo 11757Egypt Department of Communications and Electronics Delta Higher Institute of Engineering and TechnologyMansoura35111Egypt Faculty of Artificial Intelligence Delta University for Science and TechnologyMansoura35712Egypt Operations research Department Faculty of Graduate Studies for Statistical ResearchCairo UniversityGiza12613Egypt Department of Mathematics and Actuarial science School of sciences Engineering The American University in CairoEgypt

Efficient decision-making remains an open challenge in the research community,and many researchers are working to improve accuracy through the use of various computational *** this case,the fuzzification and defuzzification processes can be very *** is an effective process to get a single number from the output of a fuzzy *** defuzzification as a center point of this research paper,to analyze and understand the effect of different types of vehicles according to their *** this paper,the multi-criteria decision-making(MCDM)process under uncertainty and defuzzification is discussed by using the center of the area(COA)or ***,to find the best solution,Hurwicz criteria are used on the defuzzified ***-making technique is proposed using Hurwicz criteria for triangular and trapezoidal fuzzy *** proposed technique considers all types of decision makers’perspectives such as optimistic,neutral,and pessimistic which is crucial in solving decisionmaking problems.A simple case study is used to demonstrate and discuss the Centroid Method and Hurwicz Criteria for measuring risk attitudes among *** significance of the proposed defuzzification method is demonstrated by comparing it to previous defuzzification procedures with its application.

关键词： Defuzzification decision-making fuzzy numbers Hurwicz multicriteria decision-making ranking order

Graphene oxide-based hydrogels as a nanocarrier for anticancer drug delivery

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Nano research 2019年第5期12卷 973-990页

作者： Abdullah A.Ghawanmeh Gomaa A.M.Ali H.Algarni Shaheen M.Sarkar Kwok Feng Chong Faculty of Industrial sciences & Technology Universiti Malaysia PahangGambang26300 KuantanMalaysia Chemistry Department Faculty of ScienceAl-Azhar UniversityAssiut71524Egypt Department of Physics Faculty of SciencesKing Khalid UniversityAbha 61413P. O. Box 9004Saudi Arabia research center for advanced materials science (RCAMS) King Khalid UniversityAbha 61413P. O. Box 9004Saudi Arabia Bernal Institute Department of Chemical SciencesUniversity of LimerickCastletroyV94 LimerickIreland

Graphene oxide (GO) possesses excellent mechanical strength,biocompatibility,colloidal stability,large surface area and high adsorption *** has driven to cancer nanotechnology to defeat cancer therapy obstacles,via integration into three-dimensional (3D) hydrogel network with biocompatible polymers as nanocomposites carrier,and controllable release of anticancer ***,the surface of GO affords π-π stacking and hydrophilic interactions with anticancer ***,modification of GO with various polymers such as natural and synthetic polymers enhances its biodegradability,drug loading,and target *** this review,GO based hydrogels research accomplishments are reviewed on the aspects of crosslinking strategies,preparation methods,the model drug,polymer conjugation and modification with targeting ***,swelling kinetics,drug release profile and biological activity in vivo and in vitro are *** biocompatibility of GO based hydrogels is also discussed from the perspective of its nano-bio *** from that,the clinical potential of GO based hydrogels and its major challenges are addressed in ***,this review concludes with a summary and invigorating future perspectives of GO based hydrogels for anticancer drug *** is anticipated that this review can stimulate a new research gateway to facilitate the development of anticancer drug delivery by harnessing the unique properties of GO based hydrogels,such as large surface area,chemical purity,high loading capacity of drug,chemical stability,and the nature of lipophilic for cell membrane penetration.

关键词： graphe ne oxide cancer nan otechnology hydrogel nanocarrier drug delivery

A new fractional order 6D chaotic model:Study of model dynamics,system structure graph,electronic circuit realization and fractional control

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Journal of Ocean Engineering and science 2024年第2期9卷 112-125页

作者： M.Higazy Norah Almalki Shabbir Muhammad A.Al-Ghamdi Department of Mathematics and Statistics College of ScienceTaif UniversityP.O.Box 11099Taif 21944Saudi Arabia Department of Physics and Engineering Mathematics Faculty of Electronic EngineeringMenoufia UniversityMenouf 32952Egypt research center for advanced materials science(RCAMS) King Khalid UniversityP.O.Box 9004Abha 61413Saudi Arabia Department of Chemistry College of ScienceKing Khalid UniversityP.O.Box 9004Abha 61413Saudi Arabia Department of Physics Faculty of ScienceKing Abdulaziz UniversityP.O.Box 80203Jeddah 21589Saudi Arabia

A new fractional 6D chaotic model is constructed in this *** new fractional 6D chaotic model has six positive parameters plus the fractional order with eight nonlinear *** complicated chaotic dy-namics of the new fractional 6D model is presented and *** basic properties of this model are studied and its chaotic attractors,dissipative feature,symmetry,equilibrium points,Lyapunov Exponents are *** new dynamics of the 6D fractional model is numerically simulated using Matlab *** addition,utilizing the graph theory tools certain structural characteristics are *** electrical circuit is built to implement the new 5.4 fractional order 6D ***,an active fractional order controller is proposed to control the new model at different fractional *** chaos of the new model is very useful and can be used to produce random keys for data encryption.

关键词： Chaotic systems Fractional calculus Lyapunov exponents Chaotic attractors Adjacency matrix Hermitian matrix Electronic circuit realization

Engineering of responsive polymer based nano-reactors for facile mass transport and enhanced catalytic degradation of 4-nitrophenol

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Journal of Environmental sciences 2018年第10期30卷 43-52页

作者： Robina Begum Zahoor HFarooqi Zonarah Butt Qingshi Wu Weitai Wu Ahmad Irfan Centre for Undergraduate studies University of the Punjab New Campus Institute of Chemistry University of the Punjab New Campus State Key Laboratory for Physical Chemistry of Solid Surfaces Department of Chemistry College of Chemistry and Chemical EngineeringXiamen University Department of Chemistry Faculty of Science King Khalid University research center for advanced materials science King Khalid University

Silver nanoparticles with average diameter of 10 ± 3 nm were synthesized within the sieves of poly（N-isopropylacrylamide-2-hydroxyethylmethacrylate-acrylic acid）（p（NIPAAm-HEMA-AAc））polymer microgels. Free radial emulsion polymerization was employed for synthesis of p（NIPAAm-HEMA-AAc） polymer microgels. Silver nanoparticles were introduced within the microgels sphere by in situ reduction method. Microgels and hybrid microgels were characterized by Fourier transform infrared spectroscopy, ultra violet-visible spectroscopy,transmission electron microscopy and dynamic light scattering measurements. Catalytic activity of Ag-p（NIPAAm-HEMA-AAc） hybrid microgels was studied using catalytic reduction of 4-nitrophenol（4-NP） as a model reaction in aqueous media. The influence of sodium borohydride（Na BH4） concentration, catalyst dose and 4-NP concentration on catalytic reduction of 4-NP was investigated. A linear relationship was found between catalyst dose and apparent rate constant（kapp）. The mechanism of catalysis by hybrid microgels was explored for further development in this area. The deep analysis of catalytic process reveals that the unique combination of NIPAAm, HEMA and AAc does not only stabilize silver nanoparticles in polymer network but it also enhances the mass transport of hydrophilic substrate like 4-NP from outside to inside the polymer network.

关键词： Polymer microgels Metal nanoparticles Hybrid microgels Catalytic degradation

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Few-layer Ti_(3)CN MXene for ultrafast photonics applications in visible band

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Journal of Materiomics 2023年第1期9卷 44-55页

作者： Zixin Yang Qi Yang Yulin Tian Xianghe Ren Chun Li Yuqian Zu Syed Zaheer Ud Din Lingfeng Gao Jian Wu Hualong Chen Han Zhang Jie Liu Jingliang He Abdullah GAl-Sehemi International School for Optoelectronic Engineering Qilu University of Technology(Shandong Academy of Sciences)Jinan250353China College of Material Chemistry and Chemical EngineeringKey Laboratory of Organosilicon Chemistry and Material TechnologyMinistry of Edu-cationHangzhou Normal UniversityHangzhou311121China College of advanced Interdisciplinary Studies National University of Defense TechnologyChangsha410073China Institute of Microscale Optoelectronics College of Physics and Optoelectronic EngineeringShenzhen UniversityShenzhen518060China Shandong Provincial Engineering and Technical center of Light Manipulations and Shandong Provincial Key Laboratory of Optics and Photonic Device chool of Physics and ElectronicsShandong Normal UniversityJinan250358China State Key Laboratory of Crystal materials Shandong UniversityJinan250100China research center for advanced materials science(RCAMS) King Khalid UniversityAbha61413Saudi Arabia Department of Chemistry College of ScienceKing Khalid UniversityAbha61413Saudi Arabia

Ti_(3)CN,as a typical hetero-MXene,has attracted tremendous attention for its unique ***,its ultrafast photonics applications are still ***,the few-layer Ti_(3)CN MXene was successfully prepared by selective etching and molecular delamination *** nonlinear optical response of few-layer Ti_(3)CN MXene at 640 nm was studied using the open-aperture Z-scan *** asprepared Ti_(3)CN MXene sample exhibited excellent nonlinear saturable absorption characteristics,resulting in the nonlinear absorption coefficient b of4.05×10^(-2)cm/GW,which was one order of magnitude larger than that of black phosphorus(BP)and molybdenum disulfide(MoS_(2)).For the optical modulation applications of few-layer Ti_(3)CN MXene,passively Q-switched(PQS)solid-state visible lasers based on Ti_(3)CN saturable absorber(SA)at 522 nm,607 nm,639 nm,and 721 nm were successfully ***,a Ti_(3)CN-based stable passively mode-locked Pr:YLF red laser was also successfully achieved with a pulse duration of 30 ps,and the corresponding repetition rate was 73.1 *** optical modulation device based on few-layer Ti_(3)CN MXene shows good *** work demonstrates that the tremendous prospects of the few-layer Ti_(3)CN MXene as a visible optical modulation device in ultrafast photonics applications.

关键词： Ti_(3)CN MXene Z-scan Saturable absorber Optical modulator Pulsed visible lasers