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Frontiers of Materials Science 2020年第3期14卷 243-254页

作者： Junqiang Hua Hailiang Chu Ying Zhu Tingting Fang Shujun Qiu Yongjin Zou Cuili Xiang Kexiang Zhang Bin Li Huanzhi Zhang Fen Xu Lixian Sun Guangxi Key Laboratory of Information Materials Guangxi Collaborative Innovation Centre of Structure and Property for New Energy Materialsand School of Materials Science and EngineeringGuilin University of Electronic TechnologyGuilin541004China

Silicon-based material is considered to be one of the most promising anodes for the next-generation lithium-ion batteries(LIBs)due to its rich sources,nontoxicity,low cost and high theoretical specific ***,it cannot maintain a stable electrode structure during repeated charge/discharge cycles,and therefore long cycling life is difficult to be *** address this problem,herein a simple and efficient method is developed for the fabrication of an integrated composite anode consisting of SiO-based active material and current collector,which exhibits a core-shell structure with nitrogen-doped carbon coating on SiO/P *** binder and conductive agent,the volume expansion of SiO active material in the integrated composite anode is suppressed to prevent its *** a current density of 500 mA·g−1,this integrated composite anode exhibits a reversible specific capacity of 458 mA·h·g−1 after 200 ***,superior rate performance and cycling stability are also *** work illustrates a potential method for the fabrication of integrated composite anodes with superior electrochemical properties for high-performance LIBs.

关键词： lithium-ion battery silicon monoxide red phosphorus rate performance integrated composite anode

Rambutan-like hierarchically porous carbon microsphere as electrodematerial for high-performance supercapacitors

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Carbon Energy 2021年第2期3卷 361-374页

作者： Chunfeng Shao Shujun Qiu Guiming Wu Boyang Cui Hailiang Chu Yongjin Zou Cuili Xiang Fen Xu Lixian Sun Guangxi Key Laboratory of Information Materials School of Materials Science and EngineeringGuangxi Collaborative Innovation Center of Structure and Property for New Energy and MaterialsGuilin University of Electronic TechnologyGuilinChina Key Laboratory of Fuel Cell Technology of Guangdong Province School of Chemistry and Chemical EngineeringSouth China University of TechnologyGuangzhouChina

Used as high-performance electrodes,both structural and compositional alterations of carbon materials play very important roles in energy conversion/storage *** in supercapacitors,hierarchical pores and heteroatom doping in carbon materials are *** the rambutan-like hierarchically porous carbon microspheres(PCMs)have been constructed via a hydrothermal treatment,followed by carbonization/*** hierarchically porous microstructure is composed of three-dimensional porous carbon networks,which give rise to a large surface ***,N and O functional groups are introduced in the as-prepared samples,which could generate the extra *** from the interconnected hierarchical and open structure,PCM exhibits outstanding capacitive performance,for example,superior specific capacitance and rate capability(397 and 288 F g^(−1) at 0.5 and 20A g^(−1),respectively),as well as long cycling stability(about 95%capacitance retention after 10,000 cycles).These encouraging results may pave an efficient way to fabricate advanced supercapacitors in the future.

关键词： DTPA glucose hierarchically porous carbon rambutan-like microspheres supercapacitors

Guanine-assisted N-doped ordered mesoporous carbons as efficient capacity decaying suppression materials for lithium–sulfur batteries

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Journal of Materials Science & Technology 2022年第6期101卷 155-164页

作者： Riguang Cheng Yanxun Guan Yumei Luo Chenchen Zhang Yongpeng Xia Sheng Wei Mengmeng Zhao Qi Lin Hao Li Shiyou Zheng Federico Rosei Lixian Sun Fen Xu Hongge Pan School of Material Science&Engineering Guangxi Key Laboratory of Information Materials and Guangxi Collaborative Innovation Center of Structure and Property for New Energy and MaterialsGuilin University of Electronic TechnologyGuilin 541004China School of Mechanical&Electrical Engineering Guilin University of Electronic TechnologyGuilin 541004China School of Material Science&Engineering University of Shanghai for Science&TechnologyShanghai 200093China CentreÉnergie Matériaux et TélécommunicationsInstitut National de la Recherche Scientifique1650 Boul.Lionel BouletVarennesJ3×1S2QuébecCanada School of New Energy Science and Technology Xi’an Technological UniversityChina

Lithium–sulfur(Li–S)batteries are considered promising next-generation energy storage devices due to their high weight capacities and theoretical energy densities,which are significantly higher than those of conventional lithium-ion ***,the sulfur cathode presents two major drawbacks,specifically low specific capacity caused by the poor electrical conductivities of the active materials and fast capacity decay caused by polysulfide dissolution/***,a high-rate and high-stability dendritic material consisting of N-doped ordered mesoporous carbons(NOMCs)was successfully synthesized via a facile and low-cost calcination *** highly ordered mesoporous carbon skeleton limited the growth of the sulfur nanofiller within its channels and provided the necessary electrical contact with the insulating ***,N-doped heteroatoms presented strong binding sites for trapping polysulfide intermediates,achieving high electrochemical activity,which promoted polysulfide conversion *** a result,the prepared NOMC-2/S cathode material with 1.2-1.5 mg cm^(-2)of sulfur displayed excellent electrochemical performance with a high-rate capability of 460.5 m Ah g^(-1)at 1 C,a high specific capacity of 530.9 m Ah g^(-1)after 200 cycles at 0.1 C,and a decay rate of~0.19%per cycle.

关键词： Lithium–sulfur batteries N-doped ordered mesoporous carbons Electrochemistry

Biomass Homogeneity Reinforced Carbon Aerogels Derived Functional Phase-Change Materials for Solar–Thermal Energy Conversion and Storage

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Energy & Environmental Materials 2023年第1期6卷 164-176页

作者： Qingfeng Zhang Tingfeng Xia Qihan Zhang Yucao Zhu Huanzhi Zhang Fen Xu Lixian Sun Xiaodong Wang Yongpeng Xia Xiangcheng Lin Hongliang Peng Pengru Huang Yongjin Zou Hailiang Chu Bin Li School of Material Science&Engineering Guilin University of Electronic TechnologyGuilin 541004China Guangxi Key Laboratory of Information Materials Guangxi Collaborative Innovation Center of Structure and property for new energy and materialsGuilin University of Electronic TechnologyGuilin 541004China School of Material Science&Engineering Beijing University of Chemical TechnologyBeijing 100029China

We deviseda functional form stable compositephase-change materials(PCMs)toachieve a three-dimensional(3D)interconnectedporous carbon aerogel structure for encapsulating polyethyleneglycol(PEG).Anovelhomogeneity reinforced carbonaerogel witha well-interconnected porous structure was constructed bycombining a flexible carbonresource from biomass guar gum with hard-brittle carbonfrom polyimide,to overcome severeshrinkage andpoor mechanical performance of traditionalcarbon *** aerogel-encapsulated PEG produced thenovel composite PCMswithgood structure stability andcomprehensive energy storage *** showed thatthecomposite PCMsdisplayed awell-defined 3Dinterconnected structure,and theirenergy storage capacities were 171.5 and169.5 J/g,which changed onlyslightlyafter 100 thermalcycles,andthe compositescould maintainthe equilibrium temperature at50.0−58.1℃ for about 760.3 *** thermal conductivityofthe compositescould reach0.62 W m^(−1) K^(−1),which effectively enhanced the thermalresponse *** thecomposite PCMs exhibited good leakage-proof performance andexcellent light–thermal *** compressive strengthof thecomposite PCMscan improveupto 1.602 *** indicatethatthisstrategy canbe efficiently usedtodevelop novel composite PCMswithimproved comprehensive thermalperformance and high light–thermal conversion.

关键词： carbon aerogels composite PCMs energy storage capacity solar-thermal conversion

Enhanced hydrogen storage of alanates: Recent progress and future perspectives

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Progress in Natural Science:Materials International 2021年第2期31卷 165-179页

作者： Li Zhao Fen Xu Chenchen Zhang Zhenyue Wang Hanyu Ju Xu Gao Xiaoxu Zhang Lixian Sun Zongwen Liu Guangxi Key Laboratory of Information Materials Guangxi Collaborative Innovation Center of Structure and Property for New Energy and Materials School of Materials Science and Engineering Guilin University of Electronic Technology School of Chemical and Biomolecular Engineering The University of Sydney The University of Sydney Nano Institute The University of Sydney

The global energy crisis and environmental pollution have caused great concern. Hydrogen is a renewable and environmentally friendly source of energy and has potential to be a major alternative energy carrier in the *** to its high capacity and relatively low cost of raw materials, alanate has been considered as one of the most promising candidates for hydrogen storage. Among them, LiAlH4and NaAlH4, as two representative metal alanates, have attracted extensive attention. Unfortunately, the high desorption temperature and sluggish kinetics restrict its practical application. In this paper, the basic physical and chemical properties as well as the hydrogenation/dehydrogenation reaction mechanism of LiAlH4and NaAlH4are briefly reviewed. The recent progress on strategic optimizations toward tuning the thermodynamics and kinetics of the alanate including nanoscaling,doping catalysts and compositing modification are emphatically discussed. Finally, the coming challenges and the development prospects are also proposed in this review.

关键词： Hydrogen storage LiAlH 4 NaAlH 4 Nanoscaling Catalysts Mechanism

Optimizing hydrogen ad/desorption of Mg-based hydrides for energy-storage applications

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Journal of Materials Science & Technology 2023年第10期141卷 221-235页

作者： Zeng-Yi Li Yu-Jia Sun Chen-Chen Zhang Sheng Wei Li Zhao Ju-Lan Zeng Zhong Cao Yong-Jin Zou Hai-Liang Chu Fen Xu Li-Xian Sun Hong-Ge Pan Guangxi Key Laboratory of Information Materials and Guangxi Collaborative Innovation Center of Structure and Property for New Energy and Materials School of Material Science&EngineeringGuilin University of Electronic TechnologyGuilin 541004China Department of Radiology Stanford UniversityStanfordCA 94305USA School of Chemistry and Chemical Engineering Guangxi UniversityNanning 530004China Beijing Advanced Innovation Center for Materials Genome Engineering Institute for Advanced Materials and TechnologyUniversity of Science and Technology BeijingBeijing 100083China School of Chemistry and Chemical Engineering Changsha University Of Science&TechnologyChangsha 410114China Institute of Science and Technology for New Energy Xi’an Technological UniversityXi’an 710021China

Hydrogen energy is expected to be an“ideal fuel”in the era of *** discovery,de-velopment,and modification of high-performance hydrogen storage materials are the keys to the fu-ture development of solid-state hydrogen storage and hydrogen energy *** hydride(MgH_(2)),with its high hydrogen storage capacity,abundant natural reserves,and environmental friend-liness,has been extensively ***,we briefly summarize the typical structure and hy-drogenation/dehydrogenation reaction mechanism of MgH_(2)and provide a comprehensive overview of strategies to effectively tune the thermodynamics and kinetics of Mg-based materials,such as alloy-ing,nanosizing,the introduction of additives,and composite *** substantial efforts,great achievements have been achieved,such as lower absorption/desorption temperatures and better cy-cling ***,some pivotal issues remain to be addressed,such as unfavorable hydro-genation/dehydrogenation factors,harsh conditions,slow kinetics,incomplete dehydrogenation,low hy-drogen purity,expensive catalysts,and a lack of valid exploration of mechanisms in the hydrogena-tion/dehydrogenation ***,some future development prospects of MgH_(2)in energy-efficient conversion and storage have been presented,including advanced manufacturing ways,stabilization of nanostructures,the introduction of additives combined with structural modification,and utilization of advanced characterization techniques.

关键词： Mg-based hydrides Hydrogen storage A lloying Catalysts Mechanism

Enhanced hydrogen evolution performance by 3D ordered macroporous Ru-CoP@NC electrocatalysts

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Rare Metals 2024年第3期43卷 1095-1107页

作者： Chen-Chen Zhang Sheng Wei Li-Xian Sun Yi-Fang Ouyang Fen Xu Hai-Liang Chu Hong-GePan Li-Xin Chen Xue-Zhang Xiao School of Material Science and Engineering Guilin University of Electronic TechnologyGuilin541004China School of Chemistry and Chemical Engineering Guangxi UniversityNanning530004China Shenzhen Institute of Advanced Technology Chinese Academy of SciencesShenzhen518055GuangdongChina Institute of Science and Technology for New Energy Xi'an Technological UniversityXi'an710021China School of Materials Science and Engineering Zhejiang UniversityHangzhou310058China

Electrocatalytic water splitting coupled with sustainable energies is identified as an environmentally friendly and renewable strategy to generate high-quality hydrogen for the fuel ***,the main challenge is to develop high performance,low cost and chemically stable electrocatalysts to decline the energy barriers and enhance the sluggish kinetics of hydrogen evolution reaction(HER).Herein,a three-dimensional hierarchically ordered macroporous Ru-CoP@NC electrocatalyst(3DOM Ru-CoP@NC)derived from ordered macro-microporous metal-organic frameworks has been prepared using the precursor@template and double-solvent *** prepared 3DOM Ru-CoP@NC catalyst exhibits an overpotential of 15 mV(j=10 mA·cm^(-2))and a reaction Tafel slope of 38 mV·dec^(-1)in alkaline electrolyte,which are superior to commercial Pt@C ***,the overpotential and reaction Tafel slope of this catalyst in acidic media are 45 mV and 50 mV·dec^(-1),*** outstanding HER activities of 3DOM Ru-CoP@NC catalysts are ascribed to the 3D highly interconnectedreticular nanospaces that can increase effective reaction active *** N dope d carbon framework improves the electronic properties and ***,the strong interaction of Ru and CoP nanoparticles also boosts the HER *** results indicate that 3DOM Ru-CoP@NC catalysts with high catalytic activities have a broad application prospect in the future.

关键词： Hydrogen evolution reaction Template method 3D ordered macroporous Ru-CoP@NC

Modulated noble metal/2D MOF heterostructures for improved hydrogen storage of MgH_(2)

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Rare Metals 2024年第4期43卷 1672-1685页

作者： Zeng-Yi Li Li-Xian Sun Fen Xu Yu-Mei Luo Yong-Peng Xia Sheng Wei Chen-Chen Zhang Ri-Guang Cheng Chao-Feng Ye Meng-Yuan Liu Ju-Lan Zeng Zhong Cao Hong-Ge Pan School of Material Science and Engineering Guilin University of Electronic TechnologyGuilin541004China School of Chemistry and Chemical Engineering Changsha University of Science and TechnologyChangsha410114China Institute of Science and Technology for New Energy Xi’an Technological UniversityXi’an710021China

The conjugation of external species with twodimensional(2D)materials has broad application *** this study,we have explored the potential of noble metal/2D MOF heterostructures in hydrogen ***,the MgH_(2)-Ni-MOF@Pd system has shown remarkable hydrogen desorption/sorption performances,starting to liberate hydrogen at 1810C,which is 2300C lower than that of pristine *** the catalytic effect of Ni-MOF@Pd,the dehydrogenation apparent activation energy of MgH2 is noticeably decreased from(133.5±17.5)to(34.58±1.87)kJ·moL^(-1),and the hydrogenation apparent activation energy is reduced from(70.41±7.43)to(25.78±4.64)kJ·moL^(-1),which is lowered by 63.4%.The fully-dehydrogenated MgH2-NiMOF@Pd composite rapidly uptakes hydrogen,with 2.62wt%at 100℃and 6.06 wt%at 150℃within 300 s,*** mechanism analysis of MgH2 catalyzed by Ni-MOF@Pd has revealed that the transformation of Mg_2Ni and Mg_2NiH_4 could act as a"hydrogen pump",providing numerous channels for fast diffusion and transport of hydrogen ***,in the dehydrogenation process,the element Pd reacts with MgH_(2)to form the MgPd alloy phase,which makes MgH_(2)take precedence to decompose through the Mg-Pd alloy rather than self-decomposition,further reducing thermal stability and improving de/hydrogenation *** synergistic effect of Mg-Pd,Mg_2Ni,and the special ultra-thin 2D sheet structure of the additive is the main reason for the good hydrogen storage property of MgH_(2)-Ni-MOF@*** findings provide inspiration for designing efficient multifunctional additives with unique morphologies to optimize the hydrogen desorption/sorption behaviors of hydrogen storage materials.

关键词： Hydrogen storage Magnesium hydride 2D metal-organic framework nanosheets Ni/Pd Synergistic catalysis

Remarkable catalysis of spinel ferrite XFe2O4(X=Ni,Co,Mn,Cu,Zn)nanoparticles on the dehydrogenation properties of LiAlH_(4):An experimental and theoretical study

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Journal of Materials Science & Technology 2022年第16期111卷 189-203页

作者： Sheng Wei Jiaxi Liu Yongpeng Xia Huanzhi Zhang Riguang Cheng Lixian Sun Fen Xu Pengru Huang Federico Rosei Aleskey A.Pimerzin Hans Jüergen Seifert Hongge Pan School of Material Science&Engineering Guangxi Key Laboratory of Information Materials and Guangxi Collaborative Innovation Center of Structure and Property for New Energy and MaterialsGuilin University of Electronic TechnologyGuilin 541004China School of Mechanical&Electrical Engineering Guilin University of Electronic TechnologyGuilin 541004China CentreÉnergie Matériaux et TélécommunicationsInstitut National de la Recherche Scientifique1650 Boul.Lionel BouletVarennesJ3×1S2QuébecCanada Samara State Technical University Samara443100Russia Institute for Applied Materials Karlsruhe Institute of TechnologyHermann von Helmholtz Platz 176344 Eggenstein LeopoldshafenGermany School of New Energy Science and Technology Xi’an Technological UniversityXi’an 710021China

Safe,compact,lightweight and cost-effective hydrogen storage is one of the main challenges that need to be addressed to effectively deploy the hydrogen ***_(4),as a solid-state hydrogen storage material,presents several advantages such as high hydrogen storage capacity,low price and abundant ***,neither thermodynamic nor kinetic properties of dehydrogenation for LiAlH_(4)can fulfill the requirements of practical ***,a series of spinel ferrite nanoparticles such as XFe_(2)O_(4)(X=Ni,Co,Mn,Cu,Zn,Fe)were prepared by using the modified thermal decomposition method,and then doped into LiAlH_(4)by using ball *** results show that LiAlH_(4)doped with 7 wt%NiFe_(2)O_(4)starts to release hydrogen at 69.1°C,and the total amount of hydrogen released is 7.29 wt%before 300°*** activation energies of the two-step hydrogen release reactions of LiAlH_(4)doped with 7 wt%NiFe_(2)O_(4)are 42.32 kJ mol^(-1)and 71.42 k J mol,which are 59.0%and 63.6%lower than those of as-received LiAlH_(4),*** the density functional theory(DFT)calculations,we reveal that both the presence of Ni FeOand in-situ formed AlNiin ball-milling decrease the desorption energy barrier of Al-H bonding in LiAlH_(4)and accelerate the breakdown of Al-H bonding through the interfacial charge transfer and the dehybridization of the Al-H ***,the experimental and theoretical results open a new avenue toward designing high effective catalysts applied to LiAlH_(4)as a candidate for hydrogen storage.

关键词： Hydrogen storage Lithium aluminum Spinel ferrite nanoparticles