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The role of morphology on the electrochemical CO_(2) reduction performance of transition metal-based catalysts

Journal of Energy Chemistry 2023年第10期85卷 198-219,I0007页

作者： Umar Mustapha Chidera C.Nnadiekwe Maria Abdulkarim Alhaboudal Umar Yunusa Abdulhakam Shafiu Abdullahi Ismail Abdulazeez Ijaz Hussain Saheed A.Ganiyu Abdulaziz A.Al-Saadi Khalid Alhooshani Department of Chemistry King Fahd University of Petroleum and MineralsDhahran 31261Saudi Arabia Interdisciplinary Research Center for Refining&Advanced Chemicals King Fahd University of Petroleum&MineralsDhahran 31261Saudi Arabia Interdisciplinary Research Center for Membranes and Water Security King Fahd University of Petroleum and MineralsDhahran 31261Saudi Arabia

The continued increase in population and the industrial revolution have led to an increase in atmospheric carbon dioxide(CO_(2)) concentration. Consequently, developing and implementing effective solutions to reduce CO_(2) emissions is a global priority. The electrochemical CO_(2) reduction reaction(CO_(2)RR) is strongly believed to be a promising alternative to fossil fuel-based technologies for the production of value-added chemicals. So far, the implementation of CO_(2)RR is hindered by associated electrochemical reactions, such as low selectivity, hydrogen evolution reaction(HER), and additional overpotential induced in some cases. As a result, it is necessary to conduct a timely evaluation of the state-of-the-art strategies in CO_(2)RR, with a focus on the engineering of the electrocatalytic systems. Catalyst morphology is one factor that plays a critical role in overcoming these drawbacks and significantly contributes to enhancing product selectivity and Faradaic efficiency(FE). This review article summarizes the recent advances in the rational design of electrocatalysts with various morphologies and the influence of these morphologies on CO_(2)RR. To compare literature findings in a meaningful way, the article focuses on results reported under a well-defined period and considers the first three rows of the d-block metal catalysts. The discussion typically covers the design of nanostructured catalysts and the molecular-level understanding of morphology-performance relationship in terms of activity, selectivity, and stability during CO_(2) electrolysis. Among others, it would be convenient to recommend a comprehensive discussion on the morphologies of single metals and heterostructures, with a detailed emphasis on their impact on CO_(2) conversion.

关键词： CO_(2)electroreduction Electrochemical reduction of CO_(2) Morphology Catalysts d-block metals catalysts Faradaic efficiency Selectivity

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