检索结果-南通市图书馆

Realizing interfacial coupled electron/ion transport through reducing the interfacial oxygen density of carbon skeletons for high-performance lithium metal anodes

在线全文

学校读者我要写书评

暂无评论

Journal of Energy Chemistry 2025年第2期101卷 744-750页

作者： Yao-Lu Ye Yan zhou huan Ye Fei-Fei Cao College of Chemistry Huazhong Agricultural University Institute of Applied Mycology College of Plant Science and Technology Huazhong Agricultural University

Lithium plating/stripping occurs at the a node/electrolyte interface which involves the flow of electrons from the current collector and the migration of lithium ions from the solid-electrolyte interphase（SEI）.The dual continuous rapid transport of interfacial electron/ion is required for homogeneous Li ***,we propose a strategy to improve the Li metal anode performance by rationally regulating the interfacial electron density and Li ion transport through the SEI *** key technique involves decreasing the interfacial oxygen density of biomass-derived carbon host by regulating the arrangement of the celluloses precursor *** higher specific surface area and lower interfacial oxygen density decrease the local current density and ensure the formation of thin and even SEI film,which stabilized Li+transfer through the Li/electrolyte ***,the improved graphitization and the interconnected conducting network enhance the surface electronegativity of carbon and enable uninterruptible electron *** result is continuous and rapid coupled interfacial electron/ion transport at the anode/electrolyte reaction interface,which facilitates uniform Li deposition and improves Li anode *** Li/C anode shows a high initial Coulombic efficiency of 98% and a long-term lifespan of over 150cycles at a practical low N/P（negative-to-positive） ratio of 1.44 in full cells.

关键词： Cellulose Electron/ion conducting Interfacial oxygen density Lithium metal batteries Lithium-lean metal anodes

Arbuscular mycorrhizal fungi promote functional gene regulation of phosphorus cycling in rhizosphere microorganisms of Iris tectorum under Cr stress

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

Journal of Environmental Sciences 2025年第5期151卷 187-199页

作者： Sixi zhu huan Mao Suxia Sun Xiuqin Yang Wei Zhao Luying Sheng Zhongbing Chen College of Eco-environment Engineering Guizhou Minzu UniversityThe Karst Environmental Geological Hazard Prevention of Key Laboratory of State Ethnic Affairs CommissionGuiyang 550025China Department of Applied Ecology Faculty of Environmental SciencesCzech University of Life Sciences PragueKamycka 129Praha-Suchdol 16500Czech Republic

The mutualistic symbiotic system formed by clumping arbuscular mycorrhizal fungi(AMF)and plants can remediate heavy metal-contaminated ***,the specific mechanisms underlying the interaction between AMF and inter-root microbial communities,particularly their impact on organic phosphorus(P)cycling,remain *** study investigated the gene regulation processes involved in inter-root soil phosphorus cycling in wetland plants,specifically Iris tectorum,following inoculation with AMF under varying concentrations of chromium(Cr)*** macro-genome sequencing,we analyzed the composition and structure of the inter-root soil microbial community associated with Iris tectorum under greenhouse pot *** results demonstrated significant changes in the diversity and composition of the inter-root soil microbial community following AMF inoculation,with Proteobacteria,Actinobacteria,Chloroflexi,Acidobacteria,and Bacteroidetes being the dominant *** Cr stress,species and gene co-occurrence network analysis revealed that AMF promoted the transformation process of organic phosphorus mineralization and facilitated inorganic phosphorus ***,network analysis of functional genes indicated strong aggregation of(pstS,pstA,pstC,***,phoR,pp-gppA)genes,which collectively enhanced phosphorus uptake by *** findings shed light on the inter-root soil phosphorus cycling process during the co-remediation of Cr-contaminated soil by AMF-Iris tectorum symbiosis,providing valuable theoretical support for the application of AMF-wetland plant symbiosis systems to remediate heavy metal-contaminated soil.

关键词： Metagenome Arbuscular mycorrhizal fungi Phosphorus Iris tectorum Cr

Study on the hydrogen absorption properties of a YGdTbDyHo rare-earth high-entropy alloy

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

International Journal of Minerals,Metallurgy and Materials 2025年第1期32卷 127-135页

作者： Tongyue Li Ziliang Xie Wenjiao zhou huan Tong Dawen Yang Anjia Zhang Yuan Wu Xiping Song State Key Laboratory for Advanced Metals and Materials University of Science and Technology BeijingBeijing 100083China Whole Win(Beijing)Materials Sci.&Tech.Co. Ltd.Beijing 100083China

This study investigated the microstructure and hydrogen absorption properties of a rare-earth high-entropy alloy(HEA),*** indicated that the YGdTbDyHo alloy had a microstructure of equiaxed grains,with the alloy elements distributed *** hydrogen absorption,the phase structure of the HEA changed from a solid solution with an hexagonal-close-packed(HCP)structure to a high-entropy hydride with an faced-centered-cubic(FCC)structure without any secondary phase *** alloy demonstrated a maximum hydrogen storage capacity of 2.33 H/M(hydrogen atom/metal atom)at 723 K,with an enthalpy change(ΔH)of-141.09 kJ·mol^(-1)and an entropy change(ΔS)of-119.14 J·mol^(-1)·K^(-1).The kinetic mechanism of hydrogen absorption was hydride nucleation and growth,with an apparent activation energy(E_(a))of 20.90 kJ·mol^(-1).Without any activation,the YGdTbDyHo alloy could absorb hydrogen quickly(180 s at 923 K)with nearly no incubation period *** reason for the obtained value of 2.33 H/M was that the hydrogen atoms occupied both tetrahedral and octahedral *** results demonstrate the potential application of HEAs as a high-capacity hydrogen storage material with a large H/M ratio,which can be used in the deuterium storage field.

关键词： rare-earth high-entropy alloy hydrogen absorption capacity pressure–composition–temperature curves kinetics

在线全文

学校读者我要写书评

暂无评论

潮汐作用下的沉管隧道竖向位移计算

岩土力学 2021年第10期42卷 2785-2794,2807页

作者：周桓竹寇晓强王延宁汕头大学土木与环境工程系广东汕头515063 汕头大学广东省结构安全与监测工程技术研究中心广东汕头515063 中国矿业大学深部岩土力学与地下工程国家重点实验室江苏徐州221008 中交天津港湾工程研究院天津300222

港珠澳大桥和深中通道工程中跨越深水航道部分均采用了沉管隧道的通过方式,传统理论分析往往将地基简化为多个互不联系的弹簧,忽略了土体的连续性,模型简单、参数少。考虑潮汐荷载影响,将沉管隧道管节等效为置于Vlasov双参数地基上的Tim... 详细信息

港珠澳大桥和深中通道工程中跨越深水航道部分均采用了沉管隧道的通过方式,传统理论分析往往将地基简化为多个互不联系的弹簧,忽略了土体的连续性,模型简单、参数少。考虑潮汐荷载影响,将沉管隧道管节等效为置于Vlasov双参数地基上的Timoshenko梁,以此推导了其竖向变形计算公式,并与Winkler地基上的Timoshenko梁计算模型进行对比分析以验证所提出的计算方法的合理性。以甬江沉管隧道工程为例,分析潮汐荷载影响下的沉管隧道管节接头竖向位移,将两种模型的理论计算结果与实测结果进行对比分析。研究结果表明,基于Vlasov双参数地基上的Timoshenko梁假设的简化模型能更好地描述沉管隧道管节接头竖向位移特征,与实测数据更吻合。该研究结果对沉管隧道的设计计算具有一定指导意义。

关键词：沉管隧道地基−隧道相互作用铁木辛柯梁地基模型循环荷载

Construction of eco-friendly dual carbon dots ratiometric fluorescence probe for highly selective and efficient sensing mercury ion

在线全文

学校读者我要写书评

暂无评论

Journal of Environmental Sciences 2025年第2期148卷 1-12页

作者： Yongli Liu Xiaoyan Su huanjia Liu Guifen zhu Guobei Ge Yuxin Wang Penghui zhou Qingxiang zhou School of Environment Henan Key Laboratory for Environmental Pollution ControlKey Laboratory for Yellow River and Huai River Water Environmental and Pollution ControlMinistry of EducationHenan Normal UniversityXinxiang 453007China College of Chemical Engineering and Environment China University of Petroleum-BeijingBeijing 102249China

In present work,blue carbon dots(b-CDs)were derived from ammonium citrate and guanidine hydrochloride,and red carbon dots(r-CDs)were stemmed from malonate,ethylenediamine and meso-tetra(4-carboxyphenyl)porphin based on facile hydrothermal ***-friendly ratiometric fluorescence probe was innovatively constructed to effectively measure Hg2+utilizing b-CDs and *** developed probe displayed two typical emission peaks at 450 nm from b-CDs and 650 nm from r-CDs under the excitation at 360 *** ion has strong quenching effect on the fluorescence intensity at 450 nm due to the electron transfer process and the fluorescence change at 450 nm was used as the response signal,whereas the fluorescence intensity at 650 nm kept unchangeable which resulted from the chemical inertness between Hg^(2+)and r-CDs,serving as the reference signal in the sensing *** optimal circumstances,this probe exhibited an excellent linearity between the fluorescence response values of F450/F650 and Hg^(2+)concentrations over range of 0.01-10μmol/L,and the limit of detectionwas down to 5.3 nmol/***,this probe was successfully employed for sensing Hg^(2+)in practical environmental water samples with satisfied recoveries of 98.5%-105.0%.The constructed ratiometric fluorescent probe provided a rapid,environmental-friendly,reliable,and efficient platform for measuring trace Hg^(2+)in environmental field.

关键词： Blue carbon dots Red carbon dots Electron transfer Hg^(2+) Eco-friendliness

A composite hydrogel with porous and homogeneous structure for efficient osmotic energy conversion

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Chinese Chemical Letters 2025年第2期36卷 234-238页

作者： Guilong Li Wenbo Ma Jialing zhou Caiqin Wu Chenling Yao huan Zeng Jian Wang College of Materials and Chemistry & Chemical Engineering Chengdu University of Technology

With the impact of energy crisis and environmental problems, it is urgent to develop green sustainable energy. Osmotic energy stored in the salinity difference between seawater and river water is one of the sustainable, abundant, and renewable energy. However, the membranes used to capture osmotic energy by reverse electrodialysis （RED） always suffer from low ion selectivity, low stability and low *** with three-dimensional （3D） networks have shown great potential for ion transportation and energy conversion. In this work, based on the homogeneity and porosity characteristics of acrylamide（AM） hydrogel, as well as the remarkable stability and abundant negative charge of 3-sulfopropyl acrylate potassium salt （SPAK）, a high-performance AM/SPAK cation-selective hydrogel membrane was successfully developed for harvesting osmotic energy. Compared to AM hydrogels, utilizing AM/SPAK as a monomer mixture greatly facilitated the preparation of homogeneous polymers, exhibiting a porous structure, exceptional ion selectivity, and remarkable stability. A maximum output power density of 13.73 W/m2was achieved at a 50-fold NaCl concentration gradient, exceeding the commercial requirement of 5 W/m2. This work broadens the idea for the construction and application of composite hydrogel in high efficiency osmotic energy conversion.

关键词： Cation-selective membrane Osmotic energy Porous structure Power density Stability

Efficient activation of peroxymonosulfate for catalytic degradation of organic pollutants by simultaneously using low-level cobalt ions and calcium carbonate micro-particles

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

Journal of Environmental Sciences 2025年第5期151卷 113-124页

作者： Yu zhou Xiaobo Wang Nan Wang Shuangshuang huang Lihua zhu College of Chemistry and Chemical Engineering Huazhong University of Science and TechnologyWuhan 430074China College of Chemistry and Chemical Engineering Hubei Polytechnic UniversityHuangshi 435003China College of Chemistry and Environmental Engineering Wuhan Polytechnic UniversityWuhan 430023China School of Physics and Technology Center for Electron MicroscopyWuhan UniversityWuhan 430072China

An efficient catalytic system was developed to remove various organic pollutants by simultaneously using low-level cobalt ions,calcium carbonate micro-particles and peroxymonosulfate(PMS).A simple base-induced precipitation was used to successfully loaded Co-centered reactive sites onto the surface of CaCO_(3)*** optimal conditions at 25°C,10 mg/L methylene blue(MB)could be completely degraded within 10 min with 480μg/L Co^(2+),0.4 g/L CaCO_(3)microparticles(or 0.4 g/L Co@CaCO_(3))and 0.1 g/L *** MB degradation followed the pseudo first order kinetics with a rate constant of 0.583 min^(−1),being 8.3,11.5 and 53.0 times that by using Co-OH(0.07 min^(−1)),Co^(2+)(0.044 min^(−1))and CaCO_(3)(0.011 min^(−1))as the catalyst,*** was confirmed that there was a synergistic effect in the catalytic activity between Co species and the CaCO_(3)particles but the major contributor was the highly dispersed Co *** Co^(2+)-containing simulated electroplating wastewater was used as the Co^(2+)source,not only the added MB was also completely degraded within 5 min in this catalytic system,but also the coexisting heavy metal ions were substantially *** presently developed method was applied to simultaneously treat organic wastewater and heavy metals *** present method was also successfully used to efficiently degrade other organic pollutants including bisphenol A,sulfamethoxazole,rhodamine B,tetrabromobisphenol A,ofloxacin and benzoic acid.A catalytic mechanism was proposed for the PMS activation by Co@CaCO_(3).The surface of CaCO_(3)particles favors the adsorption of Co^(2+).More importantly,the surface of CaCO_(3)particles provides plentiful surface-OH and-CO_(3)^(2+),and these surface groups complex with Co^(2+)to producemore catalytically active species such as surface[CoOH]^(−),resulting in rapid Co^(2+)/Co^(3+)cycling and electron *** interactions cause the observed synergistic effect between Co species and Ca

关键词： CaCO3 Low-level cobalt Peroxymonosulfate Oxidative degradation

Effect of graphene addition on activation and kinetic properties of La-Mg-Ni-based hydrogen storage alloys

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Journal of Iron and Steel Research International 2025年第1期32卷 227-238页

作者： Dian-chen Feng Chun-ling Zheng Zhi-yuan Zhao Dong-sheng zhou Hui-ping Ren Yang-huan Zhang School of Materials and Metallurgy Inner Mongolia University of Science and TechnologyBaotou014010Inner MongoliaChina Collaborative Innovation Center of Integrated Exploitation of Bayan Obo Multi-Metal Resources Inner Mongolia University of Science and TechnologyBaotou014010Inner MongoliaChina Department of Functional Material Research China Iron and Steel Research Institute GroupBeijing100081China

The La_(1.7)Pr_(0.3)Mg_(16)Ni hydrogen storage alloy was prepared by medium-frequency induction melting,and then the composite hydrogen storage alloy powder of La_(1.7)Pr_(0.3)Mg_(16)Ni+x wt.%(x=0,2,4,and 6)graphene was prepared by ball milling for 10 *** effect of the addition of graphene on the activation and hydrogen de/absorption properties of La_(1.7)Pr_(0.3)Mg_(16)Ni alloy was *** result demonstrated that these composite alloys were composed of La_(2)Mg_(17),La_(2)Ni_(3),and Mg_(2)Ni *** saturated hydrogen absorption,it was composed of LaH_(3),Mg_(2)NiH_(4),and MgH_(2)phases,while during the dehydrogenation process,it was composed of LaH_(3),Mg,and Mg_(2)Ni *** addition of graphene can help get a more homogeneous granule after ball milling and accelerate the first activation of dehydrogenation/hydrogen *** hydrogen release activation energy of the alloys first decreases and then increases as the graphene content increases from x=0 wt.%to x=6 wt.%.The minimum activation energy of the composite hydrogen storage alloy is 51.22 kJ mol^(-1) when x=4 wt.%.

关键词： La-Mg-Ni alloy Graphene Mechanical ball milling Activation property Dynamic performance

Classifying extended,localized and critical states in quasiperiodic lattices via unsupervised learning

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Chinese Physics B 2025年第1期34卷 422-427页

作者： Bohan Zheng Siyu zhu Xingping zhou Tong Liu School of Computer Science and Technology School of SoftwareNanjing University of Posts and TelecommunicationsNanjing 210023China Institute of Quantum Information and Technology Nanjing University of Posts and TelecommunicationsNanjing 210003China Department of Applied Physics School of ScienceNanjing University of Posts and TelecommunicationsNanjing 210003China

Classification of quantum phases is one of the most important areas of research in condensed matter *** this work,we obtain the phase diagram of one-dimensional quasiperiodic models via unsupervised ***,we choose two advanced unsupervised learning algorithms,namely,density-based spatial clustering of applications with noise(DBSCAN)and ordering points to identify the clustering structure(OPTICS),to explore the distinct phases of the Aubry–André–Harper model and the quasiperiodic p-wave *** unsupervised learning results match well with those obtained through traditional numerical ***,we assess similarity across different algorithms and find that the highest degree of similarity between the results of unsupervised learning algorithms and those of traditional algorithms exceeds 98%.Our work sheds light on applications of unsupervised learning for phase classification.

关键词： quantum phase quasiperiodic machine learning