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Journal of Energy Chemistry 2024年第8期95卷 540-553,I0012页

作者： Yihan lin liheng li Longjie Tan Yongliang li Xiangzhong Ren Peixin Zhang Chuanxin He lingna Sun College of Chemistry and Environmental Engineering Shenzhen UniversityShenzhen 518060GuangdongChina

Although lithium-sulfur batteries(LSBs)exhibit high theoretical energy density,their practical application is hindered by poor conductivity of the sulfur cathode,the shuttle effect,and the irreversible deposition of li_(2)*** address these issues,a novel composite,using electrospinning technology,consisting of Fe_(3)Se_(4)and porous nitrogen-doped carbon nanofibers was designed for the interlayer of *** porous carbon nanofiber structure facilitates the transport of ions and electrons,while the Fe_(3)Se_(4)material adsorbs lithium polysulfides(liPSs)and accelerates its catalytic conversion ***,the Fe_(3)Se_(4)material interacts with soluble liPSs to generate a new polysulfide intermediate,li_(x)FeS_(y)complex,which changes the electrochemical reaction pathway and facilitates the three-dimensional deposition of li_(2)S,enhancing the reversibility of *** designed LSB demonstrates a high specific capacity of1529.6 mA h g^(-1)in the first cycle at 0.2 *** rate performance is also excellent,maintaining an ultra-high specific capacity of 779.7 mA h g^(-1)at a high rate of 8 *** investigation explores the mechanism of the interaction between the interlayer and liPSs,and provides a new strategy to regulate the reaction kinetics and li_(2)S deposition in LSBs.

关键词： lithium-sulfur batteries Polysulfide intermediates li_(2)S electrodeposition Interlayers Electrostatic spinning Adsorption Catalysis

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地方政府债务:现状、成因与管控

国有经济评论 2013年第1期5卷 126-136页

作者：李中义吉林大学中国国有经济研究中心

2008年世界性金融危机以来,我国地方政府为筹集国家项目配套资金和发展地方经济举借了大量债务。随着债务规模的不断膨胀,地方政府债务在发行、管理和使用各个环节中的问题不断暴露。本文阐述了地方政府债务的现状,分析了地方政府债务... 详细信息

2008年世界性金融危机以来,我国地方政府为筹集国家项目配套资金和发展地方经济举借了大量债务。随着债务规模的不断膨胀,地方政府债务在发行、管理和使用各个环节中的问题不断暴露。本文阐述了地方政府债务的现状,分析了地方政府债务规模超常规增长的原因,提出了对地方政府债务进行控制和管理的对策。

关键词：地方政府债务分税制管理控制

有机物料对喀斯特地区石灰土有效N、Fe、Zn含量的影响

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生态学报 2021年第19期41卷 7743-7750页

作者：李忠意杨希赵新儒程永毅西南大学资源环境学院重庆400716 重庆市巴南区农业技术推广站重庆401320

为研究不同有机物料对喀斯特石灰土元素有效性的影响,采用40 d的室内培养实验,比较了单独添加不同比例(1%、3%、5%)的生物质炭、鸡粪肥、羊粪肥对喀斯特石灰土有效N、Fe、Zn含量的影响。结果表明:添加生物质炭提高了喀斯特石灰土的pH值... 详细信息

为研究不同有机物料对喀斯特石灰土元素有效性的影响,采用40 d的室内培养实验,比较了单独添加不同比例(1%、3%、5%)的生物质炭、鸡粪肥、羊粪肥对喀斯特石灰土有效N、Fe、Zn含量的影响。结果表明:添加生物质炭提高了喀斯特石灰土的pH值,而添加鸡粪肥和羊粪肥降低了喀斯特石灰土的pH值;添加3种有机物料均增加了喀斯特石灰土的有机质含量,大小关系为:生物质炭>鸡粪肥>羊粪肥,但添加鸡粪肥和羊粪肥土壤有机质的化学活性和微生物活性更高。受pH、有机质活性、碳氮比等因素的影响,添加鸡粪肥和羊粪肥能增加土壤有效N含量,但两种有机肥对土壤有效N的提高效果相差不大,而添加生物质炭反而降低了土壤有效N的含量;3种有机物料均能提高土壤的有效Fe和有效Zn含量,其中鸡粪肥效果最佳,其次为羊粪肥和生物质炭。当3种有机物料的添加比例为5%时,生物质炭处理土壤的有效N、Fe、Zn含量分别是对照处理的0.92、1.13、1.21倍;鸡粪肥处理土壤的有效N、Fe、Zn含量分别是对照处理的1.22、1.63和3.39倍;羊粪肥处理土壤的有效N、Fe、Zn含量分别是对照处理的1.27、1.34和2.59倍。所以,相对于生物质炭,有机粪肥对喀斯特地区的石灰土有更好的改良效果。

关键词：喀斯特石灰土生物质炭鸡粪肥羊粪肥有效N、Fe、Zn

Boosting the performance of liNi_(0.90)Co_(0.06)Mn_(0.04)O_(2) electrode by uniform li_(3)PO_(4) coating via atomic layer deposition

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Chinese Chemical Letters 2024年第5期35卷 499-503页

作者： Mingjiao Lu Zhixing Wang Gui Luo Huajun Guo Xinhai li Guochun Yan Qihou li Xianglin li Ding Wang Jiexi Wang School of Metallurgy and Environment Central South UniversityChangsha 410083China BASF ShanShan Battery Materials Co. Ltd.Changsha 410006China Engineering Research Center of the Ministry of Education for Advanced Battery Materials Central South UniversityChangsha 410083China Hunan Provincial Key Laboratory of Nonferrous Value-Added Metallurgy Central South UniversityChangsha 410083China School of Physics and Chemistry Hunan First Normal UniversityChangsha 410205China National and Local Joint Engineering Laboratory for lithium-ion Batteries and Materials Preparation Technology Key Laboratory of Advanced Battery Materials of Yunnan ProvinceFaculty of Metallurgical and Energy EngineeringKunming University of Science and TechnologyKunming 650093China

Ultra-high nickel material is considered to be a promising cathode ***,with the increase of nickel content,the interfacial side reactions between the cathode and electrolyte become increasingly ***,an atomically controllable ionic conductor li_(3)PO_(4)(LPO)coating is deposited on the liNi_(0.90)Co_(0.06)Mn_(0.04)O_(2)(NCM9064)based electrode by the atomic layer deposition *** results shows that the LPO coating is uniformly and densely covered on the surface of secondary particles of NCM9064,helping to prevent the direct contact between the electrolyte and cathode during the chargingdischarging *** addition,the coating layer is electrochemically *** a result,the interfacial side reactions during the long cycle are effectively suppressed,and the solid electrolyte interphase layer at the interface is *** electrode with 20 layers of LPO deposition(ALD-LPO-20)exhibits an excellent capacity retention of 81%after 200 cycles in 2.8-4.3 V at 25℃,which is 18%higher than the unmodified material(ALD-LPO-0).Besides,the moderate LPO coating improves the rate capability and high temperature cycling performance of *** study provides a method for the modification of ultra-high nickel cathode materials and corresponding electrodes.

关键词： Ultra-high nickel material liNi_(0.90)Co_(0.06)Mn_(0.04)O_(2) Atomic layer deposition li_(3)PO_(4) Ionic conductor

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莱州湾渔业资源群落结构和多样性的年际变化

渔业科学进展 2016年第1期37卷 22-29页

作者：杨尧尧李忠义吴强王俊农业部海洋渔业可持续发展重点实验室山东省渔业资源与生态环境重点实验室中国水产科学研究院黄海水产研究所青岛266071 青岛海洋科学与技术国家实验室海洋渔业科学与食物产出过程功能实验室青岛266071

根据2009–2013年每年8月在莱州湾水域进行的渔业底拖网调查数据,采用生态多样性指数和多元统计分析等方法,研究了该海域的渔业资源群落结构和多样性特征的年际变化。结果显示,调查共鉴定出100种资源种类,其中鱼类56种;渔业资源种类和... 详细信息

根据2009–2013年每年8月在莱州湾水域进行的渔业底拖网调查数据,采用生态多样性指数和多元统计分析等方法,研究了该海域的渔业资源群落结构和多样性特征的年际变化。结果显示,调查共鉴定出100种资源种类,其中鱼类56种;渔业资源种类和资源量存在明显的年际变化,2013年渔业资源种类数为2012年种类数的84.4%,仅为2009年的60.3%,平均网获质量明显下降。鱼类优势种组成存在年际更替现象,主要由经济价值高、个体大的种类向经济价值低、个体小的种类演替。各生态多样性指数均呈现下降趋势,Margalef种类丰富度指数(R)变化范围为2.67?3.95,Shannon-Wiener多样性指数(H?)变化范围为0.70?3.83,Pielou均匀度指数(J?)变化范围为0.12?0.63。聚类分析(CLUSTER)和多维标度分析(MDS)分析表明,在相同的相似性水平上分组,组内平均相似性与组间相异性变大。单因子相似性分析(ANOSIM)表明,各年渔业群落结构均存在显著差异(P<0.05)。综上所述,莱州湾渔业资源逐年衰退,优势种更替明显,群落结构发生明显变化,多样性呈下降趋势。

关键词：莱州湾群落结构多样性年际变化

学深悟透笃行习近平法治思想奋力开创新时代延林法院工作新局面

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人民司法 2023年第34期 22-25页

作者：李忠义吉林省延边林区中级法院

人民法院作为国家审判机关,必须始终坚持以习近平新时代中国特色社会主义思想为指导,深刻理解、准确把握、全面贯彻习近平法治思想,在服务大局中充分发挥司法职能作用,以高质量司法服务保障经济社会高质量发展。近年来,吉林延边林区中... 详细信息

人民法院作为国家审判机关,必须始终坚持以习近平新时代中国特色社会主义思想为指导,深刻理解、准确把握、全面贯彻习近平法治思想,在服务大局中充分发挥司法职能作用,以高质量司法服务保障经济社会高质量发展。近年来,吉林延边林区中级法院党组始终将习近平法治思想贯穿法院工作全过程、各方面,以等不起的紧迫感、慢不得的危机感、坐不住的责任感不断育新机、开新局,全力以赴推动实现延边林区两级法院全面高质量发展,在司法为民、服务大局、党建队建、审判执行、新闻宣传等方面做出了有益探索。

关键词：习近平新时代中国特色社会主义思想习近平法治思想国家审判机关司法职能司法服务全面贯彻服务大局司法为民

Layered niobium carbide enabling excellent kinetics and cycling stability of li-Mg-B-H hydrogen storage material Layered niobium carbide enabling excellent kinetics

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Rare Metals 2024年第3期43卷 1153-1166页

作者： li-Wen Lu Hui Luo Guang-Xu li Yun li Xin-Hua Wang Cun-Ke Huang Zhi-QiangLan Wen-Zheng Zhou Jin Guo Mohammad Ismail Hai-Zhen liu Guangxi Novel Battery Materials Research Center of Engineering Technology Guangxi Colleges and Universities Key Laboratory of Blue Energy and Systems IntegrationSchool of Physical Science and TechnologyGuangxi UniversityNanning530004China State Key Laboratory of Featured Metal Materials and life-Cycle Safety for Composite Structures Nanning530004China School of Mechanical and Electrical Engineering Quzhou College of TechnologyQuzhou324000China Department of Materials Science and Engineering Zhejiang UniversityHangzhou310027China Faculty of Ocean Engineering Technology and Informatics Universiti Malaysia Terengganu21030Kuala NerusTerengganuMalaysia Key Laboratory of Advanced Energy Materials Chemistry(Ministry of Education) Nankai UniversityTianjin300071China

The li-Mg-B-H composite(2liBH_(4)+MgH_(2))has a high capacity of 11.4 wt%as a hydrogen storage ***,the slow kinetics and poor cycling stability severely restrict its practical *** this work,a layered Nb_(2)C MXene was first synthesized and then introduced to tailor the kinetics and cycling stability of the li-Mg-B-H *** milled 2liH+MgB_(2)composites were initially hydrogenated to obtain the 2liBH_(4)+MgH_(2)*** 2liBH_(4)+MgH_(2)+5wt%Nb_(2)C can release 9.0 wt%H_(2)in 30 min at 400℃,while it is only 2.7 wt%for the undoped 2liBH_(4)+MgH_(2).The dehydrogenation activation energies of MgH_(2)and liBH_(4)are 123 and 154 kJ·mol^(-1)respectively for the 5 wt%Nb_(2)C-doped composite,lower than the undoped composite(164 and 165 kJ·mol^(-1)).The 2liBH_(4)+MgH_(2)+5 wt%Nb_(2)C possesses excellent cycling stability,with the reversible capacity only slightly reduced from 9.4 wt%for the 1st cycle to 9.3 wt%for the 20th ***_(2)C keeps stable in the composite and acts as an efficient catalyst for the li-Mg-B-H *** is believed that both the layered structure and the active Nb element contribu te to the enhanced hydrogen storage performances of the li-Mg-B-H *** work confirms that the Nb_(2)C MXene with layered stru cture has a significant enhancing impact on the li-Mg-B-H hydrogen storage materials,which is different from the bulk NbC.

关键词： Hydrogen storage lithium borohydride Magnesium hydride Nb_(2)C MXene

Hard-carbon hybrid li-ion/metal anode enabled by preferred mesoporous uniform lithium growth mechanism

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Journal of Energy Chemistry 2024年第1期88卷 252-259,I0006页

作者： Fang Yan Yan liu Yuan li Yan Wang Zicen Deng Meng li Zhenwei Zhu Aohan Zhou Ting li Jingyi Qiu Gaoping Cao Shaobo Huang Biyan Wang Hao Zhang School of Chemistry and Biological Engineering University of Science and TechnologyBeijing 100083China Research Institute of Chemical Defense Beijing 100191China College of Physics and Engineering Henan University of Science and TechnologyLuoyang 471023HenanChina National Base for International Science&Technology Cooperation School of ChemistryXiangtan UniversityXiangtan 411105HunanChina Materials and Manufacturing Department Beijing University of TechnologyBeijing 100124China

To achieve high energy density in lithium batteries,the construction of lithium-ion/metal hybrid anodes is a promising *** particular,because of the anisotropy of graphite,hybrid anode formed by graphite/li metal has low transport kinetics and is easy to causes the growth of lithium dendrites and accumulation of dead li,which seriously affects the cycle life of batteries and even causes safety ***,by comparing graphite with two types of hard carbon,it was found that hybrid anode formed by hard carbon and lithium metal,possessing more disordered mesoporous structure and lithophilic groups,presents better *** indicate that the mesoporous structure provides abundant active site and storage space for dead *** the synergistic effect of this structure and lithophilic functional groups(–COOH),the reversibility of hard carbon/lithium metal hybrid anode is maintained,promoting uniform deposition of lithium metal and alleviating formation of lithium *** hybrid anode maintains a 99.5%Coulombic efficiency(CE)after 260 cycles at a specific capacity of 500 m Ah/*** work provides new insights into the hybrid anodes formed by carbon-based materials and lithium metal with high specific energy and fast charging ability.

关键词： Hard carbon/li metal hybrid anode Mesoporous structure Surface oxygen functional group Fast charging lithium batteries

新型聚氨酯海绵基复合材料及其对水中污染物吸附性能研究进展

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西部皮革 2018年第17期40卷 34-38页

作者：李忠义博天环境集团股份有限公司广州分公司

近年来,性能各异的大量纳米无机吸附剂被广泛应用于废水处理,可以有效去除水中的有机污染物(如染料、苯酚类小分子及抗生素等)和无机污染物(主要为重金属等)。将纳米功能材料在有机表面体进行固定后使用,不仅可以简单重复利用从而大幅... 详细信息

近年来,性能各异的大量纳米无机吸附剂被广泛应用于废水处理,可以有效去除水中的有机污染物(如染料、苯酚类小分子及抗生素等)和无机污染物(主要为重金属等)。将纳米功能材料在有机表面体进行固定后使用,不仅可以简单重复利用从而大幅度降低纳米材料的使用成本,而且有效的避免将纳米材料引入水体造成二次污染,同时对于污泥减量具有重要实际应用价值。其中,聚氨酯海绵体本身具有稳定的化学惰性和良好的机械性能,且其骨架结构表面可以附着大量功能纳米材料,这类复合材料在水处理领域具有科学探究价值和良好的市场应用前景。本文尝试综合近几年国内外聚氨酯海绵基复合材料制备方法及其去除废水中小分子有机污染物、重金属及油水分离等领域的研究现状,希望促进新型聚氨酯海绵体基复合材料在水环境净化应用领域发展。

关键词：聚氨酯海绵复合材料废水处理水污染

Catalytic anode surface enabling in situ polymerization of gel polymer electrolyte for stable li metal batteries

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Nano Research 2024年第6期17卷 5216-5223页

作者： Guocheng li Kang liang Yuanjian li Xiangrui Duan lin Fu Zhao Cai Zhaofu Zhang Jiangnan Dai Yongming Sun Wuhan National Laboratory for Optoelectronics Huazhong University of Science and TechnologyWuhan 430074China The Institute of Technological Sciences Wuhan UniversityWuhan 430074China Faculty of Materials Science and Chemistry China University of Geoscience(Wuhan)Wuhan 430074China

Employing quasi-solid-state gel polymer electrolyte(GPE)instead of the liquid counterpart has been regarded as a promising strategy for improving the electrochemical performance of li metal ***,the poor and uneven interfacial contact between li metal anode and GPE could cause large interfacial resistance and electrochemical li stripping/plating inhomogeneity,deteriorating the electrochemical ***,we proposed that the functional component of composite anode could work as the catalyst to promote the in situ polymerization reaction,and we experimentally realized the integration of polymerized-dioxolane electrolyte and li/li_(22)Sn_(5)/liF composite electrode with low interfacial resistance and good stability by in situ catalyzation ***,the reaction kinetics and stability of metallic li anode were significantly *** a demonstration,symmetric cell using such a GPE-li/li_(22)Sn_(5)/liF integration achieved stable cycling beyond 250 cycles with small potential hysteresis of 25 mV at 1 mA·cm^(−2)and 1 mAh·cm^(−2),far outperforming the counterpart regular GPE on pure *** with liNi0.5Co0.3Mn0.2O2,the full cell with the GPE-li/li_(22)Sn_(5)/liF integration maintained 85.7%of the original capacity after 100 cycles at 0.5 C(1 C=200 mA·g^(−1)).Our research provides a promising strategy for reducing the resistance between GPE and li metal anode,and realizes li metal batteries with enhance electrochemical performance.

关键词： catalyzation polymerization interface resistance interfacial stability li metal batteries electrochemical performance