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Nucleophiles promotes the decomposition of electrophilic functional groups of tetracycline in ZVI/H_(2)O_(2) system: Efficiency and mechanism

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Chinese Chemical Letters 2024年第10期35卷 414-420页

作者： Xin Li Wanting Fu Ruiqing guan Yue Yuan Qinmei zhong Gang Yao Sheng-Tao Yang Liandong Jing Song Bai Key Laboratory of Pollution Control Chemistry and Environmental Functional Materials for Qinghai-Tibet Plateau of the National Ethnic Affairs Commission School of Chemistry and EnvironmentSouthwest Minzu UniversityChengdu 610041China Key Laboratory of General Chemistry of the National Ethnic Affairs Commission School of Chemistry and EnvironmentSouthwest Minzu University.Chengdu 610041China Institute of Environmental Engineering RWTH Aachen UniversityAachen 52062Germany

When zero-valent iron(ZVI)is prepared and applied under neutral conditions,it is easy to form oxides or hydroxides on its surface,which hinders the electron release of *** this end,a nucleophile was introduced into the ZVI system to inhibit the precipitation of iron ions,improve the conductivity of the solution,and promote the removal efficiency of electrophilic functional groups in organic *** this study,the addition of nucleophiles such as ethylenediamine,methylamine and dimethylamine to the ZVI/H_(2)O_(2)system resulted in an enhanced removal efficiency of tetracycline(TC)under neutral condition,while electrophiles such as EDTA-2Na and oxalic acid dihydrate impeded the removal of *** results demonstrated that the presence of nucleophiles could effectively promote the release of iron ions and increase the proportion of ferrous in both aqueous solution and solid surface of *** and theoretical calculation results revealed that the electrophilic functional group was eliminated in the TC molecule,and the toxicity of the treated solution was reduced ***,this work provides a selection of the conditions and pollutants applicable to ZVI under neutral pH conditions.

关键词： ZVI Nucleophiles Tetracycline Electrophilicfunctionalgroup Electronic transfer

Preoperatively predicting vessels encapsulating tumor clusters in hepatocellular carcinoma:Machine learning model based on contrast-enhanced computed tomography

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World Journal of Gastrointestinal Oncology 2024年第3期16卷 857-874页

作者： Chao Zhang hai zhong Fang Zhao Zhen-Yu Ma Zheng-Jun Dai Guo-Dong Pang Department of Radiology The Second Hospital of Shandong UniversityJinan 250033Shandong ProvinceChina Department of Radiology Qilu Hospital of Shandong UniversityJinan 250014Shandong ProvinceChina Department of Radiology Linglong Yingcheng HospitalYantai 265499Shandong ProvinceChina Department of Scientific Research Huiying Medical Technology Co.LtdBeijing 100192China

BACKGROUND Recently,vessels encapsulating tumor clusters(VETC)was considered as a distinct pattern of tumor vascularization which can primarily facilitate the entry of the whole tumor cluster into the bloodstream in an invasion independent manner,and was regarded as an independent risk factor for poor prognosis in hepatocellular carcinoma(HCC).AIM To develop and validate a preoperative nomogram using contrast-enhanced computed tomography(CECT)to predict the presence of VETC+in *** We retrospectively evaluated 190 patients with pathologically confirmed HCC who underwent CECT scanning and immunochemical staining for cluster of differentiation 34 at two medical *** analysis was conducted on intratumoral and peritumoral regions in the portal vein *** features,essential for identifying VETC+HCC,were extracted and utilized to develop a radiomics model using machine learning algorithms in the training *** model’s performance was validated on two separate test *** operating characteristic(ROC)analysis was employed to compare the identified performance of three models in predicting the VETC status of HCC on both training and test *** most predictive model was then used to constructed a radiomics nomogram that integrated the independent clinical-radiological *** and decision curve analysis were used to assess the performance characteristics of the clinical-radiological features,the radiomics features and the radiomics *** The study included 190 individuals from two independent centers,with the majority being male(81%)and a median age of 57 years(interquartile range:51-66).The area under the curve(AUC)for the combined radiomics features selected from the intratumoral and peritumoral areas were 0.825,0.788,and 0.680 in the training set and the two test sets.A total of 13 features were selected to construct the *** nomogram,combining clinicalradiological and combined radiomics features could acc

关键词： Hepatocellular carcinoma Vessels encapsulating tumor clusters Intratumoral and peritumoral regions Radiomics features Nomog

Comparative transcriptomic evidence of physiological changes and potential relationships in vertebrates under different dormancy states

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Zoological Research 2024年第2期45卷 341-354页

作者： Yu-Han Niu Li-Hong guan Cheng Wang hai-Feng Jiang Guo-Gang Li Lian-Dong Yang Shun-Ping He State Key Laboratory of Freshwater Ecology and Biotechnology Institute of HydrobiologyChinese Academy of SciencesWuhanHubei 430072China College of Life Sciences Qinghai Normal UniversityXiningQinghai 810008China Academy of Plateau Science and Sustainability Qinghai Normal UniversityXiningQinghai 810016China Key Laboratory of Biodiversity Formation Mechanism and Comprehensive Utilization of the Qinghai-Tibet Plateau in Qinghai Province Qinghai Normal UniversityXiningQinghai 810008China College of Life Sciences and Technology Xinxiang Medical UniversityXinxiangHenan 453003China College of Animal Science and Technology Northwest A&F UniversityYanglingShaanxi 712100China

Dormancy represents a fascinating adaptive strategy for organisms to survive in unforgiving *** a period of dormancy,organisms often exhibit exceptional *** period is typically divided into hibernation and aestivation based on seasonal ***,the mechanisms by which organisms adapt to their environments during dormancy,as well as the potential relationships between different states of dormancy,deserve further ***,we selected Perccottus glenii and Protopterus annectens as the primary subjects to study hibernation and aestivation,*** on histological and transcriptomic analysis of multiple organs,we discovered that dormancy involved a coordinated functional response across *** analyses revealed noteworthy disparities between the two dormant species in their responses to extreme ***,similarities in gene expression patterns pertaining to energy metabolism,neural activity,and biosynthesis were noted during hibernation,suggesting a potential correlation between hibernation and *** further explore the relationship between these two phenomena,we analyzed other dormancy-capable species using data from publicly available *** comparative analysis revealed that most orthologous genes involved in metabolism,cell proliferation,and neural function exhibited consistent expression patterns during dormancy,indicating that the observed similarity between hibernation and aestivation may be attributable to convergent *** conclusion,this study enhances our comprehension of the dormancy phenomenon and offers new insights into the molecular mechanisms underpinning vertebrate dormancy.

关键词： Hibernation Aestivation Multi-organs Convergent evolution

Polymer-on-HOF:a new strategy for fabricating“armour-plated”HOFs to sequester radioactive anions

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Science China Chemistry 2024年第9期67卷 2958-2967页

作者： hai-Ruo Li Shitao Wu Xuezhuo Jing Zhengyi Di Kun Liu Lu Wang Cheng-Peng Li zhong Liu Miao Du College of Chemistry Tianjin Key Laboratory of Structure and Performance for Functional MoleculesTianjin Normal UniversityTianjin 300387China Shanghai Key Laboratory of High-Resolution Electron Microscopy School of Physical Science and TechnologyShanghaiTech UniversityShanghai 201210China Key Laboratory of Comprehensive and Highly Efficient Utilization of Salt Lake Resources Qinghai Provincial Key Laboratory of Resources and Chemistry of Salt LakesQinghai Institute of Salt LakesChinese Academy of SciencesXining 810008China College of Material and Chemical Engineering Institute of New Energy Science and TechnologySchool of Future Hydrogen Energy TechnologyZhengzhou University of Light IndustryZhengzhou 450001China

The development of hydrogen-bonded organic frameworks(HOFs)faces significant constraints,primarily attributed to their fragile architectures and limited functionalization *** overcome these limitations,this work presents a new polymeron-HOF strategy by covalently tethering armor-like polymers onto the surface of *** application of this approach not only bolsters the stability of HOFs,but also facilitates the customization of their functional expansion in radionuclide *** optimized HOF-polymer materials display extraordinary ability in radionuclide sequestration,achieving uptake of I^(-)(0.699 g g^(-1)),IO_(3)^(-)(0.285 g g^(-1))and ReO_(4)^(-)(1.616 g g^(-1),setting a world record),fast adsorption kinetics(~100% removal within 45 s),and exceptional regeneration capability(>30 cycles)under continuous flow *** outstanding performances benefit from the internal porous channels and surface imidazolium polymer coatings of HOFs,as proved by density functional theory calculation and molecular dynamics *** work paves the way for the rational design of HOF-based hybrid materials tailored to versatile applications.

关键词： hydrogen-bonded organic frameworks(HOFs) post-synthetic modification radionuclide sequestration

Enhanced Photocatalytic CO_(2) Reduction via Linkage Substitution in Porphyrinic Covalent Organic Frameworks

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CCS Chemistry 2024年第7期6卷 1689-1697页

作者： Suleman Suleman Kang Sun Yiming Zhao Xinyu guan zhongyuan Lin Zheng Meng hai-Long Jiang Department of Chemistry University of Science and Technology of ChinaHefeiAnhui 230026

A catalytic performance is greatly impacted by the microenvironment surrounding the catalytic ***,efforts to modify the microenvironment are primarily directed towards the first coordination spheres,while controlling the secondary coordination spheres is entirely *** this work,a series of porphyrin-based covalent organic frameworks(COFs)with distinct linkage were rationally designed to investigate the structure-property relationship between the secondary coordination spheres of catalytic centers and CO_(2) *** secondary coordination spheres of COFs could be changed readily by manipulating the organic *** photocatalytic CO_(2) reduction,the COF withβ-ketoenamine as the linkage(NiPor-BDOB)exhibited superior activity,selectivity,and stability over its imine-linked counterpart(NiPor-BDA).Experiments and theoretical calculations indicated that the distinct secondary coordination sphere resulted in an electronic density change of Ni centers,leading to enhanced photocatalytic *** study highlights the significance of controlling the secondary coordination sphere around the active site.

关键词： covalent organic frameworks linkage substitution photocatalysis CO_(2)reduction activity selectivity

Pulsations of Three Rapidly Oscillating Ap Stars TIC 96315731,TIC72392575,and TIC 318007796

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Research in Astronomy and Astrophysics 2024年第8期24卷 157-168页

作者： hai-Jian zhong Dong-Xiang Shen Chun-Hua Zhu He-Lei Liu Su-Fen Guo Guo-Liang Lü School of Physical Science and Technology Xinjiang UniversityUrumqi 830046China Xinjiang Astronomical Observatory National Astronomical ObservatoriesChinese Academy of SciencesUrumqi 830000China

We analyze the frequencies of three known roAp stars,TIC 96315731,TIC 72392575,and TIC 318007796,using the light curves from the Transiting Exoplanet Survey *** TIC 96315731,the rotational and pulsational frequencies are 0.1498360 day^(-1)and 165.2609 day^(-1),*** the case of TIC 72392575,the rotational frequency is 0.25551 day^(-1).We detect a quintuplet of pulsation frequencies with a center frequency of135.9233 day^(-1),along with two signals within the second pair of rotational sidelobes of the quintuplet separated by the rotation *** two signals may correspond to the frequencies of a dipole *** TIC318007796,the rotational and pulsational frequencies are 0.2475021 day^(-1),192.73995 day^(-1),and196.33065 day^(-1),*** on the oblique pulsator model,we calculate the rotation inclination(i)and magnetic obliquity angle(b)for the stars,which provide the geometry of the pulsation *** the phases of the frequency quintuplets,the pulsation amplitude and phase modulation curves,and the results of spherical harmonic decomposition,we conclude that the pulsation modes of frequency quintuplets in TIC96315731,TIC 72392575,and TIC 318007796 correspond to distorted dipole mode,distorted quadrupole mode,and distorted dipole mode,respectively.

关键词： asteroseismology-techniques photometric-stars oscillations(including pulsations)-stars chemically peculiar

Molecular mechanism of a coastal cyanobacterium Synechococcus *** 7002 adapting to changing phosphate concentrations

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Marine Life Science & Technology 2024年第3期6卷 562-575页

作者： Qiao-Wei Sun Yu Gao Jordan Wang Fei-xue Fu Cheng-Wen Yong Shuang-Qing Li hai-Long Huang Wei-zhong Chen Xin-Wei Wang hai-Bo Jiang School of Marine Sciences Ningbo UniversityNingbo 315211China Southern Marine Science and Engineering guangdong Laboratory(Zhuhai) Zhuhai 519080China School of Life Sciences Central China Normal UniversityWuhan 430079China Department of Biological Sciences University of Southern CaliforniaLos AngelesCA 90089USA

Phosphorus concentration on the surface of seawater varies greatly with different environments,especially in *** molecular mechanism by which cyanobacteria adapt to fluctuating phosphorus bioavailability is still *** this study,transcriptomes and gene knockouts were used to investigate the adaptive molecular mechanism of a model coastal cyanobacterium Synechococcus *** 7002 during periods of phosphorus starvation and phosphorus recovery(adding sufficient phosphorus after phosphorus starvation).The findings indicated that phosphorus deficiency affected the photosynthesis,ribosome synthesis,and bacterial motility pathways,which recommenced after phosphorus was *** more,most of the metabolic pathways of cyanobacteria were enhanced after phosphorus recovery compared to the control which was kept in continuous phosphorus replete *** on transcriptome,54 genes potentially related to phosphorusdeficiency adaptation were selected and knocked out individually or in *** was found that five mutants showed weak growth phenotype under phosphorus deficiency,indicating the importance of the genes(A0076,A0549-50,A1094,A1320,A1895)in the adaptation of phosphorus *** mutants were found to grow better than the wild type under phosphorus deficiency,suggesting that the products of these genes(A0079,A0340,A2284–86)might influence the adaptation to phosphorus *** analysis revealed that cyanobacteria exposed to highly fluctuating phosphorus concentrations have more sophisticated phosphorus acquisition *** results elucidated that Synechococcus *** 7002 have variable phosphorus response mechanisms to adapt to fluctuating phosphorus concentration,providing a novel perspective of how cyanobacteria may respond to the complex and dynamic environments.

关键词： Synechococcus sp PCC 7002 Phosphorus fluctuation Cyanobacteria ・Gene knockout Molecular mechanism

Geology and mineralization of the Dongping supergiant alkalic-hosted Au-Te deposit(>100 t Au)in Northern Hebei Province,China:A review

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China Geology 2024年第3期7卷 533-550页

作者： Shi-min Zhen Da-zhao Wang zhong-jian Zha hai-jun Bai Jiang Wang Development and Research Center of China Geological Survey Ministry of Natural ResourcesBeijing 100037China Technical Guidance Center for Mineral Resources Exploration Ministry of Natural ResourcesBeijing 100037China State Key Laboratory of Nuclear Resources and Environment East China University of TechnologyNanchang 330013China Institute of Geological Surveying and Mapping Technology of Anhui Province Hefei 230022China Third Geological Brigade of Hebei Bureau of Geology and Mineral Resources Zhangjiakou 075000China Ulanqab Real Estate Registration Center Ulanqab 012099China

The Dongping deposit is the largest alkalic-hosted gold deposit in China containing>100 t of *** paper presents a new understanding for Dongping ore system,based on the previous *** mineralization originally occurred at 400-380 Ma,simultaneous with emplacement of the Shuiquangou alkaline complex,and was overprinted by the hydrothermal activity in the *** compositions of ores indicate metals of the deposit are mainly provided by the Shuiquangou ***-forming fluids are characterized by increasing oxygen fugacity and decreasing sulfur fugacity,while tellurium fugacity increased in the Stage II-2 and decreased in Stage *** systematic changes are closely related to the processes of mineral precipitation and fluid *** precipitation from Stage Ⅰ to Stage Ⅱ was triggered by fluid boiling,which leads to the precipitation of Pb-Bi-Te,due to decrement of sulfur *** of gas phase containing high concentration of H_2Te leads to precipitation of Te-Au-Ag minerals and native *** on these hypotheses,this paper present a polyphase metallogenic model as *** the Devonian,fluids were released from alkaline magmas,which carried ore-forming materials form the surrounding rocks and precipitate the early *** the Jurassic-Cretaceous,fluorine-rich fluids exsolved from highly factionated Shangshuiquan granite,which extracted and concentrated Au from the Shuiquangou complex and the Sanggan Group metamorphic rocks,and finally formed the Dongping gold deposit.

关键词： Mineralization and alteration Alkaline intrusion Au deposit Physicochemical conditions Metallogenic model Oxygen fugacity Sulfur fugacity Mechanisms of mineral precipitation Fluid boiling Fluorine-enriched fluid Dongping gold deposit North China Craton Mineral exploration engineering

Utilization of 3D printing technology in hepatopancreatobiliary surgery

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Journal of Zhejiang University-Science B(Biomedicine & Biotechnology) 2024年第2期25卷 123-134页

作者： Wujiang SHI Jiangang WANG Jianjun GAO Xinlei ZOU Qingfu DONG Ziyue HUANG Jialin SHENG Canghai guan Yi XU Yunfu CUI Xiangyu zhong Department of Hepatopancreatobiliary Surgery the Second Affiliated Hospital of Harbin Medical UniversityHarbin150086China Department of General Surgery Tangdu HospitalAir Force Medical UniversityXi’an710032China Key Laboratory of Basic Pharmacology of Ministry of Education Zunyi Medical UniversityZunyi563006China Key Laboratory of Functional and Clinical Translational Medicine Fujian Province UniversityXiamen Medical CollegeXiamen361000China Department of Pathology Li Ka Shing Faculty of MedicineThe University of Hong KongHong KongChina Jiangsu Province Engineering Research Center of Tumor Targeted Nano Diagnostic and Therapeutic Materials Yancheng Teachers UniversityYancheng224007China Key Laboratory of Biomarkers and In Vitro Diagnosis Translation of Zhejiang Province Hangzhou310053China Key Laboratory of Gastrointestinal Cancer(Fujian Medical University) Ministry of EducationSchool of Basic Medical SciencesFujian Medical UniversityFuzhou350122China Key Laboratory of Myocardial Ischemia Harbin Medical UniversityMinistry of EducationHarbin150086China

The technology of three-dimensional(3D)printing emerged in the late 1970s and has since undergone considerable development to find numerous applications in mechanical engineering,industrial design,and *** biomedical science,several studies have initially found that 3D printing technology can play an important role in the treatment of diseases in hepatopancreatobiliary *** example,3D printing technology has been applied to create detailed anatomical models of disease organs for preoperative personalized surgical strategies,surgical simulation,intraoperative navigation,medical training,and patient ***,cancer models have been created using 3D printing technology for the research and selection of chemotherapy *** the aim to clarify the development and application of 3D printing technology in hepatopancreatobiliary surgery,we introduce seven common types of 3D printing technology and review the status of research and application of 3D printing technology in the field of hepatopancreatobiliary surgery.

关键词： 3D printing Hepatopancreatobiliary surgery Organ model Cancer model