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Carbon quantum dots modified TiO_(2) composites for hydrogen production and selective glucose photoreforming

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Journal of Energy Chemistry 2022年第1期31卷 201-208,I0006页

作者： Heng Zhao Xinti Yu Chao-Fan Li Wenbei Yu Aiguo Wang zhi-yi hu Steve Larter Yu Li Md Golam Kibria Jinguang hu Department of Chemical and Petroleum Engineering University of Calgary2500 University DriveNWCalgaryAlberta T2N 1N4Canada State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070HubeiChina Nanostructure Research Centre Wuhan University of Technology.Wuhan 430070Hubei.China Department of Geosciences University of Calgary2500 University DriveNWCalgaryAlberta T2N 1N4Canada

Lignocellulosic biomass photoreforming is a promising and alternative strategy for both sustainable H_(2) production and biomass valorization with infinite solar ***,harsh reaction conditions(high alkalinity or toxic organic solvents),with low biomass conversion and selectivity are often reported in *** this work,we report glucose photoreforming for coproduction of H_(2) and arabinose with improved selectivity under neutral condition using carbon quantum dots(CQDs)modified TiO_(2) *** show that the conventional CQDs fabricated by a facile one-step hydrothermal process could be endowed with novel color changing property,due to the particle aggregation under the regulation of incident *** as-fabricated CQDs/TiO_(2) composites with certain colored CQDs could greatly improve glucose to arabinose conversion selectivity(-75%)together with efficient hydrogen evolution(up to 2.43 mmolh^(-1)g^(-1))in *** arabinose is produced via the direct C1-C2 α-scissions mechanism with reactive oxygen species of·O_(2)^(-) and·OH,as evidenced by ^(13)C labeled glucose and the electron spin-resonance(ESR)studies,*** work not only sheds new lights on CQDs assisted photobiorefinery for biomass valorization and H_(2) coproduction,but also opens the door for rationale design of different colored CQDs and their potential applications for solar energy utilization in the noble-metal-free system.

关键词： CQDs Size regulation Hydrogen production Glucose photoreforming Arabinose

Engineering surface framework TiO6 single sites for unprecedented deep oxidative desulfurization

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National Science Review 2024年第5期11卷 303-314页

作者： Shen Yu Zhan Liu Jia-Min Lyu Chun-Mu Guo Xiao-Yu Yang Peng Jiang yi-Long Wang zhi-yi hu Ming-hui Sun Yu Li Li-hua Chen Bao-Lian Su Laboratory of Living Materials at the State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology Nanostructure Research Center Wuhan University of Technology School of Chemistry Chemical Engineering and Life ScienceWuhan University of Technology Laboratory of Inorganic Materials Chemistry University of Namur

Catalytic oxidative desulfurization（ODS） using titanium silicate catalysts has emerged as an efficient technique for the complete removal of organosulfur compounds from automotive fuels. However, the precise control of highly accessible and stable-framework Ti active sites remains highly challenging. Here we reveal for the first time by using density functional theory calculations that framework hexa-coordinated Ti（TiO6） species of mesoporous titanium silicates are the most active sites for ODS and lead to a lower-energy pathway of ODS. A novel method to achieve highly accessible and homogeneously distributed framework TiO6active single sites at the mesoporous surface has been developed. Such surface framework TiO6species exhibit an exceptional ODS performance. A removal of 920 ppm of benzothiophene is achieved at60°C in 60 min, which is 1.67 times that of the best catalyst reported so far. For bulky molecules such as4,6-dimethyldibenzothiophene（DMDBT）, it takes only 3 min to remove 500 ppm of DMDBT at 60°C with our catalyst, which is five times faster than that with the current best catalyst. Such a catalyst can be easily upscaled and could be used for concrete industrial application in the ODS of bulky organosulfur compounds with minimized energy consumption and high reaction efficiency.

关键词： electrostatic interactions framework hexa-coordinated Ti site oxidative desulfurization mesoporous materials self-assembly

Three-dimensional ordered hierarchically porous carbon materials for high performance Li-Se battery

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Journal of Energy Chemistry 2022年第5期31卷 624-636页

作者： Hongyan Li Wenda Dong Chao Li Tarek Barakat Minghui Sun yingying Wang Liang Wu Lang Wang Lei Xia zhi-yi hu Yu Li Bao-Lian Su Laboratory of Inorganic Materials Chemistry(CMI) University of NamurB-5000 NamurBelgium Namur Institute of Structured Matter(NISM) University of NamurB-5000 NamurBelgium State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430074HubeiChina

Developing host materials with high specific surface area, good electron conductivity, and fast ion transportation channel is critical for high performance lithium-selenium(Li-Se) batteries. Herein, a series of three dimensional ordered hierarchically porous carbon(3D OHPC) materials with micro/meso/macropores are designed and synthesized for Li-Se battery. The porous structure is tuned by following the concept of the generalized Murray’s law to facilitate the mass diffusion and reduce ion transport *** optimized 3D Se/OHPC cathode exhibits a very high 2 nd discharge capacity of 651 m Ah/g and retains 361 m Ah/g after 200 cycles at 0.2 C. Even at a high current rate of 5 C, the battery still shows a discharge capacity as high as 155 m Ah/g. The improved electrochemical performance is attributed to the synergy effect of the interconnected and well-designed micro, meso and macroporosity while shortened ions diffusion pathways of such Murray materials accelerate its ionic and electronic conductivities leading to the enhanced electrochemical reaction. The diffusivity coefficient in Se/OHPC can reach a very high value of 1.3 × 10^(-11)cm^(2)/s, much higher than those in single pore size carbon hosts. Their effective volume expansion accommodation capability and reduced dissolution of polyselenides ensure the high stability of the battery. This work, for the first time, established the clear relationship between textural properties of cathode materials and their performance and demonstrates that the concept of the generalized Murray’s law can be used as efficient guidance for the rational design and synthesis of advanced hierarchically porous materials and the great potential of 3D OHPC materials as a practical high performance cathode material for Li-Se batteries.

关键词： 3D ordered hierarchically porous carbon(OHPC) Shuttle effect Cyclability High rate capability The generalized Murray’s law Li-Se batteries

Highly Selective Photocatalytic Conversion of Glucose on Holo-Symmetrically Spherical Three-Dimensionally Ordered Macroporous Heterojunction Photonic Crystal

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CCS Chemistry 2023年第8期5卷 1773-1788页

作者： Ting-Wei Wang zhi-Wen yin yin-Hao Guo Fang-Yuan Bai Jun Chen Wenda Dong Jing Liu zhi-yi hu Lihua Chen Yu Li Bao-Lian Su State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology430070 Wuhan Nanostructure Research Centre(NRC) Wuhan University of Technology430070 Wuhan Laboratory of Inorganic Materials Chemistry(CMI) University of NamurB-5000 Namur

Photocatalytic conversion of biomass is considered an effective,clean,and environmentally friendly route to obtain high-valued chemicals and ***,the limited conversion efficiency and poor selectivity are still the main bottlenecks for photocatalytic biomass ***,we report the highly selective photocatalytic conversion of glucose solution on holosymmetrically spherical three-dimensionally ordered macroporous TiO_(2)-CdSe heterojunction photonic crystal structure(s-TCS).The obtained s-TCS photocatalysts show excellent stability and strong light harvesting,uniform mass diffusion and exchange,and efficient photogenerated electrons/holes separation and *** optimized s-TCS-4 photocatalyst displays the highest photocatalytic performance for glucose oxidation and hydrogen *** glucose conversion,lactic acid selectivity,and yield on s-TCS-4 are about 95.9%,94.3%,and 96.4%,*** photocatalytic production of lactic acid for s-TCS-4(18.5 g/L)is 2.3 times higher than the pure spherical TiO_(2) photonic crystal without CdSe(s-TiO_(2),8.1 g/L),and the hydrogen production rate of s-TCS-4 is 9.4 times that of s-TiO_(2).For the first time,we reveal that the photocatalytic conversion of glucose to lactic acid is a third-order and four-electron-involved *** work could shed some new light on the efficient photocatalysis conversion of biomass to highly value-added products with high selectivity and yield,and simultaneously sustainable hydrogen evolution.

关键词： TiO_(2)-CdSe heterojunction spherical photonic crystal high-selective photocatalytic glucose conversion lactic acid photocatalytic H2 production four-electron involved reaction third-order reaction

Repetitive transcranial magnetic stimulation in Alzheimer’s disease:effects on neural and synaptic rehabilitation

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Neural Regeneration Research 2025年第2期20卷 326-342页

作者： yi Ji Chaoyi Yang Xuerui Pang yibing Yan Yue Wu zhi Geng Wenjie hu Panpan hu Xingqi Wu Kai Wang Department of Neurology The First Affiliated Hospital of Anhui Medical UniversityHefeiAnhui ProvinceChina Anhui Province Key Laboratory of Cognition and Neuropsychiatric Disorders HefeiAnhui ProvinceChina Collaborative Innovation Center of Neuropsychiatric Disorders and Mental Health HefeiAnhui ProvinceChina Institute of Artificial Intelligence Hefei Comprehensive National Science CenterHefeiAnhui ProvinceChina Department of Psychology and Sleep Medicine The Second Affiliated Hospital of Anhui Medical UniversityHefeiAnhui ProvinceChina

Alzheimer’s disease is a neurodegenerative disease resulting from deficits in synaptic transmission and *** Alzheimer’s disease brain tends to be hyperexcitable and hypersynchronized,thereby causing neurodegeneration and ultimately disrupting the operational abilities in daily life,leaving patients *** transcranial magnetic stimulation is a cost-effective,neuro-modulatory technique used for multiple neurological *** the past two decades,it has been widely used to predict cognitive decline;identify pathophysiological markers;promote neuroplasticity;and assess brain excitability,plasticity,and *** has also been applied to patients with dementia,because it can yield facilitatory effects on cognition and promote brain recovery after a neurological ***,its therapeutic effectiveness at the molecular and synaptic levels has not been elucidated because of a limited number of *** study aimed to characterize the neurobiological changes following repetitive transcranial magnetic stimulation treatment,evaluate its effects on synaptic plasticity,and identify the associated *** review essentially focuses on changes in the pathology,amyloidogenesis,and clearance pathways,given that amyloid deposition is a major hypothesis in the pathogenesis of Alzheimer’s *** mechanisms associated with repetitive transcranial magnetic stimulation procedures and different pathways mediating gene transcription,which are closely related to the neural regeneration process,are also ***,we discuss the outcomes of animal studies in which neuroplasticity is modulated and assessed at the structural and functional levels by using repetitive transcranial magnetic stimulation,with the aim to highlight future directions for better clinical translations.

关键词： Alzheimer’s disease amyloid deposition apoptotic mechanisms biomarker neural regeneration neurodegeneration repetitive transcranial magnetic stimulation synaptic plasticity

Phase-junction Ag/TiO_(2)nanocomposite as photocathode for H_(2)generation

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Journal of Materials Science & Technology 2021年第24期83卷 179-187页

作者： Hemdan S.H.Mohamed Mohamed Rabia Xian-Gang Zhou Xu-Sen Qin Gomaa Khabiri Mohamed Shaban hussein A.Younus S.Taha zhi-yi hu Jing Liu Yu Li Bao-Lian Su State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan430070China Physics Department Faculty of ScienceFayoum UniversityFayoum63514Egypt Nanophotonics and Applications Lab Physics DepartmentFaculty of ScienceBeni-Suef UniversityBeni-Suef62514Egypt Chemistry Department Faculty of ScienceFayoum UniversityFayoum63514Egypt Nanostructure Research Centre(NRC) Wuhan University of TechnologyWuhan430070China Laboratory of Inorganic Materials Chemistry(CMI) University of Namur61 rue de Bruxelles5000NamurBelgium

Developing anatase/rutile phase-junction in Ti O_(2)to construct Z-scheme system is quite effective to improve its photoelectrochemical *** this work,the anatase/rutile phase-junction Ag/Ti O_(2)nanocomposites are developed as photocathodes for hydrogen *** optimized Ag/Ti O_(2)nanocomposite achieves a high current density of 1.28 m A cm-2,an incident photon-to-current conversion efficiency(IPCE)of 10.8%,an applied bias photon-to-current efficiency(ABPE)of 0.32 at 390 nm and a charge carriers’lifetime up to 2000 *** enhancement on photoelectrochemical activity can be attributed to:(ⅰ)the generated Z-scheme system in the anatase/rutile phase-junction Ag/Ti O_(2)photocathode enhances the separation,diffusion and transformation of electron/hole pairs inside the structure,(ⅱ)Ag nanodots modification in the anatase/rutile phases leading to the tuned band gap with enhanced light absorption and(ⅲ)the formed Schottky barrier after Ag nanodots surface modification provides enough electron traps to avoid the recombination of photogenerated electrons and *** results here suggest that developing phase-junction nanocomposite as photocathode will provide a new vision for their enhanced photoelectrochemical generation of hydrogen.

关键词： Ag/TiO_(2)nanocomposites Anatase/rutile phase-junction Z-scheme Photocathode H2 generation

Slow Photon-Enhanced Heterojunction Accelerates Photocatalytic Hydrogen Evolution Reaction to Unprecedented Rates

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CCS Chemistry 2023年第2期5卷 372-384页

作者： Jing Liu yin-Hao Guo zhi-yi hu Heng Zhao Ze-Chuan Yu Lihua Chen Yu Li Gustaaf Van Tendeloo Bao-Lian Su State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology430070 Wuhan Nanostructure Research Centre(NRC) Wuhan University of Technology430070 Wuhan School of Civil Engineering and Architecture Wuhan University of Technology430070 Wuhan EMAT University of AntwerpB-2020 Antwerp Laboratory of Inorganic Materials Chemistry(CMI) University of NamurB-5000 Namur

In photocatalysis,both the photogenerated charge separation and transport and the induced light utilization greatly influence *** this work,highly ordered CdS@ZnO core-shell inverse opal(CdS@ZnO-csIO)nanocomposites have been successfully designed as a model to couple the heterojunction system with the slow photon effect for photocatalytic H2 *** calculations and experimentation provide direct evidence for the slow photon effect in the CdS@ZnO-csIO *** type II heterojunction is responsible for promoting the migration and separation of photogenerated charges,and the slow photon effect is in charge of enhancing light harvesting in the CdS@ZnO-csIO *** synergy of two functions gives rise to a significantly enhanced photocatalytic H2 production rate under simulated solar light for the CdS@ZnO-csIO *** highest H2 production rate reaches 48.7 mmol g^(−1)h^(−1)under simulated solar light with the benchmark performance for all reported CdS@ZnO *** work provides proof-of-principle that coupling the heterojunction system with the slow photon effect can greatly enhance the photocatalytic activity of composite photocatalysts.

关键词： type II heterojunction slow photon effect CdS@ZnO nanocomposites 3D core-shell inverse opal nanocomposites photocatalytic H2 production

Interwoven scaffolded porous titanium oxide nanocubes/carbon nanotubes framework for high-performance sodium-ion battery

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Journal of Energy Chemistry 2021年第8期30卷 38-46,I0002页

作者： Wen-Bei Yu Wen-Da Dong Chao-Fan Li Nasiruddin Macadam Jiu-Xiang Yang Guo-Bin Zhang zhi-yi hu Tien-Chun Wu Yu Li Tawfique Hasan Li-hua Chen Li-Qiang Mai Bao-Lian Su State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China Cambridge Graphene Centre University of Cambridge9 JJ Thomson AvenueCB30FA CambridgeUnited Kingdom Nanostructure Research Centre(NRC) Wuhan University of TechnologyWuhan 430070China Laboratory of Inorganic Materials Chemistry(CMI) University of Namur61 rue de Bruxelles5000 NamurBelgium

Supercapacitor-like Na-ion batteries have attracted much attention due to the high energy density of batteries and power density of *** dioxide(TiO_(2)),is a promising anode *** performance is however seriously hindered by its low electrical conductivity and the sluggish diffusion of sodium ions(Na^(+))in the TiO_(2)***,this work combines porous TiO_(2)nanocubes with carbon nanotubes(CNTs)to enhance the electrical conductivity and accelerate Na^(+)diffusivity for Na-ion batteries(NIBs).In this composite,an interwoven scaffolded TiO_(2)/CNTs framework is formed to provide abundant channels and shorter diffusion pathways for electrons and *** in-situ X-ray diffraction and cyclic voltammetry confirm the low strain and superior transport kinetics in Na^(+)intercalation/extraction *** addition,the chemically bonded TiO_(2)/CNTs hybrid provides a more feasible channel for Na^(+)insertion/extraction with a much lower energy ***,the TiO_(2)/CNTs composite exhibits excellent electrochemical performance with a capacity of 223.4 m Ah g^(-1)at 1 C and a capacity of 142.8 m Ah g^(-1)at 10 C(3.35 A g^(-1)).The work here reveals that the combination of active materials with CNTs can largely improve the utilization efficiency and enhance their sodium storage.

关键词： Supercapacitor-like Interwoven scaffold Na-ion battery TiO_(2) Carbon nanotubes

Bioinspired Noncyclic Transfer Pathway Electron Donors for Unprecedented Hydrogen Production

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CCS Chemistry 2023年第6期5卷 1470-1482页

作者： Jing Liu Chao Wang Wenbei Yu Heng Zhao zhi-yi hu Fu Liu Tawfique Hasan Yu Li Gustaaf Van Tendeloo Can Li Bao-Lian Su State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology430070 Wuhan Nanostructure Research Centre(NRC) Wuhan University of Technology430070 Wuhan School of Materials Science and Engineering Zhejiang University310027 Hangzhou Cambridge Graphene Centre University of CambridgeCambridge CB30FA EMAT(Electron Microscopy for Materials Science) University of AntwerpB-2020 Antwerp State Key Laboratory of Catalysis Dalian Institute of Chemical Physics116023 Dalian Laboratory of Inorganic Materials Chemistry(CMI) University of NamurB-5000 Namur

Electron donors are widely exploited in visible-light photocatalytic hydrogen *** a typical electron donor pair and often the first choice for hydrogen production,the sodium sulfide-sodium sulfite pair has been extensively ***,the resultant thiosulfate ions consume the photogenerated electrons to form an undesirable pseudocyclic electron transfer pathway during the photocatalytic process,strongly limiting the solar energy conversion ***,we report novel and bioinspired electron donor pairs offering a noncyclic electron transfer pathway that provides more electrons without the consumption of the photogenerated *** to the state-of-the-art electron donor pair Na_(2)S-Na_(2)SO_(3),these novel Na_(2)S-NaH_(2)PO_(2)and Na_(2)S-NaNO_(2)electron donor pairs enable an unprecedented enhancement of up to 370%and 140%for average photocatalytic H_(2)production over commercial CdS nanoparticles,and they are versatile for a large series of photocatalysts for visible-light water *** discovery of these novel electron donor pairs can lead to a revolution in photocatalysis and is of great significance for industrial visible-light-driven H_(2)production.

关键词： noncyclic electron transfer Na_(2)SNaH_(2)PO_(2) Na_(2)S-NaNO_(2) electron donor pairs photocatalytic H_(2)production