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Optimizing 3d spin polarization of CoOOH by in situ Mo doping for efficient oxygen evolution reaction

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Carbon Energy 2024年第1期6卷 236-244页

作者： Zhichao Jia Yang Yuan Yanxing Zhang Xiang Lyu Chenhong Liu Xiaoli Yang zhengyu Bai Haijiang wang Lin Yang Key Laboratory of Green Chemical Media and Reactions School of Chemistry and Chemical EngineeringCollaborative Innovation Center of Henan Province for Green Manufacturing of Fine ChemicalsMinistry of EducationHenan Normal UniversityXinxiangHenanChina School of Physics Henan Normal UniversityXinxiangHenanChina Oak Ridge National Laboratory Electrification and Energy Infrastructures DivisionOak RidgeTennesseeUSA Department of Mechanical and Energy Engineering Key Laboratory of Energy Conversion and Storage TechnologiesSouthern University of Science and TechnologyShenzhenGuangdongChina

Transition-metal oxyhydroxides are attractive catalysts for oxygen evolution reactions(OERs).Further studies for developing transition-metal oxyhydroxide catalysts and understanding their catalytic mechanisms will benefit their quick transition to the next ***,Mo-doped CoOOH was designed as a high-performance model electrocatalyst with durability for 20 h at 10 mAcm−***,it had an overpotential of 260 mV(glassy carbon)or 215 mV(nickel foam),which was 78 mV lower than that of IrO_(2)(338 mV).In situ,Raman spectroscopy revealed the transformation process of *** using the density functional theory showed that during OER,doped Mo increased the spin-up density of states and shrank the spin-down bandgap of the 3d orbits in the reconstructed CoOOH under the electrochemical activation process,which simultaneously optimized the adsorption and electron conduction of oxygen-related intermediates on Co sites and lowered the OER *** research provides new insights into the methodical planning of the creation of transition-metal oxyhydroxide OER catalysts.

关键词： electrocatalyst in situ Raman Mo-doped CoOOH oxygen evolution reaction

Resource Allocation for IRS Assistedmm Wave Wireless Powered Sensor Networks with User Cooperation

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工程与科学中的计算机建模(英文) 2024年第1期138卷 663-677页

作者： Yonghui Lin zhengyu Zhu Network Center Zhengzhou UniversityZhengzhou450001China School of Electrical and Information Engineering Zhengzhou UniversityZhengzhou450001China

In this paper,we investigate IRS-aided user cooperation(UC)scheme in millimeter wave(mmWave)wirelesspowered sensor networks(WPSN),where two single-antenna users are wireless powered in the wireless energy transfer(WET)phase first and then cooperatively transmit information to a hybrid access point(AP)in the wireless information transmission(WIT)phase,following which the IRS is deployed to enhance the system performance of theWET *** maximized the weighted sum-rate problem by jointly optimizing the transmit time slots,power allocations,and the phase shifts of the *** to the non-convexity of the original problem,a semidefinite programming relaxation-based approach is proposed to convert the formulated problem to a convex optimization framework,which can obtain the optimal global *** results demonstrate that the weighted sum throughput of the proposed UC scheme outperforms the non-UC scheme whether equipped with IRS or not.

关键词： Intelligent reflecting surface millimeter wave wireless powered sensor networks user cooperation resource allocation

Distal-scanning common path probe for optical coherence tomography

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Journal of Innovative Optical Health Sciences 2024年第3期17卷 84-92页

作者： zhengyu Chen Bin He Zichen Yin Zhangwei Hu Yejiong Shi Chengming wang Xiao Zhang Ning Zhang Linkai Jing Guihuai wang Ping Xue State Key Laboratory of Low-dimensional Quantum Physics and Department of Physics Tsinghua UniversityBeijingChina Frontier Science Center for Quantum Information BeijingChina Jinsp Company Limited BeijingChina Beijing Institute of Technology BeijingChina Institute of Forensic Science Ministry of Public Security BeijingChina Department of Neurosurgery Beijing Tsinghua Changgung HospitalSchool of Clinical Medicine and Institute of Precision MedicineTsinghua UniversityBeijingChina

In this paper,we present a distal-scanning common path probe for optical coherence tomography(OCT)equipped with a hollow ultrasonic motor and a simple and specially designed *** novel probe proves to be able to effectively circumvent polarization and dispersion mismatch caused by fiber motion and is more robust to a variety of interfering factors during the imaging process,experimentally compared to a conventional noncommon path ***,our design counteracts the attenuation of backscattering with depth and the fall-off of the signal,resulting in a more balanced signal range and greater imaging ***-domain OCT imaging of phantom and biological tissue is also demonstrated with a sensitivity of∼100dB and a lateral resolution of∼3μ*** low-cost probe offers simplified system configuration and excellent robustness,and is therefore particularly suitable for clinical diagnosis as one-off medical apparatus.

关键词： Common path optical coherence tomography endoscopic probe

图像中的国家与地方社会——从一套十三世纪的匝嘎利看图像与文字的双向锚固

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西藏大学学报（社会科学版） 2023年第2期38卷 104-111页

作者：王正宇西藏大学中华民族共同体研究院藏拉萨850000

综合利用符号学、历史学、人类学等相关理论、方法与材料,可以发现十三世纪的匝嘎利作品中不仅包含了宗教与艺术,还包含了政治权力等社会性因素。因应多民族国家重新恢复统一的历史进程,僧人发展了特殊的匝嘎利艺术形式,在符号层面实现... 详细信息

综合利用符号学、历史学、人类学等相关理论、方法与材料,可以发现十三世纪的匝嘎利作品中不仅包含了宗教与艺术,还包含了政治权力等社会性因素。因应多民族国家重新恢复统一的历史进程,僧人发展了特殊的匝嘎利艺术形式,在符号层面实现了国家与地方社会的双向锚固。一定程度上,这套匝嘎利反映了当时统一的多民族国家中国家与西藏地方社会的双向互动与建构过程已经深入人心,而不仅仅是国家对西藏地方的政治或文化征服。

关键词：图像国家地方社会双向锚固匝嘎利

Fc receptor-like 5(FCRL5)-directed CAR-T cells exhibit antitumor activity against multiple myeloma

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Signal Transduction and Targeted Therapy 2024年第2期9卷 724-737页

作者： zhengyu Yu Hexian Li Qizhong Lu Zongliang Zhang Aiping Tong Ting Niu Department of Hematology State Key Laboratory of Biotherapy and Cancer CenterWest China HospitalSichuan UniversityChengdu 610041China

Multiple myeloma(MM)remains a challenging hematologic malignancy despite advancements in chimeric antigen receptor T-cell(CAR-T)*** targets of CAR-T cells used in MM immunotherapy have limitations,with a subset of patients experiencing antigen loss resulting in ***,novel targets for enhancing CAR-T cell therapy in MM remain *** receptor-like 5(FCRL5)is a protein marker with considerably upregulated expression in MM and has emerged as a promising target for CAR-T cell therapeutic interventions,offering an alternative treatment for *** further explore this option,we designed FCRL5-directed CAR-T cells and assessed their cytotoxicity in vitro using a co-culture system and in vivo using MM cell-derived xenograft models,specifically focusing on MM with gain of chromosome *** the challenges in CAR-T therapies arising from limited T cell persistence,our approach incorporates interleukin-15(IL-15),which enhances the functionality of central memory T(TCM)cells,into the design of FCRL5-directed CAR-T cells,to improve cytotoxicity and reduce T-cell dysfunction,thereby promoting greater CAR-T cell survival and *** in vitro and xenograft models displayed that FCRL5 CAR-T cells incorporating IL-15 exhibited potent antitumor efficacy,effectively inhibiting the proliferation of MM cells and leading to remarkable tumor *** results highlight the capacity of FCRL5-specific CAR-T cells with the integration of IL-15 to improve the therapeutic potency,suggesting a potential novel immunotherapeutic strategy for MM treatment.

关键词： directed thereby offering

Palladium-Catalyzed[4+2]and[6+2]Dipolar Cycloadditions for the Construction of Benzo[d]isothiazole 1,1-Dioxide Fused 1,3-Oxazinanes and 1,3-Oxazocanes

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Chinese Journal of Chemistry 2024年第8期42卷 829-834页

作者： Lei Chen Hongling Xie Yu Xue zhengyu Han Jianwei Sun Hai Huang Jiangsu Key Laboratory of Advanced Catalytic Materials&Technology School of Petrochemical EngineeringChangzhou UniversityChangzhouJiangsu213164 China Department of Chemistry The Hong Kong University of Science and TechnologyClear Water BayKowloonHong Kong SARChina

Comprehensive Summary,The Pd-catalyzed dipolar cycloaddition represents a significant synthetic strategy for the construction of useful heterocyclic *** study developed the dipolar[4+2]and[6+2]cycloaddition reactions of benzo[d]isothiazole 1,1-dioxides(BDs)leading to the synthesis of BD-fused 1,3-oxazinane and 1,3-oxazocane derivatives,*** particular,the synthesis of BD-fused 1,3-oxazinanes demonstrated regio-and enantioselective characteristics,resulting in products with good yields,enantioselectivity and regioselectivity(if applicable).Furthermore,the[6+2]cycloaddition reaction developed in this work represented the first strategy for the synthesis of medium-sized ring compounds based on BDs.

关键词： Cycloaddition 1,3-Oxazinanes 1,3-Oxazocanes Medium-ring compounds Stereochemistry N-Heterocycles Sulfonamides Enantioselectivity Asymmetricsynthesis

Effects of ambient humidity and thermal aging on properties of Nomex insulation in mining dry‐type transformer

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High Voltage 2021年第1期6卷 71-81页

作者： Lu Li Jiancheng Song Zhipeng Lei Ailiang Kang zhengyu wang Rujia Men Yun Ma Shanxi Key Laboratory of Mining Electrical Equipment and Intelligent Control College of Electrical and Power EngineeringTaiyuan University of TechnologyTaiyuan ShanxiChina Zhengzhou Power Supply Company State Grid Henan Electric Power CompanyZhengzhou HenanChina Jinzhong Power Supply Company State Grid Shanxi Electric Power CompanyJinzhong ShanxiChina

Temperature and humidity are the main factors that cause the decomposition of Nomex paper widely used as turn‐to‐turn insulation material of mining dry‐type transformers. In this study, for understanding the effect of ambient humidity and thermal aging on the properties of Nomex paper, specimens with the initial moisture content of 7% were aged in the oven for 168, 504, 672 h at 180°C, respectively. After thermal aging, corona discharge experiments of unaged and aged specimens with different aging degrees were carried out at different relative humidity (RH) levels from 10 to 70%. The characteristic parameters of corona discharge, such as the average discharge amplitude and the number of discharges, were measured. Then, the surface conductivity and the surface potential decay rate were measured. The morphology and attenuated total internal reflectance Fourier transform infrared spectroscopy were also analysed for explaining the difference of properties be-tween unaged and aged specimens. The experiment results indicate that the average discharge amplitude decreases with the increase of RH or the deepening of the aging degree of specimens, but the number of discharges shows the reversal tendency. The changes in the physical structure and chemical composition, which is induced by the hydrolysis reaction of Nomex paper, accelerate the surface potential decay and increase the surface conductivity.

关键词： aging thermal humidity

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金属膜圆孔阵列异常透射特性的波导机制

光学学报 2022年第4期42卷 220-228页

作者：薛润玉王正宇王正岭江苏大学物理与电子工程学院江苏镇江212013

对线偏振平面波垂直入射到亚微米金属膜圆孔阵列的透射谱进行了研究,优化结构参数后得到的最大透射率可达0.896,远大于圆孔阵列的孔填充比,突破了传统理论的预期。对金属膜圆孔阵列的电场分布、波导模式、相位特征及色散关系等进行了分... 详细信息

对线偏振平面波垂直入射到亚微米金属膜圆孔阵列的透射谱进行了研究,优化结构参数后得到的最大透射率可达0.896,远大于圆孔阵列的孔填充比,突破了传统理论的预期。对金属膜圆孔阵列的电场分布、波导模式、相位特征及色散关系等进行了分析,研究了基于金属膜圆孔波导的异常透射机制。研究发现,表面Bloch波的存在使得金属膜圆孔阵列的上方形成了一套二维周期性的光晶格,并且光晶格的电场分布中心正好在金属膜圆孔部分的上方。当光晶格的电场模式与圆孔中的横向本征电场模式匹配时,将导致较大的耦合效率。如果电场模式沿着圆孔传播时满足相位匹配条件,就能保证圆孔中的光能从圆孔中有效地耦合出来,进而形成较大的透射率。该机制不但可以解释较厚的二维金属膜圆孔阵列的光频段异常透射现象,而且适用于太赫兹波段。如果在圆孔中填充大折射率介质,还可以实现波长远大于孔半径情况下的较大透射率。

关键词：薄膜圆孔阵列透射机制模式特性圆孔波导

Construction of a Metallacyclopentadiene Ring through the Attack of Carbanions to M≡C Bond Followed by C—H Activation

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Chinese Journal of Chemistry 2024年第3期42卷 235-242页

作者： Chun Tang Shengjie Zhang zhengyu Lu Qian Li Ming Luo Dafa Chen Haiping Xia State Key Laboratory of Physical Chemistry of Solid Surfaces College of Chemistry and Chemical EngineeringCollaborative Innovation Center of Chemistry for Energy MaterialsXiamen UniversityXiamenFujian361005 China Shenzhen Grubbs Institute and Guangdong Provincial Key Laboratory of Catalysis Department of ChemistrySouthern University of Science and TechnologyShenzhenGuangdong518055 China

Metallacyclopentadienes are important metallacycles and regarded as intermediates in many reactions,therefore,new methods to achieve them are *** this study,a formal[3+2]method,through the reactions of an osmapentalyne with benzyl carbanions,was *** reactions underwent a nucleophilic attack of carbanions to the Os≡C bond,followed by C—H activation to form the five-membered osmacyclopentadiene *** of the reactions were carried out at room temperature,the substituents on the aromatic rings of benzyl carbanions are diverse,and the resulting products contain an Os—H bond,representing a novel type of 10C-carbolong *** work provides a new convenient route to construct metallacyclopentadienes,which is expected to further promote the development of such a type of substances.

关键词： Metallacyclopentadiene Carbolong chemistry Osmium C–H activation Nucleophilic addition