检索结果-南通市图书馆

“Capture-activation-recapture” mechanism-guided design of double-atom catalysts for electrocatalytic nitrogen reduction

引用

Journal of Energy Chemistry 2024年第9期96卷 437-447页

作者： Cheng he Shiqi Yan Wenxue Zhang State Key Laboratory for Mechanical Behavior of Materials School of Materials Science and EngineeringXi’an Jiaotong UniversityXi’an 710049ShaanxiChina School of Materials Science and Engineering Chang’an UniversityXi’an 710064ShaanxiChina

Compared with the traditional industrial nitrogen fixation, electrocatalytic methods, especially those utilizing double-atom catalysts containing nonmetals, can give good consideration to the economy and environmental protection. However, the existing “acceptance-donation” mechanism is only applicable to bimetallic catalysts and nonmetallic double-atom catalysts containing boron atoms. herein, a novel “capture-activation-recapture” mechanism for metal-nonmetal double-atom catalyst is proposed to solve the problem by adjusting the coordination environments of nonmetallic atoms and utilizing the activation effect of metal atoms on nitrogen. Based on this mechanism, the nitrogen reduction reaction (NRR) activity of 48 structures is calculated by density functional theory calculation, and four candidates are selected as outstanding electrocatalytic nitrogen reduction catalysts: Si-Fe@NG (U_(L) = –0.14 V), Si-Co@NG (U_(L)= –0.15 V), Si-Mo@BP1 (U_(L) = 0 V), and Si-Re@BP1 (U_(L) = –0.02 V). The analyses of electronic properties further confirm “capture-activation-recapture” mechanism and suggest that the difference in valence electron distribution between metal and Si atoms triggers the activation of N≡N bonds. In addition, a machine learning approach is utilized to generate an expression and an intrinsic descriptor that considers the coordination environment to predict the limiting potential. This study offers profound insight into the synergistic mechanism of TM and Si for NRR and guidance in the design of novel double-atom nitrogen fixation catalysts.

关键词： "Capture-activation-recapture"mechanism Double-atom catalyst Nitrogen reduction reaction Density functional theory

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Novel Method for Evaluating the Aging of Aviation Turbine Engine Oils via High-Temperature Bearing Deposit Tests

引用

China Petroleum Processing & Petrochemical Technology 2024年第1期26卷 67-77页

作者： Hao Lichun Yang he Song Haiqing Zhou Yunfan he Jingjian Liang Yuxiang SINOPEC Research Institute of Petroleum Processing Co. Ltd.Beijing 100083

Aviation turbine engine oils require excellent thermal-oxidative stability because of their high-temperature ***-temperature bearing deposit testing is a mandatory method for measuring the thermal-oxidative performance of aviation lubricant oils,and the relevant apparatus was improved in the present *** different commercial aviation turbine engine oils were tested,one with standard performance(known as the SL oil)and the other with high thermal stability,and their thermal-oxidative stability characteristics were *** 100 h of high-temperature bearing testing,the SL oil was analyzed by using various analytical techniques to investigate its thermal-oxidative process in the bearing test,with its thermal-oxidative degradation mechanism also being *** results indicate that the developed high-temperature bearing apparatus easily meets the test requirements of method 3410.1 in standard *** viscosity and total acid number(TAN)of the SL oil increased with the bearing test time,and various deposits were produced in the bearing test,with the micro-particles of the carbon deposits being sphere-like,rod-like,and sheet-like in *** antioxidant additives in the oil were consumed very rapidly in the first 30 h of the bearing test,with N-phenyl-1-naphthylamine being consumed faster than ***,the oil thermal-oxidative process involves very complex physical and chemical mechanisms.

关键词： aviation turbine engine oil high-temperature bearing deposit test thermal-oxidative degradation antioxidant additives

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Geoengineering: proactive measures to tackle climate change

引用

National Science Review 2024年第4期11卷 299-304页

作者：朱禾 the editorial office of NSR in Beijing

As of 20 August, 2023, extensive parts of northern China including the capital city of Beijing had experienced arguably the hottest summer in recent years, recording consecutive days of high temperatures at or near 40°C. Against this backdrop, National Science Review (NSR) organized a web forum on a climate-related topic that needs more exposure to Chinese public and researchers alike:geoengineering.

关键词：

来源：

同方期刊数据库评论

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

No basalt accumulation and segregation atop the 660-km discontinuity beneath the Sea of Okhotsk

引用

Earth and Planetary Physics 2024年第4期8卷 621-631页

作者： BingXin Zhou XiaoBo he Marine Science and Technology College Zhejiang Ocean UniversityZhoushan Zhejiang 316022China

Recent seismic evidence shows that basalt accumulation is widespread in the mantle transition zone(MTZ),yet its ubiquity or sporadic nature remains *** investigate this phenomenon further,we characterized the velocity structure across the 660-km discontinuity that separates the upper mantle from the lower mantle beneath the Sea of Okhotsk by modeling the waveform of the S660P phase,a downgoing S wave converting into a P wave at the 660-km *** waves were excited by two regional>410-km-deep events and were recorded by stations in central *** findings showed no need to introduce velocity anomalies at the base of the MTZ to explain the S660P waveforms because the IASP91 model adequately reproduced the *** finding indicates that the basalt accumulation has not affected the bottom of the MTZ in the study ***,this discontinuity is primarily controlled by temperature or water content variations,or ***,we argue that the basalt accumulation at the base of the MTZ is sporadic,not ubiquitous,reflecting its heterogeneous distribution.

关键词： 660-km discontinuity S660P basalt segregation mantle transition zone western Pacific subduction zone

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Designing novel adaptive dynamic event-triggered protocols for uncertain multi-agent systems

引用

Science China(Information Sciences) 2024年第1期67卷 310-311页

作者： Bin CheNG Bin he College of Electronics and Information Engineering Tongji University Frontiers Science Center for Intelligent Autonomous Systems

Multi-agent systems (MASs) have garnered widespread attention and have been investigated by numerous researchers in recent years, primarily due to their broad applications in industry, transportation, agriculture, and astronomy. While studying the cooperative control of MASs, numerous researchers place emphasis on reducing the frequency of communication among neighboring agents.

关键词： Directed graphs

来源：

同方期刊数据库评论

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

Toxicity mechanisms of photodegraded polyvinyl chloride nanoplastics on pea seedlings

引用

Frontiers of Environmental Science & Engineering 2024年第4期18卷 111-124页

作者： Hao Wu Beibei he Bocheng Chen An Liu College of Chemistry and Environmental Engineering Shenzhen UniversityShenzhen 518060China

Nanoplasctics(NPs),which are very small in particle size,exert toxic effect to ***,compared to original NPs,photodegraded NPs would pose higher *** is because their relatively higher specific surface areas and the presence of additives which can more easily *** original NPs and aged NPs affect plant growth has not been widely *** work chose polyvinyl chloride NPs(PVC-NPs)that were subjected to up to 1000 h UV light radiation to explore the impact of PVC-NPs on the growth of pea seedlings(Pisum Sativum L.).The results indicated the existence of PVC-NPs with longer UV light radiation time and higher concentrations had more negative influences on pea seedlings’growth such as germination rate(decreased by 10.6%–22.5%),stem length(decreased by 2.8%–8.1%),dry weight(decreased by 6.3%–7.1%)and fresh weight(decreased by 6.7%–14.8%).It was also noted that photodegraded PVC-NPs resulted in damage to leaf stomata and roots,hindering photosynthesis and absorption of nutrients and hence the decrease in chlorophyll and soluble sugar *** to transcriptomic investigation results,the presence of aged PVC-NPs primarily influenced protein processing in endoplasmic reticulum(upregulated metabolic pathway)and phenylpropanoid biosynthesis(downregulated metabolic pathway)of pea *** results provide an in-depth understanding of how NPs influence the growth of plants.

关键词： Nanoplasctics Polyvinyl chloride Toxicity mechanisms Plant growth

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Neural Stem Cell Competition

引用

Neuroscience Bulletin 2024年第2期40卷 277-279页

作者： Yanan Li Jie he State Key Laboratory of Neuroscience Institute of NeuroscienceCenter for Excellence in Brain Science and Intelligence TechnologyChinese Academy of SciencesShanghai 200031China University of Chinese Academy of Sciences Beijing 100049China

Cell competition is an adaptive surveillance mechanism to ensure the robustness of developmental outputs,maintain tissue integrity,and regulate tumor progression in multicellular organisms,which is highly conserved from invertebrates to vertebrates[1].At the cellular level,cell competition represents a non-cell-autonomous process in that cells can sense the fitness of their neighbors through cellular interactions,thereby eliminating low-fitness cells and expanding high-fitness counterparts,however,cells develop normally in homogenous populations.

关键词： thereby maintain eliminating

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Illuminating functions of evolutionarily conserved long non-coding RNAs

引用

Science China(Life Sciences) 2024年第9期67卷 2043-2044页

作者： Ruiqiao he Fangqing Zhao Institute of Zoology Chinese Academy of SciencesBeijing 100101China Key Laboratory of Systems health Science of Zhejiang Province Hangzhou Institute for Advanced StudyUniversity of Chinese Academy of SciencesHangzhou 310024China

Long non-coding RNAs(lnc RNAs)serve as crucial regulators of gene expression,influencing various physiological processes and disease states(Cabili et al.,2011;Ulitsky and Bartel,2013;Yao et al.,2019).Dysregulation of certain notable lnc RNAs,such as HOTAIR and MALAT1,has been implicated in a wide range of pathological processes,including tumorigenesis in various human cancers(Gupta et al.,2010;Kim et al.,2018).However,the functions of the majority of lnc RNAs remain elusive.

关键词： MALAT1 HOTAIR

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

The Role of Adipose Tissue-derived Exosomes in Chronic Metabolic Disorders

引用

Current Medical Science 2024年第3期44卷 463-474页

作者： Rui he Yong CheN Division of Endocrinology Department of Internal MedicineTongji HospitalTongji Medical CollegeHuazhong University of Science and TechnologyWuhan430030China Laboratory of Endocrinology & Metabolism Key Laboratory of Vascular Aging of the Ministry of EducationTongji HospitalTongji Medical CollegeHuazhong University of Science and TechnologyWuhan430030China Branch of National Clinical Research Center for Metabolic Diseases Wuhan430030China

Excessive fat deposition in obese subjects promotes the occurrence of metabolic diseases,such as type 2 diabetes mellitus(T2DM),cardiovascular diseases,and non-alcoholic fatty liver disease(NAFLD).Adipose tissue is not only the main form of energy storage but also an endocrine organ that not only secretes adipocytokines but also releases many extracellular vesicles(EVs)that play a role in the regulation of whole-body *** are a subtype of EVs,and accumulating evidence indicates that adipose tissue exosomes(AT Exos)mediate crosstalk between adipose tissue and multiple organs by being transferred to targeted cells or tissues through paracrine or endocrine ***,the roles of AT Exos in crosstalk with metabolic organs remain to be fully *** this review,we summarize the latest research progress on the role of AT Exos in the regulation of metabolic ***,we discuss the potential role of AT Exos as biomarkers in metabolic diseases and their clinical application.

关键词： exosome adipose tissue obesity diabetes chronic metabolic disorder miRNA

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Polymeric hollow fiber membrane for cooling crystallization seeding:On the mechanism of induced nucleation based on thermal transfer Author links open overlay panel

引用

Particuology 2024年第8期91卷 38-49页

作者： Zeman he Shaofu Du Guanying Shao Peiyu Li Lei Sheng Gaohong he Xiaobin Jiang Wu Xiao State Key Laboratory of Fine Chemicals School of Chemical EngineeringEngineering Laboratory for Petrochemical Energy-efficient Separation Technology of Liaoning ProvinceDalian University of TechnologyDalian 116024China

Cooling crystallization is an important separation process and particuology technology that requires accurate nucleation control ***,we introduced the polymeric hollow fiber membrane with proper thermal properties as the effective nucleation induction interface during cooling *** heterogeneous nucleation control mechanism was introduced based on classical nucleation theory and the thermal transfer *** properties and the thermal conductivity of two kinds of polymeric membranes,polytetrafluoroethylene(PTFE)and polyethersulfone(PES),were measured and simulated with the developed *** two membranes possessed different nucleation induction periods,nucleation rates and crystallization performances,which validated that the hollow fiber membrane module could effectively accelerate the nucleation process compared to conventional cooling crystallization owing to the shorter nucleation induction period and the reduced solution surface *** to the higher hydrophobicity and the lower roughness of the membrane surface,the PTFE membrane possessed a more moderate performance in generating stable heterogeneous nucleation than the one of PES ***,the adjustable membrane property enabled the hollow fiber membrane-assisted cooling crystallization to possess the accurate nucleation control and desired terminal particle products.

关键词： Cooling crystallization Nucleation Particle process Hollow fiber membrane Induction period Process control

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

欢迎您,

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案：

请选择收藏分类：

通借通还

欢迎您,

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：