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Processing of a low-costγ-γ'NiPtAl coating with improved oxidation resistance

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Rare Metals 2024年第6期43卷 2832-2841页

作者： Yan Jiang Liang-Liang Wei Jian He hong-Bo guo School of Materials Science and Engineering Beihang UniversityBeijing 100191China Key Laboratory of High-Temperature Structural Materials and Protective Coatings Ministry of Industry and Information TechnologyBeihang UniversityBeijing 100191China

A novelγ-γ'(Ni solid solution—Ni_(3)Al)NiPtAl coating was produced on advanced single-crystal(SC)superalloy N5 by electroplating of a thin Pt coating with~3μm in thickness followed by heat treatment at 1000℃in *** comparison,a traditionalγ-γ'NiPtAl coating was also produced by electroplating of a thick Pt coating with~6μm in thickness followed by heat treatment at 1100℃in *** novel coating has a mass gain of~0.5 mg·cm^(-2)after 100 h 1-h cyclic oxidation at 1150℃,showing better oxidation resistance than the traditional *** oxide scale mostly consisting ofα-Al_(2)O_(3)grew on the novel coating because the element Cr from the SC alloy substrate contributes to the formation ofα-Al_(2)O_(3).Pt content in the novel coating has significant effect on the oxidation *** optimized Pt content in the coating is about 16 at%,which is helpful to reduce the diffusion of harmful elements from the substrate into the coating but also to reduce the cost of the coating.

关键词： γ-γ'NiPtAl coating Platinum Oxidation Al_(2)O_(3) Superalloy

A one-step procedure for facile, selective synthesis of protected d-glucopyranosides with free 2-C hydroxyl group starting from peracetylated β-D-glucopyranose

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Chinese Journal of Chemistry 1996年第2期14卷 190-192页

作者： LIU,Mei-zheng FAN,hong-Ni guo,Zhong-Wu HUI,Yong-zhengNational Laboratory of Bio-Organic and Natural Product Chemistry,Shanghai Institute of Organic Chemistry,Chinese Academy of Sciences,Shanghai 200033,China National Laboratory of Bio‐Organic and Natural Product Chemistry Shanghai Institute of Organic Chemistry Chinese Academy of Sciences Shanghai 200032 China

An important field in carbohydrate chemistry is to look for regioselective re-actions of saccharides to simplify the chemical synthesis of oligosaccharides. Oneof such efforts nowadays is directed to the convenient pr... 详细信息

关键词： One-step reaction protected D-glucopyranosides with free 2-hydroxyl group

BIM-based framework of automatic tunnel segment assembly and deviation control

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Underground Space 2024年第3期16卷 59-78页

作者： Jian Gong Tengfei Bao zheng Zhu hong Yu Yangtao Li The National Key Laboratory of Water Disaster Prevention Hohai UniversityNanjing 210098China College of Water Conservancy and Hydropower Engineering Hohai UniversityNanjing 210098China College of Hydraulic and Environmental Engineering China Three Gorges UniversityYichang 443002China Zhejiang Design Institute of Water Conservancy and Hydro-Electric Power Hangzhou 310002China

The design of universal segments and deviation control of segment assembly are essential for robust and low-risk tunnel construction.A building information modeling(BIM)-based framework was proposed for parametric modeling,automatic assembly,and deviation control of universal ***,segment models of different levels of detail(LoDs)were built based on BIM visual programming language(VPL)for different project life ***,the geometric constraints,requirements,and procedures for parametric segment assembly were distilled to develop a program that combines a novel typesetting algorithm with a 3D path replanning *** is implemented by introducing a point indication matrix,characterizing segments by sides,and manipulating geometries in a ***,3D path replanning,with non-uniform rational B-splines(NURBS)and arcs as basic shapes,was used to resolve unacceptable deviation situations after ***,the proposed framework was validated on a water diversion line and was found to be more effective and accurate than the previous method.

关键词： Parametric generative design BIM Deviation control Typesetting 3D path replanning

Warming intensified the effects of nitrogen addition on N_(2)O emissions from alpine meadow in the northern Qinghai-Tibet Plateau

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Advances in Climate Change Research 2024年第1期15卷 101-112页

作者： Ming-Jie LI Yi-Qing GE Hasbagan GANJURJAV guo-zheng HU hong-Bao WU Jun YAN Shi-Cheng HE Qing-Zhu GAO Institute of Environment and Sustainable Development in Agriculture Chinese Academy of Agricultural SciencesBeijing 100081China National Agricultural Experimental Station for Agricultural Environment Nagqu 852100China Ecology and Nature Conservation Institute Chinese Academy of ForestryBeijing 100091China College of Resource and Environment Anhui Science and Technology UniversityFengyang 233100China Nagqu Agriculture Animal Husbandryand Prataculture Science and Technology Research and Extension CenterNagqu 852100China Tongliao Experimental Middle School Tongliao 028000China

Warming and nitrogen(N)addition may impact soil nitrous oxide(N_(2)O)emissions,but the relationship between plant community composition and soil microbial activities remains *** a two-year field study in the Qinghai-Tibet Plateau,open-top chambers were used to quantify the effects of warming,N-addition,and their interactions on N_(2)O *** found that the N-addition greatly increased N_(2)O emissions by 77.4%in 2018 when compared to the control *** contrast,warming showed little effect on N_(2)0 emissions but did increase the activity of enzymes associated with soil nitrification and denitrification.A combined effect of warming and N-addition of resulted in 208.6%(2018)and 90.8%(2019)increase in N_(2)0 emissions,respectively,compared to the individual treatments of warming or *** warming in alpine meadows is causally linked to increased legume biomass which is further intensified with the *** legume biomass(p<0.05),soil moisture(p<0.001)and enzyme activity(p<0.001)had a positive effect on N_(2)0 emissions,while diminished microbial carbon/nitrogen(MBC/MBN)(p<0.05)correlated with reduced N_(2)O *** results indicated that N-addition has a positive effect on N_(2)O emissions,and the addition of warming further intensifies this *** increased dominance of legumes and microbial N content contributes to this *** outcomes suggest that warming and atmospheric N deposition can stimulate N_(2)O emissions of alpine meadows inthefuture.

关键词： Alpine meadow Community composition Nitrogen addition Nitrous oxide flux Qinghai-Tibet Plateau Warming

Addressing chemoresistance with a lipid gemcitabine nanotherapeutic strategy for effective treatment of pancreatic cancer

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Nano Research 2024年第9期17卷 8377-8388页

作者： Jiawei hong Shiyun Xian Shusen zheng Hangxiang Wang Donghai Jiang The First Affiliated Hospital NHC Key Laboratory of Combined Multi-Organ TransplantationCollaborative Innovation Center for Diagnosis and Treatment of Infectious DiseasesState Key Laboratory for Diagnosis and Treatment of Infectious DiseasesSchool of MedicineZhejiang UniversityHangzhou 310003China Jinan Microecological Biomedicine Shandong Laboratory Jinan 250117China

Resistance to gemcitabine in pancreatic cancer poses a significant clinical *** investigation is warranted to assess whether nano-formulation strategy can be employed to enhance the sensitivity of resistant strains to gemcitabine *** this study,using gemcitabine-resistant pancreatic cancer cell lines,we examined the therapeutic potential of a gemcitabine nanodelivery platform and assessed the ability to overcome drug resistance against resistant *** of human equilibrative nucleoside transporter 1(hENT1)led to reduced cellular uptake of gemcitabine,resulting in chemoresistance in pancreatic *** nanoparticles circumvented the entry blockade caused by hENT1 silencing through *** entry via clathrin-mediated endocytosis increased intracellular gemcitabine accumulation in gemcitabine-resistant pancreatic cancer ***,gemcitabine nanoparticles are preferential in vivo delivery to tumor tissues,likely due to the enhanced permeability and retention *** comparison to free gemcitabine,gemcitabine nanoparticles demonstrate a more pronounced cytotoxic effect on gemcitabine-resistant pancreatic cancer cells,with favorable *** study improved the efficacy of gemcitabine through nanotechnology,providing a novel strategy to address gemcitabine-resistant pancreatic cancer.

关键词： pancreatic cancer gemcitabine resistance gemcitabine nanoparticle human equilibrative nucleoside transporter 1

Effect of solvent on the initiation mechanism of living anionic polymerization of styrene:A computational study

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Chinese Journal of Chemical Engineering 2024年第5期69卷 135-142页

作者： Shen Li Yin-Ning Zhou Zhong-Xin Liu zheng-hong Luo School of Chemical Engineering and Technology Hainan UniversityHaikou 570228China Department of Chemical Engineering School of Chemistry and Chemical EngineeringState Key Laboratory of Metal Matrix CompositesShanghai Jiao Tong UniversityShanghai 200240China

For living anionic polymerization(LAP),solvent has a great influence on both reaction mechanism and *** this work,by using the classical butyl lithium-styrene polymerization as a model system,the effect of solvent on the mechanism and kinetics of LAP was revealed through a strategy combining density functional theory(DFT)calculations and kinetic *** terms of mechanism,it is found that the stronger the solvent polarity,the more electrons transfer from initiator to solvent through detailed energy decomposition analysis of electrostatic interactions between initiator and solvent ***,we also found that the stronger the solvent polarity,the higher the monomer initiation energy barrier and the smaller the initiation rate ***,initiation is more favorable at lower temperatures based on the calculated results ofΔG_(TS).Finally,the kinetic characteristics in different solvents were further examined by kinetic *** is found that in benzene and n-pentane,the polymerization rate exhibits first-order ***,slow initiation and fast propagation were observed in tetrahydrofuran(THF)due to the slow free ion formation rate,leading to a deviation from first-order kinetics.

关键词： Living anionic polymerization Solvent effect Reaction kinetics Computational chemistry Mathematical modeling Kinetic modeling

Mechanical Behavior Based on Aggregates Microstructure of Ultra-high Performance Concrete

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Journal of Wuhan University of Technology(Materials Science) 2024年第3期39卷 673-681页

作者：丁庆军 ZHOU Changsheng 张高展 guo hong LI Yang ZHANG Yongyuan guo Kaizheng School of Materials Science and Engineering Wuhan University of TechnologyWuhan 430070China Advanced Building Materials Key Laboratory of Anhui Province School of Material Science and Chemical EngineeringAnhui Jianzhu UniversityHefei 230601China China Railway 17th Bureau Group Co. Ltd.Taiyuan 030006China

We developed ultra-high performance concrete(UHPC)incorporating mullite sand and brown corundum sand(BCS),and the quartz sand UHPC was utilized to prepare for *** properties of compressive strength,elastic modulus,ultrasonic pulse velocity,flexural strength,and toughness were *** electron microscopy and nanoindentation were also conducted to reveal the underlying mechanisms affecting macroscopic *** to the superior interface bonding properties between mullite sand and matrix,the compressive strength and flexural toughness of UHPC have been significantly *** sand and BCS aggregates have higher stiffness than quartz sand,contributing to the excellent elastic modulus exhibited by *** stiffness and volume of aggregates have a more significant impact on the elastic modulus of UHPC than interface performance,and the latter contributes more to the strength of *** study will provide a reference for developing UHPC with superior elastic modulus for structural engineering.

关键词： ultra-high performance concrete mechanical properties fine aggregates microstructure nanoindentation

Oxidative spirolactonisation for modular access of γ-spirolactones via a radical tandem annulation pathway

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Chinese Chemical Letters 2024年第10期35卷 249-252页

作者： Jindian Duan Xiaojuan Ding Pui Ying Choy Binyan Xu Luchao Li hong Qin zheng Fang Fuk Yee Kwong Kai guo College of Biotechnology and Pharmaceutical Engineering State Key Laboratory of Materials-Oriented Chemical EngineeringNanjing Tech UniversityNanjing 211816China Department of Chemistry and State Key Laboratory of Synthetic Chemistry The Chinese University of Hong KongHong KongChina

An oxidative annulation of 2-arylidene-1,3-indanediones with Meldrum's acid has been developed for the divergent syntheses of spirolactones with a spirocenter located at theγ-position with respect to the carbonyl *** heteroannulation protocol tolerates various functional groups and delivers moderate-to-good product ***,the reaction outcomes are exclusively controlled by the reaction oxidant/*** annulation strategy can also be executed in the flow system with decent product *** experiments revealed that the reaction proceeds via a radical tandem annulation pathway.

关键词： Spirolactonisation y-Spirolactones 2-Arylidene-1,3-indanediones Meldrum's acid Divergentsynthesis

Freezing imaginarity of quantum states based onℓ_(1)-norm

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Chinese Physics B 2024年第10期33卷 166-175页

作者： Shuo Han Bingke zheng Zhihua guo School of Mathematics and Statistics Shaanxi Normal UniversityXi’an 710119China

We discuss freezing of quantum imaginarity based onℓ_(1)-*** properties about a quantity of imaginarity based onℓ_(1)-norm are *** a qubit(2-dimensional)system,we characterize the structure of real quantum operations that allow for freezing the quantity of imaginarity of any ***,we characterize the structure of local real operations which can freeze the quantity of imaginarity of a class of N-qubit quantum states.

关键词： imaginarity freezing ℓ_(1)-norm real operation