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Journal of Environmental Sciences 2025年第3期149卷 374-385页

作者： Qian Ma Yinghao xue Chuning zhang Yanyan Chen Wei Teng Hua zhang Jianwei Fan State Key Laboratory of Pollution Control and Resources Reuse College of Environmental Science and EngineeringTongji UniversityShanghai 200092China

Electrocatalytic reduction of nitrate to ammonia has been considered a promising and sustainable pathway for pollutant treatment and ammonia has significant potential as a clean ***,the method has received much *** this work,Cu/Fe 2D bimetallic metal-organic frameworks were synthesized by a facile method applied as cathode materials without high-temperature *** centers(Cu,Fe)with enhanced intrinsic activity demonstrated higher removal ***,the 2D nanosheet reduced themass transfer barrier between the catalyst and nitrate and increased the reaction ***,the catalysts with a 2D structure showed much better removal efficiency than other structures(3D MOFs and BulkMOFs).Under optimal conditions,Cu/Fe-2D MOF exhibited high nitrate removal efficiency(87.8%)and ammonium selectivity(89.3%)*** ammonium yielded up to significantly 907.2μg/(hr·mg_(cat))(7793.8μg/(hr·mg_(metal)))with Faradaic efficiency of 62.8%at an initial 100 mg N/*** catalyst was proved to have good stability and was recycled 15 times with excellent *** simulations confirm the reduced Gibbs free energy of Cu/Fe-2D *** study demonstrates the promising application of Cu/Fe-2D MOF in nitrate reduction to ammonia and provides new insights for the design of efficient electrode materials.

关键词： Metal-organic frameworks Electrochemical denitrification Ammonium selectivity 2D bimetal materials

Ligand-mediated reactivity in CO oxidation of yttrium-nickel monoxide carbonyl complexes

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Chinese Chemical Letters 2025年第2期36卷 179-183页

作者： Jumei zhang Ziheng zhang gang Li Hongjin Qiao Hua Xie Ling Jiang School of Life Science Ludong University State Key Laboratory of Molecular Reaction Dynamics Dalian Institute of Chemical PhysicsChinese Academy of Sciences

A series of heteronuclear yttrium-nickel monoxide carbonyl complexes YNiO（CO）_n-（n=1–5） were generated in a pulsed-laser vaporization source and characterized by mass-selected photoelectron velocity-map spectroscopy combined with theoretical *** ligand-mediated reactivity in CO oxidation of yttrium-nickel monoxide carbonyl complexes was experimentally and theoretically *** the consecutive CO adsorption,aμ2-O linear structure was most favorable for YNiO（CO）_n-（n=1,2）,then a structure in which the terminal O was bonded to the Y atom became favored for YNiO（CO）3-,and finally a structure bearing a CO2moiety was most favorable for YNiO（CO）_n-（n=4,5）.Theoretical calculations indicated that the Ni atom acted as an electron acceptor and accumulated electron density at n≤3,and then served as an electron donor along with the Y atom to contribute electron density in the rearrangement that accompanied CO oxidation at n>3.

关键词： CO oxidation Electron donor Heteronuclear cluster Photoelectron velocity-map imaging spectroscopy Quantum chemical calculation

Predictive value of N-terminal pro-brain natriuretic peptide in combination with the sequential organ failure assessment score in sepsis

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Chinese Medical Journal 2012年第11期125卷 1893-1898页

作者： JU Min-jie ZHU Du-ming TU Guo-wei HE Yi-zhou xue zhang-gang LUO Zhe WU Zhao-guang Department of Anesthesiology Zhongshan Hospital Fudan University Shanghai 200032 China Department of General Surgery Zhongshan Hospital Fudan University Shanghai 200032 China

Background The prognostic power of n-terminal pro-brain natriuretic peptide （NT-proBNP） in sepsis is disputable and unstable among different models. We attempt to evaluate the prognostic potential of NT-proBNP in combination with the sequential organ failure assessment （SOFA） score in sepsis. Methods In this retrospective study, 100 consecutive sepsis patients were enrolled. Clinical data such as admission SOFA, the Acute Physiologic and Chronic Health Evaluation score, shock prevalence, use of lung protective ventilation, vasopressors, and glucocorticoids were recorded. Additionally, serum creatinine （Scrl and Scr3） and NT-proBNP （NT-proBNP1 and NT-proBNP3） were assayed and evaluated at admission and on day 3 respectively. Results ANT-proBNP （NT-proBNP3 minus NT-proBNP1）（P 〈0.001, Hazard ratio （HR）=1.245, 95% confidence interval （CI）, 1.137-1.362） and admission SOFA （P 〈0.001, HR=1.197, 95% CI, 1.106-1.295） were independently related to in-hospital mortality. Their combination was a more robust predictor for in-hospital mortality than either of them individually. Patients with high ANT-proBNP and SOFA had the poorest prognosis. Conclusions In our study, both ANT-proBNP and SOFA were independent predictors of septic patients＇ prognosis. Moreover, the combination of ,~NT-proBNP and admission SOFA provided a novel strategy that contained information regarding both the response to treatment and sepsis severity.

关键词： sepsis prognosis N-terminal pro-brain natriuretic peptide sequential organ failure assessment score combination

皮下埋藏式中心静脉导管应用于肿瘤化疗患者的临床效果

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中华医学杂志 2008年第33期88卷 2331-2334页

作者：葛峰仓静薛张纲复旦大学附属中山医院麻醉科上海200032

目的探讨皮下埋藏式中心静脉导管应用于肿瘤化疗患者的安全性和有效性，以寻找一种合理的可长期留置的中央静脉导管给药方式。方法120例肿瘤根治术后患者，需长期全身化疗（9个月至2年）。分3组：40例患者采用经皮外周插入式中央导管（P... 详细信息

目的探讨皮下埋藏式中心静脉导管应用于肿瘤化疗患者的安全性和有效性，以寻找一种合理的可长期留置的中央静脉导管给药方式。方法120例肿瘤根治术后患者，需长期全身化疗（9个月至2年）。分3组：40例患者采用经皮外周插入式中央导管（PICC）化疗（PICC组），40例患者采用反复中心静脉穿刺置管（CVC）行化疗（CVC组：颈内静脉组和锁骨下静脉组各20例），40例患者采用皮下埋藏式中心静脉导管（PORT）行化疗（PORT组：颈内静脉组和锁骨下静脉组各20例）。比较3组患者导管植入并发症及化疗期间生活质量满意度评分。结果PICC组的近期并发症主要表现为置入导管位置异常；中心静脉穿刺的近期并发症主要表现为血肿（颈内静脉）和气胸（锁骨下静脉）。PICC组导管阻塞及血栓形成的发生率明显高于另两组（均P〈0．05）。发生局部组织感染和全身感染的机会PICC组和CVC组明显高于PORT组（均P〈0．05）。PORT组患者化疗期间生活质量满意度评分明显高于另两组（均P〈0．05）。结论经皮下泵中心静脉留置技术在肿瘤化疗患者应用中可减少并发症，提高患者生活质量。

关键词：肿瘤药物疗法导管插入术中心静脉皮下埋藏式

mRNA vaccines for gastrointestinal malignancies:cutting-edge advances and future perspectives

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Science Bulletin 2025年第2期70卷 128-131页

作者： gang zhang Xing Huang Tingbo Liang Zhejiang Provincial Key Laboratory of Pancreatic Disease Department of Hepatobiliary and Pancreatic SurgeryThe First Affiliated HospitalZhejiang University School of MedicineHangzhou 310058China MOE Joint International Research Laboratory of Pancreatic Diseases Hangzhou 310003China

Gastrointestinal malignancies encompass cancers of the esophagus,stomach,pancreas,liver,gallbladder,biliary tract,colon,and *** to the 2020 global cancer statistics,gastrointestinal malignancies accounted for approximately 26.4%of all new cancer cases and 36.3%of new deaths(Text S1 online)[1–3].The high incidence and mortality of gastrointestinal malignancies pose a tremendous threat to human *** significant strides in the management of advanced and metastatic gastrointestinal malignancies(Text S2 online),they frequently prove incurable,with 5-year survival rates consistently remaining<20%across various affected sites[4,5].Emerging evidence increasingly underscores the promising therapeutic potential of mRNA vaccines in the field of cancer *** vaccines offer several advantages over traditional strategies(Texts S3 and S4 online)[6–8].Here,we discuss the recent progress and future perspectives of m RNA vaccines in gastrointestinal malignancies.

关键词： gastrointestinal vaccines stomach

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大体积混凝土芯部温度监测及力学性能变化

筑路机械与施工机械化 2011年第5期28卷 74-77页

作者：张学钢陕西铁路工程职业技术学院陕西渭南714000

在实验室模拟大体积混凝土的芯部状态,连续监测混凝土温度变化,并制定混凝土匹配养护制度,在实验室进行匹配养护和标准养护,测试混凝土在不同养护条件下的力学性能,得到大体积混凝土芯部力学性能变化规律,对控制裂缝的出现,提高工程的... 详细信息

在实验室模拟大体积混凝土的芯部状态,连续监测混凝土温度变化,并制定混凝土匹配养护制度,在实验室进行匹配养护和标准养护,测试混凝土在不同养护条件下的力学性能,得到大体积混凝土芯部力学性能变化规律,对控制裂缝的出现,提高工程的安全性和耐久性具有重要意义。

关键词：大体积混凝土匹配养护力学性能裂缝

An Online Exploratory Maximum Likelihood Estimation Approach to Adaptive Kalman Filtering

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IEEE/CAA Journal of Automatica Sinica 2025年第1期12卷 228-254页

作者： Jiajun Cheng Haonan Chen Zhirui xue Yulong Huang Yonggang zhang the College of Intelligent Systems Science and Engineering Harbin Engineering University the Engineering Research Center of Navigation Instruments Ministry of Education the College of Intelligent Systems Science and Engineering the College of Future Technology Harbin Engineering University IEEE

Over the past few decades, numerous adaptive Kalman filters(AKFs) have been proposed. However, achieving online estimation with both high estimation accuracy and fast convergence speed is challenging, especially when both the process noise and measurement noise covariance matrices are relatively inaccurate. Maximum likelihood estimation(MLE) possesses the potential to achieve this goal, since its theoretical accuracy is guaranteed by asymptotic optimality and the convergence speed is fast due to weak dependence on accurate state ***, the maximum likelihood cost function is so intricate that the existing MLE methods can only simply ignore all historical measurement information to achieve online estimation,which cannot adequately realize the potential of MLE. In order to design online MLE-based AKFs with high estimation accuracy and fast convergence speed, an online exploratory MLE approach is proposed, based on which a mini-batch coordinate descent noise covariance matrix estimation framework is developed. In this framework, the maximum likelihood cost function is simplified for online estimation with fewer and simpler terms which are selected in a mini-batch and calculated with a backtracking method. This maximum likelihood cost function is sidestepped and solved by exploring possible estimated noise covariance matrices adaptively while the historical measurement information is adequately utilized. Furthermore, four specific algorithms are derived under this framework to meet different practical requirements in terms of convergence speed, estimation accuracy,and calculation load. Abundant simulations and experiments are carried out to verify the validity and superiority of the proposed algorithms as compared with existing state-of-the-art AKFs.

关键词： Adaptive Kalman filtering coordinate descent maximum likelihood estimation mini-batch optimization unknown noise covariance matrix

Solid-state synthesis of mesoporous metals via mechanochemical coordination self-assembly

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Science China Chemistry 2025年第2期68卷 492-498页

作者： Hailong Xiong Chunyu Qi Lantian xue Ling zhang Hanyu Liu Zhen-An Qiao State Key Laboratory of Inorganic Synthesis and Preparative Chemistry Jilin UniversityChangchun 130012China State Key Laboratory of Supramolecular Structure and Materials College of ChemistryJilin UniversityChangchun 130012China State Key Laboratory of Superhard Materials College of PhysicsJilin UniversityChangchun 130012China Hefei National Research Center for Physical Sciences at the Microscale University of Science and Technology of ChinaHefei 230026China

Mesoporous metals with large surface area,high pore volume,and uniform pore structure hold excellent advantages for various ***,the state-of-the-art synthesis methods are still limited to wet chemistry,which requires excessive solvents and a time-consuming drying ***,we report a facile and general mechanochemical coordination self-assembly strategy to prepare mesoporous metals(e.g.,Rh,Ru,Ir,Pt,Pd,Ag,Co,and Ni)with remarkable porous properties by using metal chlorides and cationic polymer *** with the wet chemistry process,this method proceeds without solvents and does not need complicated experimental conditions and long synthetic periods,which not only greatly reduces the consumption of cost and energy and environmental pollution,but also improves the synthesis efficiency and yield of target *** believe the developed approach will provide a general pathway for the scalable preparation of advanced porous materials.

关键词： mechanochemistry self-assembly mesoporous materials mesoporous metals electrocatalysis

Meteorological effects on sources and future projection of nitrogen deposition to lakes in China

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Journal of Environmental Sciences 2025年第5期151卷 100-112页

作者： Cheng Shi Hao Guo xue Qiao Jingsi Gao Ying Chen Hongliang zhang Department of Biological and Ecological Engineering Oregon State UniversityCorvallisOR 97331USA State Key Laboratory of Organic Geochemistry Guangzhou Institute of GeochemistryChinese Academy of SciencesGuangzhou 510640China Institute of New Energy and Low-carbon Technology Sichuan UniversityChengdu 610065China Engineering Technology Development Center of Urban Water Recycling Shenzhen PolytechnicShenzhen 518055China Shanghai Key Laboratory of Atmospheric Particle Pollution and Prevention Department of Environmental Science and EngineeringFudan UniversityShanghai 200438China IRDR ICoE on Risk Interconnectivity and Governance on Weather/Climate Extremes Impact and Public Health Fudan UniversityShanghai 200438China

Lake ecosystems are extremely sensitive to nitrogen growth,which leads to water quality degradation and ecosystem health *** depositions,as one of the main sources of nitrogen in water,are expected to change under future climate change ***,it remains not clear how nitrogen deposition to lakes respond to future meteorological *** this study,a source-oriented version of Community Multiscale Air Quality(CMAQ)Model was used to estimate nitrogen deposition to 263 lakes in 2013 and under three RCP scenarios(4.5,6.0 and 8.5)in *** total deposition of 58.2 Gg nitrogen was predicted for all lakes,with 23.3 Gg N by wet deposition and 34.9 Gg N by dry *** and ammonium in aerosol phase are the major forms of wet deposition,while NH3 and HNO_(3)in gas phase are the major forms of dry *** emissions contribute to 57%of wet deposition and 44%of dry *** future meteorological conditions,wet deposition is predicted to increase by 5.5%to 16.4%,while dry deposition would decrease by 0.3%to 13.0%.Changes in wind speed,temperature,relative humidity(RH),and precipitation rates are correlated with dry and wet deposition *** predicted changes in deposition to lakes driven by meteorological changes can lead to significant changes in aquatic chemistry and ecosystem *** from future emission scenarios,different climate scenarios should be considered in future ecosystem health evaluation in response to nitrogen deposition.

关键词： Deposition Nitrogen Lakes CMAQ Meteorological variations

Oxygen vacancies-rich molybdenum tungsten oxide nanowires as a highly active nitrogen fixation electrocatalyst

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Chinese Chemical Letters 2025年第1期36卷 545-548页

作者： Jincheng zhang Mengjie Sun Jiali Ren Rui zhang Min Ma Qingzhong xue Jian Tian School of Materials Science and Engineering Shandong University of Science and TechnologyQingdao 266590China

Herein,vacancy engineering is utilized reasonably to explore molybdenum tungsten oxide nanowires(W_(4)MoO_(3)NWs)rich in O-vacancies as an advanced electrochemical nitrogen reduction reaction(eNRR)electrocatalyst,realizing further enhancement of NRR *** 0.1 mol/L Na_(2)SO_(4),W_(4)MoO_(3)NWs rich in O vacancies(CTAB-D-W_(4)MoO_(3))achieve a large NH3yield of 60.77μg h^(-1)mg^(-1)***-0.70 V *** and a high faradaic efficiency of 56.42%at-0.60 V,much superior to the W_(4)MoO_(3)NWs deficient in oxygen vacancies(20.26μg h^(-1)mg^(-1)*** 17.1%at-0.70 V ***).Meanwhile,W_(4)MoO_(3)NWs rich in O-vacancies also show high electrochemical *** functional theory(DFT)calculations present that O vacancies in CTAB-D-W_(4)MoO_(3)reduce the energy barrier formed by the intermediate of^(*)N-NH,facilitate the activation and further hydrogenation of^(*)N-N,promote the NRR process,and improve NRR activity.

关键词： Electrocatalytic N_(2) reduction reaction Molybdenum-tungsten oxide Nanowires Oxygen vacancies Non-noble metal