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Petrogenesis, oxidation state and volatile content of Dongga tonalite in the Gangdese belt, Xizang: Implication for porphyry Cu mineralization

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Acta Geochimica 2024年第2期43卷 280-295页

作者： Liqiang Zhang Xilian Chen Shaohao zou Deru Xu Xuena Wang Hua Wang State Key Laboratory of Nuclear Resources and Environment East China University of TechnologyNanchang 330013China School of Earth Sciences East China University of TechnologyNanchang 330013China

The Gangdese belt in Xizang has experienced both Jurassic subduction and Cenozoic continental collision processes, making it a globally renowned region for magmatic rocks and porphyry copper deposits. Numerous Jurassic intrusions have been identified in the belt. Apart from the quartz diorite porphyry in the large Xietongmen deposit, the Cu mineralization potential of other Jurassic intrusions in this belt remains unclear. This study presents zircon U–Pb dating and trace elements, apatite major and trace elements as well as published whole-rock geochemical and isotopic data of the Dongga tonalite in the central part of the Gangdese belt, aiming to reveal the petrogenesis, oxidation state, volatile content, and Cu mineralization potential of this intrusion. The Dongga tonalite has a zircon U–Pb age of 179.4 ± 0.9 Ma. It exhibits high whole-rock V/Sc values(8.76–14.6), relatively low apatite CeN/CeN*ratios(1.04–1.28), elevated zircon(Eu/Eu*)Nvalues(an average of 0.44), high Ce4+/Ce3+values(205–1896), and high ?FMQ values(1.3–3.7), collectively suggesting a high magmatic oxygen fugacity. The Dongga tonalite features amphibole phenocrysts, relatively high whole-rock Sr/Y ratios(20.3–58.9), and lower zircon Ti temperatures (502–740 ℃), reflecting a high magmatic water content. Estimation of magmatic sulfur content(0.002–0.024 wt%) based on apatite SO3contents indicates an enriched magma sulfur content. Combined with previous studies and the collected Sr–Nd–Hf isotopes, the Dongga tonalite is derived from juvenile lower crust related with subduction of the Neo-Tethys oceanic slab. When compared with Xietongmen orebearing porphyries, the Dongga tonalite exhibits remarkable similarities with the Xietongmen ore-bearing porphyries in terms of magma source, tectonic background, magmatic redox state, and volatile components, which indicates that the Dongga tonalite has a high porphyry Cu mineralization potential, and therefore, provides important guidance for the future mineral

关键词： Tonalite Zircon Apatite Mineralization potential Dongga area Gangdese belt

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In situ sulfur-doped mesoporous tungsten oxides for gas sensing toward benzene series

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Chinese Chemical Letters 2024年第7期35卷 502-507页

作者： Yu Deng Yan Liu Yonghui Deng Jinsheng Cheng Yidong zou Wei Luo State Key Laboratory for Modification of Chemical Fibers and Polymer Materials College of Materials Science and EngineeringDonghua UniversityShanghai 201620China Department of Chemistry State Key Laboratory of Molecular Engineering of PolymersShanghai Key Laboratory of Molecular Catalysis and Innovative MaterialsiChEMFudan UniversityShanghai 200433China Department of Polymeric Materials School of Materials Science and EngineeringTongji UniversityShanghai 201804China Henry-Fork School of Food Sciences Shaoguan UniversityShaoguan 512005China State Key Lab of Transducer Technology Shanghai Institute of Microsystem and Information TechnologyChinese Academy of SciencesShanghai 200050China

Benzene series as highly toxic gases have inevitably entered human life and produce great threat to human health and ecological environment,and thus it is distinctly meaningful to monitor benzene series with quickly,real-time and efficient ***,novel sulfur-doped mesoporous WO_(3)materials were synthesized via classical in-situ solvent evaporation induced co-assembly strategy combined with doping engineering,which possessed highly crystallized frameworks,high specific surface area(40.9–63.8 m^(2)/g)and uniform pore size(~18 nm).Benefitting from abundant oxygen vacancy and defects via S-doping,the tailored mesoporous S/m WO_(3)exhibited excellent benzene sensing performance,including high sensitivity(50 ppm vs.48),low detection limit(ca.500 ppb),outstanding selectivity and favorable *** addition,the reduction of band gap resulted from S-doping promotes the carrier migration in the sensing materials and the reaction at the gas–solid sensing *** provides brand-new approach to design sensitive materials with multiple reaction sites.

关键词： Mesoporous materials Benzene series Tungsten oxides Sulfur doping Gas sensor

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Alkyl chain modulation of asymmetric hexacyclic fused acceptor synergistically with wide bandgap third component for high efficiency ternary organic solar cells

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International Journal of Minerals,Metallurgy and Materials 2024年第7期31卷 1713-1719页

作者： Shufang Li Huilan Guan Can Zhu Chaoyuan Sun Qingya Wei Jun Yuan Yingping zou College of Chemistry and Chemical Engineering Central South UniversityChangsha 410083China Beijing National Laboratory for Molecular Sciences CAS Key Laboratory of Organic SolidsInstitute of ChemistryChinese Academy of SciencesBeijing 100190China Institute of Carbon Neutrality and New Energy School of Electronics and InformationHangzhou Dianzi UniversityHangzhou 310018China

Herein,two asymmetric hexacyclic fused small molecule acceptors(SMAs),namely BP4F-HU and BP4F-UU,were *** elongated outside chains in the BP4F-UU molecule played a crucial role in optimizing the morphology of blend film,thereby improving charge mobility and reducing energy loss within the corresponding ***,the PM6:BP4F-UU device exhibited a higher open-circuit voltage(V_(oc))of 0.878 V compared to the PM6:BP4F-HU device with a V_(oc)of 0.863 ***,a new wide bandgap SMA named BTP-TA was designed and synthesized as the third component to the PM6:BP4F-UU host binary devices,which showed an ideal complementary absorption spectrum in PM6:BP4F-UU *** addition,BTP-TA can achieve efficient intermolecular energy transfer to BP4F-UU by fluorescence resonance energy transfer(FRET)pathway,due to the good overlap between the photoluminescence(PL)spectrum of BTP-TA and the absorption region of ***,ternary devices with 15wt%BTP-TA exhibits broader photon utilization,optimal blend morphology,and reduced charge recombination compared to the corresponding binary ***,PM6:BP4F-UU:BTP-TA ternary device achieved an optimal power conversion efficiency(PCE)of 17.83%with simultaneously increased V_(oc)of 0.905 V,short-circuit current density(J_(sc))of 26.14 mA/cm^(2),and fill factor(FF)of 75.38%.

关键词： asymmetric hexacyclic acceptor outside chain wide bandgap acceptor ternary organic solar cells

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Salinity Acclimation Induces Reduced Energy Metabolism,Osmotic Pressure Regulation and Transcriptional Reprogramming in Hypotrichida Ciliate Gastrostyla setifera

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Journal of Ocean University of China 2024年第2期23卷 539-549页

作者： JI Xin BI Luping zou Songbao LI Wenlu JI Daode ZHANG Qianqian School of Ocean Yantai UniversityYantai 264005China Key Laboratory of Coastal Environmental Processes and Ecological Remediation Yantai Institute of Coastal Zone ResearchChinese Academy of SciencesYantai 264003China Zhejiang Institute of Freshwater Fisheries Huzhou 313001China Muping Coastal Environment Research Station Yantai Institute of Coastal Zone ResearchChinese Academy of SciencesYantai 264117China

Coastal and estuarine protists are frequently exposed to salinity *** the tolerance and stress responses of microalgae to salinity have been extensively studied,there have been scarce studies on the physiological response of heterotrophic protists to salinity *** this study,we investigated the physiological response of the heterotrophic ciliate Gastrostyla setifera to a salinity of 3,via a transcriptomic *** first transcriptome of genus Gastrostyla was obtained utilizing a group of manually isolated ciliate individuals(cells)and RNA-seq *** completeness of the transcriptome was *** expressed gene(DEG)analysis was performed among the transcriptomes of *** acclimated in saline water(salinity 3)and those cultured in fresh *** results demonstrated a significant alternation in gene transcription,in which the ciliate exhibits a transcripttomic acclimation in responding salinity *** up-regulated DEGs were enriched in the pathways of cytoskeleton proteins,membrane trafficking,protein kinases and protein *** may represent enhanced functions of ion transport,stress response and cell *** involved in energy metabolism and biosynthesis were markedly down-regulated,reflecting decreased cell ***,we detected significantly down-regulated genes involved in several pathways of amino acid catabolism,which may lead to accumulation of amino acids in the ciliate *** acid could act as compatible solutes in the cytoplasm to maintain the osmotic balance in saline ***,this work is an initial exploration to the molecular basis of the heterotrophic protist responding to salinity *** result sheds light on the mechanisms of enhancement of cell protection,reduction of cell activity,and osmotic pressure regulation in ciliates acclimated to salinity.

关键词： salinity stress heterotrophic protist ciliate Gastrostyla setifera transcriptome differentially expressed gene

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Pathological and physiological functional cross-talks ofα-synuclein and tau in the central nervous system

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Neural Regeneration Research 2024年第4期19卷 855-862页

作者： Mingyue Jin Shengming Wang Xiaodie Gao Zhenyou zou Shinji Hirotsune Liyuan Sun Guangxi Key Laboratory of Brain and Cognitive Neuroscience Guilin Medical University Department of Genetic Disease Research Osaka Metropolitan University Graduate School of Medicine Department of Scientific Research Brain Hospital of Guangxi Zhuang Autonomous Region

α-Synuclein and tau are abundant multifunctional brain proteins that are mainly expressed in the presynaptic and axonal compartments of neurons,*** works have revealed that intracellular deposition ofα-synuclein and/or tau causes many neurodegenerative disorders,including Alzheimer’s disease and Parkinson’s *** intense investigation,the normal physiological functions and roles ofα-synuclein and tau are still unclear,owing to the fact that mice with knockout of either of these proteins do not present apparent ***,the co-occurrence ofα-synuclein and tau aggregates was found in post-mortem brains with synucleinopathies and tauopathies,some of which share similarities in clinical ***,the direct interaction ofα-synuclein with tau is considered to promote the fibrillization of each of the proteins in vitro and in *** the other hand,our recent findings have revealed thatα-synuclein and tau are cooperatively involved in brain development in a stage-dependent *** findings indicate strong cross-talk between the two proteins in physiology and *** this review,we provide a summary of the recent findings on the functional roles ofα-synuclein and tau in the physiological conditions and pathogenesis of neurodegenerative diseases.A deep understanding of the interplay betweenα-synuclein and tau in physiological and pathological conditions might provide novel targets for clinical diagnosis and therapeutic strategies to treat neurodegenerative diseases.

关键词： alpha-synuclein microtubule-associated protein neurodegenerative disease tau

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3-D Tunnel Seismic Advance Prediction Method with Wide Illumination and High-Precision

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Journal of Earth Science 2024年第3期35卷 970-979页

作者： Peng Guan Cuifa Shao Yuyong Jiao Guohua Zhang Junpeng zou Fei Tan Faculty of Engineering China University of GeosciencesWuhan 430074China

Tunnel seismic advance prediction can effectively reduce the construction risk during tunnel *** with the 2-D method,the 3-D method is more conducive to describing the spatial characteristics of the geological body by adding the seismic data in the vertical ***,some drawbacks still need improvement in the current 3-D tunnel seismic prediction method.(1)The geometry is complex,which is destructiveness,high cost,and time-consuming,and will delay the tunnel construction schedule.(2)Illumination of the anomalous body is insufficient,and the precision of migration imaging is low.(3)Shot points are far away from the tunnel face,the energy loss at the shot points is more serious.(4)The received signals at the tunnel wall have the surface wave with strong energy when the shot points are placed on the tunnel wall.(5)The geometry is not linear,so the directional filtering method cannot be used to extract the reflection *** overcome the drawbacks of the current prediction method,a new 3-D symmetrical tunnel seismic prediction method is *** geophones are installed on the tunnel wall,two on the left side,two on the right side,and two on the top ***-four shot points are placed on the tunnel face and near both sides of the tunnel wall,twelve shot points on the left side and twelve shot points on the right *** shot points will move along with the forward excavation of the *** wavefield analysis,illumination statistics,and 3-D reverse time migration imaging are used to evaluate the proposed *** result of modeled data indicates that the proposed 3-D geometry has some advantages:(1)the geometry is simple and the geophone installation time is short;(2)it has high illumination energy,wide illumination range,and can improve the prediction distance and imaging accuracy;(3)the proposed 3-D method can better estimate the velocity of surrounding rock and is more conducive to extracting the reflection wave with high resolut

关键词： tunnels excavation geophone shot points migration imaging method engineering ge-ology.

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Investigation on occupant presence and appliance operation schedules for university campus in south China sub-tropical area

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Building Simulation 2024年第2期17卷 301-318页

作者： Siwei Lou Zhongyuan Lin Yukai zou Dawei Xia Yu Huang Zhuohong Li Zhaowen Gu School of Civil Engineering Guangzhou UniversityGuangzhou Higher Edu.Mega CenterGuangzhouChina School of Architecture and Urban Planning Guangzhou UniversityGuangzhou Higher Edu.Mega CenterGuangzhouChina

Building occupant presence during varying periods is crucial to the performance studies of buildings and city ***,the understanding of the building occupancies on the university campus remains *** address this gap,our study employs field measurements,payment records,course arrangements,and building access systems to depict the occupancy patterns of the canteen,dormitory,library,and teaching and lab buildings during weekdays and *** found that the occupancy rates across different buildings are somehow interrelated,given that the total number of occupants on campus is generally ***,dormitory occupancy rates tend to be low during the morning and afternoon course hours,which inversely correlates with the high occupancy rates in the teaching and lab buildings during these ***,canteens experience surges in occupancy during meal times,which coincide with a decrease in library ***,we established appliance operation schedules for dormitories through surveys and on-site *** dispensers and electronic devices were identified as the primary energy consumers for both male and female occupants,with desk-top fans and hairdryers being significant energy users for male and female occupants,*** findings are essential for energy studies within a campus setting,underlining the importance of considering occupant behaviors on a regional scale.

关键词： building occupant behavior university campus occupancy schedule appliance operation schedule

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High-efficiency CO_(2) sequestration through direct aqueous carbonation of carbide slag: determination of carbonation reaction and optimization of operation parameters

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Frontiers of Environmental Science & Engineering 2024年第1期18卷 157-167页

作者： Zhiqiang Wang Longpeng Cui Yanfang Liu Jili Hou Hongwei Li Liang zou Fuxia Zhu Department of Coal and Syngas Conversion Sinopec Research Institute of Petroleum Processing Co.Ltd.Beijing 100083China

Under the dual-carbon target, CO_(2) mineralization through solid wastes presents a mutually beneficial approach for permanent carbon emission reduction at a low material cost, while also enabling the resource utilization of these wastes. However, despite its potential, a comprehensive understanding about the effect of industrial solid waste properties and operating parameters on the carbonation process, and the mechanism of direct aqueous carbonation is still lacking. A series of experiments were conducted to compare the carbonation performance of fly ash, steel slag, and carbide slag. Subsequently, CO_(2) mineralization by carbide slag was systematically studied under various operating parameters due to its high CO_(2) sequestration capacity. Results showed the reactivity of CaO and Ca(OH)2 was higher than that of CaO·SiO_(2) and 2CaO·SiO_(2). Carbide slag demonstrated a sequestration capacity of 610.8 g CO_(2)/kg and carbonation efficiency ζCa of 62.04% under the conditions of 65 ℃, 1.5 MPa initial CO_(2) pressure, 15 mL/g liquid-to-solid ratio, and 200 r/min stirring speed. Moreover, the formation of carbonates was confirmed through XRD, SEM-EDS, TG, and FTIR. A mechanism analysis revealed that initially, the rate of the carbonation process was primarily controlled by the mass transfer of CO_(2) in the gas–liquid interface. However, the rate-determining step gradually shifted to the mass transfer of Ca2+ in the solid–liquid interface as the reaction time increased. This study lays the foundation for the large-scale implementation of CO_(2) sequestration through carbide slag carbonation.

关键词： Industrial by-products Direct aqueous carbonation CO_(2)sequestration Mass transfer

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Economical Quadrupedal Multi-Gait Locomotion via Gait-Heuristic Reinforcement Learning

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Journal of Bionic Engineering 2024年第4期21卷 1720-1732页

作者： Lang Wei Jinzhou zou Xi Yu Liangyu Liu Jianbin Liao Wei Wang Tong Zhang School of Power and Mechanical Engineering Wuhan UniversityLuojiashanWuhan430072HubeiChina State Key Laboratory of Information Engineering in Surveying Mapping and Remote SensingWuhan UniversityLuojiashanWuhan430072HubeiChina

In order to strike a balance between achieving desired velocities and minimizing energy consumption,legged animals have the ability to adopt the appropriate gait pattern and seamlessly transition to another if *** ability makes them more versatile and efficient when traversing natural terrains,and more suitable for long *** the same way,it is meaningful and important for quadruped robots to master this *** achieve this goal,we propose an effective gait-heuristic reinforcement learning framework in which multiple gait locomotion and smooth gait transitions automatically emerge to reach target velocities while minimizing energy *** incorporate a novel trajectory generator with explicit gait information as a memory mechanism into the deep reinforcement learning *** allows the quadruped robot to adopt reliable and distinct gait patterns while benefiting from a warm start provided by the trajectory ***,we investigate the key factors contributing to the emergence of multiple gait *** tested our framework on a closed-chain quadruped robot and demonstrated that the robot can change its gait patterns,such as standing,walking,and trotting,to adopt the most energy-efficient gait at a given ***,we deploy our learned controller to a quadruped robot and demonstrate the energy efficiency and robustness of our method.

关键词： Legged robots Deep reinforcement learning Central pattern generator Quadrupedal gait

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Lanthanum promoting bone formation by regulating osteogenesis,osteoclastogenesis and angiogenesis

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Journal of Rare Earths 2024年第3期42卷 621-628,I0007页

作者： Dandan zou Runlian Lin Yu Han Juan Jia Guoqiang Zhou Haisong Zhang Kun Ge Hebei Key Laboratory of Chronic Kidney Diseases and Bone Metabolism Affiliated Hospital of Hebei UniversityBaoding071000China Key Laboratory of Medicinal Chemistry and Molecular Diagnosis of the Ministry of Education Key Laboratory of Chemical Biology of Hebei ProvinceCollege of Chemistry and Environmental ScienceHebei UniversityBaoding071002China

With lanthanum(La) in agriculture, medicine, and the chemical industry, La shows accumulation in the body, especially in the bone, because of its similar structure to calcium. Moreover, La has a direct role in bone formation regulating osteoblasts and osteoclasts. Nevertheless, bone formation is complex under the regulation of osteogenesis, osteoclastogenesis, and angiogenesis in the bone microenvironment. It is difficult to comprehensively understand the regulation of bone homeostasis from a single kind of ***, some bone microenvironment-related cells and mouse calvaria culture models were used to study the regulatory effect of La-based compound-lanthanum nitrate(La(NO_(3))_(3)) on bone ***(NO_(3))_(3) has good biological safety, and the osteogenic differentiation is significantly increased under La(NO_(3))_(3) treatment for bone marrow mesenchymal stem cells(BMMSC). In contrast, the differentiation,maturation, and bone erosion ability of osteoclasts are significantly decreased. Meanwhile, the angiogenesis ability of human umbilical vein endothelial cells(HUVEC) is significantly promoted when treated with La(NO_(3))_(3). Furthermore, bone metabolism and angiogenesis are improved under La(NO_(3))_(3) treatment in the calvaria ex vivo culture model and BMMSC-HUVEC co-culture system. These results suggest that La has the beneficial effect of promoting bone metabolism and improving bone formation in the bone microenvironment.

关键词： Lanthanum Bone microenvironment Osteogenic differentiation Angiogenesis Rare earths

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