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Defects and morphology engineering for constructing V_(s)-Ni_(3)S_(2)@V_(s)-Cu_(2)S nanotube heterojunction arrays toward efficient bifunctional electrocatalyst for overall water splitting

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Journal of Energy Chemistry 2024年第7期94卷 29-40页

作者： Wenyuan sun Alan Meng Lei Wang Guicun Li Jinfeng Cui Yongkai sun Zhenjiang Li College of Materials Science and Engineering Qingdao University of Science and TechnologyQingdao 266042ShandongChina Key Laboratory of Optic-electric Sensing and Analytical Chemistryfor Life Science MOE College of Chemistry and Molecular EngineeringQingdao Universityof Science and TechnologyQingdao 266042ShandongChina College of Environment and Safety Engineering Qingdao University of Science and TechnologyQingdao 266042ShandongChina Qingdao Huanghai University Qingdao 266000ShandongChina College of Electromechanical Engineering Qingdao University of Science and TechnologyQingdao 266061ShandongChina

The development of highly active,stable and inexpensive electrocatalysts for hydrogen production by defects and morphology engineering remains a great ***,S vacancies-rich Ni_(3)S_(2)@Cu_(2)S nan-otube heterojunction arrays were in-situ grown on copper foam(V_(s)-Ni_(3)S_(2)@V_(s)-Cu_(2)S NHAs/CF)for efficient electrocatalytic overall water *** the merits of nanotube arrays and efficient electronic mod-ulation drived by the OD vacancy defect and 2D heterojunction defect,the resultant V_(s)-Ni_(3)S_(2)@V_(s)-Cu_(2)S NHAs/CF electrocatalyst exhibits excellent electrocatalytic activity with a low overpotential of 47 mV for the hydrogen evolution reaction(HER)at 10 mA cm^(-2) current density,and 263 mV for the oxygen evolution reaction(OER)at 50 mA cm^(-2) current density,as well as a cell voltage of 1.48 V at 10 mA cm^(-2).Moreover,the nanotube heterojunction arrays endows V_(s)-Ni_(3)S_(2)@V_(s)-Cu_(2)S NHAs/CF with outstanding stability in long-term catalytic processes,as confirmed by the continuous chronopotentiom-etry tests at current densities of 10 mA cm^(-2) for 100 h.

关键词： Nanotubearrays Heterojunction Vacancy Bifunctional electrocatalyst Overall water splitting

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NADPH oxidase 4(NOX4)as a biomarker and therapeutic target in neurodegenerative diseases

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Neural Regeneration Research 2024年第9期19卷 1961-1966页

作者： Napissara Boonpraman sun Shin Yi BK21 four Program Department of Medical SciencesSoonchunhyang UniversityAsanSouth Korea Department of Biomedical Laboratory Science Soonchunhyang UniversityAsanSouth Korea iConnectome Co.Ltd.CheonanSouth Korea

Diseases like Alzheimer’s and Parkinson’s diseases are defined by inflammation and the damage neurons undergo due to oxidative stress. A primary reactive oxygen species contributor in the central nervous system, NADPH oxidase 4, is viewed as a potential therapeutic touchstone and indicative marker for these ailments. This in-depth review brings to light distinct features of NADPH oxidase 4, responsible for generating superoxide and hydrogen peroxide, emphasizing its pivotal role in activating glial cells, inciting inflammation, and disturbing neuronal functions. Significantly, malfunctioning astrocytes, forming the majority in the central nervous system, play a part in advancing neurodegenerative diseases, due to their reactive oxygen species and inflammatory factor secretion. Our study reveals that aiming at NADPH oxidase 4 within astrocytes could be a viable treatment pathway to reduce oxidative damage and halt neurodegenerative processes. Adjusting NADPH oxidase 4 activity might influence the neuroinflammatory cytokine levels, including myeloperoxidase and osteopontin, offering better prospects for conditions like Alzheimer’s disease and Parkinson’s disease. This review sheds light on the role of NADPH oxidase 4 in neural degeneration, emphasizing its drug target potential, and paving the path for novel treatment approaches to combat these severe conditions.

关键词： Alzheimer’s disease astrocytes mitochondrial dysfunction myeloperoxidase NADPH oxidase 4 NADPH oxidase 4 inhibitors neurodegenerative diseases osteopontin Parkinson’s disease reactive oxygen species

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Optimization of confined aquifer dewatering for long-deep excavation using simulation–optimization method

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Underground Space 2024年第4期17卷 246-266页

作者： Yanxiao sun Zhenxiong Jiang Liyuan Tong Jiawei sun Jia Cui Xin Zhou Songyu Liu Institute of Geotechnical Engineering Southeast UniversityNanjing 211189China Nanjing Modern Multimodal Transportation Laboratory Nanjing 211100China Jiangsu Provincial Transportation Construction Bureau Nanjing 210004China

The confined aquifer dewatering for long-deep excavations usually encounters challenges due to complicated geotechnical conditions,large excavation sizes,and high hydraulic *** propose the most efficient scheme of confined aquifer dewatering for long-deep excavations,dewatering optimizations were performed using the simulation–optimization *** open cut tunnel of the Jiangyin-Jingjiang Yangtze River Tunnel Project was taken as an *** methods of finite element and linear programming(LP)were combined to optimize the dewatering process.A three-dimensional finite element model was *** simulating the pumping tests,hydraulic conductivity was ***,necessary parameters in the LP method were determined by simulating dewatering with each pumping well,and various LP models were developed based on some important influence factors such as dewatering sequence,considered pumping wells,and pumping rate ***,the optimal pumping rates were solved and applied to the numerical model,with induced drawdown and ground settlement computed for *** results indicate that the optimization can significantly reduce the required wells in the original *** in the deepest zone exhibits the highest efficiency for long-deep excavations with gradually varying *** the dewatering sequence from the shallowest to the deepest zone,more pumping wells are required but less energy is *** quantity and more advantageous locations of pumping wells in the LP model usually result in lower total pumping rate,drawdown,and ground *** more pumping wells are considered in the deepest zone,pumping rate limitation of single well will only slightly increase the total pumping rate,number of required pumping wells,drawdown,and ground settlement.

关键词： Dewatering Confined aquifer Simulation-optimization Linear programming Open cut tunnel

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Experimental and simulation research on hollow AZ31 magnesium alloy three-channel joint by hot extrusion forming with sand mandrel

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Journal of Magnesium and Alloys 2024年第1期12卷 98-109页

作者： Shi Shengnan Wang Hongyu Teng Fei Jiang Lei sun Juncai sun Jie Zhang Shunhu Transportation Engineering College Dalian Maritime UniversityDalianLiaoning 106026China State Key Laboratory of Rolling and Automation Northeastern UniversityShenyangLiaoning 110819China Shagang School of Iron and Steel Soochow UniversitySuzhouJiangsu 215021China

Magnesium alloy is one of the lightest metal structural *** weight is further reduced through the hollow ***,the hollow structure is easily damaged during *** order to maintain the hollow structure and to transfer the stresses during the high temperature deformation,the sand mandrel is *** this paper,the hollow AZ31 magnesium alloy three-channel joint is studied by hot extrusion *** as one of solid granule medium is used to fill the hollow magnesium *** extrusion temperatures are 230℃ and 300℃,*** process parameters(die angle,temperature,bottom thickness,sidewall thickness,edge-to-middle ratio in bottom,bottom shape)of the hollow magnesium alloy are analyzed based on the results of experiments and the finite element *** results are shown that the formability of the hollow magnesium alloy will be much better when the ratio of sidewall thickness to the bottom thickness is 1:*** when edge-to-middle ratio in bottom is about 1:1.5,a better forming product can be *** best bottom shape in these experiments will be convex based on the forming *** grain will be refined obviously after the *** the microstructures will be shown as *** these lines will be well agreement with the mold in the corner.

关键词： AZ31 magnesium alloy Three-channel joint Sand Experiments and the finite element Die angle

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Insight into the development of electrolytes for aqueous zinc metal batteries from alkaline to neutral

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Chinese Chemical Letters 2024年第2期35卷 232-241页

作者： An Duan Sha Luo Wei sun School of Materials and Energy University of Electronic Science and Technology of ChinaChengdu 611731China

Aqueous zinc metal batteries are considered as promising candidates for next-generation electrochemical energy storage devices,especially for large-scale energy storage,due to the advantages of high-safety,high energy density and low *** the bridge connecting cathode and anode,electrolyte provides a realistic operating *** alkaline and neutral aqueous zinc metal batteries,issues associated with electrolyte and anode are still *** this review,we reveal the development and evolution of electrolytes for aqueous zinc metal batteries from alkaline to neutral via the description of fundamentals and challenges in terms of comparison and *** also elaborate the strategies in electrolytes regulation and highlight the basic roles and progresses in additives engineering.

关键词： Aqueous electrolytes Zinc metal batteries pH-dependent chemistry Electrolyte regulation Additives engineering

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Batteries for electric vehicles:Technical advancements,environmental challenges,and market perspectives

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SusMat 2024年第5期4卷 1-30页

作者： Axel Celadon Huaihu sun Shuhui sun Gaixia Zhang Department of Electrical Engineering Ecole de Technologie Superieure(ETS)MontrealQuebecCanada Institut National de la Recherche Scientifique(INRS) Centre Energie Materiaux TelecommunicationsVarennesQuebecCanada

The rapid evolution of electric vehicles(EVs)highlights the critical role of bat-tery technology in promoting sustainable *** review offers a comprehensive introduction to the diverse landscape of batteries for *** particular,it examines the impressive array of available battery technologies,focusing on the predominance of lithium-based batteries,such as lithium-ion and lithium-metal ***,it explores battery technologies beyond lithium(“post-lithium”),including aluminum,sodium,and magnesium *** potential of solid-state batteries is also discussed,along with the current status of various battery types in EV *** review further addresses end-of-life treatment strategies for EV batteries,including reuse,remanufactur-ing,and recycling,which are essential for mitigating the environmental impact of batteries and ensuring sustainable lifecycle ***,market per-spectives and potential future research directions for battery technologies in EVs are also discussed.

关键词： electric vehicles environmental challenges market perspectives rechargeable batteries technical advancements

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Towards Data-Driving Multi-View Evaluation Framework for Scratch

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Tsinghua Science and Technology 2024年第2期29卷 517-528页

作者： Xiaolin Chai Yan sun Yan Gao Department of Computer Science Beijing University of Posts and TelecommunicationBeijing 100876China Intellectual Property Institute Shandong Polytechnic CollegeJining 272067China

As one of the most popular visual programming languages,Scratch has a lot of evaluation around *** evaluation can help programmers understand their projects *** the same time,it can also provide a reference for them to browse other projects in the online *** of the existing evaluations on Scratch are carried from three perspectives:Computational Thinking(CT)ability,visual presentation aesthetics,and code *** them,the assessment of CT and code quality is mainly carried out from the program script,while the evaluation of visual aesthetics is analyzed from the perspective of image sequences generated by project *** single-view evaluation focuses on the performance of a program in a certain aspect and is *** this paper,we propose a multi-view evaluation framework to integrate various evaluations using different *** quantitatively analyze the assessment of different views driven by *** with overall evaluations that represent human opinions,we analyze their differences and *** experiments,we determine the weights of different integration policies,the proposed multi-view evaluation method can generate evaluation results similar to human opinions.

关键词： Scratch Computational Thinking(CT) visual aesthetic static analysis integration policy machine learning

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Direct numerical simulation of shock wave/boundary layer interaction controlled by steady microjet in a compression ramp

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Chinese Journal of Aeronautics 2024年第10期37卷 83-102页

作者： Ruoye XIAO Dong sun Jian YU School of Aeronautic Science and Engineering Beihang UniversityBeijing 100191China State Key Laboratory of Aerodynamics Mianyang 621000China

Shock wave/boundary layer interaction in a 24°turning angle of the compression ramp at Mach number 2.9 controlled by steady microjet is investigated using direct numerical *** different jet spacings which are termed as sparse,moderate and dense are considered,and the induced vortex system and shock structures are compared.A moderate jet spacing configuration is found to generate counter-rotating vortex pairs that transport high-momentum fluid towards the vicinity of wall and strengthen the boundary layer to resist separation,reducing the separation *** dense jet spacing configuration creates a larger momentum deficit region,reducing the friction downstream of the *** of pressure and pressure gradient reveals that dense jet spacing configuration reduces the intensity of separation *** impact of varying jet spacings on the turbulent kinetic energy transport mechanism is also investigated by decomposing the budget terms in the transport ***,the spectral characteristics of the separation region are studied using power spectral density and dynamic mode decomposition methods,revealing that moderate jet spacing configuration suppresses low-frequency fluctuations in the separation region.

关键词： Shock wave/boundary layer interaction Compression ramp Steady microjet Different jet spacings Direct numerical simulation

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Influence of nitrogen status on fermentation performances of non-Saccharomyces yeasts:a review

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Food Science and Human Wellness 2024年第2期13卷 556-567页

作者： Jinchen Li Mengmeng Yuan Nan Meng Hehe Li Jinyuan sun Baoguo sun Key Laboratory of Brewing Molecular Engineering of China Light Industry Beijing Key Laboratory of Flavor ChemistryBeijing Technology&Business UniversityBeijing 100048China

Nitrogen,one of the most crucial nutrients present in grapes and musts,plays a key role in yeast activities during alcoholic *** influences are imposed on yeast growth and fermentation performances including the formation of secondary *** cerevisiae,the main yeast responsible for fermentation,has been studied extensively regarding nitrogen *** the other hand,a similar study for non-Saccharomyces yeasts,whose contributions to winemaking have gradually been acknowledged,remains to be fully explored,with a few studies being *** review starts by discussing nitrogen impacts on non-Saccharomyces yeast growth and fermentation kinetics in different case scenarios,then proceeds to summarize the nitrogen preferences of individual yeast strains with regulation mechanisms elucidated by recent *** discussions on the influences on the production of volatile compounds and proposed pathways therein are made,followed by future work suggested as the final *** summarizing the nitrogen impacts on non-Saccharomyces yeasts throughout alcoholic fermentation,this review will be helpful in obtaining a more comprehensive view on these non-conventional wine yeasts in terms of nutrient requirements and corresponding volatile *** gaps will therefore be elucidated for future research.

关键词： Non-Saccharomyces yeasts Nitrogen Fermentation kinetics Nitrogen preference Wine aroma

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Numerical study on the use of soft material walls to enhance seismic performance of an existing tunnel

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Underground Space 2024年第2期15卷 90-112页

作者： Qiangqiang sun Menghao Hou Daniel Dias Institute of Geotechnical Engineering College of Civil Engineering and ArchitectureHebei UniversityBaoding 071002China Laboratory 3SR CNRS UMR 5521Grenoble Alpes UniversityGrenoble 38000France

Seismic risk is one of the biggest challenges for tunnel safety,and several mitigation techniques have been proposed to enhance the seismic performance of existing *** paper aims to investigate the effectiveness of an innovative approach for reducing the seismic risk of existing tunnels by using soft material walls(SMW)symmetrically installed in the surrounding *** investigation is performed with a two-dimensional numerical model and the effectiveness of SMW in mitigating the seismic-induced lining forces is quantitatively evaluated by reduction *** influences of nonlinear properties of soil,SMW and tunnel lining on the isolation effectiveness are also *** parametric studies show that the computed reduction ratio is strongly affected by the modulus ratio between the SMW and the soil,the wall geometric parameter,and the flexibility *** is more effective for the thick and soft isolation walls that are inserted near a stiff tunnel in the soft *** tunnel seismic response can be reduced by up to 50%for the scenarios ***,the parametric study identifies an optimum normalized depth of SMW and recommends a relation between the maximum isolation effect and the flexibility ***,simple charts are suggested in this work for estimating the isolation effect in specific conditions of the soil and the *** these lines,the results of this work may be used in the seismic retrofitting of an existing tunnel,aiding the preliminary design of the isolation walls.

关键词： Tunnels Earthquakes Seismic analysis Isolation walls Soft material

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