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Boosting sodium-storage properties of hierarchical Na_(3)V_(2)(PO_(4))_(3)@C micro-flower cathodes by tiny Cr doping:The effect of“four ounces moving a thousand pounds”

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Nano Research 2024年第1期17卷 235-244页

作者： Yongjia Wang Guoshuai Su Xiaoying li linrui Hou Longwei liang Changzhou yuan School of Materials Science&Engineering University of JinanJinan 250022China

Na_(3)V_(2)(PO_(4))_(3)(NVP),as a great potential cathode candidate for Na-ion batteries(NIBs),has attracted enormous interest due to its three-dimensional(3D)large open framework for convenient Na+transport,yet its practical application is still limited by its inferior electron conductivity and sluggish Na+diffusion ***,the tiny Cr doped hierarchical NVP micro-flower cathodes(i.e.,Na_(3)V_(2-x)Crx(PO_(4))_(3)@C,x≤0.1),which are self-assembled with single-crystal nanoflake subunits in-situ coated with carbon nano-shell,are designed and fabricated via a scalable *** optimized cathode,i.e.,Na_(3)V_(1.94)Cr_(0.06)(PO_(4))_(3)@C(NVCP-6),was endowed with more electro-active Na(2)sites and higher electronic/ionic conductivity for efficient sodium *** from these competitive merits,the NVCP-6,when evaluated as a cathode towards NIBs,exhibits an ultrahigh-rate capability of 99.8 mAh·g^(-1)at 200 C and superior stability of 82.2%over 7300 cycles at 50 ***,the NVCP-6 based full NIBs display remarkable electrochemical properties in terms of both high-rate capacities and long-duration cycling properties at different temperatures(-20–50°C).The contribution,i.e.,the design of“four ounces can move a thousand pounds”,here will promote the practical industrial application of NVP towards advanced NIBs.

关键词： Na_(3)V_(2)(PO_(4))_(3)cathode tiny Cr doping active Na sites ultrahigh-rate capability Na-ion batteries

Flower-like tin oxide membranes with robust three-dimensional channels for efficient removal of iron ions from hydrogen peroxide

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Chinese Journal of Chemical Engineering 2024年第1期65卷 1-7页

作者： Risheng Shen Shilong li Yuqing Sun yuan Bai Jian Lu Wenheng Jing State Key Laboratory of Materials-Oriented Chemical Engineering Nanjing Tech UniversityNanjing 210009China National Energy Group Science and Technology Research Institute Co. Ltd.Nanjing 210023China

Membrane technology has become the mainstream process for the production of electronic grade hydrogen peroxide(H_(2)O_(2)).But due to the oxidation degradation of the organic membranes(***)by the strong oxidative radicals(e.g.OH)generated via the activation of H_(2)O_(2)by iron ions(Fe^(3+)),the short effective lifetime of membranes remains a *** nano tin oxide(SnO_(2))has great potential for the removal of Fe^(3+)in strongly oxidative H_(2)O_(2)because of its ability to stabilize H2O_(2)and preferentially adsorb Fe^(3+).Herein,we have designed for the first time a flower-like robust SnO_(2)membrane on the ceramic support by in situ template-free one-step hydrothermal *** three-dimensional loose pore structure in the membrane built by interlacing SnO_(2)nanosheets endows the SnO_(2)membrane with a high specific surface area and abundant adsorption sites(AOH).Based on the coordination complexation and electrostatic attraction between the SnO_(2)surface and Fe^(3+),the membrane shows a high Fe3+removal efficiency(83%)and permeability(24 L·m^(-2)·h^(-1)·MPa^(-1))in H_(2)O_(2).This study provides an innovative and simple approach to designing robust SnO_(2)membranes for highly efficient removal of Fe^(3+)in harsh environments,such as strong oxidation conditions.

关键词： Hydrogen peroxide SnO_(2)membrane Adsorption Hydrothermal

qSTA2-2,a novel QTL that contributes to seed starch synthesis in Zea mays L.

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Journal of Integrative Agriculture 2024年第4期23卷 1118-1133页

作者： Minghao Cai Xuhui li Zhi liang Jie Wang Delin li Zhipeng yuan Riliang Gu Jianhua Wang li li State Key Laboratory of Maize Bio-breeding/Key Laboratory of Crop Heterosis Utilization Ministry of Education/Beijing Innovation Center for Crop Seed Technology/College of Agronomy and BiotechnologyChina Agricultural UniversityBeijing 100193China Institute of Nanfan&Seed Industry Guangdong Academy of ScienceGuangzhou 510316China Institute of Crop Sciences Chinese Academy of Agricultural SciencesBeijing 100081China

The seed storage materials accumulate during seed development,and are essential for seed germination and seedling *** we employed two bi-parental populations of an F2:3 population developed from a cross of improved 220(I220,small seeds with low starch)and PH4CV(large seeds with high starch),as well as recombinant-inbred lines(RILs)of X178(high starch)and its improved introgression line I178(low starch),to identify the genes that control seed storage *** identified a total of 12 QTLs for starch,protein and oil,which explained 3.44-10.79%of the phenotypic *** them,qSTA2-1 identified in F2:3 and qSTA2-2 identified in the RILs partially overlapped at an interval of 7.314-9.554 Mb,and they explained 3.44-10.21%of the starch content variation,so they were selected for further *** mapping of qSTA2-2 with the backcrossed populations of ^(I220)/PH4CV in each generation narrowed it down to a 199.7 kb interval that contains 14 open reading frames(ORFs).Transcriptomic analysis of developing seeds from the near-isogenic lines(NILs)of ^(I220)/PH4CV(BC_(5)F_(2))showed that only 11 ORFs were expressed in 20 days after pollination(DAP)*** of them were upregulated and six of them were downregulated in NIL^(I220),and the differentially expressed genes(DEGs)between NIL^(I220) and NIL^(PH4CV) were enriched in starch metabolism,hormone signal transduction and glycosaminoglycan *** the eleven NIL^(I220) differential expressed ORFs,ORF4(Zm00001d002260)and ORF5(Zm00001d002261)carry 75%protein sequence similarity,both encodes an glycolate oxidase,were the possible candidates of *** analysis and validation indicated that mutation of the qSTA2-2 locus resulted in the dysfunction of ABA accumulation,the embryo/endosperm ratio and the starch and hormone levels.

关键词： QTL mapping seed starch transcriptomic analysis hormone

Energy-saving design and optimization of pressure-swing-assisted ternary heterogenous azeotropic distillations

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Chinese Journal of Chemical Engineering 2024年第4期68卷 1-7页

作者： lianjie Wu Kun Lu Qirui li lianghua Xu Yiqing Luo Xigang yuan Tianjin Key Laboratory of Organic Solar Cells and Photochemical Conversion College of Chemical and Chemical EngineeringTianjin University of TechnologyTianjin 300384China State Key Laboratory of Chemical Engineering Tianjin UniversityTianjin 300072China

A huge amount of energy is always consumed to separate the ternary azeotropic mixtures by *** heterogeneous azeotropic distillation and the pressure-swing distillation are two kinds of effective technologies to separate heterogeneous azeotropes without entrainer *** give better play to the synergistic energy-saving effect of these two processes,a novel pressure-swing-assisted ternary heterogeneous azeotropic distillation(THAD)process is proposed *** this process,the ternary heterogeneous azeotrope is decanted into two liquid phases before being refluxed into the azeotropic distillation column to avoid the aqueous phase remixing,and three columns'pressures are modified to decrease the flowrates of the recycle *** the dividing wall column and heat integration technologies are introduced to further reduce its energy consumption,and the pressureswing-assisted ternary heterogeneous azeotropic dividing-wall column and its heat integration structure are achieved.A genetic algorithm procedure is used to optimize the proposed *** design results show that the proposed processes have higher energy efficiencies and lower CO_(2)emissions than the published THAD process.

关键词： Distillation Separation Process control Process systems

Printable,flexible ceramic fiber paper based on electrospinning

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Rare Metals 2024年第6期43卷 2739-2746页

作者： Yong-Shuai Xie yuan Cheng Yang Lyu Rui li Jie-Cai Han National Key Laboratory of Science and Technology on Advanced Composites in Special Environments Harbin Institute of TechnologyHarbin 150001China State Key Laboratory of Intelligent Manufacturing Equipment and Technology Huazhong University of Science and TechnologyWuhan 430074China

Based on the fact that it is challenging for the polymer flexible circuit substrates to meet the requirements of serving in high-temperature environments,this work proposed the idea of using printable ceramic fiber paper as a high-temperature flexible circuit substrate.A ceramic fiber paper with all ceramic components had been developed via electrospinning,solving the problems of low strength and severe strength drop at high temperatures of traditional ceramic fiber *** tensile strength of the prepared ceramic fiber paper is 2.63 MPa,and the reliable service temperature is 1200℃.Its bulk density is about 1.5 times that of traditional ceramic fiber *** can be printed with patterns by commercial inkjet printers like ordinary printing paper and has excellent *** feasibility of ceramic fiber paper as a flexible circuit substrate was verified by constructing a simple *** the fiber paper is significantly bent,the circuit still forms a complete path,which proves that it has a strong application potential for high-temperature flexible circuit substrate and is expected to promote the development of flexible electronic devices serving at extreme high-temperature environments.

关键词： Ceramic fiber paper High temperature Inkjet printing Flexible electronic

Anti-explosion performance and dynamic response of an innovative multi-layer composite explosion containment vessel

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Defence Technology（防务技术） 2024年第6期36卷 105-121页

作者： Zhen Wang Heng Chen Qi yuan Wenbin Gu Xingbo Xie Hongwei li College of Field Engineering Army Engineering University of PLANanjing 210007China College of Civil Engineering and Architecture Southwest University of Science and TechnologySichuanMianyang 621010China

An innovative multi-layer composite explosion containment vessel(CECV)utilizing a sliding steel platealuminum honeycomb-fiber cloth sandwich is put forward to improve the anti-explosion capacity of a conventional single-layer explosion containment vessel(SECV).Firstly,a series of experiments and finite element(FE)simulations of internal explosions are implemented to understand the basic anti-explosion characteristics of a SECV and the rationality of the computational models and methods is verified by the comparison between the experimental results and simulation *** on this,the CECV is designed in detail and a variety of FE simulations are carried out to investigate effects of the sandwich structure,the explosive quantity and the laying mode of the fiber cloth on anti-explosion performance and dynamic response of the CECV under internal *** results indicate that the end cover is the critical position for both the SECV and *** maximum pressure of the explosion shock wave and the maximum strain of the CECV can be extremely declined compared to those of the *** a result,the explosive quantity the CECV can sustain is up to 20 times of that the SECV can ***,as the explosive quantity increases,the internal pressure of the CECV keeps growing and the plastic deformation and failure of the sandwich structure become more and more severe,yielding plastic strain of the CECV in addition to elastic *** results also reveal that the laying angles of the fiber cloth's five layers have an impact on the anti-explosion performance of the *** example,the CECV with fiber cloth layered in 0°/45°/90°/45°/0°mode has the optimal anti-capacity,compared to 0°/0°/0°/0°/0°and 0°/30°/60°/30°/0°***,owing to remarkable anti-explosion capacity,this CECV can be regarded as a promising candidate for explosion resistance.

关键词： Explosive container Honeycomb-fiber cloth Anti-explosion Aluminum honeycomb core Composite

A performance prediction method for on-site chillers based on dynamic graph convolutional network enhanced by association rules

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Building Simulation 2024年第7期17卷 1213-1229页

作者： Qiao Deng Zhiwen Chen Wanting Zhu Zefan li Yifeng yuan Weihua Gui School of Automation Central South UniversityChangsha 410083China Xiangjiang Laboratory of Hunan Province Changsha 410205China Shenzhen DAS Intellitech Co. Ltd.Shenzhen 518057China

Accurately predicting the chiller coefficient of performance(COP)is essential for improving the energy efficiency of heating,ventilation,and air conditioning(HVAC)systems,significantly contributing to energy conservation in *** performance prediction methods often overlook the dynamic interaction among sensor variables and face challenges in using extensive historical data efficiently,which impedes accurate *** overcome these challenges,this paper proposes an innovative on-site chiller performance prediction method employing a dynamic graph convolutional network(GCN)enhanced by association *** distinctive feature of this method is constructing an association graph bank containing static graphs in each operating mode by mining the association rules between various sensor variables in historical operating data.A real-time graph is created by analyzing the correlation between various sensor variables in the current operating *** graph is fused online with the static graph in the current operating mode to obtain a dynamic graph used for feature extraction and training of *** effectiveness of this method has been empirically confirmed through the operational data of an actual building chiller *** analysis with state-of-the-art methods highlights the superior performance of the proposed method.

关键词： chillers performance prediction dynamic graph convolutional network association rules operating modes

Flow Boiling Heat Transfer Characteristics and Delayed Dry-Out Ability of Non-Azeotropic Mixtures R245fa/R134a in Microchannels

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Journal of Thermal Science 2024年第3期33卷 1174-1188页

作者： LU Yongjie liNG Yongjun ZHUANG yuan li Chenyang OUYANG Hongsheng HAN Xiaohong Key Laboratory of Refrigeration and Cryogenic Technology of Zhejiang Province Institute of Refrigeration and CryogenicsZhejiang UniversityHangzhou310007China Zhejiang Zhongguang Electrical Co. Ltd.Lishui323000China State Key Lab for Fluorine Greenhouse Gases Replacement and Control Treatment Zhejiang Research Institute of Chemical IndustryHangzhou310014China

Microchannel flow boiling heat transfer has the advantages of strong heat dissipation capacity,good temperature uniformity,and compact *** is an excellent way to thermally manage electronic devices,but when the heat flux exceeds CHF(Critical Heat Flux),the heat transfer performance deteriorates as the working fluid dries ***-azeotropic mixtures have the potential to effectively delay or avoid dry-out during the boiling process due to their temperature slide characteristics which causes the mass transfer *** understand the influence of non-azeotropic mixtures on microchannel flow boiling,using the phase-change microchannel heat sink as the research object,the experiments on the flow boiling heat transfer performance of R245fa/R134a mixtures under different working conditions were carried out,and the characteristics of flow boiling heat transfer were obtained under the different working conditions,and comparison was developed with those of pure substance *** results demonstrated that a small amount of low-boiling-point components in the high-boiling-point working fluid inhibited boiling heat transfer to some extent,and lowered the average heat transfer coefficient under the non-dryout condition slightly lower than that of the pure substance;however,it also effectively delayed the onset of local dry-out and prevented significant deterioration in thermal transfer performance under the lower mass flow rate and higher heat flux,which could enhance the heat sink's stability.

关键词： microchannel flow boiling non-azeotropic mixture heat transfer characteristics dry-out

pH Induced Self-assembly of AIE Fluorescent Probe for Tumor Imaging

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Chinese Journal of Polymer Science 2024年第1期42卷 7-13,I0005页

作者： Jing-yuan Xiang Wen-Long Zhang He-Ting li Ya-Ning He Department of Chemical Engineering Key Laboratory of Advanced Materials(MOE)Tsinghua UniversityBejing 100084China

This work reported an AIE fluorescent probe for tumor imaging based on the p H induced self-assembly strategy. The fluorescent probe was composed of an acid-responsive soluble copolymer PEG-b-PAMA-DMMA with a maleic acid amide group and an anionic soluble aggregation-induced emission fluorogen(AIEgen) TPE-2SO_(3)^(-). The polymer could be transformed into a protonated amine-containing polymer after the hydrolysis of maleic acid amide in acidic tumor microenvironment, which would be further self-assembled with TPE-2SO_(3)^(-)to form aggregated nanoparticles. The transition of TPE-2SO_(3)^(-)from dispersed state to aggregated state led to an obvious increase in fluorescence intensity due to its AIE characteristics.

关键词： p H-responsive Self-assembly Fluorescent probe AIE Tumor imaging