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Well-dispersed NiCoS_(2) nanoparticles/rGO composite with a large specific surface area as an oxygen evolution reaction electrocatalyst

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Rare Metals 2021年第11期40卷 3156-3165页

作者： Duan Wang yu-xin chang Ya-Ru Li Shi-Lin Zhang Sai-Long Xu School of Environment and Safety Engineering North University of ChinaTaiyuan 030051China State Key Laboratory of Chemical Resource Engineering Beijing University of Chemical TechnologyBeijing 100029China Institute for Superconducting and Electronic Materials School of MechanicalMaterialsMechatronics and Biomedical EngineeringUniversity of WollongongWollongong 2522Australia

Developing efficient oxygen evolution reaction(OER) electrocatalysts such as transition metal sulfides(TMSs) is of great importance to advance renewable hydrogen fuel toward further practical ***,NiCoS_(2) nanoparticles well decorated on double-sided N-doped reduced graphene oxide sheets(NiCoS_(2)/rGO) are prepared from an Al-containing ternary NiCoAl-layered double hydroxide precursor(NiCoAl-LDH) grown on GO support as an OER *** Al-confinementassisted sulfurization,followed by selective acid treatment,endows the resulting NiCoS_(2)/rGO composite with the advantages:well-dispersed NiCoS_(2) nanoparticles,dualsided rGO support,as well as a large specific surface area of 119.4 m^(2)·g^(-1) and meso-/macroporous size *** NiCoS_(2)/rGO electrocatalyst exhibits an overpotential of 273 mV at 10 mA·cm^(-2) and a good stability of 24 h,which outperform those of the counterparts of NiS_(2)/rGO and CoS_(2)/*** results of electrochemical active surface area and electrochemical impedance spectra experimentally provide convincing rationales of the information of active sites and good conductivity,both underpin the enhanced electrocatalytic performances.

关键词： NiCoS_(2)nanoparticles Double-sided support Layered double hydroxide precursor Large specific surface area Oxygen evolution reaction

Elucidation of the sodium kinetics in layered P-type oxide cathodes

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Science China Chemistry 2022年第10期65卷 2005-2014页

作者： Lianzheng yu Haojie Dong yu-xin chang Zhiwei Cheng Kang Xu Yi-Hu Feng Duo Si Xu Zhu Mengting Liu Bing Xiao Peng-Fei Wang Sailong Xu State Key Laboratory of Chemical Resource Engineering Beijing University of Chemical TechnologyBeijing 100029China Center of Nanomaterials for Renewable Energy State Key Laboratory of Electrical Insulation and Power EquipmentSchool of Electrical EngineeringXi’an Jiaotong UniversityXi’an 710049China

Sodium-ion intercalation oxides generally possess high compositional diversity according to their different stacking *** sodium diffusion pathway in layered P-type materials used in sodium-ion batteries is open,which can increase their rate capability by directly transmitting Na+between adjacent triangular prismatic channels,rather than passing through an intermediate tetrahedral site in O-type ***,how the structure chemistry of the P-type oxides determines their electrochemical properties has not been fully understood ***,by comparing the crystalline structures,electrochemical behaviors,ion/electron transport dynamics of a couple of P-type intercalation cathodes,P2-Na_(2/3)Ni1/3Mn_(2/3)O_(2)and P3-Na_(2/3)Ni_(1/3)Mn_(2/3)O_(2)with the same compositions,we demonstrate experimentally and computationally that the P2 phase delivers better cycling stability and rate capability than the P3 counterpart due to the predominant contribution of the faster intrinsic Na diffusion kinetics in the P2 *** also point out that it is the electronic conductivity that captures the key electrochemistry of layered P3-type materials and makes them possible to enhance the sodium storage *** results reveal that the correlation between stacking structure and functional properties in two typical layered P-type cathodes,providing new guidelines for preparing and designing alkali-metal layered oxide materials with improved battery performance.

关键词： sodium-ion batteries cathode P2 phase P3 phase kinetics

Severity of sepsisis is correlated with the elevation of serum high-mobility group box 1 in rats

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Chinese Medical Journal 2009年第4期122卷 449-454页

作者： HOU Li-chao QIN Ming-zhe ZHENG Li-na LU Yan WANG Qiang PENG Dao-rong yu xin-ping xin yu-chang JI Gen-lin XIONG Li-ze Department of Anesthesiology Xijing Hospital Fourth Military Medical University Xi'an Shaanxi 710032 China Center for Clinical Laboratory Medicine of People's LiberationArmy Department of Clinical Laboratory Xijing Hospital Fourth Military Medical University Xi'an Shaanxi 710032 China Department of Anesthesiology Tangdu Hospital Fourth Military Medical University Xi'an Shaanxi 710038 China

Background Sepsis is a leading cause of death in the intensive care units. The late inflammatory cytokine, high-mobility group box 1 （HMGB1）, plays a critical role in sepsis. In the present study, we investigated the association between the serum HMGB1 levels and the severity of organ injury in the lipopolysaccharide-induced sepsis in rats. Methods To produce an animal model of sepsis with different degree of organ injury, animals were treated with three different doses of lipopolysaccharide （4, 8 and 16 mg/kg）, and the animals in control group were treated with the same volume of the vehicle （saline）. The levels of serum HMGB1 were measured at 0, 2, 4, 8, 16, 24, 32 and 48 hours after lipopolysaccharide （LPS） or vehicle injection, meanwhile the biochemical and histopathological indicators for the severity of organ injury were assessed. Results The level of HMGB1 had a positive, high correlation with the abnormal changes of serum cardiac troponin I, alanine aminotransferase, aspartate aminotransferase, creatinine and blood urea nitrogen, as well as the pathologic scores of heart, lung, liver and kidney. Conclusions The level of serum HMGB1 is highly correlated with the severity of sepsis in rats, suggesting that HMGB1 could serve as a valuable adjunct in the diagnosis and management of sepsis.

关键词： lipopolysaccharide sepsis high-mobility group box 1 rat

考虑热效应的圆柱滚子轴承内外圈位移及滚道应力特性分析

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机械工程学报 2022年第5期58卷 151-160页

作者：郝旭李宁于长鑫翟敬宇瓦房店轴承集团国家轴承工程技术研究中心有限公司大连116300 大连理工大学机械工程学院大连116024

针对圆柱滚子轴承热特性如何影响轴承内外圈变形等轴承接触力学特性机理不明的问题,开展了考虑温度、转速、润滑等参数影响圆柱滚子轴承内外圈位移及滚道应力特性的动态分析。建立了轴承系统热-力耦合有限元模型,通过测试轴承变形量以... 详细信息

针对圆柱滚子轴承热特性如何影响轴承内外圈变形等轴承接触力学特性机理不明的问题,开展了考虑温度、转速、润滑等参数影响圆柱滚子轴承内外圈位移及滚道应力特性的动态分析。建立了轴承系统热-力耦合有限元模型,通过测试轴承变形量以及网格尺寸合理性分析验证了有限元模型的有效性。分析了不同转速、润滑油温度与流速下轴承内外圈位移及滚道应力特性。结果表明,轴承套圈位移随转速的增加逐渐增加;润滑油温度对滚道应力的影响取决于轴承游隙的大小,低温润滑下轴承滚道应力较大;轴承从启动状态到热平衡状态过程中内外圈位移变化明显,不同套圈角位置处位移变化幅度不同,整体上外圈位移大于内圈位移。

关键词：圆柱滚子轴承热特性套圈变形滚道应力

Extraction of U(VI) and Th(IV) with a novel extractant N,N'-tetrahexylmalonamide (THMA) in toluene

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Nuclear Science and Techniques 1998年第2期9卷 115-117页

作者： Sun Guo-xin Han Jing-Tian Bao Bo-Rong (Shanghai Institute of Nuclear Research, the Chinese Academy of Sciences, Shanghai 201800)Bao Meng Cui yu and Liu chang-xin (Department of Applied Chemistry, Institute of Shandong Building Materials Industry,Jinan ShanghaiInstituteofNuclearResearch TheChineseAcademyofSciencesShanghai201800 DepartmentofAppliedChem

The dependence of THMA extraction behaviour for U(VI) alld Th(IV) on nitric acid concentration, THMA concentration and molecular structure of extracted complex has been studied. For nitric acid solutions of 3.0mol/L a coordinative mechanism may possibly dominate in the extraction of metal cations. The complex composition of UO2(NO3)2(THMA)2,Th(NO3)4 (THMA)2 and Th(NO3)4 (THMA)3 are proved.

关键词：铀钍溶剂提取

Metal-organic frameworks with dinuclear metal centers for synergistically boosting CO2 photoreduction

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Science China Chemistry 2025年第01期 201-208页

作者： Hui-Feng Wang Wen-Jie Shi yu-xin Yang Bao-Xia Dong Tong-Bu Lu Di-chang Zhong School of Chemistry and Chemical Engineering Yangzhou University Institute for New Energy Materials and Low Carbon Technologies School of Materials Science and Engineering Tianjin University of Technology

Dinuclear metal synergistic catalysis （DMSC） has been proved powerful in boosting CO2reduction,while this has not been achieved in heterogeneous catalysts with long-range order *** this study,we,by introduction of metal catalytic centers into an indium-based metal-organic framework （MOF）,obtained a series of isostructural In-MOFs,including three MOFs with mononuclear metal catalytic center （M-In）,three MOFs with dinuclear homometallic catalytic centers （MM-In）,and three MOFs with dinuclear heterometallic catalytic centers (MM’-In,M/M’=Co（II）,Ni（II）,Zn（II）).It was found that all these MOFs can serve as catalysts for photochemical CO2reduction to *** with M-In,the catalytic activities of MM-In were obviously enhanced,and that of MM’-In was further significantly *** example,the CO yield of Co Zn-In reaches a record value of 12,700μmol g-1h-1,which is 4.0,8.1,9.4,and 18.6-fold higher than that of Co Co-In,Zn Zn-In,Co-In,and Zn-In,***,the catalytic activities of Co Ni-In and Ni Zn-In also show different fold increase than those of corresponding dinuclear homometallic and mononuclear metallic *** results of control experiments and theoretical calculation reveal that the higher catalytic activities of MM-In over M-In can be ascribed to the DMSC effect,and the higher catalytic activity of MM’-In over MM-In can be ascribed to the strengthened DMSC *** work reveals the relationship between DMSC effect and bimetal centers in CO2reduction,which provides new insights into the DMSC and paves a new way to design highly active catalysts for photochemical CO2reduction.

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Targeting TrkB–PSD-95 coupling to mitigate neurological disorders

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Neural Regeneration Research 2025年第3期20卷 715-724页

作者： xin Yang yu-Wen Alvin Huang John Marshall Department of Molecular Biology Cell Biology and BiochemistryBrown UniversityProvidenceRIUSA Department of Neurology Warren Alpert Medical School of Brown UniversityProvidenceRIUSA Center for Translational Neuroscience Robert J.and Nancy D.Carney Institute for Brain Science and Brown Institute for Translational ScienceBrown UniversityProvidenceRIUSA

Tropomyosin receptor kinase B(TrkB)signaling plays a pivotal role in dendritic growth and dendritic spine formation to promote learning and *** activity-dependent release of brain-derived neurotrophic factor at synapses binds to pre-or postsynaptic TrkB resulting in the strengthening of synapses,reflected by long-term ***,the association of postsynaptic density protein-95 with TrkB enhances phospholipase Cγ-Ca^(2+)/calmodulin-dependent protein kinaseⅡand phosphatidylinositol 3-kinase-mechanistic target of rapamycin signaling required for long-term *** this review,we discuss TrkB-postsynaptic density protein-95 coupling as a promising strategy to magnify brain-derived neurotrophic factor signaling towards the development of novel therapeutics for specific neurological disorders.A reduction of TrkB signaling has been observed in neurodegenerative disorders,such as Alzheimer's disease and Huntington's disease,and enhancement of postsynaptic density protein-95 association with TrkB signaling could mitigate the observed deficiency of neuronal connectivity in schizophrenia and *** with brain-derived neurotrophic factor is problematic,due to poor pharmacokinetics,low brain penetration,and side effects resulting from activation of the p75 neurotrophin receptor or the truncated TrkB.T1 *** TrkB agonists and antibodies that activate TrkB are being intensively investigated,they cannot distinguish the multiple human TrkB splicing isoforms or cell type-specific *** TrkB–postsynaptic density protein-95 coupling provides an alternative approach to specifically boost TrkB signaling at localized synaptic sites versus global stimulation that risks many adverse side effects.

关键词： Angelman syndrome autism brain-derived neurotrophic factor depression neurodegenerative disorder neurodevelopmental disorder postsynaptic density protein-95 synaptic plasticity TrkB

Interconnections between diabetic corneal neuropathy and diabetic retinopathy:diagnostic and therapeutic implications

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Neural Regeneration Research 2025年第8期20卷 2169-2180页

作者： Mingyi yu Faith Teo En Ning chang Liu yu-Chi Liu Tissue Engineering and Stem Cell Group Singapore Eye Research InstituteSingapore Yong Loo Lin School of Medicine National University of SingaporeSingapore Department of Cornea and External Eye Disease Singapore National Eye CenterSingapore Ophthalmology and Visual Sciences Academic Clinical Program Duke-NUS Medical SchoolSingapore

Diabetic corneal neuropathy and diabetic retinopathy are ocular complications occurring in the context of diabetes *** corneal neuropathy refers to the progressive damage of corneal *** retinopathy has traditionally been considered as damage to the retinal ***,growing evidence suggests that diabetic retinopathy is a complex neurovascular disorder resulting from dysfunction of the neurovascular unit,which includes both the retinal vascular structures and neural *** retinopathy is one of the leading causes of blindness and is frequently screened for as part of diabetic ocular ***,diabetic corneal neuropathy is commonly overlooked and underdiagnosed,leading to severe ocular surface *** studies have found that these two conditions tend to occur together,and they share similarities in their pathogenesis pathways,being triggered by a status of chronic *** review aims to discuss the interconnection between diabetic corneal neuropathy and diabetic retinopathy,whether diabetic corneal neuropathy precedes diabetic retinopathy,as well as the relation between the stage of diabetic retinopathy and the severity of corneal *** also endeavor to explore the relevance of a corneal screening in diabetic eyes and the possibility of using corneal nerve measurements to monitor the progression of diabetic retinopathy.

关键词： cornea corneal nerves diabetes diabetic corneal neuropathy diabetic retinopathy retina

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化学氧呼吸器生氧装置防护性能数值模拟

工程科学学报 2015年第9期37卷 1198-1205页

作者：焦璐璐刘应书祝显强余新昌北京科技大学机械工程学院北京100083

以实验室化学氧呼吸器生氧装置为研究对象,建立了二维轴对称数学模型,对生氧装置防护性能进行了数值模拟.首先通过模型验证实验验证了模型的合理性,其次对比研究了劳动强度、入口CO2体积分数、生氧药剂颗粒当量直径以及入口管径对生氧... 详细信息

以实验室化学氧呼吸器生氧装置为研究对象,建立了二维轴对称数学模型,对生氧装置防护性能进行了数值模拟.首先通过模型验证实验验证了模型的合理性,其次对比研究了劳动强度、入口CO2体积分数、生氧药剂颗粒当量直径以及入口管径对生氧装置防护时间和出口温度的影响.结果表明:劳动强度和入口CO2体积分数对生氧装置防护性能影响显著,高劳动强度和高CO2体积分数均会引起防护时间缩短以及出口峰值温度升高;颗粒当量直径与防护时间近似呈负相关线性关系,12 mm颗粒的防护时间比6 mm颗粒少32.15 min,但是大粒径颗粒会使得出口峰值温度显著降低;入口管径对生氧装置防护时间和出口温度的影响均非常有限.

关键词：呼吸器生氧装置防护时间出口温度数值模拟