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Unveiling the role of Ni in Ru-Ni oxide for oxygen evolution: Lattice oxygen participation enhanced by structural distortion

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Journal of Energy Chemistry 2023年第2期77卷 54-61,I0003页

作者： young-Jin Ko Man Ho Han Chulwan Lim Seung-Ho Yu Chang Hyuck Choi Byoung Koun Min jae-young Choi Woong Hee Lee Hyung-Suk Oh Clean Energy Research Center Korea Institute of Science and Technology(KIST)Hwarang-ro 14-gil 5Seongbuk-guSeoul 02792Republic of Korea Department of Chemical and Biological Engineering Korea University145Anam-roSeongbuk-guSeoul 02841Republic of Korea Department of Chemistry Pohang University of Science and Technology(POSTECH)Pohang 37673Republic of Korea National Agenda Research Division Korea Institute of Science and Technology(KIST)Hwarang-ro 14-gil 5Seonbuk-guSeoul 02792Republic of Korea Graduate School of Energy and Environment(KU-KIST Green School) Korea University145 Anam-roSeongbuk-guSeoul 02841Republic of Korea School of Advanced Materials Science&Engineering Sungkyunkwan University(SKKU)Suwon 16419Republic of Korea KIST-SKKU Carbon-Neutral Research Center Sungkyunkwan University(SKKU)Suwon 16419Republic of Korea

Introducing Ni in Ru oxide is a promising approach to enhance the catalytic activity for the oxygen evolution reaction(OER).However,the role of Ni(which has a poor intrinsic activity)is not fully ***,a Ru NiO_(x)electrode fabricated via a modified dip coating method exhibited excellent OER performance in acidic media,and neutral media for CO_(2)reduction *** combined in-situ/operando X-ray absorption near-edge structure and on-line inductively coupled plasma mass spectrometry studies to unveil the role of the Ni introduced in the Ru *** propose that the Ni not only transforms the electronic structure of the Ru oxide,but also produces a large number of oxygen vacancies by distorting the oxygen lattice structure at low overpotentials,increasing the participation of lattice oxygen for *** work demonstrates the real behavior of bimetallic oxide materials under applied potentials and provides new insights into the development of efficient electrocatalysts.

关键词： Oxygen evolution reaction Ru electrode Ni electrode Oxygen vacancies In-situ/Operando studies

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Function-regeneration of non-porous hydrolyzed-MOF-derived materials

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Nano Research 2019年第8期12卷 1921-1930页

作者： Yo Chan Jeong Jin Weon Seo jae Ho Kim Seunghoon Nam Min Chang Shin young Shik Cho Jin Syul Byeon Chong Rae Park Seung jae Yang Carbon Nanomaterials Design Laboratory Research Institute of Advanced Materials and Department of Materials Science and Engineering Seoul National UniversitySeoul 08826Republic of Korea Advanced Nanohybrids Lab. Department of Chemical Engineering Inha UniversityIncheon 22212Republic of Korea School of Advanced Materials Engineering College of Engineering Andong National University Andong Gyeongsangbuk-do 36729Republic of Korea

A facile synthetic strategy based on a water-based process is developed for the preparation of metal-organic framework (MOF)-derived materials by revisiting the hydrolyzed non-porous metal-organic frameworks (h-MOF). The poor water stability of MOF has been recognized as key limitations for its commercialization and large-scale applications because the hydrolysis resulted in the complete loss of their functionalities. However, we found that the negative effect of hydrolysis on MOF can be nullified during the heat treatment. As similar to the intact MOF, h-MOF can be used as a precursor for the preparation of MOF-derived materials from porous MOF-derived carbons (MDCs) to MDC@ZnO composites. The property of h-MOF-derived materials is almost equivalent to that of MOF-derived materials. In addition, h-MOF turned the weakness of water instability to the strength of facile water-based process for hybridization. With the demonstration of the hybrid composite between h-MDC@ZnO and reduced graphene oxide (rGO) as a prototype example, it exhibited superior electrochemical performance when evaluated as an electrode material for lithium-ion batteries.

关键词： nanomaterials metal-organic framework (MOF) porous materials MOF-derived carbon hydrolyzed MOF

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Utilizing 3,4-ethylenedioxythiophene(EDOT)-bridged non-fullerene acceptors for efficient organic solar cells

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Journal of Energy Chemistry 2022年第2期31卷 194-204页

作者： Sung jae Jeon young Hoon Kim Ie Na Kim Nam Gyu Yang Ji Hee Yun Doo Kyung Moon Nano and Information Materials(NIMs)Laboratory Department of Chemical EngineeringKonkuk University120 Neungdong-ro Gwangjin-guSeoul 05029South Korea Department of Academy of Applied Science and Technology Konkuk University120 Neungdong-ro Gwangjin-guSeoul 05029South Korea

A rational design of efficient low-band-gap non-fullerene acceptors(NFAs)for high-performance organic solar cells(OSCs)remains challenging;the main constraint being the decrease in the energy level of the lowest unoccupied molecular orbitals(LUMOs)as the bandgap of A-D-A-type NFAs ***,the short current density(J_(sc))and open-circuit voltage(V_(oc))result in a trade-off relationship,making it difficult to obtain efficient ***,three NFAs(IFL-ED-4 F,IDT-ED-4 F,and IDTT-ED-2 F)were synthesized to address the above-mentioned issue by introducing 3,4-ethylenedioxythiophene(EDOT)as aπ-*** NFAs exhibit relatively low bandgaps(1.67,1.42,and 1.49 eV,respectively)and upshifted LUMO levels(-3.88,-3.84,and-3.81 eV,respectively)compared with most reported low-band-gap ***,the photovoltaic devices based on IDT-ED-4 F blended with a PBDB-T donor polymer showed the best power conversion efficiency(PCE)of 10.4%with a high J_(sc) of 22.1 mA cm^(-2) and Voc of 0.884 V among the examined *** contrast,IDTT-ED-4 F,which was designed with an asymmetric structure of the D-p-A type,showed the lowest efficiency of 1.5%owing to the poor morphology and charge transport properties of the binary ***,when this was introduced as the third component of the PM6:BTP-BO-4 Cl,complementary absorption and cascade energy-level alignment between the two substances could be ***,the IDTT-ED-4 F-based ternary blend device not only improved the Jscand Voc,but also achieved a PCE of 15.2%,which is approximately 5.3%higher than that of the reference device with a minimized energy loss of 0.488 *** addition,the universality of IDTT-ED-2 F as a third component was effectively demonstrated in other photoactive systems,specifically,PM6:BTPe C9 and PTB7-Th:IEICO-4 *** work facilitates a better understanding of the structure–property relationship for utilizing efficient EDOT-bridged NFAs in high-performance OSC applications.

关键词： Non-fullerene acceptor 3,4-ethylenedioxythiophene Organic solar cell π-bridge π-spacer

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Electrical resistivity evolution in electrodeposited Ru and Ru-Co nanowires

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Journal of Materials Science & Technology 2022年第10期105卷 17-25页

作者： Jun Hwan Moon Seunghyun Kim Taesoon Kim Yoo Sang Jeon Yanghee Kim jae-Pyoung Ahn young Keun Kim Department of Materials Science and Engineering Korea UniversitySeoul 02841Republic of Korea Institute of Engineering Reserch Korea UniversitySeoul 02481Republic of Korea Advanced Analysis Center Korea Institute of Science and TechnologySeoul 02792Republic of Korea Research Resources Division Korea Institute of Science and TechnologySeoul 02792Republic of Korea

Nanoscale ruthenium(Ru)-based materials are promising replacements for existing multilayered Cu interconnects in integrated ***,it is not easy to apply the results of previously reported studies directly to the electrochemical damascene process because the previous studies have mainly focused on thin flms by dry ***,we report the electrical resistivity and microstructure of electrodeposited Ru *** estimate that the resistivity value of a 10 nm diameter Ru nanowire to be71.6μΩcm after analyzing the resistivity values of individual nanowires with various ***,we investigate the electrical properties of Ru_(x)Co_(1-x)nanowires where x is 0.04–0.99 at.%as possible replacements of the current Ta N barrier *** the entire composition range,the resistivity values of alloys are much lower than that of the conventional Ta ***,Ru and Ru-alloy nanowires surrounded by dielectric silica are thermally stable after 450°C heat ***,the nanoscale Ru and Ru-Co alloys possessing low resistivity values can be candidates for the interconnect and barrier materials,respectively.

关键词： Ruthenium(Ru) Ruthenium-cobalt(Ru-Co) Nanowire Electrical resistivity Microstructure Electrodeposition

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Monolayer Graphitic Carbon Nitride as Metal-Free Catalyst with Enhanced Performance in Photo- and Electro-Catalysis

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Nano-Micro Letters 2022年第3期14卷 308-321页

作者： Huiyan Piao Goeun Choi Xiaoyan Jin Seong‑Ju Hwang young jae Song Sung‑Pyo Cho Jin‑Ho Choy Intelligent Nanohybrid Materials Laboratory(INML) Institute of Tissue Regeneration Engineering(ITREN)Dankook UniversityCheonan 31116Republic of Korea College of Science and Technology Dankook UniversityCheonan 31116Republic of Korea Department of Nanobiomedical Science and BK21 PLUS NBM Global Research Center for Regenerative Medicine Dankook UniversityCheonan 31116Republic of Korea Department of Materials Science and Engineering College of EngineeringYonsei UniversitySeoul 03722Republic of Korea SKKU Advanced Institute of Nanotechnology(SAINT) Sungkyunkwan University(SKKU)Suwon 440‑746Republic of Korea Department of Nano Engineering Sungkyunkwan University(SKKU)Suwon 440‑746Republic of Korea National Center for Inter‑University Research Facilities(NCIRF) Seoul National UniversitySeoul 08826Republic of Korea Graphene Research Center Advanced Institute of Convergence TechnologySuwon 16229Republic of Korea Department of Pre‑Medical Course College of MedicineDankook UniversityCheonan 31116Republic of Korea Tokyo Tech World Research Hub Initiative(WRHI) Institute of Innovative ResearchTokyo Institute of TechnologyYokohama 226‑8503Japan

The exfoliation of bulk graphitic carbon nitride(g-C_(3)N_(4))into monolayer has been intensively studied to induce maximum sur-face area for fundamental studies,but ended in failure to realize chemi-cally and physically well-defined monolayer of g-C_(3)N_(4)mostly due to the difficulty in reducing the layer thickness down to an atomic *** has,therefore,remained as a challenging issue in two-dimensional(2D)chemistry and physics *** this study,an“atomic monolayer of g-C_(3)N_(4)with perfect two-dimensional limit”was successfully prepared by the chemically well-defined two-step *** atomically resolved monolayer of g-C_(3)N_(4)was also confirmed by spectroscopic and micro-scopic *** addition,the experimental Cs-HRTEM image was collected,for the first time,which was in excellent agreement with the theoretically simulated;the evidence of monolayer of g-C_(3)N_(4)in the perfect 2D limit becomes now clear from the HRTEM image of orderly hexagonal symmetry with a cavity formed by encirclement of three adjacent heptazine *** to bulk g-C_(3)N_(4),the present g-C_(3)N_(4)monolayer showed significantly higher photocatalytic gen-eration of H2O2 and H2,and electrocatalytic oxygen reduction *** addition,its photocatalytic efficiency for H2O2 production was found to be the best for any known g-C_(3)N_(4)nanomaterials,underscoring the remarkable advantage of monolayer formation in optimizing the catalyst performance of g-C_(3)N_(4).

关键词： Graphitic carbon nitride Monolayer Atomic image Electro-and photo-catalysis

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Improved MIMO Signal Detection Based on DNN in MIMO-OFDM System

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Computers, Materials & Continua 2022年第2期70卷 3625-3636页

作者： jae-Hyun Ro Jong-Gyu Ha Woon-Sang Lee young-Hwan You Hyoung-Kyu Song Department of Convergence Engineering for Intelligent Drone Sejong UniversitySeoul05006Korea Department of Information and Communication Engineering Convergence Engineering for Intelligent DroneSejong UniversitySeoul05006Korea Department of Computer Engineering Convergence Engineering for Intelligent DroneSejong UniversitySeoul05006Korea

This paper proposes the multiple-input multiple-output(MIMO)detection scheme by using the deep neural network(DNN)based ensemble machine learning for higher error performance in wireless communication *** the MIMO detection based on the ensemble machine learning,all learning models for the DNN are generated in offline and the detection is performed in online by using already learned *** the offline learning,the received signals and channel coefficients are set to input data,and the labels which correspond to transmit symbols are set to output *** the online learning,the perfectly learned models are used for signal detection where the models have fixed bias and *** performance improvement,the proposed scheme uses the majority vote and the maximum probability as the methods of the model combinations for obtaining diversity gains at the MIMO *** simulation results show that the proposed scheme has improved symbol error rate(SER)performance without additional receive antennas.

关键词： MIMO DNN ensemble machine learning ML

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Efficient Gauss-Seidel Precoding with Parallel Calculation in Massive MIMO Systems

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Computers, Materials & Continua 2022年第1期70卷 491-504页

作者： Hyun-Sun Hwang jae-Hyun Ro Chan-Yeob Park young-Hwan You Hyoung-Kyu Song Department of Information and Communication Engineering Convergence Engineering for Intelligent DroneSejong UniversitySeoul05006Korea Department of Convergence Engineering for Intelligent Drone Sejong UniversitySeoul05006Korea Department of Computer Engineering Convergence Engineering for Intelligent DroneSejong UniversitySeoul05006Korea

A number of requirements for 5G mobile communication are satisfied by adopting multiple input multiple output(MIMO)*** inter user interference(IUI)which is an inevitable problem in MIMO systems becomes controllable when the precoding scheme is *** this paper,the horizontal Gauss-Seidel(HGS)method is proposed as precoding scheme in massive MIMO *** massive MIMO systems,the exact inversion of channel matrix is impractical due to the severe computational ***,the conventionalGauss-Seidel(GS)method is used to approximate the inversion of channel *** GS has good performance by using previous calculation results as ***,the required time for obtaining the precoding symbols is too long due to the sequential process of ***,the HGS with parallel calculation is proposed in this paper to reduce the required *** rows of channel matrix are eliminated for parallel calculation *** addition,HGSuses the ordered channelmatrix to prevent performance degradation which is occurred by parallel *** HGS with proper number of parallelly computed symbols has better performance and reduced required time compared to the traditional GS.

关键词： Massive MIMO GS matrix inversion linear precoding

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Evaluation of simulated CO_2 Concentrations from the CarbonTracker-Asia Model Using In-situ Observations over East Asia for 2009–2013

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Advances in Atmospheric Sciences 2019年第6期36卷 603-613页

作者： Samuel Takele KENEA young-Suk OH jae-Sang RHEE Tae-young GOO young-Hwa BYUN Shanlan LI Lev D.LABZOVSKII Haeyoung LEE Robert F.BANKS Climate Research Division National Institute of Meteorological Sciences Environmental Meteorology Research Division National Institute of Meteorological Sciences Meteorology Department Delta Air LinesInc.

The CarbonTracker(CT) model has been used in previous studies for understanding and predicting the sources, sinks, and dynamics that govern the distribution of atmospheric CO_2 at varying ranges of spatial and temporal scales. However, there are still challenges for reproducing accurate model-simulated CO_2 concentrations close to the surface, typically associated with high spatial heterogeneity and land cover. In the present study, we evaluated the performance of nested-grid CT model simulations of CO_2 based on the CT2016 version through comparison with in-situ observations over East Asia covering the period 2009–13. We selected sites located in coastal, remote, inland, and mountain areas. The results are presented at diurnal and seasonal time periods. At target stations, model agreement with in-situ observations was varied in capturing the diurnal cycle. Overall, biases were less than 6.3 ppm on an all-hourly mean basis, and this was further reduced to a maximum of 4.6 ppm when considering only the daytime. For instance, at Anmyeondo, a small bias was obtained in winter, on the order of 0.2 ppm. The model revealed a diurnal amplitude of CO_2 that was nearly flat in winter at Gosan and Anmyeondo stations, while slightly overestimated in the summertime. The model's performance in reproducing the diurnal cycle remains a challenge and requires improvement. The model showed better agreement with the observations in capturing the seasonal variations of CO_2 during daytime at most sites, with a correlation coefficient ranging from 0.70 to 0.99. Also, model biases were within-0.3 and 1.3 ppm, except for inland stations(7.7 ppm).

关键词： model evaluation in-situ observations CarbonTracker East Asia

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Weighted Gauss-Seidel Precoder for Downlink Massive MIMO Systems

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Computers, Materials & Continua 2021年第5期67卷 1729-1745页

作者： Jun-Yong Jang Won-Seok Lee jae-Hyun Ro young-Hawn You Hyoung-Kyu Song Department of Information and Communication Engineering Convergence Engineering for Intelligent DroneSejong UniversitySeoul05006Korea Department of Computer Engineering Sejong UniversitySeoul05006Korea

In this paper,a novel precoding scheme based on the Gauss-Seidel(GS)method is proposed for downlink massive multiple-input multiple-output(MIMO)*** GS method iteratively approximates the matrix inversion and reduces the overall complexity of the precoding *** addition,the GS method shows a fast convergence rate to the Zero-forcing(ZF)method that requires an exact invertible ***,to satisfy demanded error performance and converge to the error performance of the ZF method in the practical condition such as spatially correlated channels,more iterations are necessary for the GS method and increase the overall *** efficient approximation with fewer iterations,this paper proposes a weighted GS(WGS)method to improve the approximation accuracy of the GS *** optimal weights that accelerate the convergence rate by improved accuracy are computed by the least square(LS)*** the computation of weights,the different weights are applied for each iteration of the GS *** addition,an efficient method of weight computation is proposed to reduce the complexity of the LS *** simulation results show that bit error rate(BER)performance for the proposed scheme with fewer iterations is better than the GS method in spatially correlated channels.

关键词： Massive MIMO GS matrix inversion complexity weight

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Investigating the Calculation of Rotational Viscosity of the Mixture Comprising Different Kinds of Liquid Crystals： Molecular Dynamics Computer simulation Approach

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Chinese Journal of Chemistry 2011年第1期29卷 48-52页

作者： Kim, Jinsoo Jamil, Muhammad Jung, jae Eun Jang, jae Eun Farzana, Ahmad Jin, Woo Lee Sang, Woo Park Woo, Min-Kyung Kwak, Ji Yeon Jeon, young-jae Liquid Crystal Research Centre Department of Chemistry Konkuk University 143-701 Seoul Korea Division of International Affairs University College Konkuk University 143-701 Seoul Korea Samsung Advanced Institute of Technology (SAID) Yongin-shi Gyeonggi-do 446-712 Korea

Molecular dynamics （MD） computer simulation techniques, as a powerful tool commonly utilized by the liquid crystal display （LCD） community, usually are employed for computing the equilibrium and transport properties of a classical many body system, since they are very similar to real experiments in many respects. In this paper we pre- sent molecular dynamics computer simulation results taken for a mixture of the two different kinds of nematic liq- uid crystals （LCs）. We calculated rotational viscosity from Brownian behavior with friction of the mean director of the mixture comprising pentylcyanobiphenol （5CB） and decylcyanobiphenol （10CB） by using molecular dynamics computer simulation, where intermolecular potential parameter is Generalized AMBER force field （GAFF）. Our computed results show a good agreement with the experimental results.

关键词： liquid crystal mixture ab initio calculations rotational viscosity generalized AMBER force field(GAFF) molecular dynamics simulation nematic liquid crystals computer simulation

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