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N-doped carbon-embedded TiN nanowires as a multifunctional separator for Li–S batteries with enhanced rate capability and cycle stability

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Journal of Energy Chemistry 2021年第6期30卷 10-18,I0001页

作者： yoongon kim Yuseong Noh Jaejin Bae Hyunwoo Ahn Minho kim Won Bae kim Department of Chemical Engineering Pohang University of Science and Technology(POSTECH)77 Cheongam-roNam-guPohang 37673South Korea

Lithium-sulfur(Li-S)batteries have attracted considerable attention as next-generation energy storage devices owing to their high theoretical specific capacity and ***,the commercialization of Li-S batteries is hindered by critical issues,including the migration of the dissolved lithium polysulfides(LiPSs)from the sulfur electrode to the lithium metal anode,resulting in poor cycling ***,we report a multifunctional interlayer configured with an N-doped carbon framework and titanium nitride nanowires on a polypropylene separator(NC/TiN NWs@PP)to suppress the polysulfide shuttling ***/TiN NWs@PP can be obtained by electrospinning and the subsequent scalable solution-based vacuum *** one-dimensional structure of the TiN NWs can shorten the Li-ion diffusion distance with large electrode/electrolyte ***,the N-doped carbon framework in the NWs enables facile electron transportation and allows the suppression of the shuttle effect to improve the electrochemical reaction *** Li-S battery with a NC/TiN NWs@PP separator exhibited enhanced cycling stability and rate capability,indicating that this could be a new research direction for Li-S batteries.

关键词： Li-S battery Shuttle effect Interlayer Separator TiN N-doped carbon 1D Nanowire

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Implanting a preferential solid electrolyte interphase layer over anode electrode of lithium ion batteries for highly enhanced Li^+ diffusion properties

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Journal of Energy Chemistry 2020年第9期29卷 285-292,I0009页

作者： Ye Kyu kim yoongon kim Jaejin Bae Hyunwoo Ahn Yuseong Noh Hyunsu Han Won Bae kim Department of Chemical Engineering Pohang University of Science and Technology(POSTECH)Nam-gu 37673PohangSouth Korea

The lithium-ion batteries are recognized as the most promising energy storage system,but it still does not meet the power requirements of electric vehicle batteries owing to low volumetric energy density with the traditional graphite electrode *** this study,we report the development of a novel electrode system fabricated by implantation of a solid electrolyte interphase(SEI)layer on the graphite *** SEI-implanted graphite electrode is made using a lithium bis(trifluoromethanesulfonyl)imide(LiTFSI)-based electrolyte and cycled with a lithium tetrafluoroborate LiBF4-based *** new electrode system shows significantly enhanced electrochemical properties owing to the rapid and efficient diffusion of Li ions through the SEI layer between the electrolyte and *** graphite electrode with its pre-formed SEI layer achieves a reversible capacity of 357 mAh g^-1 at 0.5 C after 50 cycles,which is significantly higher than that of commercial lithium-ion battery systems constructed with LiPF6(312mAh g^-1).The resulting unique electrode system could present a new avenue in SEI research for highperformance lithium-ion batteries.

关键词： SEI layer Graphite Implanting Li ion diffusion LiTFSI LiBF4 Artificial Mobility

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