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Cycloaddition of CO_2 with epoxides by using an amino-acid-based Cu(Ⅱ)–tryptophan MOF catalyst

Chinese Journal of Catalysis 2018年第1期39卷 63-70页

作者： Gyeong Seon Jeong Amal Cherian Kathalikkattil Robin Babu yongchul greg chung Dae Won Park Division of Chemical and Biomolecular Engineering Pusan National University Busan 609‐735 Korea School of Chemistry University of Dublin Trinity College Dublin 2 Ireland

Metal organic frameworks(MOFs)constructed from natural/biological units(amino acids)are prospective candidates as catalysts in CO2chemistry owing to their natural origin and high abundance of Lewis acid/base sites and functional ***,we report the catalytic efficiency of an amino‐acid‐based Cu‐containing MOF,denoted as CuTrp(Trp=L‐tryptophan).The CuTrp catalyst was synthesized by direct mixing at room temperature using methanol as a solvent-a synthetic route with notable energy *** catalyst was characterized using various physicochemical techniques,including XRD,FT‐IR,TGA,XPS,ICP‐OES,FE‐SEM,and BET *** catalytic activity of CuTrp was assessed in the synthesis of cyclic carbonates from epoxides and *** CuTrp operated in synergy with the co‐catalyst tetrabutylammonium bromide under solvent‐free *** reaction parameters were studied to identify the optimal reaction conditions and a reaction mechanism was proposed based on experimental evidence and previous density functional theory *** CuTrp also exhibited satisfactory stability in water and could be reused more than three times without any significant loss of activity.?2018,Dalian Institute of Chemical Physics,Chinese Academy of *** by Elsevier *** rights reserved.

关键词： Metal organic frameworks Amino acid Copper tryptophan complex Direct mixing Carbon dioxide Cyclic carbonate

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Anion storing,oxygen vacancy incorporated perovskite oxide composites for high-performance aqueous dual ion hybrid supercapacitors

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Journal of Energy Chemistry 2024年第7期94卷 646-655页

作者： Taehun Kang Puritut Nakhanivej Kyung Jae Wang Yu Chen yongchul G chung Ho Seok Park School of Chemical Engineering Sungkyunkwan University(SKKU)2066Seobu-roJangan-guSuwonGyeonggi-do 16419Republic of Korea Warwick Manufacturing Group(WMG) University of WarwickCoventry CV47ALUnited Kingdom School of Chemical Engineering Pusan National UniversityGeumjeong-guBusanGyeongsangnam-do 46241Republic of Korea SKKU Institute of Energy Science and Technology(SIEST) Sungkyunkwan University2066SeoburoJangan-guSuwon 440-746Republic of Korea SKKU Advanced Institute of Nano Technology(SAINT) Sungkyunkwan University2066SeoburoJangan-guSuwon 440-746Republic of Korea Department of Health Sciences and Technology Samsung Advanced Institute for Health Sciences and Technology(SAIHST)Sungkyunkwan UniversitySuwon 16419Republic of Korea

Dual ion storage hybrid supercapacitors(HsCs)are considered as a promising device to overcome the limited energy density of existing supercapacitors while preserving high power and long ***,the development of high-capacity anion-storing materials,which can be paired with fast charg-ing capacitive electrodes,lags behind cation-storing ***,we demonstrate the surface faradaic OH-storage mechanism of anion storing perovskite oxide composites and their application in high-performance dual ion *** oxygen vacancy and nanoparticle size of the reduced LaMnO_(3)(r-LaMnO_(3))were controlled,while r-LaMnO_(3) was chemically coupled with ozonated carbon nanotubes(oCNTs)for the improved anion storing capacity and cycle *** taken by in-situ and ex-situ spectroscopic and computational analyses,OH-ions are inserted into the oxygen vacancies coordi-nating with octahedral Mn with the increase in the oxidation state of Mn during the charging process or vice *** OH-storing r-LaMnO_(3)/oCNT composite with Na*storing MXene,the as-fabricated aqueous dual ion HSCs achieved the cycle performance of 73.3%over 10,000 cycles,delivering the max-imum energy and power densities of 47.5 w h kg^(-1) and 8 kw kg^(-1),respectively,far exceeding those of previously reported aqueous anion and dual ion storage *** research establishes a foundation for the unique anion storage mechanism of the defect engineered perovskite oxides and the advancement of dual ion hybrid energy storage devices with high energy and power densities.

关键词： Anion storage Dual ion storage Defect engineered perovskites Hybrid supercapacitors Nanocomposites

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Sn-Ag-Cu BGA元件使用共晶Pb-Sn焊膏的焊点可靠性（一）

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现代表面贴装资讯 2006年第3期5卷 44-51页

作者：康雪晶（编译） Fay Hua Raiyo Aspandiar Cameron Anderson greg Clemons Chee-key chung Mustapha Faizul

在电子产业无铅化的转折期。元件供应商也许要为区分无铅与含铅的不同元件而准备双重的生产线。这会给制造部门的后勤供应带来问题。当生产中实现全部的无铅化后，这一问题才可能解决。因此，研究Sn—Ag—CuBGA元件使用共晶Pb—Sn焊膏... 详细信息

在电子产业无铅化的转折期。元件供应商也许要为区分无铅与含铅的不同元件而准备双重的生产线。这会给制造部门的后勤供应带来问题。当生产中实现全部的无铅化后，这一问题才可能解决。因此，研究Sn—Ag—CuBGA元件使用共晶Pb—Sn焊膏的焊点可靠性问题，在当前非常必要。本文提出了关于VFBGA（极细间距BGA）及SCSP（芯片级尺寸封装）无铅封装元件在印刷电路板（PCB）组装中使用共晶Pb—Sn焊膏的焊点可靠性评估。在标准的Pb—Sn组装环境下，使用了各种不同的回流曲线。峰值温度从208℃至222℃。回流曲线类型为浸润型曲线（Soak Profile）及帐篷型曲线（Direct Ramp Up Profile）。组装后的PCB板被选择进行了板级温度循环测试（-40℃至125℃，每30分钟循环一次）及跌落测试。失效细节分析同样会在本文提及。

关键词：焊点可靠性 BGAs 无铅 Pb—Sn与Sn—Ag—Cu焊点兼容性

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SAC BGA元件使用共晶锡铅焊膏的焊点可靠性评定（二）

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现代表面贴装资讯 2006年第4期5卷 46-52页

作者： Fay Hua Raiyo Aspandiar Cameron Anderson greg Clemons Chee-key chung Mustapha Faizul 康雪晶（编译）

本文是英特尔公司关于研究Sn—Ag—Cu BGA类型元件使用共晶Pb—Sn焊膏（无铅的向下兼容问题）的一系列研究报告中的第二篇。在此系列研究中所使用的封装类型包括：a）0．5mm间距的vfBGA（极细间距BGA），b）0．8mm间距的SCSP（芯片级尺... 详细信息

本文是英特尔公司关于研究Sn—Ag—Cu BGA类型元件使用共晶Pb—Sn焊膏（无铅的向下兼容问题）的一系列研究报告中的第二篇。在此系列研究中所使用的封装类型包括：a）0．5mm间距的vfBGA（极细间距BGA），b）0．8mm间距的SCSP（芯片级尺寸封装），C）1．0mm及1．27mm间距的wbPBGA（引线键合塑封BGA）。本文集中讨论wbPBGA元件与另外两种类型元件在使用共晶Pb-Sn焊膏的向下兼容问题上的对比效果。元件的组装在标准的Pb—Sn组装条件下使用不同的回流温度曲线。峰值温度的设定从208℃到222℃。回流曲线类型有浸润型曲线（Soak profile）以及帐篷型曲线（Direct ramp up profile）。回流后的结果既有因为Sn—Ag—Cu BGA焊球完全熔化和塌落形成的一致的焊点微观结构，也有由于BGA焊球的部分熔化和塌落形成的非一致的焊点微观结构。焊点可靠性（SJR）的评估是根据温度循环（-40℃至125℃，每30分钟循环一次）以及机械震动测试所产生的失效来分析。焊点可靠性的测试及失效细节分析将在本文中被一一提及。

关键词：焊点可靠性 BGAs Pb—Free Pb—Sn Sn—Ag—Cu 焊点兼容性

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An Earth-mass planet in a time of COVID-19:KMT-2020-BLG-0414Lb

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Research in Astronomy and Astrophysics 2021年第9期21卷 243-261页

作者： Weicheng Zang Cheongho Han Iona Kondo Jennifer C.Yee chung-Uk Lee Andrew Gould Shude Mao Leandro de Almeida Yossi Shvartzvald Xiangyu Zhang Michael D.Albrow Sun-Ju chung Kyu-Ha Hwang Youn Kil Jung Yoon-Hyun Ryu In-Gu Shin Sang-Mok Cha Dong-Jin Kim Hyoun-Woo Kim Seung-Lee Kim Dong-Joo Lee Yongseok Lee Byeong-Gon Park Richard W.Pogge John Drummond Thiam-Guan Tan JoséDias do Nascimento Júnior Dan Maoz Matthew T.Penny Wei Zhu Ian A.Bond Fumio Abe Richard Barry David P.Bennett Aparna Bhattacharya Martin Donachie Hirosane Fujii Akihiko Fukui Yuki Hirao Yoshitaka Itow Rintaro Kirikawa Naoki Koshimoto Man Cheung Alex Li Yutaka Matsubara Yasushi Muraki Shota Miyazaki greg Olmschenk Clément Ranc Nicholas J.Rattenbury Yuki Satoh Hikaru Shoji Stela Ishitani Silva Takahiro Sumi Daisuke Suzuki Yuzuru Tanaka Paul J.Tristram Tsubasa Yamawaki Atsunori Yonehara Andreea Petric Todd Burdullis Pascal Fouqué Department of Astronomy Tsinghua UniversityBeijing 100084China Department of Physics Chungbuk National UniversityCheongju 28644Republic of Korea Department of Earth and Space Science Graduate School of ScienceOsaka UniversityToyonakaOsaka 560-0043Japan Center for Astrophysics j Harvard&Smithsonian 60 Garden St.CambridgeMA 02138USA Korea Astronomy and Space Science Institute Daejon 34055Republic of Korea University of Science and Technology Korea(UST)217 Gajeong-ro Yuseong-guDaejeon 34113Republic of Korea Max-Planck-Institute for Astronomy Königstuhl 1769117 HeidelbergGermany Department of Astronomy Ohio State University140 W.18th Ave.ColumbusOH 43210USA National Astronomical Observatories Chinese Academy of SciencesBeijing 100101China Universidade Federal do Rio Grande do Norte(UFRN) Departamento de F´1sica59078-970NatalRNBrazil Department of Particle Physics and Astrophysics Weizmann Institute of ScienceRehovot 76100Israel University of Canterbury Department of Physics and AstronomyPrivate Bag 4800Christchurch 8020New Zealand School of Space Research Kyung Hee UniversityYonginKyeonggi 17104Republic of Korea Possum Observatory PatutahiGisbourneNew Zealand Perth Exoplanet Survey Telescope PerthAustralia School of Physics and Astronomy Tel-Aviv UniversityTel-Aviv 6997801Israel Department of Physics and Astronomy Louisiana State UniversityBaton RougeLA 70803 USA Canadian Institute for Theoretical Astrophysics University of Toronto60 St George StreetTorontoON M5S 3H8Canada Institute of Natural and Mathematical Sciences Massey UniversityAuckland 0745New Zealand Institute for Space-Earth Environmental Research Nagoya UniversityNagoya 464-8601Japan Code 667 NASA Goddard Space Flight CenterGreenbeltMD 20771USA Department of Astronomy University of MarylandCollege ParkMD 20742USA Department of Physics University of AucklandPrivate Bag 92019AucklandNew Zealand Department of Earth and Planetary Science Graduate School of ScienceThe University of Tokyo7-3-1 Hongo

We report the discovery of KMT-2020-BLG-0414 Lb,with a planet-to-host mass ratio q2=0.9-1.2×10-5=3-4 q⊕at 1σ,which is the lowest mass-ratio microlensing planet to *** with two other recent discoveries(4?q/q⊕?6),it fills out the previous empty sector at the bottom of the triangular(log s,log q)diagram,where s is the planet-host separation in units of the angular Einstein radiusθ***,these discoveries call into question the existence,or at least the strength,of the break in the mass-ratio function that was previously suggested to account for the paucity of very low-q *** to the extreme magnification of the event,Amax~1450 for the underlying single-lens event,its light curve revealed a second companion with q3~0.05 and|log s3|~1,i.e.,a factor~10 closer to or farther from the host in *** measurements of the microlens parallaxπE and the angular Einstein radiusθE allow estimates of the host,planet and second companion masses,(M1,M2,M3)~(0.3 M⊙,1.0 M⊕,17 MJ),the planet and second companion projected separations,(a⊥,2,a⊥,3)~(1.5,0.15 or 15)au,and system distance DL~1 *** lens could account for most or all of the blended light(I~19.3)and so can be studied immediately with high-resolution photometric and spectroscopic observations that can further clarify the nature of the *** planet was found as part of a new program of high-cadence follow-up observations of high-magnification *** detection of this planet,despite the considerable difficulties imposed by COVID-19(two KMT sites and OGLE were shut down),illustrates the potential utility of this program.

关键词： gravitational lensing:micro

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挑选一个表情符号

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空中英语教室（初级版．大家说英语） 2020年第9期 43-44,55,56页

作者： Linda M.chung 不详

会话A(在摄影棚)葛瑞格:这还真有趣。爱丽丝:什么东西真有趣?葛瑞格:我在看我朋友的儿子发的短信。爱丽丝:好吧,有什么问题吗?葛瑞格:没有,他只是用了很多小图案。看到了吗?这是挥手的图案,还有一个傻笑的脸。爱丽丝:哦,那是表情符号。... 详细信息

会话A(在摄影棚)葛瑞格:这还真有趣。爱丽丝:什么东西真有趣?葛瑞格:我在看我朋友的儿子发的短信。爱丽丝:好吧,有什么问题吗?葛瑞格:没有,他只是用了很多小图案。看到了吗?这是挥手的图案,还有一个傻笑的脸。爱丽丝:哦,那是表情符号。葛瑞格:表情……什么?爱丽丝:表情符号。这种图案可以表达情感,很好玩!

关键词：表情符号爱丽丝摄影棚傻笑表达情感好玩图案

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